{"id":261294,"date":"2024-07-07T06:22:00","date_gmt":"2024-07-06T22:22:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261294"},"modified":"2024-07-06T10:32:46","modified_gmt":"2024-07-06T02:32:46","slug":"%e6%ad%a6%e6%b1%89%e5%a4%a7%e5%ad%a6%e9%99%88%e8%83%9c%e5%88%a9%e6%95%99%e6%8e%88afm%ef%bc%9aall-in-one%e7%a6%bb%e8%81%9a%e7%89%a9%e8%ae%be%e8%ae%a1%e7%ad%96%e7%95%a5%e6%8f%90%e5%8d%87%e7%87%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261294","title":{"rendered":"\u6b66\u6c49\u5927\u5b66\u9648\u80dc\u5229\u6559\u6388AFM\uff1aall-in-one\u79bb\u805a\u7269\u8bbe\u8ba1\u7b56\u7565\u63d0\u5347\u71c3\u6599\u7535\u6c60\u6548\u7387\u548c\u7a33\u5b9a\u6027"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261298\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-4.png\" alt=\"\" width=\"692\" height=\"295\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-4.png 692w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-4-300x128.png 300w\" sizes=\"(max-width: 692px) 100vw, 692px\" \/><\/p>\n<p><strong>\u3010\u6587\u7ae0\u4fe1\u606f\u3011<\/strong><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u7b2c\u4e00\u4f5c\u8005\uff1a\u6731\u798f\u9f99<\/span><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u901a\u8baf\u4f5c\u8005\uff1a\u9648\u80dc\u5229\u6559\u6388<\/span><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u5355\u4f4d\uff1a\u6b66\u6c49\u5927\u5b66<\/span><\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u3010\u7814\u7a76\u80cc\u666f\u3011<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><a name=\"OLE_LINK1\"><\/a><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60<\/span><span lang=\"EN-US\" style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">(<a name=\"OLE_LINK2\"><\/a>PEMFC)<\/span><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u5177\u6709\u884c\u9a76\u91cc\u7a0b\u957f\u3001\u5145\u7535\u65f6\u95f4\u77ed\u3001\u96f6\u6c61\u67d3\u7269\u6392\u653e\u7b49\u4f18\u70b9\uff0c\u5728\u91cd\u578b\u8f66\u8f86\u7684\u52a8\u529b\u7cfb\u7edf\u4e2d\u6709\u7740\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002\u76ee\u524d\uff0c\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u50ac\u5316\u5c42<span lang=\"EN-US\">(CL)<\/span>\u4e2d\u901a\u5e38\u4f7f\u7528\u5168\u6c1f\u78fa\u9178<span lang=\"EN-US\">(PFSA)<\/span>\u79bb\u805a\u7269\u4f5c\u4e3a\u7c98\u7ed3\u5242\u548c\u8d28\u5b50\u5bfc\u4f53\u3002\u4e3a\u4e86\u5f62\u6210\u826f\u597d\u7684\u8d28\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u71c3\u6599\u7535\u6c60\u5fc5\u987b\u5145\u5206\u52a0\u6e7f\uff0c\u4fc3\u8fdb\u4fa7\u94fe\u4e2d\u7684\u78fa\u9178\u57fa\u4e2d\u8d28\u5b50\u5b8c\u5168\u89e3\u79bb\uff0c\u5e76\u4e14\u4f7f\u79bb\u805a\u7269\u7684\u4eb2\u6c34\u79bb\u5b50\u57df\u5f7c\u6b64\u76f8\u4e92\u8fde\u901a\uff0c\u4ee5\u5b9e\u73b0<span lang=\"EN-US\">PEMFC<\/span>\u8f93\u51fa\u66f4\u9ad8\u7684\u529f\u7387\u5bc6\u5ea6\u3002\u7136\u800c\uff0c\u91cd\u578b\u8f66\u8f86\u4e2d<span lang=\"EN-US\">PEMFC<\/span>\u7684\u52a0\u6e7f\u8fc7\u7a0b\u589e\u52a0\u4e86\u7cfb\u7edf\u7684\u590d\u6742\u6027\u3001\u4f53\u79ef\u548c\u6210\u672c\u3002\u9664\u6b64\u4e4b\u5916\uff0c<span