{"id":261945,"date":"2024-08-13T06:23:14","date_gmt":"2024-08-12T22:23:14","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261945"},"modified":"2024-08-12T21:37:16","modified_gmt":"2024-08-12T13:37:16","slug":"%e5%8c%97%e4%ba%ac%e5%8c%96%e5%b7%a5%e5%a4%a7%e5%ad%a6small%ef%bc%9a%e5%88%a9%e7%94%a8%e6%b0%a2%e9%94%ae%e8%a7%a3%e7%a6%bb%e6%95%88%e5%ba%94%e5%92%8c%e5%a4%9a%e5%ad%94%e7%a2%b3%e7%ae%a1%e8%b4%9f","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261945","title":{"rendered":"\u5317\u4eac\u5316\u5de5\u5927\u5b66Small\uff1a\u5229\u7528\u6c22\u952e\u89e3\u79bb\u6548\u5e94\u548c\u591a\u5b54\u78b3\u7ba1\u8d1f\u8f7dCoNiFeP\u5f02\u8d28\u7ed3\u50ac\u5316\u5242\u5b9e\u73b0\u8d85\u9ad8\u950c\u7a7a\u4e8c\u6b21\u7535\u6c60\u80fd\u91cf\u6548\u7387"},"content":{"rendered":"

\u5f15\u8a00<\/span><\/b><\/p>\n

\u950c\u7a7a\u6c14\u7535\u6c60\u3001\u9502\u6c27\u7535\u6c60\u7b49\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u56e0\u5176\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u8d44\u6e90\u4e30\u5bcc\u548c\u73af\u5883\u53cb\u597d\u6027\uff0c\u88ab\u89c6\u4e3a\u7535\u52a8\u6c7d\u8f66\u548c\u53ef\u518d\u751f\u80fd\u6e90\u50a8\u5b58\u9886\u57df\u6781\u5177\u6f5c\u529b\u7684\u80fd\u6e90\u6280\u672f\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u7535\u6c60\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u9762\u4e34\u7740\u80fd\u91cf\u6548\u7387\u4f4e\u4e0b\u7684\u95ee\u9898\uff0c\u4e3b\u8981\u7531\u4e8e\u6c27\u6c14\u5206\u5b50\u8fd8\u539f\u548c\u6c34\u5206\u5b50\u6c27\u5316\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\uff0c\u5bfc\u81f4\u7535\u5316\u5b66\u6781\u5316\u73b0\u8c61\u4e25\u91cd\uff0c\u80fd\u91cf\u6548\u7387\u4ec5\u4e3a<\/span>55-71%<\/span>\u3002\u73b0\u6709\u5728\u50ac\u5316\u5242\u7684\u5f00\u53d1\u53ca\u5176\u7ed3\u6784\u529f\u80fd\u5173\u7cfb\u4e0a\u53d6\u5f97\u4e86\u5f88\u5927\u8fdb\u5c55\uff0c\u63ed\u793a\u4e86\u6d3b\u5316\u80fd\u548c\u6e29\u5ea6\u7684\u53d8\u5316\u5bf9\u6c34\u5206\u5b50\u8f6c\u5316\u901f\u7387\u7684\u5f71\u54cd\u89c4\u5f8b\u3002\u76ee\u524d\u6709\u5173\u8fc7\u6cb8\u70b9\u73af\u5883\u4e0b\u6c34\u5206\u5b50\u7279\u6b8a\u6d3b\u6027\u7684\u7814\u7a76\u5374\u9c9c\u6709\u62a5\u9053\uff0c\u672c\u7814\u7a76\u65e8\u5728\u63a2\u7d22\u4e00\u79cd\u65b0\u50ac\u5316\u5242\u548c\u8d85\u9ad8\u6e29\u7535\u89e3\u65b0\u7b56\u7565\uff0c\u6700\u5927\u7a0b\u5ea6\u63d0\u9ad8\u6c34\u5206\u5b50\u8f6c\u6362\u901f\u5ea6\uff0c\u4ee5\u63d0\u5347\u4e8c\u6b21\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u80fd\u91cf\u6548\u7387\u3002<\/span><\/p>\n

