{"id":261490,"date":"2024-07-17T06:45:21","date_gmt":"2024-07-16T22:45:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261490"},"modified":"2024-07-16T20:55:05","modified_gmt":"2024-07-16T12:55:05","slug":"%e8%a1%a2%e5%b7%9e%e5%ad%a6%e9%99%a2%e5%90%95%e4%ba%ae%e8%b4%b2%e6%b5%b7%e5%a9%95coord-chem-rev-%e6%9c%80%e6%96%b0%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%a6%bb%e5%ad%90%e5%85%b1%e4%bb%b7%e6%9c%89%e6%9c%ba","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261490","title":{"rendered":"\u8862\u5dde\u5b66\u9662\u5415\u4eae&#038;\u8d32\u6d77\u5a55Coord. Chem. Rev.\u6700\u65b0\u7efc\u8ff0\uff1a\u79bb\u5b50\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff1a\u4ece\u5408\u6210\u7b56\u7565\u5230\u5148\u8fdb\u7684\u7535\u3001\u5149\u548c\u70ed\u80fd\u529f\u80fd"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261492\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-17.png\" alt=\"\" width=\"691\" height=\"297\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-17.png 691w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/1-17-300x129.png 300w\" sizes=\"(max-width: 691px) 100vw, 691px\" \/><\/p>\n<p>\u8fd1\u65e5<strong>\uff0c\u8862\u5dde\u5b66\u9662\u5316\u5b66\u4e0e\u6750\u6599\u5de5\u7a0b\u5b66\u9662<\/strong>\u7684<strong>\u5415\u4eae<\/strong>\u548c<strong>\u8d32\u6d77\u5a55<\/strong>\u79d1\u7814\u56e2\u961f\u5728Coordination Chemistry Reviews\u4e0a\u53d1\u8868\u9898\u4e3a\u201cIonic covalent organic frameworks From synthetic strategies to advanced electro-, photo-, and thermo- energy functionalities\u201d\u7684\u7efc\u8ff0\u3002<\/p>\n<p>\u79bb\u5b50\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08iCOFs\uff09\u662f\u4e00\u4e2a\u65b0\u5174\u7684COFs\u6750\u6599\u7684\u5b50\u96c6\uff0c\u5177\u6709\u5e26\u7535\u4f4d\u70b9\u548c\u6709\u5e8f\u6846\u67b6\uff0c\u5728\u8bf8\u591a\u80fd\u6e90\u529f\u80fd\u5e94\u7528\u4e2d\u5c55\u73b0\u6f5c\u529b\uff0c\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\u3002\u672c\u6587\u7efc\u8ff0\u4e86iCOFs\u7684\u5148\u8fdb\u7535\u3001\u5149\u548c\u70ed\u80fd\u529f\u80fd\uff08<strong>\u56fe<\/strong><strong>1<\/strong>\uff09\u3002\u4ece\u5bf9iCOFs\u7684\u5206\u7c7b\u548c\u6784\u5efa\u5355\u5143\u7684\u53cd\u601d\u5f00\u59cb\uff0c\u9610\u8ff0\u4e86iCOFs\u7684\u6784\u5efa\u539f\u5219\uff0c\u5e76\u603b\u7ed3\u4e86iCOFs\u5728\u5149\u80fd\u3001\u7535\u80fd\u53ca\u70ed\u80fd\u9886\u57df\u7684\u7814\u7a76\u8fdb\u5c55\u3002\u6b64\u5916\uff0c\u672c\u6587\u8fd8\u5bf9iCOFs\u4e2d\u79bb\u5b50\u7ed3\u6784\u548c\u5404\u79cd\u529f\u80fd\u4e4b\u95f4\u7684\u6784\u6548\u5173\u7cfb\u8fdb\u884c\u8ba8\u8bba\u3002\u6700\u540e\uff0c\u5168\u9762\u5206\u6790\u4e86iCOFs\u6240\u9762\u4e34\u7684\u673a\u9047\u6311\u6218\u3002\u672c\u7efc\u8ff0\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u6027\u80fdiCOFs\u7684\u5236\u9020\u94fa\u5e73\u4e86\u9053\u8def\uff0c\u5e76\u4e3a\u5176\u5e7f\u6cdb\u7684\u5de5\u4e1a\u5e94\u7528\u5f00\u8f9f\u4e86\u65b0\u7684\u524d\u666f\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261493\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-18.png\" alt=\"\" width=\"700\" height=\"690\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-18.