lang=\"EN-US\">PFSA<\/span>\u79bb\u805a\u7269\u5728<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\u7684\u5438\u9644\u4f5c\u7528\u4f7f\u5f97\u79bb\u805a\u7269\u5728\u50ac\u5316\u5242\u8868\u9762\u5f62\u6210\u81f4\u5bc6\u7684\u7ed3\u6676\u5c42\uff0c\u963b\u788d\u6c27\u6c14\u7684\u6e17\u900f\uff0c\u589e\u5927\u4e86\u5c40\u57df\u6c27\u4f20\u8f93\u963b\u6297\u3002\u540c\u65f6\uff0c\u957f\u671f\u8010\u4e45\u6027\u4e00\u76f4\u662f\u71c3\u6599\u7535\u6c60\u9762\u4e34\u7684\u6700\u91cd\u8981\u5730\u6311\u6218\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u4fdd\u6e7f\u6027\u3001\u5f31\u5438\u9644\u53ca\u8fc7\u6c27\u5316\u7269\u6e05\u9664\u6027\u79bb\u805a\u7269\u5bf9\u4e8e\u964d\u4f4e\u71c3\u6599\u7535\u6c60\u6210\u672c\u3001\u63d0\u5347\u7535\u6c60\u8f93\u51fa\u6027\u80fd\u4ee5\u53ca\u8010\u4e45\u6027\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u71c3\u6599\u7535\u6c60\u9634\u6781\u50ac\u5316\u5c42\u4e2d\u79bb\u805a\u7269\u6750\u6599\u7684\u5f00\u53d1\u63d0\u4f9b\u4e00\u4e2a\u65b0\u7684\u7814\u7a76\u89c6\u89d2\u3002<\/span><\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8fd1\u65e5\uff0c\u6765\u81ea<b>\u6b66\u6c49\u5927\u5b66\u7684\u9648\u80dc\u5229\u6559\u6388<\/b>\uff0c\u5728\u56fd\u9645\u77e5\u540d\u671f\u520a<b><span lang=\"EN-US\">Advanced Functional Materials<\/span><\/b>\u4e0a\u53d1\u8868\u9898\u4e3a\u201c<b><span lang=\"EN-US\">A Highly Hygroscopic, Weakly Adsorbable, and Peroxide Scavenging Ionomer for Low-Pt Proton Exchange Membrane Fuel Cells<\/span><\/b>\u201d\u7684\u6587\u7ae0\u3002\u672c\u6587\u8bbe\u8ba1\u3001\u5408\u6210\u4e86\u4e00\u79cd\u7531\u9ad8\u4eb2\u6c34\u6027\u6742\u591a\u9178\u5171\u4ef7\u4fee\u9970\u5728\u5168\u6c1f\u6811\u8102\u4fa7\u94fe\u4e0a\u4ee3\u66ff\u78fa\u9178\u57fa\u7684\u7b56\u7565\uff0c\u89e3\u51b3\u71c3\u6599\u7535\u6c60\u5728\u4f4e\u6e7f\u5ea6\u4e0b\u7684\u8f93\u51fa\u6027\u80fd\u5dee\u548c\u957f\u671f\u8010\u4e45\u6027\u95ee\u9898\u3002\u8be5\u79bb\u805a\u7269\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u76f8\u5206\u79bb\u7ed3\u6784\uff0c\u4e3a\u8d28\u5b50\u63d0\u4f9b\u4f20\u8f93\u901a\u9053\u3002\u540c\u65f6\uff0c\u79bb\u805a\u7269\u5728<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\u7684\u5438\u9644\u8f83\u5f31\uff0c\u91ca\u653e\u4e86\u66f4\u591a\u50ac\u5316\u5242\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\uff0c\u63d0\u9ad8\u4e86\u71c3\u6599\u7535\u6c60\u8f93\u51fa\u6027\u80fd\u3002\u79bb\u805a\u7269\u5177\u6709\u6e05\u9664\u8fc7\u6c27\u5316\u7269\u7684\u4f5c\u7528\uff0c\u6539\u5584\u4e86\u71c3\u6599\u7535\u6c60\u7684\u957f\u671f\u8010\u4e45\u6027\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261299\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-5.png\" alt=\"\" width=\"700\" height=\"479\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-5.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-5-300x205.