\u6210\u679c\u7b80\u4ecb<\/span><\/b><\/p>\n

\u8fd1\u671f\uff0c\u5317\u4eac\u5316\u5de5\u5927\u5b66\u6f58\u519b\u9752\u6559\u6388\u8bfe\u9898\u7ec4\u9488\u5bf9\u91d1\u5c5e\u7a7a\u6c14\u4e8c\u6b21\u7535\u6c60\u80fd\u91cf\u6548\u7387\u4f4e\u7b49\u95ee\u9898\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u50ac\u5316\u5242\u548c\u7535\u89e3\u8d28\u8054\u5408\u8bbe\u8ba1\u7b56\u7565\u3002\u6210\u529f\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e<\/span>MIL-68<\/span>\uff08<\/span>In<\/span>\uff09\u884d\u751f\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ba1\u652f\u6491\u7684<\/span>CoNiFeP<\/span>\u5f02\u8d28\u7ed3\u5408\u91d1\u50ac\u5316\u5242\uff0c\u5e76\u7ed3\u5408\u8fc7\u6cb8\u70b9\u7535\u89e3\u6db2\uff0c\u5b9e\u73b0\u4e86\u6c34\u5206\u5b50\u5728<\/span>125o<\/sup>C<\/span>\u65f6\u4e0b\u7684\u8d85\u9ad8\u901f\u6c27\u5316\uff0c\u53d6\u5f97\u4e86<\/span>110 mV@10 mA cm-2<\/sup><\/span>\u7684\u8d85\u4f4e\u8fc7\u7535\u4f4d\uff0c\u663e\u8457\u4f18\u4e8e\u5546\u4e1a<\/span>Ir\/C<\/span>\u50ac\u5316\u5242\uff0c\u4e5f\u4f18\u4e8e\u81ea\u8eab<\/span>25o<\/sup>C<\/span>\u4e0b<\/span>198 mV@10 mA cm-2<\/sup><\/span>\u7684\u8fc7\u7535\u4f4d\u3002<\/span><\/p>\n

\u7ed3\u6784\u8868\u5f81\u548c<\/span>DFT<\/span>\u8ba1\u7b97\u8868\u660e\uff0c\u50ac\u5316\u5242\u65b0\u7ed3\u6784\u5927\u5927\u964d\u4f4e\u4e86\u6c34\u6c27\u5316\u8fc7\u7a0b\u7684\u81ea\u7531\u80fd\u3002\u8fc7\u6cb8\u70b9\u5de5\u4f5c\u6761\u4ef6\u8fdb\u4e00\u6b65\u52a0\u901f\u4e86\u6c34\u5206\u5b50\u4e2d<\/span>O-H<\/span>\u548c\u6c34\u5206\u5b50\u95f4\u6c22\u952e\u7684\u89e3\u79bb\uff0c\u4ee5\u53ca\u751f\u6210\u7684<\/span>O2<\/sub><\/span>\u5206\u5b50\u7684\u91ca\u653e\u3002\u6d4b\u8bd5\u8868\u660e\uff0c\u7ec4\u88c5\u7684\u950c\u7a7a\u6c14\u7535\u6c60\u968f\u7740\u6e29\u5ea6\u7684\u9010\u6e10\u5347\u9ad8\uff0c\u80fd\u91cf\u6548\u7387\u5728<\/span>50o<\/sup>C<\/span>\u65f6\u51fa\u73b0\u7b2c\u4e00\u6b21\u98de\u8dc3\uff0c\u5728<\/span>85o<\/sup>C<\/span>\u65f6\u8d8b\u4e8e\u7a33\u5b9a\u3002\u5f53\u6e29\u5ea6\u7ee7\u7eed\u5347\u9ad8\u65f6\uff0c\u5728<\/span>100o<\/sup>C<\/span>\u53d1\u751f\u7b2c\u4e8c\u6b21\u98de\u8dc3\uff0c\u5e76\u5728<\/span>125o<\/sup>C<\/span>\u8fbe\u5230<\/span>88.1%<\/span>\u80fd\u91cf\u6548\u7387\u3002\u65b0\u50ac\u5316\u5242\u5728\u8d85\u9ad8\u6e29\u7535\u89e3\u6db2\u73af\u5883\u4e0b\u7ecf\u8fc7<\/span>150<\/span>\u6b21\u5faa\u73af\u540e\u5177\u6709<\/span>0.0068%<\/span>\u7684\u6781\u4f4e\u8870\u51cf\u7387\uff0c\u8868\u660e\u5177\u6709\u7a81\u51fa\u7684\u7a33\u5b9a\u6027\u548c\u8010\u8150\u8680\u6027\u3002\u8fd9\u4e00\u7814\u7a76\u4e3a\u6784\u5efa\u66f4\u9ad8\u80fd\u91cf\u6548\u7387\u7684\u4e8c\u6b21\u71c3\u6599\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u8bbe\u8ba1\u601d\u8def\uff0c\u5e76\u91cd\u65b0\u5ba1\u89c6\u7535\u6c60\u7684\u6700\u4f73\u5de5\u4f5c\u6e29\u5ea6\u3002\u76f8\u5173\u6210\u679c\u4ee5\u6807\u9898\u4e3a\u201c<\/span>Ultrafast