{"id":260318,"date":"2024-05-21T07:20:40","date_gmt":"2024-05-20T23:20:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=260318"},"modified":"2024-05-20T22:31:08","modified_gmt":"2024-05-20T14:31:08","slug":"%e6%9c%ac%e7%a7%91%e7%94%9f%e4%b8%80%e4%bd%9c%ef%bc%81%e6%b8%a4%e6%b5%b7%e5%a4%a7%e5%ad%a6ceram-int-bi3%e6%8e%ba%e6%9d%82%e7%ad%96%e7%95%a5%e5%a2%9e%e5%bc%basofc%e9%92%99%e9%92%9b%e7%9f%bf","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=260318","title":{"rendered":"\u672c\u79d1\u751f\u4e00\u4f5c\uff01\u6e24\u6d77\u5927\u5b66Ceram.\u00a0Int.: Bi3+\u63ba\u6742\u7b56\u7565\u589e\u5f3aSOFC\u9499\u949b\u77ff\u9634\u6781\u7684ORR\u50ac\u5316\u6d3b\u6027\u548c\u8010CO2\u6027\u80fd"},"content":{"rendered":"

\u7814\u7a76\u80cc\u666f\uff1a<\/b><\/strong><\/p>\n

\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60(SOFC)\u56e0\u5176\u9ad8\u6548\u7684\u80fd\u6e90\u8f6c\u6362\u6548\u7387\u3001\u71c3\u6599\u7684\u9009\u62e9\u591a\u6837\u6027\u548c\u5bf9\u73af\u5883\u7684\u4f4e\u6c61\u67d3\u7b49\u7279\u6027\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u9ad8\u6548\u7eff\u8272\u65e0\u6c61\u67d3\u7684\u53d1\u7535\u6280\u672f\u3002\u7136\u800c\uff0c\u4f20\u7edfSOFC\u7684\u9ad8\u64cd\u4f5c\u6e29\u5ea6(800-1000 \u2103)\u5e26\u6765\u4e86\u8bf8\u591a\u6311\u6218\uff0c\u5305\u62ec\u754c\u9762\u53cd\u5e94\u3001\u6750\u6599\u517c\u5bb9\u6027\u4ee5\u53ca\u7cfb\u7edf\u957f\u671f\u7a33\u5b9a\u6027\u7b49\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5e76\u5f00\u53d1\u4e2d\u6e29(600-800 \u2103)SOFC\u7cfb\u7edf\u53ef\u4ee5\u89e3\u51b3\u9ad8\u6e29\u8fd0\u884c\u5e26\u6765\u7684\u6280\u672f\u969c\u788d\uff0c\u540c\u65f6\u63d0\u9ad8SOFC\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u5e76\u6269\u5927\u5176\u5b9e\u9645\u5e94\u7528\u9886\u57df\u3002\u4f46\u662f\uff0c\u7531\u4e8eORR\u7684\u70ed\u6d3b\u5316\u7279\u6027\uff0c\u5de5\u4f5c\u6e29\u5ea6\u7684\u964d\u4f4e\u4f1a\u5bfc\u81f4\u9634\u6781\u9ad8\u7684\u6781\u5316\u7535\u963b\u548c\u7f13\u6162\u7684ORR\u52a8\u529b\u5b66\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5728\u4e2d\u6e29\u533a\u5177\u6709\u9ad8\u6548\u7535\u5316\u5b66\u50ac\u5316\u6d3b\u6027\u7684SOFC\u9634\u6781\u6750\u6599\u81f3\u5173\u91cd\u8981\u3002\u672c\u7814\u7a76\u4e2d\u91c7\u7528Bi3+<\/sup>\u63ba\u6742\u7684\u7b56\u7565\u5408\u6210\u4e86PrBa0.<\/sub>9<\/sub>Bi0.<\/sub>1<\/sub>CoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\u9634\u6781\uff0c\u6709\u6548\u63d0\u5347\u4e86\u94b4\u57fa\u53cc\u9499\u949b\u77ff\u9634\u6781\u7684\u7535\u5316\u5b66\u50ac\u5316\u6027\u80fd\u548c\u8010CO2<\/sub>\u6027\u80fd\u3002<\/p>\n

\u6587\u7ae0\u7b80\u4ecb<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

\u8fd1\u65e5\u6e24\u6d77\u5927\u5b66\u59da\u4f20\u521a\u526f\u6559\u6388\u3001\u8521\u514b\u8fea\u6559\u6388\u53ca\u5218\u5b9b\u5b81\u672c\u79d1\u751f\u91c7\u7528Bi3+<\/sup>\u63ba\u6742\u7684\u7b56\u7565\uff0c\u8c03\u8282\u9499\u949b\u77ff\u9634\u6781\u7684\u6c27\u7a7a\u4f4d\u542b\u91cf\u548c\u8f7d\u6d41\u5b50\u6d53\u5ea6\uff0c\u63d0\u5347PrBa0.<\/sub>9<\/sub>Bi0.<\/sub>1<\/sub>CoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\uff08PBBCCO\uff09\u9634\u6781\u7684\u50ac\u5316\u6d3b\u6027\u548c\u8010CO2<\/sub>\u6027\u3002\u5f1b\u8c6b\u65f6\u95f4\u5206\u5e03\uff08DRT\uff09\u5206\u6790\u8868\u660e\uff0cBi3+<\/sup>\u7684\u63ba\u6742\u53ef\u589e\u5f3a\u6c27\u7684\u5438\u9644\u3001\u89e3\u79bb\u548c\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u3002\u5728800 \u2103\u65f6\uff0cPBBCCO\u7684\u6781\u5316\u7535\u963b\uff08Rp\uff09\u548c\u6700\u5927\u529f\u7387\u5bc6\u5ea6\uff08MPD\uff09\u5206\u522b\u4e3a0.026 \u03a9 cm-2<\/sup>\u548c631 mW cm-2<\/sup>\u3002\u76f8\u8f83\u4e8e\u57fa\u4f53\u6750\u6599PrBaCoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\uff08PBCCO\uff09\uff0cRp\u964d\u4f4e\u4e8652.45%\uff0cMPD\u589e\u957f\u4e8645.11%\u3002\u6b64\u5916\uff0cPBBCCO\u5c55\u73b0\u51fa\u5353\u8d8a\u7684CO2<\/sub>\u8010\u53d7\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cEnhancing the ORR kinetics and CO2<\/sub>\u00a0tolerance in PrBaCoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\u00a0cathode\u00a0for solid oxide fuel cells by bismuth doping\u201d\u53d1\u8868\u5728\u8457\u540d\u671f\u520aCeramics International<\/i><\/em>\u00a0(DOI:\u00a010.1016\/j.ceramint.2024.02.061)\u4e0a\u30022020\u7ea7\u672c\u79d1\u751f\u5218\u5b9b\u5b81\u4e3a\u8be5\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u5185\u5bb9\u8868\u8ff0<\/b><\/strong>\uff1a<\/b><\/strong><\/p>\n

\u672c\u6587\u62a5\u9053\u4e86Bi3+<\/sup>\u63ba\u6742\u7684PrBa0.<\/sub>9<\/sub>Bi0.<\/sub>1<\/sub>CoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\u6750\u6599\u4f5c\u4e3a\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60(SOFC)\u9634\u6781\u6750\u6599\u3002\u5982\u56fe1\uff0c\u9996\u5148\u5bf9\u6837\u54c1\u8fdb\u884c\u4e86XRD\u8868\u5f81\u4ee5\u53caRietveld\u7cbe\u4fee\u3002\u53ef\u4ee5\u770b\u51fa\uff0c\u6240\u6709\u6837\u54c1\u90fd\u662f\u5c5e\u4e8eP4\/mmm\u7a7a\u95f4\u7fa4\u7684\u56db\u65b9\u53cc\u9499\u949b\u77ff\u7ed3\u6784\uff0c\u672a\u89c2\u5bdf\u5230\u6742\u76f8\u3002\u4e0e\u63ba\u6742\u524d\u76f8\u6bd4\uff0c\u63ba\u6742\u540e\u7684PBBCCO\u7684\u4e3b\u7279\u5f81\u5cf0\u5411\u5927\u89d2\u5ea6\u65b9\u5411\u79fb\u52a8\uff0c\u8868\u660e\u4e86\u6676\u683c\u5c3a\u5bf8\u7684\u51cf\u5c0f\u3002\u540c\u65f6\uff0cPBBCCO\u548cLSGM\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u5316\u5b66\u517c\u5bb9\u6027\u826f\u597d\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1\u00a0(a) \u9634\u6781\u6750\u6599\u7684XRD\u56fe\u8c31\uff1b (b) PBBCCO\u4e0eLSGM\u76f8\u5bb9\u6027\u6d4b\u8bd5XRD\u56fe\u8c31; (c) PBCCO\u548c(d) PBBCCO\u7684Rietveld\u7cbe\u4fee\u56fe\u8c31<\/p>\n