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe<span lang=\"EN-US\">1. <\/span>\u9634\u6781\u50ac\u5316\u5c42\u4e2d\u8d28\u5b50\u548c\u6c27\u6c14\u5728\u591a\u9178\u57fa\u79bb\u805a\u7269\u4e2d\u7684\u4f20\u8f93\u673a\u7406\u793a\u610f\u56fe\uff1b\u4ee5\u53ca\u79bb\u805a\u7269\u5728<span lang=\"EN-US\">MEA<\/span>\u4e2d\u7684\u71c3\u6599\u7535\u6c60\u8f93\u51fa\u6027\u80fd\u3002<span lang=\"EN-US\">\u00a0<\/span><\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u3010\u672c\u6587\u8981\u70b9\u3011<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8981\u70b9\u4e00\uff1a\u65b0\u578b\u79bb\u805a\u7269\u5206\u5b50\u7684\u8bbe\u8ba1<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8fd9\u9879\u5de5\u4f5c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u79bb\u805a\u7269\u7b56\u7565\u6765\u89e3\u51b3\u4f4e\u6e7f\u5ea6\u4e0b\u8d28\u5b50\u4f20\u5bfc\u548c\u6c27\u6c14\u6e17\u900f\u7684\u95ee\u9898\u3002\u591a\u91d1\u5c5e\u6c27\u9178\u76d0\uff08<span lang=\"EN-US\">POM<\/span>\uff09\u662f\u4e00\u79cd\u4e9a\u7eb3\u7c73\u7ea7\u7684\u9634\u79bb\u5b50\u56e2\u7c07\uff0c\u5177\u6709\u591a\u4e2a\u8d1f\u7535\u8377\uff0c\u4e14\u672b\u7aef\u6c27\u539f\u5b50\u4e3a\u8d28\u5b50\u63d0\u4f9b\u8df3\u8dc3\u4f4d\u70b9\u3002\u8fd9\u79cd\u7ed3\u6784\u7279\u5f81\u4f7f\u5b83\u4eec\u4e0d\u4ec5\u5177\u6709\u5f3a\u9178\u6027\uff0c\u643a\u5e26\u66f4\u591a\u6613\u89e3\u79bb\u548c\u9ad8\u8fc1\u79fb\u6027\u7684\u8d28\u5b50\uff0c\u540c\u65f6\u5177\u6709\u5f88\u5f3a\u7684\u5438\u6e7f\u6027\u3002\u56e0\u6b64\uff0c\u6211\u4eec\u901a\u8fc7\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u5c06<span lang=\"EN-US\">Anderson<\/span>\u578b\u591a\u91d1\u5c5e\u6c27\u9178\u76d0<span lang=\"EN-US\">[MnMo<sub>6<\/sub>O<sub>18<\/sub>(OH)<sub>6<\/sub>]<sup>3<\/sup><\/span><sup>\u2212<\/sup>\u5171\u4ef7\u63a5\u679d\u5230\u5168\u6c1f\u805a\u5408\u7269\u7684\u4fa7\u94fe\u4e0a\uff0c\u53d6\u4ee3\u78fa\u9178\u57fa\u4f5c\u4e3a\u8d28\u5b50\u8f7d\u4f53\uff0c\u5b9e\u73b0\u79bb\u805a\u7269\u7684\u4fdd\u6e7f\u7279\u6027\uff0c\u964d\u4f4e\u71c3\u6599\u7535\u6c60\u7684\u8fd0\u884c\u6e7f\u5ea6\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261300\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-5.png\" alt=\"\" width=\"768\" height=\"528\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-5.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-5-300x206.png 300w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/p>\n<p>\u56fe<span lang=\"EN-US\">2. PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u5408\u6210\u793a\u610f\u56fe\u4ee5\u53ca\u5206\u5b50\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8981\u70b9\u4e8c\uff1a<span lang=\"EN-US\">Pt\/<\/span>\u79bb\u805a\u7269\u754c\u9762\u7ed3\u6784<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u4f17\u6240\u5468\u77e5\uff0c\u4f20\u7edf<span lang=\"EN-US\">Nafion<\/span>\u79bb\u805a\u7269\u4e2d\u78fa\u9178\u57fa\u4e0e\u919a\u952e\u4f1a\u5171\u5438\u9644\u5728<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\uff0c\u5360\u636e\u50ac\u5316\u5242\u7684\u53cd\u5e94\u6d3b\u6027\u4f4d\u70b9\uff0c\u964d\u4f4e\u6c27\u8fd8\u539f\u53cd\u5e94\u6d3b\u6027\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u6211\u4eec\u901a\u8fc7\u79bb\u805a\u7269\u4fee\u9970\u7684\u591a\u6676<span