conversion of water and oxygen molecules with dissociation of hydrogen bonding effect to achieve extra-high energy efficiency of secondary metal-air batteries<\/span>\u201d\u53d1\u8868\u5728<\/span>Small<\/span>\uff08<\/span>DOI<\/span>\uff1a<\/span>10.1002\/smll.202405441<\/span>\uff09\u3002\u8bfe\u9898\u7ec4\u5b8b\u91d1\u7984\u7855\u58eb\u751f\u4e3a\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u3002<\/span><\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/span><\/b><\/b><\/p>\n

\"\"<\/p>\n

\u56fe<\/span><\/b>1.<\/span><\/b>\uff08<\/span>a<\/span>\uff09\u6e29\u5ea6\u53d8\u5316\u5bf9\u6c34\u5206\u5b50\u89e3\u79bb\u7684\u5f71\u54cd\u793a\u610f\u56fe\u3002<\/span>\uff08<\/span>b<\/span>\uff09<\/span>PNCNT@CoNiFeP<\/span>\u5408\u6210\u793a\u610f\u56fe\u3002\uff08<\/span>c<\/span>\uff09<\/span>Fe2<\/sub>P<\/span>\uff0c\uff08<\/span>d<\/span>\uff09<\/span>Ni2<\/sub>P<\/span>\uff0c\uff08<\/span>e<\/span>\uff09<\/span>NiCoP<\/span>\u5728<\/span>PNCNT<\/span>\u4e0a\u7684\u7535\u8377\u5bc6\u5ea6\u5206\u5e03\u3002\uff08<\/span>f<\/span>\uff09<\/span>Fe2<\/sub>P<\/span>\uff0c\uff08<\/span>g<\/span>\uff09<\/span>Ni2<\/sub>P<\/span>\uff0c\uff08<\/span>h<\/span>\uff09<\/span>NiCoP<\/span>\u5355\u72ec\u8d1f\u8f7d\u5728<\/span>PNCNT<\/span>\u4e0a\u7684\u6001\u5bc6\u5ea6\u6bd4\u8f83\u3002<\/span><\/p>\n

\u901a\u8fc7\u6c34\u70ed\u6cd5\u5236\u5907\u4e86<\/span>MIL-68<\/span>\uff08<\/span>In<\/span>\uff09\u884d\u751f\u7684\u4e2d\u7a7a\u591a\u5b54\u78b3\u7eb3\u7c73\u68d2\uff0c\u5e76\u8fdb\u4e00\u6b65\u8f6c\u5316\u4e3a<\/span>N<\/span>\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1\uff08<\/span>PNCNT<\/span>\uff09\u3002\u5728\u6b64\u7ed3\u6784\u4e0a\uff0c\u901a\u8fc7\u4e00\u7cfb\u5217\u5316\u5b66\u8fc7\u7a0b\u8d1f\u8f7d\u4e86<\/span>Fe2<\/sub>P<\/span>\u3001<\/span>Ni2<\/sub>P<\/span>\u548c<\/span>NiCoP<\/span>\u5f02\u8d28\u7ed3\u5408\u91d1\uff0c\u5f62\u6210\u4e86\u5177\u6709\u9ad8\u6d3b\u6027\u4f4d\u70b9\u7684\u50ac\u5316\u5242\u3002\u5728\u8fc7\u6cb8\u70b9\u7684\u6761\u4ef6\u4e0b\uff0c\u8fd9\u79cd\u50ac\u5316\u5242\u80fd\u591f\u663e\u8457\u964d\u4f4e\u6c34\u6c27\u5316\u8fc7\u7a0b\u7684\u81ea\u7531\u80fd\uff0c\u52a0\u901f<\/span>O-H<\/span>