{"id":261580,"date":"2024-07-21T15:00:55","date_gmt":"2024-07-21T07:00:55","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261580"},"modified":"2024-07-21T15:00:55","modified_gmt":"2024-07-21T07:00:55","slug":"%e7%be%8e%e5%9b%bd%e5%8c%97%e4%bc%8a%e5%88%a9%e8%af%ba%e4%bc%8a%e5%a4%a7%e5%ad%a6%e9%98%bf%e8%b4%a1%e5%9b%bd%e5%ae%b6%e5%ae%9e%e9%aa%8c%e5%ae%a4_%e5%85%b7%e6%9c%89%e9%92%95ii%e6%8e%ba%e6%9d%82","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261580","title":{"rendered":"\u7f8e\u56fd\u5317\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66&#038;\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4_\u5177\u6709\u9495(II)\u63ba\u6742\u7684\u6742\u5316\u9499\u949b\u77ff\u4e2d\u5149\u8bf1\u5bfc\u7684\u7c7b\u8fd1\u85e4\u6fc0\u5b50-\u81ea\u65cb\u8026\u5408\u6548\u5e94"},"content":{"rendered":"<p><strong>\u4e00\u3001 \u3010\u5bfc\u8bfb\u3011 \u00a0<\/strong><\/p>\n<p>\u5b9e\u73b0\u5bf9\u5149\u751f\u6fc0\u5b50\u4e2d\u5177\u6709\u91cf\u5b50\u7ea0\u7f20\u5c5e\u6027\u7684\u7535\u5b50-\u7a7a\u7a74\u64cd\u63a7\u662f\u91cf\u5b50\u79d1\u5b66\u4e2d\u7684\u4e00\u9879\u5173\u952e\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u3002\u5728\u7269\u7406\u5b66\u4e2d\uff0c\u8fd1\u85e4\u6548\u5e94\u4ea7\u751f\u4e8e\u78c1\u6027\u6742\u8d28\u5143\u7d20\u4e2d\u5c40\u57df\u81ea\u65cb\u7535\u5b50\u548c\u91d1\u5c5e\u6750\u6599\u4e2d\u5de1\u6e38\u7535\u5b50\u4e4b\u95f4\u7684\u53cd\u94c1\u78c1\u4ea4\u6362\u4f5c\u7528\u3002\u5728\u5927\u90e8\u5206\u60c5\u51b5\u4e0b\uff0c\u8fd1\u85e4\u6548\u5e94\u4f5c\u4e3a\u4e00\u9879\u7535\u5b66\u7684\u8f93\u8fd0\u7279\u6027\uff0c\u53ea\u5b58\u5728\u4e8e\u91d1\u5c5e\u6216\u91d1\u5c5e\u5408\u91d1\u4e2d\uff0c\u4e5f\u5076\u5c14\u5b58\u5728\u4e8e\u91cf\u5b50\u70b9\u6750\u6599\u4e2d\u3002\u5c06\u8fd1\u85e4\u6548\u5e94\u96c6\u6210\u8fdb\u5177\u6709\u5149\u6fc0\u53d1\u54cd\u5e94\u7684\u534a\u5bfc\u4f53\u6750\u6599\u5e76\u5b9e\u73b0\u5149\u5b66\u8c03\u63a7\u7684\u6848\u4f8b\u5374\u9c9c\u6709\u62a5\u9053\u3002\u56e0\u4e3a\u534a\u5bfc\u4f53\u6750\u6599\u53ef\u901a\u8fc7\u5149\u6fc0\u53d1\u5c06\u79bb\u57df\u7535\u5b50\u548c\u7a7a\u7a74\u5206\u522b\u6ce8\u5165\u6750\u6599\u5bfc\u5e26\u548c\u4ef7\u5e26\uff0c\u56e0\u6b64\u53ef\u6f5c\u5728\u6210\u4e3a\u4e00\u9879\u975e\u63a5\u89e6\u5f0f\u3001\u53ef\u5149\u5b66\u5f00\u5173\u7684\u81ea\u65cb\u7535\u5b50\u5668\u4ef6\u548c\u57fa\u4e8e\u7535\u5b50\u81ea\u65cb\u6001\u7684\u91cf\u5b50\u8ba1\u7b97\u6280\u672f\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u7f8e\u56fd\u5317\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66Tao Xu\u56e2\u961f\u548c\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7eb3\u7c73\u5c3a\u5ea6\u6750\u6599\u4e2d\u5fc3Benjamin T. Diroll, Saw Wai Hla\u7b49\u4eba\u5728Nature Communications\uff08\u300a\u81ea\u7136\u00b7\u901a\u8baf\u300b\uff09\u4e0a\u53d1\u8868\u7814\u7a76\u8bba\u6587\u3002\u901a\u8fc7\u7b5b\u90094f\u7535\u5b50\u8f68\u9053\u80fd\u7ea7\u63a5\u8fd1\u4e8e\u6742\u5316\u9499\u949b\u77ffCH<sub>3<\/sub>NH<sub>3<\/sub>PbI<sub>3<\/sub>\u7981\u5e26\u5e26\u8fb9\u533a\u57df\u7684\u9495(II)\u79bb\u5b50\u4f5c\u4e3a\u63ba\u6742\u5143\u7d20\uff0c\u5229\u7528\u6676\u4f53\u573a\u88c2\u5206\u7406\u8bba\u4e2d\u4e0e\u5f31\u57fa\u56e2I<sup>&#8211;<\/sup>\u5728\u516b\u9762\u4f53\u914d\u4f4d\u4e0b\u7684\u9ad8\u81ea\u65cb\u6570\u76ee\u4ee5\u5f62\u6210\u9ad8\u6d53\u5ea6\u5c40\u57df\u5316\u201c\u78c1\u9488\u201d\u7279\u70b9\uff0c\u5b9e\u73b0\u4e86\u9495(II)\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u5728\u5149\u6fc0\u53d1\u548c\u4f4e\u6e29\u6761\u4ef6\u4e0b\u7684\u957f\u8f7d\u6d41\u5b50\u5bff\u547d\uff0810\u500d\u4e8e\u65e0\u63ba\u6742\u7684\u9499\u949b\u77ff\u6750\u6599\uff09\u3002\u9495(II)\u79bb\u5b50\u76846s5d\u7535\u5b50\u8f68\u9053\u80fd\u7ea7\u901a\u8fc7\u7d2b\u5916\u5149\u7535\u5b50\u80fd\u8c31\u8868\u5f81\u548c\u5177\u6709\u975e\u5f39\u6027