lang=\"EN-US\">Pt<\/span>\u76d8\u7535\u6781\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u8fdb\u884c\u7535\u5316\u5b66\u6d4b\u8bd5\uff0c\u6b63\u5982\u56fe<span lang=\"EN-US\">3<\/span>\u6240\u793a\uff0c\u4ece<span lang=\"EN-US\">CV<\/span>\u66f2\u7ebf\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c<a name=\"OLE_LINK3\"><\/a><span lang=\"EN-US\">Pt-Nafion<\/span>\u7535\u6781\u5728<span lang=\"EN-US\">0.18V<\/span>\u9644\u8fd1\u6709\u4e00\u5bf9\u53ef\u9006\u7684\u5438<span lang=\"EN-US\">&#8211;<\/span>\u8131\u9644\u5cf0\uff0c\u8fd9\u5f52\u56e0\u4e8e\u78fa\u9178\u57fa\u5728<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\u7684\u5438\u9644\u3002\u800c<span lang=\"EN-US\">Pt-PFSN-MnMo<sub>6<\/sub>-D<\/span>\u7535\u6781\u6ca1\u6709\u53d1\u751f\u989d\u5916\u7684\u6cd5\u62c9\u7b2c\u7535\u6d41\u54cd\u5e94\uff0c\u8868\u660e\u4e86<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u5177\u6709\u5f31\u5438\u9644\u6027\u8d28\u3002\u4ece<span lang=\"EN-US\">ORR<\/span>\u66f2\u7ebf\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\uff0c<span lang=\"EN-US\">Pt-PFSN-MnMo<sub>6<\/sub>-D<\/span>\u7535\u6781\u7684\u6781\u9650\u7535\u6d41\u5bc6\u5ea6\u548c\u534a\u6ce2\u7535\u4f4d\u5747\u9ad8\u4e8e<span lang=\"EN-US\">Pt-Nafion<\/span>\u7535\u6781\uff0c\u6697\u793a\u4e86\u6c27\u6c14\u66f4\u5bb9\u6613\u901a\u8fc7<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u6e17\u900f\u5230<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\u53d1\u751f\u6c27\u8fd8\u539f\u53cd\u5e94\uff0c\u8fd9\u662f\u56e0\u4e3a<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u7684\u5f31\u5438\u9644\u6027\u8d28\uff0c\u4f7f\u5176\u4e0d\u6613<span lang=\"EN-US\">Pt<\/span>\u8868\u9762\u5f62\u6210\u81f4\u5bc6\u7684\u7ed3\u6676\u5c42\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u6c27\u6c14\u6e17\u900f\u80fd\u529b\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261301\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72474-5.png\" alt=\"\" width=\"768\" height=\"297\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72474-5.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72474-5-300x116.png 300w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/p>\n<p>\u56fe<span lang=\"EN-US\">3. <\/span>\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\uff0c<span lang=\"EN-US\">Pt<\/span>\u3001<span lang=\"EN-US\">Pt-Nafion<\/span>\u548c<span lang=\"EN-US\">Pt-PFSN-MnMo<sub>6<\/sub>-D<\/span>\u7535\u6781\u7684<span lang=\"EN-US\">CV<\/span>\u66f2\u7ebf\u548c<span lang=\"EN-US\">ORR<\/span>\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8981\u70b9\u4e09\uff1a\u79bb\u805a\u7269\u5728<span lang=\"EN-US\">MEA<\/span>\u4e2d\u7684\u7535\u5316\u5b66\u6027\u80fd<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u5c06\u79bb\u805a\u7269\u4f5c\u4e3a\u9634\u6781\u50ac\u5316\u5c42\u7c98\u7ed3\u5242\uff0c\u7ec4\u88c5\u6210\u5355\u7535\u6c60\u8fdb\u884c\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u3002\u6b63\u5982\u56fe<span