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/2-18-300x296.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong> iCOFs\u7684\u6027\u8d28\u548c\u5149\u3001\u7535\u548c\u70ed\u80fd\u529f\u80fd\u3002<\/p>\n<p><strong>\u672c\u6587\u91cd\u70b9\uff1a<\/strong><\/p>\n<p>\uff081\uff09\u2192\u9996\u6b21\u6982\u8ff0iCOFs\u7684\u7efc\u5408\u80fd\u6e90\u529f\u80fd\u3002<\/p>\n<p>\uff082\uff09\u2192\u5408\u6210\u5177\u6709\u4e0d\u540c\u6027\u8d28\u7684\u5404\u79cdiCOF\u7ed3\u6784\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\uff083\uff09\u2192\u529f\u80fd\u5316\u7b56\u7565\u4ee5\u63d0\u9ad8\u76ee\u6807\u80fd\u6e90\u5e94\u7528\u4e2d\u7684\u6027\u80fd\u3002<\/p>\n<p>\uff084\uff09\u2192\u63a8\u8fdbiCOFs\u9886\u57df\u7684\u672a\u6765\u5c55\u671b\u548c\u6f5c\u5728\u65b9\u5411\u3002<\/p>\n<p><strong>1.iCOFs<\/strong><strong>\u7684\u5408\u6210<\/strong><\/p>\n<p>\u8fdc\u8ddd\u79bb\u6709\u5e8fiCOFs\u7684\u5408\u6210\u4e3b\u8981\u4f9d\u8d56\u4e8e\u5316\u5b66\u8bf1\u5bfc\u7684\u52a8\u6001\u5171\u4ef7\u5316\u5b66\uff08DCC\uff09\u3002\u901a\u8fc7\u9009\u62e9\u5408\u9002\u7684\u5408\u6210\u65b9\u6cd5\uff0c\u53ef\u4ee5\u8c03\u6574\u548c\u63a7\u5236iCOFs\u7684\u5f62\u8c8c\u548c\u6027\u80fd\u7684\u3002\u57fa\u4e8eDCC\uff0ciCOFs\u6709\u4e24\u79cd\u4e3b\u8981\u7684\u8bbe\u8ba1\u7b56\u7565\uff1a\u76f4\u63a5\u5408\u6210\u548c\u540e\u4fee\u9970\u3002\u76f4\u63a5\u5408\u6210\u6cd5\u6709\u6eb6\u5242\u70ed\u6cd5\uff0c\u673a\u68b0\u5408\u6210\u6cd5\uff0c\u5fae\u6ce2\u5408\u6210\u6cd5\uff0c\u5ba4\u6e29\u5408\u6210\u6cd5\u7b49\u3002\u540e\u4fee\u9970\u6cd5\u53ef\u4ee5\u5206\u4e3a\u4fa7\u94fe\u540e\u4fee\u9970\u548c\u4e3b\u94fe\u540e\u4fee\u9970\u3002\u76f4\u63a5\u5408\u6210\u4e2d\u6700\u5178\u578b\u7684\u662f\u6eb6\u5242\u70ed\u6cd5\uff0c\u800c\u540e\u4fee\u9970\u6cd5\u5e38\u7528\u7684\u5b98\u80fd\u56e2\u548c\u5177\u4f53\u4f8b\u5b50\u5982\u56fe2\u6240\u793a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261494\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-17.png\" alt=\"\" width=\"700\" height=\"640\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-17.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/3-17-300x274.