\u5982\u56fe2\u6240\u793a\uff0cXPS\u5206\u6790\u7ed3\u679c\u8bc1\u5b9e\u4e86PBBCCO\u6750\u6599\u5185\u90e8Pr3+<\/sup>\/Pr4+<\/sup>\u3001Co3+<\/sup>\/Co4+<\/sup>\u548cCu+<\/sup>\/Cu2+<\/sup>\u591a\u4ef7\u6001\u6df7\u5408\u79bb\u5b50\u7684\u5b58\u5728\u3002\u540c\u65f6\u5176\u8f83\u9ad8\u7684OA<\/sub>\/OL<\/sub>\u503c\u8868\u660eBi\u63ba\u6742\u4fc3\u8fdb\u4e86\u6750\u6599\u4e2d\u6c27\u7a7a\u4f4d\u7684\u751f\u6210\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2\u00a0\u5ba4\u6e29\u4e0bPBBCCO\u7c89\u4f53\u7684XPS\u56fe\u8c31\uff1a(a) \u5168\u5149\u8c31\uff0c(b) Pr 3d \u548c Cu 2p\uff0c(c) Co 2p \u548c Ba 3d\uff0c\u4ee5\u53ca (d) O 1s<\/p>\n

\u5982\u56fe3\u6240\u793a\uff0cBi\u7684\u5f15\u5165\u5bfc\u81f4\u7535\u5bfc\u7387\u964d\u4f4e\uff0c\u4f46PBBCCO\u6837\u54c1\u4ecd\u80fd\u4fdd\u6301\u6700\u4f4e\u4e3a177.89 S cm\u22121<\/sup>\u7684\u7535\u5bfc\u7387\uff0c\u6ee1\u8db3\u4e86SOFC\u9634\u6781\u7684\u8981\u6c42\u3002PBBCCO\u7684\u5e73\u5747TEC\u4e3a17.05 \u00d7 10\u22126<\/sup>\u00a0K\u22121<\/sup>\uff0c\u8f83\u4f4e\u7684TEC\u503c\u4fdd\u8bc1\u4e86\u9634\u6781\u6750\u6599\u4e0e\u7535\u89e3\u8d28\u7684\u70ed\u5339\u914d\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3\u00a0(a) PBBCCO\u7684\u70ed\u81a8\u80c0\u7cfb\u6570\u66f2\u7ebf; (b) PBCCO\u4e0ePBBCCO\u7684\u7535\u5bfc\u7387\u4e0e\u6e29\u5ea6\u5173\u7cfb\u66f2\u7ebf\u00a0<\/p>\n

