{"id":261350,"date":"2024-07-17T10:00:10","date_gmt":"2024-07-17T02:00:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261350"},"modified":"2024-07-17T10:00:10","modified_gmt":"2024-07-17T02:00:10","slug":"nature-catalysis%ef%bc%9a%e4%bb%8b%e8%a7%82%e5%b0%ba%e5%ba%a6%e7%9a%84%e8%b4%a8%e9%87%8f%e8%be%93%e8%bf%90%e5%af%b9%e7%94%b5%e5%82%ac%e5%8c%96%e9%80%89%e6%8b%a9%e6%80%a7%e7%9a%84%e5%bd%b1%e5%93%8d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261350","title":{"rendered":"Nature Catalysis\uff1a\u4ecb\u89c2\u5c3a\u5ea6\u7684\u8d28\u91cf\u8f93\u8fd0\u5bf9\u7535\u50ac\u5316\u9009\u62e9\u6027\u7684\u5f71\u54cd"},"content":{"rendered":"<p>\u5f20\u7199\u7199<\/p>\n<p>\u4e00\u3001 \u3010\u79d1\u5b66\u80cc\u666f\u3011 <strong>\u00a0\u00a0<\/strong><\/p>\n<p>\u591a\u76f8\u7535\u50ac\u5316\u662f\u53d1\u5c55\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u7684\u6838\u5fc3\u3002\u7136\u800c\uff0c\u66f4\u6709\u6548\u7684\u7535\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u53d6\u51b3\u4e8e\u5bf9\u6f5c\u5728\u53cd\u5e94\u673a\u5236\u7406\u89e3\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8fd9\u4e9b\u5fae\u89c2\u5c42\u9762\u7684\u673a\u5236\u51e0\u4e4e\u90fd\u662f\u901a\u8fc7\u50ac\u5316\u6d3b\u6027\u70b9\u4f4d\u900f\u955c\u6765\u8fdb\u884c\u7814\u7a76\u3002\u65b0\u5174\u7684\u673a\u7406\u56fe\u5b8c\u5168\u96c6\u4e2d\u5728\u8868\u9762\u7ed3\u5408\u53cd\u5e94\u7684\u4e2d\u95f4\u4f53\u4e0a\uff0c\u5e76\u7b80\u5355\u5047\u8bbe\u50ac\u5316\u901f\u7387\u7531\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u5f3a\u5ea6\u76f4\u63a5\u63a7\u5236\u3002\u56e0\u6b64\uff0c\u540e\u7eed\u7684\u50ac\u5316\u5242\u56f4\u7ed5\u7740\u8c03\u6574\u6d3b\u6027\u4f4d\u70b9\u7684\u6027\u8d28\u8fdb\u884c\u8bbe\u8ba1\uff0c\u4f8b\u5982\uff0c\u63ba\u6742\u6216\u5408\u91d1\u5316\u3002\u8fd9\u79cd\u65b9\u6cd5\u5728\u8ba1\u7b97\u7b5b\u9009\u7814\u7a76\u4e2d\u6210\u529f\u5730\u9884\u6d4b\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u8d8b\u52bf\uff0c\u4f8b\u5982\u7535\u5316\u5b66\u6c27\u8fd8\u539f\u53cd\u5e94(ORR), CO<sub>2<\/sub>\u8fd8\u539f\u53cd\u5e94(CO<sub>2<\/sub>RR)\u548c\u8bb8\u591a\u5176\u4ed6\u53cd\u5e94\u3002\u7136\u800c\uff0c\u8fd9\u79cd\u65b9\u6cd5\u65e0\u6cd5\u5bf9\u7535\u5316\u5b66\u52a8\u529b\u5b66\u7cbe\u7ec6\u7684\u65b9\u9762\u8fdb\u884c\u66f4\u6df1\u5165\u7684\u7814\u7a76\u3002\u8fd9\u4e9b\u65b9\u9762\u5728\u51b3\u5b9a\u6b63\u5728\u8fdb\u884c\u7684\u53cd\u5e94\u8def\u5f84\u4ee5\u53ca\u6b63\u5728\u5f62\u6210\u7684\u6700\u7ec8\u4ea7\u7269\u65b9\u9762\u5177\u6709\u51b3\u5b9a\u6027\u4f5c\u7528\u3002\u4f8b\u5982\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u5b9e\u9a8c\u8bc1\u636e\u8868\u660e\uff0c\u968f\u7740\u50ac\u5316\u5242\u8d1f\u8f7d\u6216\u53cd\u5e94\u5668\u8bbe\u8ba1\u7684\u53d8\u5316\uff0c\u7535\u50ac\u5316\u9009\u62e9\u6027\u4f1a\u4ee5\u4e00\u79cd\u4e0d\u660e\u663e\u7684\u65b9\u5f0f\u53d8\u5316\uff0c\u4e0d\u80fd\u901a\u8fc7\u8003\u8651\u6d3b\u6027\u4f4d\u70b9\u53ca\u5176\u76f4\u63a5\u5316\u5b66\u73af\u5883\u6765\u7b80\u5355\u5730\u5408\u7406\u5316\u3002\u8fd9\u4e9b\u4ee4\u4eba\u8d39\u89e3\u7684\u6548\u5e94\u4f7f\u6211\u4eec\u5bf9\u6d3b\u6027\u90e8\u4f4d\u6a21\u578b\u6709\u4e86\u65b0\u7684\u8ba4\u8bc6\uff0c\u5e76\u63d0\u51fa\u4e86\u4ecb\u89c2\u5c3a\u5ea6\u8d28\u91cf\u8f93\u8fd0\u53ef\u80fd\u5b58\u5728\u7684\u4e00\u4e2a\u91cd\u8981\u673a\u5236\u3002<\/p>\n<p>\u4ecb\u89c2\u8d28\u91cf\u8f93\u8fd0\u53ef\u4ee5\u901a\u8fc7\u4e0d\u540c\u7684\u65b9\u5f0f\u5f71\u54cd\u7535\u50ac\u5316\u8fc7\u7a0b\u672c\u6587\u5c06\u91cd\u70b9\u653e\u5728\u4e00\u4e2a\u7814\u7a76\u76f8\u5bf9\u8f83\u5c11\u7684\u8d28\u91cf\u4f20\u8f93\u6548\u5e94\u4e0a:\u5728\u7535\u50ac\u5316\u5242\u8868\u9762\u548c\u5927\u5757\u7535\u89e3\u8d28\u4e4b\u95f4\u4ea4\u6362\u6325\u53d1\u6027\u53cd\u5e94\u4e2d\u95f4\u4f53\u6240\u4ea7\u751f\u7684\u52a8\u529b\u5b66\u7ade\u4e89\u3002\u8be5\u53cd\u5e94\u6a21\u578b\u6700\u65e9\u7531Behm\u7b49\u4eba\u63d0\u51fa\uff0c\u5e76\u63d0\u51fa\u4e86\u89e3\u5438-\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\uff0c, \u5373\u6269\u6563\u7269\u8d28\u8fd4\u56de\u8868\u9762\u7ee7\u7eed\u53cd\u5e94\u800c\u4e0d\u662f\u4f5c\u4e3a\u65e9\u671f\u4e2d\u95f4\u4ea7\u7269\u9038\u51fa\u3002\u56e0\u6b64\uff0c\u7535\u50ac\u5316\u9009\u62e9\u6027\u662f\u7531\u8868\u9762\u52a8\u529b\u5b66\u548c\u6269\u6563\u4e4b\u95f4\u7684\u7ade\u4e89\u9a71\u52a8\u7684\u3002\u8003\u8651\u5230\u8fd9\u79cd\u7ade\u4e89\uff0c\u50ac\u5316\u5242\u8d1f\u8f7d\u6216\u9897\u7c92\u95f4\u8ddd\u79bb\u53d8\u5f97\u81f3\u5173\u91cd\u8981\uff0c\u56e0\u4e3a\u5b83\u4eec\u76f4\u63a5\u5f71\u54cd\u518d\u5438\u9644\u7684\u53ef\u80fd\u6027\u3002<\/p>\n<p>\u867d\u7136\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u88ab\u5ffd\u89c6\uff0c\u4f46\u5df2\u7ecf\u6709\u4e00\u4e9b\u5b9e\u9a8c\u62a5\u544a\u627f\u8ba4\u5728\u4e2a\u522b\u60c5\u51b5\u4e0b\u89e3\u5438-\u518d\u5438\u9644\u53cd\u5e94\u673a\u5236\u7684\u4f5c\u7528\u3002\u6700\u8fd1\uff0c\u7c7b\u4f3c\u7684\u673a\u7406\u8bba\u8bc1\u89e3\u91ca\u4e86\u5f53\u50ac\u5316\u5242\u5f62\u6001(\u4f8b\u5982\uff0c\u901a\u8fc7\u7eb3\u7c73\u9897\u7c92\u7684\u8986\u76d6\u8303\u56f4\u3001\u8ddd\u79bb\u3001\u5f62\u72b6\u548c\u5927\u5c0f)\u6216\u53cd\u5e94\u5668\u8bbe\u7f6e\u4e2d\u7684\u53cd\u5e94\u7269\u6d41\u6539\u53d8\u65f6\uff0cCu\u5728CO<sub>2<\/sub>RR\u8fc7\u7a0b\u4e2d\u5bf9CO\u7684\u9009\u62e9\u6027\u53d8\u5316\u3002\u7136\u800c\uff0c\u8131\u9644-\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\u7684\u5f71\u54cd\u53ca\u5176\u5728\u4e0d\u540c\u8fc7\u7a0b\u548c\u4f53\u7cfb\u4e2d\u7684\u673a\u7406\u4ecd\u4e0d\u6e05\u695a\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010<\/strong>\u521b\u65b0\u6210\u679c<strong>\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea\u5fb7\u56fd\u9a6c\u514b\u65af\u00b7\u666e\u6717\u514b\u5b66\u4f1a\u5f17\u91cc\u8328\u00b7\u54c8\u4f2f\u7814\u7a76\u6240\u7684Hendrik H. Heenen\u3001Vanessa J. Bukas\u7b49\u7814\u7a76\u8005\u5728Nature Catalysis\u671f\u520a\u53d1\u8868\u4e86\u9898\u4e3a\u201cExploring mesoscopic mass transport effects on electrocatalytic