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe2. \u540e\u4fee\u9970\u5e38\u7528\u7684\u5b98\u80fd\u56e2\u548c\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>2.iCOFs<\/strong><strong>\u5728\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528<\/strong><\/p>\n<p><strong>\u8c03\u6574\u7684\u5b54\u9699\u73af\u5883\u3001\u6781\u6027\u9aa8\u67b6\u3001\u7535\u5b50\u4f20\u8f93\u79bb\u5b50<\/strong><strong>COFs<\/strong><strong>\u7684\u80fd\u529b\u548c\u5bc6\u5ea6\u8868\u660e\u5728\u8bb8\u591a\u9886\u57df\u4e2d\u7684\u5e94\u7528<\/strong><strong>,<\/strong><strong>\u672c\u6587\u4e2d\u4e3b\u8981\u9610\u8ff0\u4e86\u79bb\u5b50\u578b<\/strong><strong>COFs<\/strong><strong>\u5728<\/strong>\u5148\u8fdb\u7535\u3001\u5149\u548c\u70ed\u80fd\u529f\u80fd\u65b9\u9762\u7684\u5e94\u7528\u3002<\/p>\n<p><strong>3.1 <\/strong><strong>\u7535\u80fd\u529f\u80fd<\/strong><\/p>\n<p>\u7535\u80fd\u80fd\u6e90\u4e3b\u8981\u53ef\u4ee5\u5206\u4e3a\u7535\u6c60\u548c\u7535\u50ac\u5316\u4e24\u4e2a\u65b9\u9762\u3002\u57fa\u4e8eICOF\u7684\u7535\u6c60\u53ef\u5206\u4e3a\u9502\u79bb\u5b50\u3001\u9502\u786b\u548c\u71c3\u6599\u7535\u6c60\u3002<\/p>\n<p><strong>\u9502\u79bb\u5b50\u7535\u6c60<\/strong><\/p>\n<p>\u5b83\u5728\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u5f97\u5230\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u5177\u6709\u4ee5\u4e0b\u4f18\u70b9\uff1a\u4ece\u56fe3\u4e2d\u53ef\u4ee5\u770b\u51fa\u9502\u79bb\u5b50\u4f5c\u4e3a\u53cd\u79bb\u5b50\u88ab\u56fa\u5b9a\u5728\u4e00\u4e2a\u521a\u6027\u6846\u67b6\u5185\uff0c\u53ef\u4ee5\u8bf1\u5bfc\u589e\u5f3a\u7684\u56fa\u6709\u7535\u5bfc\u7535\u6027\u3002\u5e26\u7535\u9aa8\u67b6\u4e0e\u8fc1\u79fb\u79bb\u5b50\u4e4b\u95f4\u7684\u9759\u7535\u529b\u6709\u6548\u5730\u51cf\u8f7b\u4e86\u8fd0\u884c\u8fc7\u7a0b\u4e2d\u7684\u79bb\u5b50\u6cc4\u6f0f\uff0c\u4ece\u800c\u786e\u4fdd\u4e86\u7535\u6c60\u7cfb\u7edf\u7684\u7a33\u5b9a\u548c\u9ad8\u6548\u8fd0\u884c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261495\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-16.png\" alt=\"\" width=\"700\" height=\"380\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-16.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/4-16-300x163.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe3. iCOFs\u5728\u9502\u7535\u6c60\u4e2d\u529f\u80fd\u5316\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u9502\u786b\u7535\u6c60<\/strong><\/p>\n<p>\u9502\u786b\u7535\u6c60\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7406\u8bba\u5bb9\u91cf\u548c\u6bd4\u80fd\u91cf\u5bc6\u5ea6\uff0c\u5728\u50a8\u80fd\u548c\u8f6c\u6362\u9886\u57df\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u4ece\u56fe4\u4e2d\u53ef\u4ee5\u5f97\u51fa\u591a\u786b\u5316\u7269\u6eb6\u89e3\u5bfc\u81f4\u7684\u53ef\u6eb6\u6027\u9502\u591a\u786b\u5316\u7269\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u548c\u7a7f\u68ad\u6548\u5e94\u662f\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u4e3b\u8981\u95ee\u9898\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261496\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/5-8.png\" alt=\"\" width=\"700\" height=\"602\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/5-8.