\u7535\u5b50\u96a7\u7a7f\u7279\u5f81\u7684\u5fae\u5206\u96a7\u7a7f\u7535\u5bfc\u56fe\u8c31\u5f97\u5230\u786e\u5b9a\uff0c\u56e0\u6b64\u9a8c\u8bc1\u4e86\u9499\u949b\u77ff\u5149\u7535\u5b50\u88ab\u9495(II)\u7535\u5b50\u8f68\u9053\u675f\u7f1a\u5e76\u4e0e4f\u81ea\u65cb\u7535\u5b50\u53d1\u751f\u4ea4\u6362\u4f5c\u7528\u7684\u57fa\u7840\u3002\u800c\u901a\u8fc7\u65bd\u52a0\u5916\u90e8\u78c1\u573a\uff0c\u6709\u65e0\u9495(II)\u79bb\u5b50\u63ba\u6742\u7684\u9499\u949b\u77ff\u5219\u5728\u4f4e\u6e29\u4e0b\u8868\u73b0\u51fa\u76f8\u8fd1\u7684\u8f7d\u6d41\u5b50\u5bff\u547d\uff0c\u56e0\u6b64\u8bc1\u660e\u4e86\u9495(II)\u4e2d\u81ea\u65cb\u7535\u5b50\u548c\u9499\u949b\u77ff\u6fc0\u5b50\u7684\u89e3\u8026\u5408\u6548\u5e94\u3002\u76f8\u5173\u7814\u7a76\u8bba\u6587\u4ee5\u201cLight-induced Kondo-like exciton-spin interaction in neodymium(II) doped hybrid perovskite\u201d\u4e3a\u9898\u53d1\u8868\u5728\u300a\u81ea\u7136\u00b7\u901a\u8baf\u300b\u4e0a\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u00a0\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u6781\u5927\u5ef6\u957f\u7684\u7535\u8377\u5206\u79bb\u6001\u4e3a\u901a\u8fc7\u5149\u8bf1\u5bfc\u7684\u9499\u949b\u77ff\u6fc0\u5b50\u548c\u9495(II)\u5c40\u57df4f 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<\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261584\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-12.png\" alt=\"\" width=\"1000\" height=\"926\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-12.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-12-300x278.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72471-12-768x711.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/> \u00a0<\/strong><\/p>\n<p><strong>\u56fe1 \u539f\u59cb\u548c\u9495(II)\u63ba\u6742\u6742\u5316\u9499\u949b\u77ff\u7684<\/strong><strong>\u6676\u4f53\u7ed3\u6784\u3001\u5143\u7d20\u5316\u5b66\u4ef7\u6001\u3001\u80fd\u7ea7\u548c\u7535\u5b50\u987a\u78c1\u5171\u632f\u56fe\u8c31\u8868\u5f81<\/strong><strong>\u00a0\u00a9 <\/strong>2024 Nature publishing group<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261585\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-12.png\" alt=\"\" width=\"1000\" height=\"1162\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-12.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-12-258x300.png 258w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-12-768x892.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72472-12-881x1024.png 881w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/strong><\/p>\n<p><strong>\u56fe2 \u00a0\u53d8\u6e29\u9759\u6001\u5149\u81f4\u53d1\u5149\u5f3a\u5ea6\u548c\u77ac\u6001\u8367\u5149\u5bff\u547d\u5728\u4e0d\u540cNd<\/strong><strong><sup>2+<\/sup><\/strong><strong>\u63ba\u6742\u6d53\u5ea6\/\u6fc0\u53d1\u5149\u5149\u5b50\u6570\u548c\u78c1\u573a\u4f5c\u7528\u4e0b\u7684\u53d8\u5316 \u00a0\u00a9 <\/strong>2024 Nature publishing group<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-261586\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-13.png\" alt=\"\" width=\"1000\" height=\"870\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-13.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-13-300x261.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/07\/\u56fe\u72473-13-768x668.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/strong><\/p>\n<p><strong>\u56fe3 \u00a0\u9495(II)\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u4e0d\u540c\u6837\u54c1\u533a\u57df\u4e0b\u7684<\/strong><strong>\u626b\u63cf\u96a7\u9053\u663e\u5fae\u56fe (a)\u3001\u7535\u6d41-\u7535\u538b\u56fe\u8c31 (b,d)\u3001\u5fae\u5206\u96a7\u7a7f\u7535\u5bfc (c,e)\u3001\u4e8c\u9636\u5fae\u5206\u96a7\u7a7f\u7535\u5bfc (f)<\/strong><strong>\u00a0\u00a9 <\/strong>2024 Nature publishing 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