\u5982\u56fe4\u6240\u793a\uff0c\u5728800 \u2103\u65f6\uff0cPBBCCO\u7684Rp<\/sub>\u4e3a0.026 \u03a9 cm2<\/sup>\uff0c\u76f8\u8f83\u4e8e\u57fa\u4f53\u6750\u6599\u964d\u4f4e\u4e8652.45%\u3002\u8fd9\u662f\u7531\u4e8eBi\u7684\u63ba\u6742\uff0c\u6709\u6548\u4fc3\u8fdb\u4e86\u6750\u6599\u4e2d\u7684\u6c27\u7a7a\u4f4d\u7684\u751f\u6210\u3002\u589e\u52a0\u7684\u6c27\u7a7a\u4f4d\u5728\u4fc3\u8fdb\u6c27\u8868\u9762\u4ea4\u6362\u52a8\u529b\u5b66\u3001\u9634\u6781\u5185\u7684\u4f53\u6269\u6563\u4ee5\u53ca\u9634\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7684\u7535\u8377\u8f6c\u79fb\u65b9\u9762\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 (a)\u00a0PBCCO\u548c(b)\u00a0PBBCCO\u7684\u4ea4\u6d41\u963b\u6297\u8c31\uff1b(c)\u00a0Rp<\/sub>\u503c\u548c\u76f8\u5e94\u7684\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\uff1b(d)\u00a0PBBCCO\u5728700 \u00b0C\u4e0b\u5728\u4e0d\u540c\u6c27\u5206\u538b\u4e0b\u7684EIS<\/p>\n

PBBCCO\u5177\u6709\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u6c27\u5206\u538b\u6d4b\u8bd5\u7ed3\u5408DRT\u6280\u672f\uff0c\u5bf9\u5176ORR\u8fc7\u7a0b\u8fdb\u884c\u4e86\u5206\u6790\u3002\u5982\u56fe5\u6240\u793a\uff0c\u5728\u4e2d\u3001\u4f4e\u9891\u7387\u4e0bPBBCCO\u7684DRT\u5cf0\u660e\u663e\u51cf\u5f31\uff0c\u8868\u660eBi\u63ba\u6742\u589e\u5f3a\u4e86\u6c27\u7684\u6269\u6563\u3001\u5438\u9644\u548c\u89e3\u79bb\u8fc7\u7a0b\u3002\u540c\u65f6\uff0cBi\u63ba\u6742\u6709\u6548\u6539\u5584\u4e86\u9634\u6781\u6750\u6599\u4e2d\u3001\u4f4e\u9891\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe5 (a) PBBCCO\u5728\u4e0d\u540c\u6c27\u5206\u538b\u4e0b\u7684DRT\u66f2\u7ebf\uff1b(b) Rp<\/sub>\u5bf9O2<\/sub>\u7684\u4f9d\u8d56\u6027\u66f2\u7ebf\uff1b(c) PBCCO\u548cPBBCCO\u9634\u6781\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684DRT\u66f2\u7ebf\uff1b(d) PBCCO\u548cPBBCCO\u9634\u6781\u5728650-800 \u2103\u8303\u56f4\u5185\u4e0d\u540c\u9891\u7387\u7684\u6781\u5316\u963b\u6297\u503c<\/p>\n

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\"\"<\/p>\n

\u56fe6 600 \u2103\u4e0bCO2<\/sub>\u70ed\u5904\u740610\u5c0f\u65f6\u540ePBCCO\u548cPBBCCO\u7684(a)\u00a0XRD\u56fe\u8c31\u548c(b)\u00a0FT-IR\u5149\u8c31\uff1b(c)\u00a0PBCCO\u548cPBBCCO\u5728\u4e0d\u540cCO2<\/sub>\u6d53\u5ea6\u4e0b\u7684ASR\u503c\u4ee5\u53ca(d)\u00a0EIS\u56fe\u8c31<\/p>\n

\u6700\u540e\uff0c\u5982\u56fe7\u6240\u793a\uff0c\u57fa\u4e8ePBBCCO\u9634\u6781\u7684\u5168\u7535\u6c60\u5728800 \u2103\u65f6\u62e5\u6709631 mW cm\u22122<\/sup>\u7684\u6700\u5927\u529f\u7387\u5bc6\u5ea6\uff0c\u76f8\u8f83\u4e8e\u57fa\u4f53\u6750\u6599\u63d0\u9ad8\u4e8645.11%\u3002\u7ecf\u8fc7SEM\u53ef\u4ee5\u89c2\u5bdf\u5230\u9634\u6781\u6750\u6599\u758f\u677e\u591a\u5b54\u7684\u7ed3\u6784\uff0cPBBCCO\u548cLSGM\u7535\u89e3\u8d28\u7684\u754c\u9762\u8fde\u63a5\u5904\u7ed3\u5408\u826f\u597d\uff0c\u6ca1\u6709\u89c2\u5bdf\u5230\u660e\u663e\u7684\u5f00\u88c2\u73b0\u8c61\u3002<\/p>\n