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/5-8-300x258.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe4. iCOFs\u529f\u80fd\u5316\u5728\u9502\u786b\u7535\u6c60\u4e2d\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u71c3\u6599\u7535\u6c60<\/strong><\/p>\n<p>\u56fe5\u7684\u51e0\u79cd\u4ee3\u8868\u6027\u71c3\u6599\u7535\u6c60\u53ef\u4ee5\u770b\u51fa\u5404\u79cdiCOF\u6750\u6599\u5747\u8868\u73b0\u51fa\u826f\u597d\u7684\u8d28\u5b50\u5bfc\u7535\u6027\uff0c\u5b54\u58c1\u4e0e\u8d28\u5b50\u4f20\u5bfc\u4e4b\u95f4\u7684\u6c22\u952e\u7f51\u7edc\u4e3aCOFs\u4e2d\u7684\u8d28\u5b50\u4f20\u5bfc\u63d0\u4f9b\u4e86\u4f18\u52bf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261497\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/6-6.png\" alt=\"\" width=\"700\" height=\"338\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/6-6.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/6-6-300x145.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe5. iCOFs\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u529f\u80fd\u5316\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u7535\u50ac\u5316<\/strong><\/p>\n<p>\u4ece\u56fe6\u51e0\u79cd\u5229\u7528\u79bb\u5b50COFs\u8fdb\u884c\u7535\u50ac\u5316\u7684\u6587\u732e\u4e2d\u5f97\u51fa\u4ee5\u4e0b\u7ed3\u8bba\uff1a\u5229\u7528\u79bb\u5b50\u5b98\u80fd\u56e2\uff0ciCOFs\u4e2d\u4ea7\u751f\u4e86\u9ad8\u7535\u8377\u5bc6\u5ea6\uff0c\u63d0\u4f9b\u4e86\u989d\u5916\u7684\u7535\u5b50\u8f6c\u79fb\u9014\u5f84\u548c\u6d3b\u6027\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u4fc3\u8fdb\u7535\u50ac\u5316\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u79bb\u5b50\u57fa\u56e2\u5f15\u8d77\u7684\u9759\u7535\u5438\u5f15\u53ef\u4ee5\u4fc3\u8fdb\u4e0e\u53cd\u5e94\u7269\u6216\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u6291\u5236\u526f\u53cd\u5e94\uff0c\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261498\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/7-4.png\" alt=\"\" width=\"700\" height=\"619\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/7-4.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/7-4-300x265.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe6. iCOFs\u5728\u7535\u50ac\u5316\u4e2d\u529f\u80fd\u5316\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>3.2 <\/strong><strong>\u5149\u80fd\u529f\u80fd<\/strong><\/p>\n<p><strong>\u5149\u50ac\u5316<\/strong><\/p>\n<p>\u56fe7\u4e2diCOFs\u7684\u72ec\u7279\u7279\u6027\u51b3\u5b9a\u4e86\u5b83\u4eec\u5728\u5149\u50ac\u5316\u9886\u57df\u7684\u5de8\u5927\u6f5c\u529b\uff1a(1) \u79bb\u5b50\u6846\u67b6\u4ea7\u751f\u7684\u4ecb\u7535\u5e38\u6570\u7684\u589e\u52a0\u53ef\u4ee5\u8bf1\u5bfc\u7a7a\u95f4\u6781\u5316\uff0c\u4ece\u800c\u964d\u4f4e\u6fc0\u5b50\u7684\u7ed3\u5408\u80fd\uff0c\u4ece\u800c\u4fc3\u8fdb\u7535\u8377\u7684\u8fc1\u79fb\u548c\u5206\u79bb\u3002(2) \u7531\u4e8eiCOFs\u5c42\u4e4b\u95f