lang=\"EN-US\">4<\/span>\u6240\u793a\uff0c\u5728<span lang=\"EN-US\">100%RH<\/span>\u4e0b\uff0c\u7531<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u7ec4\u88c5\u7684<span lang=\"EN-US\">MEA<\/span>\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\u63a5\u8fd1<span lang=\"EN-US\">1.7 W cm<sup>-1<\/sup><\/span>\uff0c\u9ad8\u4e8e<span lang=\"EN-US\">Nafion<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">MEA<\/span>\uff08\u7ea6\u4e3a<span lang=\"EN-US\">1.55 W cm<sup>-1<\/sup><\/span>\uff09\u3002\u5f53\u76f8\u5bf9\u6e7f\u5ea6\u964d\u4f4e\u81f3<span lang=\"EN-US\">50%RH<\/span>\u65f6\uff0c\u7531<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u7ec4\u88c5\u7684<span lang=\"EN-US\">MEA<\/span>\u5cf0\u503c\u529f\u7387\u5bc6\u5ea6\u8fdc\u5927\u4e8e<span lang=\"EN-US\">Nafion<\/span>\u79bb\u805a\u7269\uff0c\u4e14\u71c3\u6599\u7535\u6c60\u7684\u4f20\u8d28\u6781\u5316\u660e\u663e\u88ab\u6539\u5584\u3002\u4e3a\u4e86\u6df1\u5165\u5206\u6790\u5176\u539f\u56e0\uff0c\u901a\u8fc7\u6781\u9650\u7535\u6d41\u6cd5\u6d4b\u8bd5\u4e86<i><span lang=\"EN-US\">R<\/span><\/i><sub><span lang=\"EN-US\">total<\/span><\/sub>\u4e0e\u538b\u5f3a\u4e4b\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\uff0c\u5176\u4e2d\u4e0e\u538b\u5f3a\u65e0\u5173\u7684\u963b\u6297\u88ab\u8ba4\u4e3a\u662f\u5c40\u57df\u4f20\u8f93\u963b\u6297\uff08<i><span lang=\"EN-US\">R<\/span><\/i><sub><span lang=\"EN-US\">local<\/span><\/sub>\uff09\u3002\u4ece\u56fe<span lang=\"EN-US\">4(d)<\/span>\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">MEA<\/span>\u7684<i><span lang=\"EN-US\">R<\/span><\/i><sub><span lang=\"EN-US\">local<\/span><\/sub>\u503c\u4e3a<span lang=\"EN-US\">31.5<\/span><\/span> <span lang=\"EN-US\" style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">s m<sup>\u22121<\/sup><\/span><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\uff0c\u4f4e\u4e8e<span lang=\"EN-US\">Nafion<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">(43.3 s m<sup>\u22121<\/sup>)<\/span>\uff0c\u8fd9\u6697\u793a\u7740<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u5177\u6709\u66f4\u9ad8\u7684\u6c27\u6c14\u6e17\u900f\u6027\uff0c\u4e3a\u6c27\u6c14\u6e17\u900f\u5230\u50ac\u5316\u5242\u8868\u9762\u63d0\u4f9b\u6709\u5229\u6761\u4ef6\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261302\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72475-5.png\" alt=\"\" width=\"768\" height=\"508\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72475-5.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72475-5-300x198.png 300w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/p>\n<p>\u56fe<span lang=\"EN-US\">4. <\/span>\u542b<span lang=\"EN-US\">Nafion<\/span>\u548c<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">MEA<\/span>\u7684\u71c3\u6599\u7535\u6c60\u8f93\u51fa\u6027\u80fd\u3001\u7535\u5316\u5b66\u963b\u6297\u4ee5\u53ca<span lang=\"EN-US\">R<\/span><span lang=\"EN-US\">total<\/span>\u4e0e\u538b\u5f3a\u4e4b\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\u3002<\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u8981\u70b9\u56db\uff1a\u79bb\u805a\u7269\u5728<span