\u952e\u548c\u6c22\u952e\u7684\u89e3\u79bb\uff0c\u4fc3\u8fdb<\/span>O2<\/sub><\/span>\u5206\u5b50\u7684\u91ca\u653e\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08<\/span>DFT<\/span>\uff09\u8ba1\u7b97\u8bc1\u5b9e\uff0c\u7eb3\u7c73\u9897\u7c92\u4e0e<\/span>PNCNT<\/span>\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u589e\u5f3a\u4e86\u7535\u5b50\u4f20\u9012\u6027\u80fd\uff0c\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u7684\u7a33\u5b9a\u6027\u548c\u6548\u7387\u3002\u8fd9\u79cd\u8bbe\u8ba1\u4e0d\u4ec5\u907f\u514d\u4e86\u7eb3\u7c73\u9897\u7c92\u56e2\u805a\u5bfc\u81f4\u7684\u6bd4\u8868\u9762\u79ef\u66b4\u9732\u4e0d\u8db3\u548c\u6027\u80fd\u4e0b\u964d\u95ee\u9898\uff0c\u800c\u4e14\u4e3a\u6784\u5efa\u9ad8\u6548\u80fd\u7684\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u601d\u8def\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/span><\/b>2.<\/span><\/b>\uff08<\/span>a<\/span>\uff09<\/span>PNCNT<\/span>\u7684<\/span>SEM<\/span>\u56fe\u50cf\uff0c\uff08<\/span>b<\/span>\uff09<\/span>PNCNT@ZIF-67<\/span>\u7684<\/span>SEM<\/span>\u56fe\u50cf\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u7684\uff08<\/span>c<\/span>\uff09<\/span>TEM<\/span>\u56fe\u50cf\uff0c\uff08<\/span>d, e<\/span>\uff09<\/span>HR-TEM<\/span>\u56fe\u50cf\uff0c\uff08<\/span>f<\/span>\uff09<\/span>SAED<\/span>\u56fe\uff0c\uff08<\/span>g<\/span>\uff09<\/span>Co<\/span>\uff0c<\/span>Ni<\/span>\uff0c<\/span>Fe<\/span>\u548c<\/span>P<\/span>\u7684\u5143\u7d20\u6620\u5c04\u56fe\u50cf\u3002<\/span><\/p>\n

\u626b\u63cf\u7535\u955c\uff08<\/span>SEM<\/span>\uff09\u56fe\u50cf\u663e\u793a\uff0c<\/span>PNCNT<\/span>\u5177\u6709\u4e2d\u7a7a\u591a\u5b54\u7ed3\u6784\u3002<\/span>ZIF-67<\/span>\u5728<\/span>PNCNT<\/span>\u4e0a\u5747\u5300\u5206\u5e03\uff0c\u5f62\u6210\u83f1\u5f62\u6676\u4f53\uff0c\u5c3a\u5bf8\u7ea6<\/span>200 nm<\/span>\uff0c<\/span>XRD<\/span>\u56fe\u50cf\u4e5f\u8bc1\u5b9e\u4e86\u8fd9\u4e00\u70b9\u3002\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08<\/span>TEM<\/span>\uff09\u56fe\u50cf\u63ed\u793a\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u7684\u4e2d\u7a7a\u7ed3\u6784\u548c\u8868\u9762\u5bc6\u96c6\u6392\u5217\u7684\u7eb3\u7c73\u9897\u7c92\uff0c\u76f4\u5f84<\/span>15-20 nm<\/span>\uff0c\u6838\u5fc3\u4e3a\u91d1\u5c5e\u78f7\u5316\u7269\uff0c\u5916\u58f3\u4e3a\u8d85\u8584\u77f3\u58a8\u5316\u78b3\u5c42\uff0c\u6709\u52a9\u4e8e\u4fdd\u62a4\u7eb3\u7c73\u9897\u7c92\u5728\u9ad8\u6e29\u7535\u50ac\u5316\u8fc7\u7a0b\u4e2d\u4e0d\u88ab\u6c27\u5316\u3002<\/span>HRTEM<\/span>\u3001<\/span>SAED<\/span>\u548c\u6676\u683c\u95f4\u8ddd\u56fe\u8fdb\u4e00\u6b65\u63cf\u8ff0\u4e86\u7eb3\u7c73\u9897\u7c92\u7684\u7ed3\u6784\uff0c\u800c<\/span>Mapping<\/span>\u56fe\u5c55\u793a\u4e86\u5143\u7d20\u5728\u50ac\u5316\u5242\u4e2d\u7684\u5747\u5300\u5206\u5e03\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/span>3.