4\u7684\u9759\u7535\u65a5\u529b\uff0ciCOFs\u7684\u539a\u5ea6\u66f4\u5bb9\u6613\u5212\u5206\u4e3a\u7eb3\u7c73\u5c3a\u5ea6\u751a\u81f3\u4e9a\u7eb3\u7c73\u5c3a\u5ea6\uff0c\u6700\u5c0f\u5316\u5149\u4ea7\u751f\u8f7d\u6d41\u5b50\u7684\u8fc1\u79fb\u8ddd\u79bb\uff0c\u4fc3\u8fdb\u66f4\u5feb\u7684\u8fc1\u79fb\u901f\u7387\uff0c\u4ece\u800c\u51cf\u5c11\u7535\u5b50-\u7a7a\u7a74\u5bf9\u7684\u56fa\u6709\u91cd\u7ec4\u3002(3) iCOFs\u7535\u8377\u5bc6\u5ea6\u7684\u4e0d\u5747\u5300\u5206\u5e03\u63d0\u4f9b\u4e86\u66f4\u591a\u7684\u53cd\u5e94\u4f4d\u70b9\uff0c\u589e\u5f3a\u4e86\u5bf9\u53cd\u5e94\u7269\u7684\u9759\u7535\u5438\u9644\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261499\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/8-2.png\" alt=\"\" width=\"700\" height=\"712\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/8-2.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/8-2-295x300.png 295w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe7. iCOFs\u5728\u5149\u50ac\u5316\u4e2d\u529f\u80fd\u5316\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u5728\u5149\u70ed\u80fd\u8f6c\u6362\u4e2d\u7684\u529f\u80fd<\/strong><\/p>\n<p>iCOFs\u7684\u79bb\u5b50\u6210\u5206\u53ef\u4ee5\u901a\u8fc7\u63d0\u4f9b\u5f3a\u6781\u5316\u548c\u6291\u5236\u975e\u8f90\u5c04\u53d1\u5c04\u6765\u964d\u4f4e\u6fc0\u5b50\u7684\u89e3\u79bb\u80fd\uff0c\u4ece\u800c\u63d0\u9ad8\u5149\u70ed\u8f6c\u6362\u6548\u7387\uff0c\u8fd9\u662f\u8fd1\u5e74\u6765\u5728\u5149\u70ed\u8f6c\u6362\u9886\u57df\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002<\/p>\n<p><strong>3.3 <\/strong><strong>\u70ed\u80fd\u529f\u80fd<\/strong><\/p>\n<p>iCOFs\u4e2d\u7684\u79bb\u5b50\u57fa\u56e2\u4e3b\u8981\u53ef\u4ee5\u901a\u8fc7\u79bb\u5b50-\u5076\u6781\u5b50\u6216\u901a\u8fc7\u9178-\u78b1\u7684\u76f8\u4e92\u4f5c\u7528\u6765\u589e\u5f3a\u5bf9\u53cd\u5e94\u7269\u7684\u5438\u9644\u4f5c\u7528\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86CO\u2082\u7684\u9009\u62e9\u6027\u548c\u5438\u9644\u80fd\u529b\u3002\u6b64\u5916\uff0c\u9ad8\u5ea6\u6709\u5e8f\u7684\u591a\u5b54\u7ed3\u6784\u4f7f\u53cd\u5e94\u7269\u6613\u4e8e\u6e17\u900f\uff0c\u52a0\u901f\u4f20\u8d28\u548c\u63d0\u9ad8\u50ac\u5316\u6548\u7387\uff0c\u5177\u4f53\u5982\u56fe8\u6240\u793a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-261501\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/9-2.png\" alt=\"\" width=\"700\" height=\"459\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/9-2.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/9-2-300x197.