\"\"<\/p>\n

\u56fe7 \u5728650-800 \u2103\u6e29\u5ea6\u8303\u56f4\u5185\u7684I-V\u66f2\u7ebf\u4e0eI-P\u66f2\u7ebf: (a) PBCCO; (b) PBBCCO; (c)\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6; (d)\u5bf9\u79f0\u7535\u6c60\u622a\u9762\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf<\/p>\n

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\u5218\u5b9b\u5b81<\/b><\/strong>\uff0c\u6e24\u6d77\u5927\u5b662020\u7ea7\u672c\u79d1\u751f\uff0c\u4e3b\u8981\u81f4\u529b\u4e8e\u9ad8\u6548\u56fa\u4f53\u6c27\u5316\u7269\u71c3\u6599\u7535\u6c60\u9634\u6781\u7684\u8bbe\u8ba1\u53ca\u7535\u5316\u5b66\u6027\u80fd\u8c03\u63a7\u7814\u7a76\u3002\u81ea\u5165\u5b66\u4ee5\u6765\u8363\u83b7\u6e24\u6d77\u5927\u5b66\u4f18\u79c0\u5b66\u751f\uff0c\u4f18\u79c0\u5171\u9752\u56e2\u5458\u7b49\u8363\u8a89\u79f0\u53f7\uff0c\u5728ACS Sustainable Chem. Eng.\u548cCeram.\u00a0Int.\u671f\u520a\u53d1\u8868SCI\u8bba\u6587\u51712\u7bc7\u3002<\/p>\n

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\u8521\u514b\u8fea<\/b><\/strong>\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u8fbd\u5b81\u7279\u8058\u6559\u6388\uff0c\u5174\u8fbd\u82f1\u624d\u8ba1\u5212\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u201d\uff0c\u8fbd\u5b81\u7701\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u201c\u767e\u4eba\u5c42\u6b21\u201d\u3002\u83b7\u4e2d\u56fd\u4ea7\u5b66\u7814\u5408\u4f5c\u521b\u65b0\u5956(2018\u5e74)\uff0c\u8fbd\u5b81\u9752\u5e74\u79d1\u6280\u5956(2019\u5e74)\uff0c\u8fbd\u5b81\u7701\u9ad8\u6821\u4f18\u79c0\u5171\u4ea7\u515a\u515a\u5458(2021\u5e74)\uff0c\u8fbd\u5b81\u7701\u4f18\u79c0\u79d1\u6280\u5de5\u4f5c\u8005(2022\u5e74)\u3002<\/p>\n

\u73b0\u4efb\u6e24\u6d77\u5927\u5b66\u79d1\u6280\u5904\u5904\u957f\uff0c\u7535\u5316\u5b66\u50a8\u80fd\u6750\u6599\u4e0e\u6280\u672f\u7814\u7a76\u6240\u6240\u957f\u3002\u4e2d\u56fd\u8d85\u7ea7\u7535\u5bb9\u5668\u4ea7\u4e1a\u8054\u76df\u9752\u5e74\u7406\u4e8b\uff0c\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u9752\u5e74\u5de5\u4f5c\u59d4\u5458\u4f1a\u7406\u4e8b\uff0c\u4e2d\u56fd\u5316\u5b66\u4f1a\u9ad8\u7ea7\u4f1a\u5458\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u51fd\u8bc4\u4e13\u5bb6\uff0c\u6559\u80b2\u90e8\u5b66\u4f4d\u4e2d\u5fc3\u8bc4\u5ba1\u4e13\u5bb6\uff0c\u591a\u7701\u5e02\u79d1\u6280\u5956\u8bc4\u5ba1\u4e13\u5bb6\uff0c\u76ee\u524d\u62c5\u4efbAdvanced Functional Materials\u7b4920\u4f59\u4e2a\u56fd\u5185\u5916\u5b66\u672f\u671f\u520a\u5ba1\u7a3f\u4e13\u5bb6\u3002<\/p>\n