lang=\"EN-US\">MEA<\/span>\u4e2d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u79bb\u805a\u7269\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u662f\u71c3\u6599\u7535\u6c60\u957f\u671f\u8010\u4e45\u6027\u7684\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u5728\u71c3\u6599\u7535\u6c60\u4e2d\uff0c\u79bb\u805a\u7269\u7684\u964d\u89e3\u662f\u7531\u81ea\u7531\u57fa\u7684\u8fdb\u653b\u5bfc\u81f4\u805a\u5408\u7269\u5206\u5b50\u94fe\u7684\u5206\u89e3\uff0c\u5176\u4e2d\u81ea\u7531\u57fa\u662f\u7531\u8fc7\u6e21\u91d1\u5c5e<span lang=\"EN-US\">Fe<\/span>\u79bb\u5b50\u50ac\u5316\u8fc7\u6c27\u5316\u6c22\u53d1\u751f\u82ac\u987f\u53cd\u5e94\u800c\u5f62\u6210\u3002\u964d\u4f4e\u4f53\u7cfb\u4e2d\u8fc7\u6c27\u5316\u6c22\u6d53\u5ea6\u4e5f\u662f\u63d0\u9ad8\u79bb\u805a\u7269\u8010\u4e45\u6027\u7684\u4e00\u4e2a\u5173\u952e\u56e0\u7d20\u3002\u4ece\u56fe<span lang=\"EN-US\">5(c)<\/span>\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u76f8\u6bd4\u4e8e<span lang=\"EN-US\">Nafion<\/span>\u79bb\u805a\u7269\uff0c<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">MEA<\/span>\u5728<span lang=\"EN-US\">40h<\/span>\u540e\u7684\u7535\u538b\u8870\u51cf\u8f83\u5c0f\uff0c\u8fd9\u8bf4\u660e\u4e86<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u5177\u6709\u66f4\u4f18\u5f02\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002\u4e3a\u4e86\u63a2\u7a76<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u63d0\u9ad8\u7684\u673a\u7406\uff0c\u901a\u8fc7\u5728\u4e09\u7535\u6781\u4f53\u7cfb\u4e2d\u7684<span lang=\"EN-US\">RRDE<\/span>\u8fdb\u884c\u8868\u5f81\u53d1\u73b0\uff0c<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D@Pt\/C<\/span>\u7535\u6781\u7684\u8fc7\u6c27\u5316\u6c22\u4ea7\u7387\u660e\u663e\u4f4e\u4e8e<span lang=\"EN-US\">Nafion@Pt\/C<\/span>\u7535\u6781\uff0c\u8fd9\u8868\u660e\u4e86<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u4e2d\u7684<span lang=\"EN-US\">MnMo<sub>6<\/sub><\/span>\u9634\u79bb\u5b50\u7c07\u5177\u6709\u6e05\u9664\u8fc7\u6c27\u5316\u6c22\u7684\u80fd\u529b\uff0c\u56e0\u6b64\u63d0\u9ad8\u4e86<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261303\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72476-5.png\" alt=\"\" width=\"768\" height=\"534\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72476-5.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72476-5-300x209.png 300w\" sizes=\"(max-width: 768px) 100vw, 768px\" \/><\/p>\n<p>\u56fe<span lang=\"EN-US\">5. <\/span>\u542b<span lang=\"EN-US\">Nafion<\/span>\u548c<span lang=\"EN-US\">PFSN-MnMo<sub>6<\/sub>-D<\/span>\u79bb\u805a\u7269<span lang=\"EN-US\">MEA<\/span>\u7684\u71c3\u6599\u7535\u6c60\u8d28\u5b50\u963b\u6297\u3001<span lang=\"EN-US\">ECSA<\/span>\u503c\u4ee5\u53ca\u79bb\u805a\u7269\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u3010\u6587\u7ae0\u94fe\u63a5\u3011<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u201c<span lang=\"EN-US\">A Highly Hygroscopic, Weakly Adsorbable, and Peroxide Scavenging