<\/span>\uff08<\/span>a<\/span>\uff09<\/span>PNCNT@CoNiP<\/span>\u3001<\/span>PNCNT@CoFeP<\/span>\u548c<\/span>PNCNT@CoNiFeP<\/span>\u7684<\/span>XRD<\/span>\u56fe\u50cf\u3002\uff08<\/span>b<\/span>\uff09<\/span>P 2p<\/span>\uff0c\uff08<\/span>c<\/span>\uff09<\/span>Co 2p<\/span>\uff0c\uff08<\/span>d<\/span>\uff09<\/span>Ni 2p<\/span>\u548c\uff08<\/span>e<\/span>\uff09<\/span>Fe 2p<\/span>\u7684<\/span>XPS<\/span>\u56fe\u50cf\u3002<\/span><\/p>\n

X<\/span>\u5c04\u7ebf\u884d\u5c04\uff08<\/span>XRD<\/span>\uff09\u5206\u6790\u63ed\u793a\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u5176\u4e2d\u8bc6\u522b\u51fa\u591a\u4e2a\u6676\u683c\u95f4\u8ddd\uff0c\u5206\u522b\u5bf9\u5e94\u4e8e<\/span>Ni2<\/sub>P<\/span>\u3001<\/span>Fe2<\/sub>P<\/span>\u548c<\/span>NiCoP<\/span>\u7684\u4e0d\u540c\u6676\u9762\uff0c\u8fd9\u8868\u660e\u50ac\u5316\u5242\u4e2d\u5b58\u5728\u591a\u79cd\u91d1\u5c5e\u78f7\u5316\u7269\u76f8\uff0c\u5e76\u4e14\u5b83\u4eec\u5728<\/span>PNCNT<\/span>\u4e0a\u5f62\u6210\u4e86\u975e\u5747\u8d28\u7684\u754c\u9762\u3002\u8fd9\u4e9b\u754c\u9762\u6709\u5229\u4e8e\u4f18\u5316\u7535\u5b50\u7ed3\u6784\uff0c\u4ece\u800c\u4fc3\u8fdb\u6c27\u8fd8\u539f\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u5438\u9644\u548c\u89e3\u5438\u8fc7\u7a0b\u3002<\/span><\/p>\n

X<\/span>\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08<\/span>XPS<\/span>\uff09\u7684\u8fdb\u4e00\u6b65\u5206\u6790\u63d0\u4f9b\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u7684\u5316\u5b66\u7ec4\u6210\u548c\u5143\u7d20\u4ef7\u6001\u7684\u8be6\u7ec6\u4fe1\u606f\u3002\u5728<\/span>P2p<\/span>\u8c31\u4e2d\u89c2\u5bdf\u5230\u7684\u5cf0\u8868\u660e\u4e86<\/span>P-M<\/span>\u952e\u7684\u5f62\u6210\uff0c\u5e76\u4e14\u7531\u4e8e\u7a7a\u6c14\u66b4\u9732\u5bfc\u81f4\u7684\u78f7\u9178\u76d0\u6c27\u5316\u7269\uff08<\/span>PO<\/span>\uff09\u7684\u5b58\u5728\u3002<\/span>Co 2p<\/span>\u548c<\/span>Ni 2p<\/span>\u5149\u8c31\u663e\u793a\u7684\u7ed3\u5408\u80fd\u6b63\u4f4d\u79fb\u8868\u660e\uff0c\u5728<\/span>PNCNT@CoNiFeP<\/span>\u5f02\u8d28\u7ed3\u6784\u4e2d\uff0c<\/span>Co-P<\/span>\u548c<\/span>Ni-P<\/span>\u952e\u7684\u7535\u5b50\u73af\u5883\u4e0e\u5355\u4e00\u91d1\u5c5e\u78f7\u5316\u7269\u76f8\u6bd4\u53d1\u751f\u4e86\u53d8\u5316\uff0c\u8fd9\u53ef\u80fd\u662f\u7531\u4e8e\u91d1\u5c5e\u539f\u5b50\u4e4b\u95f4\u7684\u7535\u5b50\u8f6c\u79fb\u548c\u76f8\u4e92\u4f5c\u7528\u3002\u540c\u6837\uff0c<\/span>Fe 