selectivity\u201d\u7684\u8bba\u6587\uff0c\u8be5\u9879\u7814\u7a76\u5c55\u793a\u4e86\u4ecb\u89c2\u8d28\u91cf\u8f93\u8fd0\u5728\u7535\u50ac\u5316\u9009\u62e9\u6027\u4e2d\u7684\u4f5c\u7528\uff0c\u901a\u8fc7\u5efa\u7acb\u4e00\u4e2a\u7b80\u5355\u7684\u591a\u5c3a\u5ea6\u6a21\u578b\uff0c\u5c06\u6269\u6563\u8026\u5408\u5230\u7535\u5316\u5b66\u8868\u9762\u52a8\u529b\u5b66\uff0c\u5efa\u7acb\u4e86\u5bf9\u6f5c\u5728\u7684\u8131\u9644-\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\u7684\u5b9a\u91cf\u7406\u89e3\u3002\u6a21\u578b\u518d\u73b0\u4e86\u5b9e\u9a8c\u6587\u732e\u4e2d\u53d1\u73b0\u7684\u4e00\u7cfb\u5217\u8d8b\u52bf\uff0c\u540c\u65f6\u4e3a\u6d3b\u6027\u4f4d\u70b9\u6a21\u578b\u4e4b\u5916\u7684\u7535\u50ac\u5316\u9009\u62e9\u6027\u53d8\u5316\u63d0\u4f9b\u4e86\u4e00\u79cd\u66ff\u4ee3\u6216\u81f3\u5c11\u662f\u8865\u5145\u7684\u89e3\u91ca\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261351\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-11.png\" alt=\"\" width=\"1130\" height=\"547\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-11.png 1130w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-11-300x145.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-11-768x372.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-11-1024x496.png 1024w\" sizes=\"(max-width: 1130px) 100vw, 1130px\" \/>\u56fe<\/strong><strong>1 <\/strong><strong>\u89e3\u5438<\/strong><strong>&#8211;<\/strong><strong>\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe\u3002<\/strong><strong>\u00a92024 The Author(s)<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261352\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-12.png\" alt=\"\" width=\"586\" height=\"770\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-12.png 586w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-12-228x300.png 228w\" sizes=\"(max-width: 586px) 100vw, 586px\" \/><\/strong><\/p>\n<p><strong>\u56fe2 \u7535\u50ac\u5316\u5242\u7c97\u7cd9\u5ea6\u5bf9\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/strong><strong>\u00a92024 The Author(s) <\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261353\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-12.png\" alt=\"\" width=\"597\" height=\"773\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-12.png 597w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-12-232x300.png 232w\" sizes=\"(max-width: 597px) 100vw, 597px\" \/><\/strong><\/p>\n<p><strong>\u56fe3 \u7535\u50ac\u5316\u5242\u9897\u7c92\u5f62\u72b6\u548c\u8868\u9762\u6ce2\u7eb9\u5bf9\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002\u00a92024 The Author(s)<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261354\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-12.png\" alt=\"\" width=\"605\" height=\"367\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-12.png 605w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-12-300x182.png 300w\" sizes=\"(max-width: 605px) 100vw, 605px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>4 <\/strong><strong>\u5408\u91d1\u5316\u5bfc\u81f4\u7684\u7535\u50ac\u5316\u5242\u7c97\u7cd9\u5ea6\u5bf9\u9009\u62e9\u6027\u7684\u5f71\u54cd\u3002<\/strong><strong>\u00a92024 