Ionomer for Low-Pt Proton Exchange Membrane Fuel Cells<\/span>\u201d<\/span><\/p>\n<p class=\"MsoNormal\"><span lang=\"EN-US\"><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202408118\">https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.202408118<\/a><\/span><\/p>\n<p class=\"MsoNormal\"><b><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/span><\/b><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u9648\u80dc\u5229\uff0c\u6b66\u6c49\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff1b\u5206\u522b\u4e8e<span lang=\"EN-US\">1991<\/span>\u548c<span lang=\"EN-US\">1996<\/span>\u5e74\u5728\u6b66\u6c49\u5927\u5b66\u83b7\u5b66\u58eb\u548c\u535a\u58eb\u5b66\u4f4d\uff0c\u968f\u540e\u5728\u82f1\u56fd\u5e1d\u56fd\u7406\u5de5\u5b66\u9662\u5316\u5b66\u7cfb\u7b49\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff1b\u957f\u671f\u4ece\u4e8b\u80fd\u6e90\u7535\u5316\u5b66\u57fa\u7840\u4e0e\u6750\u6599\u7814\u7a76\uff0c\u5728<span lang=\"EN-US\"> Nat. Catal.<\/span>\uff0c<span lang=\"EN-US\">J. Am. Chem. Soc.<\/span>\uff0c<span lang=\"EN-US\">Nat. Commun.<\/span>\uff0c<span lang=\"EN-US\">Adv. Mater.<\/span>\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587<span lang=\"EN-US\">160<\/span>\u4f59\u7bc7\uff0c\u4f5c\u4e3a\u4e3b\u7f16\u4e4b\u4e00\u51fa\u7248\u300a\u7535\u50ac\u5316\u300b\u4e66\u7c4d\uff1b\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u7b49\uff1b\u62c5\u4efb<span lang=\"EN-US\">ACS Catalysis<\/span>\u3001<span lang=\"EN-US\">ACS Electrochemistry<\/span>\u3001\u50ac\u5316\u5b66\u62a5\u3001\u7535\u5316\u5b66\u7b49\u671f\u520a\u7f16\u59d4\uff1b\u83b7\u4e2d\u56fd\u7535\u5316\u5b66\u9752\u5e74\u5956\u3002<\/span><\/p>\n<p class=\"MsoNormal\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">\u56e2\u961f\u4e3b\u9875\uff1a<\/span><span lang=\"EN-US\"><a href=\"https:\/\/slchen.whu.edu.cn\/\"><span style=\"font-family: '\u5fae\u8f6f\u96c5\u9ed1',sans-serif;\">https:\/\/slchen.whu.edu.cn\/<\/span><\/a><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6587\u7ae0\u4fe1\u606f\u3011 \u7b2c\u4e00\u4f5c\u8005\uff1a\u6731\u798f\u9f99 \u901a\u8baf\u4f5c\u8005\uff1a\u9648\u80dc\u5229\u6559\u6388 \u5355\u4f4d\uff1a\u6b66\u6c49\u5927\u5b66 \u3010\u7814\u7a76\u80cc\u666f\u3011 \u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60(PEMFC)\u5177\u6709\u884c\u9a76\u91cc\u7a0b\u957f\u3001\u5145\u7535\u65f6\u95f4\u77ed\u3001\u96f6\u6c61\u67d3\u7269\u6392\u653e\u7b49\u4f18&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-261294","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261294"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=261294"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261294\/revisions"}],"predecessor-version":[{"id":261304,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261294\/revisions\/261304"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=261294"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=261294"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=261294"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}