2p<\/span>\u5149\u8c31\u4e2d\u7684\u7ed3\u5408\u80fd\u6b63\u504f\u79fb\u4e5f\u53cd\u6620\u4e86<\/span>Fe-P<\/span>\u952e\u5728<\/span>PNCNT@CoNiFeP<\/span>\u4e2d\u7684\u4e0d\u540c\u5316\u5b66\u72b6\u6001\u3002\u8fd9\u4e9b\u7ed3\u5408\u80fd\u7684\u53d8\u5316\u63ed\u793a\u4e86<\/span>Co<\/span>\u3001<\/span>Ni<\/span>\u3001<\/span>Fe<\/span>\u548c<\/span>P<\/span>\u5143\u7d20\u5728\u50ac\u5316\u5242\u4e2d\u7684\u4e0d\u540c\u5316\u5b66\u72b6\u6001\uff0c\u5e76\u4e14\u8868\u660e\u5728<\/span>PNCNT<\/span>\u4e0e<\/span>CoNiFeP<\/span>\u4e4b\u95f4\u7684\u7d27\u5bc6\u63a5\u89e6\u5f02\u8d28\u754c\u9762\u4e2d\u53d1\u751f\u4e86\u663e\u8457\u7684\u7535\u5b50\u8f6c\u79fb\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u4e2d\u91d1\u5c5e\u4e0e\u78f7\u4e4b\u95f4\u7684\u914d\u4f4d\u8fde\u63a5\u5728\u5f02\u8d28\u7ed3\u6784\u4e2d\u53d8\u5f97\u66f4\u5f3a\uff0c\u8fd9\u4e0d\u4ec5\u589e\u5f3a\u4e86\u6750\u6599\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u63d0\u9ad8\u4e86\u5176\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u79cd\u589e\u5f3a\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u5bf9\u4e8e\u63d0\u9ad8\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u80fd\u91cf\u6548\u7387\u81f3\u5173\u91cd\u8981\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/span><\/b>4.<\/span><\/b>\uff08<\/span>a<\/span>\uff09<\/span>LSV<\/span>\u66f2\u7ebf\uff0c\uff08<\/span>b<\/span>\uff09<\/span>6 M KOH<\/span>\u6761\u4ef6\u4e0b<\/span>PNCNT@CoNiFeP<\/span>\u548c<\/span>Ir\/C<\/span>\u5728<\/span>25o<\/sup>C<\/span>\u548c<\/span>125o<\/sup>C<\/span>\u65f6\u5bf9\u5e94\u7684<\/span>Tafel<\/span>\u66f2\u7ebf\u3002\uff08<\/span>c<\/span>\uff09<\/span>PNCNT@CoNiFeP<\/span>\u7684<\/span>OER<\/span>\u81ea\u7531\u80fd\u56fe\u3002\uff08<\/span>d<\/span>\uff09\u901a\u8fc7<\/span>Butler-Volmer<\/span>\u5f97\u5230\u7684\u52a8\u6001\u7535\u6d41\u5bc6\u5ea6\uff08<\/span>jk<\/sub><\/span>\uff09\u7684<\/span>Tafel<\/span>\u56fe\uff0c\uff08<\/span>e<\/span>\uff09\u5728<\/span>6 M KOH<\/span>\u4e2d<\/span>25o<\/sup>C<\/span>\u548c<\/span>125o<\/sup>C<\/span>\u65f6<\/span>PNCNT@CoNiFeP<\/span>\u548c<\/span>Ir\/C<\/span>\u7684<\/span>jk<\/sub><\/span>\u6bd4\u8f83\u3002<\/span>\uff08<\/span>f<\/span>\uff09<\/span>PNCNT@CoNiFeP<\/span>\u7684<\/span>OER<\/span>\u8fc7\u7a0b\u7684<\/span>4e–<\/sup><\/span>\u673a\u5236\u3002\uff08<\/span>g<\/span>\uff09<\/span>PNCNT@CoNiFeP<\/span>\u548c<\/span>Ir\/C<\/span>\u7684\u53cd\u5e94\u6d3b\u5316\u80fd\u6bd4\u8f83\u3002\uff08<\/span>h<\/span>\uff09<\/span>10 