\u8fd1\u5e74\u6765\uff0c\u4e3b\u8981\u4ece\u4e8b\u80fd\u6e90\u5316\u5b66\u4e0e\u80fd\u6e90\u6750\u6599\u9886\u57df\u7684\u57fa\u7840\u5e94\u7528\u7814\u7a76\uff0c\u5728\u65b0\u578b\u5316\u5b66\u7535\u6e90\u4f53\u7cfb\u3001\u5148\u8fdb\u7535\u6781\u6750\u6599\u6784\u5efa\u7b49\u65b9\u5411\u5f00\u5c55\u4e86\u6709\u610f\u4e49\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u5148\u540e\u4e3b\u6301\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1(\u9762\u4e0a\u3001\u9752\u5e74)\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u57fa\u91d1(\u7279\u52a9\u3001\u4e00\u7b49)\u3001\u8fbd\u5b81\u7701\u79d1\u6280\u5385\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u7b4920\u4f59\u9879\u56fd\u5bb6\u53ca\u7701\u90e8\u7ea7\u8bfe\u9898\uff0c\u5148\u540e\u5728Composites Part B\u3001Journal of Energy Chemistry\u3001ACS AMI \u7b49\u56fd\u5185\u5916\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587120\u4f59\u7bc7\uff0c\u5176\u4e2d6\u7bc7\u6587\u7ae0\u5165\u9009 ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c4\u7bc7\u6587\u7ae0\u5165\u9009ESI\u70ed\u70b9\u8bba\u6587\u3002\u7533\u62a582\u9879\u56fd\u5bb6\u4e13\u5229\u30012\u9879\u56fd\u9645\u4e13\u5229\uff0c\u5176\u4e2d\u6388\u674376\u9879\uff08\u7b2c\u4e00\u53d1\u660e\u4eba36\u9879\uff09\uff0c\u79d1\u6280\u6210\u679c\u8f6c\u53164\u9879\uff0c\u4f01\u4e1a\u76f4\u63a5\u6216\u95f4\u63a5\u7ecf\u6d4e\u5229\u6da6\u4e09\u5343\u4f59\u4e07\u5143\u3002\u5176\u4e2d\u90e8\u5206\u76f8\u5173\u79d1\u6280\u6210\u679c\u7701\u90e8\u7ea7\u4ee5\u4e0a\u9274\u5b9a\u4e3a\u201c\u56fd\u9645\u5148\u8fdb\u201d\uff0c\u5e76\u5728\u300a\u4e2d\u56fd\u53d1\u660e\u4e0e\u4e13\u5229\u300b\u3001\u300a\u8fbd\u5b81\u65e5\u62a5\u300b\u7b49\u6742\u5fd7\u62a5\u520a\u4e0a\u8fdb\u884c\u4e86\u4e13\u9898\u62a5\u9053\u3002\u53c2\u4e0e\u5236\u5b9a\u56e2\u4f53\u6807\u51c62\u9879\uff0c\u53c2\u7f16\u300aAdvanced Electrochemical Materials in Energy Conversion and Storage\u300b\u82f1\u6587\u4e13\u8457\u4e00\u90e8\uff0c\u4e3b\u7f16\u300a\u5316\u5b66\u7535\u6e90\u6280\u672f\u300b\u7b49\u5b66\u672f\u8457\u4f5c3\u90e8\u3002<\/p>\n

 <\/p>\n

\u6587\u7ae0\u4fe1\u606f\uff1aEnhancing the ORR kinetics and CO2<\/sub>\u00a0tolerance in PrBaCoCuO5+<\/sub>\u03b4<\/i><\/sub><\/em>\u00a0cathode\u00a0for solid oxide fuel cells by bismuth doping\uff0cCeram.\u00a0Int. 2024\uff0c15821-15830.<\/p>\n

DOI: 10.1016\/j.ceramint.2024.02.061<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.ceramint.2024.02.061<\/p>\n

\u4f9b\u7a3f\u4eba\uff1a\u5218\u5b9b\u5b81<\/p>\n","protected":false},"excerpt":{"rendered":"

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