The Author(s) <\/strong><\/p>\n<p><strong>\u00a0<\/strong><strong>\u4e09\u3001\u3010<\/strong>\u79d1\u5b66\u542f\u8fea<strong>\u3011<\/strong><\/p>\n<p>\u8be5\u9879\u6210\u679c\u5f15\u8d77\u4e86\u5bf9\u4ecb\u89c2\u8d28\u91cf\u8f93\u8fd0\u4f5c\u4e3a\u51b3\u5b9a\u7535\u50ac\u5316\u9009\u62e9\u6027\u7684\u51b3\u5b9a\u6027\u56e0\u7d20\u7684\u5173\u6ce8\u3002\u901a\u8fc7\u591a\u5c3a\u5ea6\u5efa\u6a21\uff0c\u4f5c\u8005\u4e13\u95e8\u63a2\u7d22\u548c\u91cf\u5316\u4e86\u8131\u9644-\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\u5728\u5404\u79cd\u5b9e\u9a8c\u6587\u732e\u4e2d\u7684\u666e\u904d\u6027\u5f71\u54cd\u3002\u6a21\u578b\u518d\u73b0\u4e86\u50ac\u5316\u5242\u5728\u6240\u6709\u4e2d\u3001\u5fae\u89c2\u548c\u539f\u5b50\u5c3a\u5ea6\u4e0a\u7684\u9009\u62e9\u6027\u8d8b\u52bf\uff0c\u5e76\u663e\u793a\u4e86\u5176\u5728\u4e0d\u540c\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3001\u4e0d\u540c\u50ac\u5316\u5242\u548c\u4e0d\u540c\u7535\u6781\u8bbe\u7f6e\u4e0b\u7684\u666e\u904d\u6027\u3002\u8fd9\u4e00\u673a\u5236\u5728\u89e3\u51b3\u50ac\u5316\u5242\u8001\u5316\u548c\u964d\u89e3\u95ee\u9898\uff0c\u4f18\u5316\u50ac\u5316\u5242\u7684\u7a33\u6001\u8fd0\u884c\u65b9\u9762\u6781\u5177\u4ef7\u503c\u3002\u6839\u636e\u8131\u9644-\u518d\u5438\u9644\u53cd\u5e94\u673a\u7406\uff0c\u50ac\u5316\u5242\u5f62\u6001\u7684\u52a8\u6001\u53d8\u5316(\u4f8b\u5982\u7531\u4e8e\u91cd\u6784\u3001\u9897\u7c92\u56e2\u805a\u6216\u6eb6\u89e3)\u4f1a\u6539\u53d8\u4ea7\u7269\u7684\u9009\u62e9\u6027\uff0c\u4ece\u800c\u6539\u53d8\u76ee\u6807\u50ac\u5316\u6027\u80fd\uff0c\u4e3a\u7535\u50ac\u5316\u9009\u62e9\u6027\u7684\u53d8\u5316\uff0c\u5f00\u8f9f\u4e86\u4ee4\u4eba\u5174\u594b\u7684\u7814\u7a76\u9014\u5f84\u3002<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/doi.org\/10.1038\/s41929-024-01177-6<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f20\u7199\u7199 \u4e00\u3001 \u3010\u79d1\u5b66\u80cc\u666f\u3011 \u00a0\u00a0 \u591a\u76f8\u7535\u50ac\u5316\u662f\u53d1\u5c55\u53ef\u6301\u7eed\u80fd\u6e90\u6280\u672f\u7684\u6838\u5fc3\u3002\u7136\u800c\uff0c\u66f4\u6709\u6548\u7684\u7535\u50ac\u5316\u5242\u7684\u5408\u7406\u8bbe\u8ba1\u53d6\u51b3\u4e8e\u5bf9\u6f5c\u5728\u53cd\u5e94\u673a\u5236\u7406\u89e3\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8fd9\u4e9b\u5fae\u89c2\u5c42\u9762\u7684\u673a\u5236\u51e0&#8230;<\/p>\n","protected":false},"author":39557,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-261350","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261350"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/39557"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=261350"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261350\/revisions"}],"predecessor-version":[{"id":261355,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261350\/revisions\/261355"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=261350"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=261350"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=261350"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}