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><\/p>\n<p>\u56fe8. iCOFs\u5728\u70ed\u50ac\u5316\u4e2d\u7684\u4ee3\u8868\u6027\u4f8b\u5b50\u3002<\/p>\n<p><strong>\u603b\u7ed3<\/strong><\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0ciCOFs\u56e0\u5176\u53ef\u8c03\u7684\u79bb\u5b50\u7279\u6027\u548c\u529f\u80fd\u6f5c\u529b\u800c\u4e3a\u6750\u6599\u7814\u7a76\u5e26\u6765\u4e86\u65b0\u7684\u673a\u9047\u3002\u968f\u7740\u5408\u6210\u65b9\u6cd5\u7684\u4e0d\u65ad\u521b\u65b0\u548c\u5bf9\u6750\u6599\u7ed3\u6784-\u6027\u80fd\u76f8\u4e92\u4f5c\u7528\u7684\u6df1\u5165\u4e86\u89e3\uff0ciCOFs\u65e0\u7591\u5c06\u5728\u79d1\u5b66\u548c\u5de5\u4e1a\u9886\u57df\u53d1\u6325\u66f4\u5173\u952e\u7684\u4f5c\u7528\uff0c\u5e76\u6709\u4fc3\u8fdb\u65b0\u6280\u672f\u521b\u65b0\u548c\u5e94\u7528\u7684\u6f5c\u529b\u3002\u673a\u9047\u548c\u6311\u6218\u5171\u5b58\u4e8e\u8fd9\u4e2a\u65b0\u751f\u7684\u9886\u57df\uff0c\u800c\u6211\u4eec\u53ea\u662f\u5728\u77a5\u89c1\u5b83\u7684\u7ec6\u5206\u5e02\u573a\u3002<strong>\u4e3a\u4e86\u6269\u5927\u79bb\u5b50\u578b<\/strong><strong>COFs<\/strong><strong>\u5728\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\uff0c\u672a\u6765\u9700\u8981\u89e3\u51b3\u4ee5\u4e0b\u95ee\u9898\uff1a<\/strong><\/p>\n<p><strong>\u638c\u63e1<\/strong><strong>iCOFs<\/strong><strong>\u5185\u7684\u8f7d\u4f53\u4f20\u8f93\u673a\u5236\u662f\u6709\u5f85\u672a\u6765\u63a2\u7d22\u7684\u5173\u952e\u6311\u6218\u3002<\/strong><\/p>\n<p><strong>\u63a2\u7d22\u5c06\u4e8c\u7ef4<\/strong><strong>iCOFs<\/strong><strong>\u5265\u79bb\u6210\u5177\u6709\u5f3a\u5927\u529b\u5b66\u6027\u80fd\u7684\u8584\u819c\u7684\u65b9\u6cd5\u3002<\/strong><\/p>\n<p><strong>\u5982\u4f55\u5236\u5907\u5177\u6709\u9ad8\u7ed3\u6676\u5ea6\u7684\u79bb\u5b50<\/strong><strong>COFs<\/strong><strong>\u4ecd\u7136\u662f\u76ee\u524d\u7684\u4e00\u4e2a\u6311\u6218\u3002<\/strong><\/p>\n<p><strong>\u63a2\u7d22\u5feb\u901f\u751f\u4ea7\u66f4\u5927\u7684<\/strong><strong>iCOFs<\/strong><strong>\u6676\u4f53\u7684\u521b\u65b0<\/strong><strong>\u65b9\u6cd5\u3002<\/strong><\/p>\n<p><strong>\u8bba\u6587\u94fe\u63a5\uff1a<\/strong><\/p>\n<p><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0010854524003497\">https:\/\/www.sciencedirect.com\/science\/article\/abs\/pii\/S0010854524003497<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd1\u65e5\uff0c\u8862\u5dde\u5b66\u9662\u5316\u5b66\u4e0e\u6750\u6599\u5de5\u7a0b\u5b66\u9662\u7684\u5415\u4eae\u548c\u8d32\u6d77\u5a55\u79d1\u7814\u56e2\u961f\u5728Coordination Chemistry Reviews\u4e0a\u53d1\u8868\u9898\u4e3a\u201cIonic covalent o&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-261490","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261490"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=261490"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261490\/revisions"}],"predecessor-version":[{"id":261502,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/261490\/revisions\/261502"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=261490"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=261490"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=261490"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}