mA cm-2<\/sup><\/span>\u548c\uff08<\/span>i<\/span>\uff09<\/span>1 A cm-2<\/sup><\/span>\u4e0b<\/span>PNCNT@CoNiFeP<\/span>\u548c<\/span>Ir\/C<\/span>\u7684<\/span>OER<\/span>\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\uff08<\/span>f<\/span>\uff09\u8fc7\u7535\u4f4d\u4e0e\u5176\u4ed6\u6587\u732e\u7684\u6bd4\u8f83\u3002<\/span><\/p>\n

\u56fe<\/span>4<\/span>\u5c55\u793a\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u6790\u6c27\u53cd\u5e94\uff08<\/span>OER<\/span>\uff09\u6027\u80fd\u3002\u5728<\/span>25o<\/sup>C<\/span>\u4e0b\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u5177\u6709\u6700\u4f4e\u7684\u8fc7\u7535\u4f4d\uff08<\/span>194 mV<\/span>\uff09\u548c\u6700\u5c0f\u7684<\/span>Tafel<\/span>\u659c\u7387\uff08<\/span>58.42 mV dec-1<\/sup><\/span>\uff09\uff0c\u4f18\u4e8e\u5176\u4ed6\u50ac\u5316\u5242\u3002\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\u81f3<\/span>125o<\/sup>C<\/span>\uff0c\u8fc7\u7535\u4f4d\u8fdb\u4e00\u6b65\u964d\u4f4e\u81f3<\/span>110 mV<\/span>\uff0c\u8fdc\u4f4e\u4e8e\u5546\u4e1a<\/span>Ir\/C<\/span>\u50ac\u5316\u5242\u3002\u5373\u4f7f\u5728<\/span>100 mA cm-2<\/sup><\/span>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b<\/span>\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u4ecd\u4fdd\u6301\u4f4e\u8fc7\u7535\u4f4d<\/span>\uff08<\/span>187 mV<\/span>\uff09<\/span>\u3002<\/span>DFT<\/span>\u8ba1\u7b97\u8868\u660e\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u4e2d\u7684<\/span>Co<\/span>\u4f4d\u70b9\u662f<\/span>OER<\/span>\u8fc7\u7a0b\u4e2d\u7684\u4f18\u5148\u6d3b\u6027\u4f4d\u70b9\u3002\u901a\u8fc7<\/span>Koutecky-Levich<\/span>\u65b9\u7a0b\u8ba1\u7b97\u5f97\u5230\u7684\u52a8\u529b\u7535\u6d41\u5bc6\u5ea6\uff08<\/span>jk<\/sub><\/span>\uff09\u548c<\/span>Butler-Volmer<\/span>\u65b9\u7a0b\u8ba1\u7b97\u5f97\u5230\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\uff08<\/span>j0<\/sub><\/span>\uff09\u5747\u663e\u793a\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u5728<\/span>125o<\/sup>C<\/span>\u4e0b\u7684\u52a8\u529b\u5b66\u6027\u80fd\u4f18\u4e8e<\/span>Ir\/C<\/span>\u3002\u6b64\u5916\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u7684\u6d3b\u5316\u80fd\uff08<\/span>Ea<\/sub><\/span>\uff09\u4e3a<\/span>11.52 kJ mol-1<\/sup><\/span>\uff0c\u4f4e\u4e8e<\/span>Ir\/C<\/span>\u7684<\/span>12.71 kJ mol-1<\/sup><\/span>\uff0c\u8868\u660e\u5176\u5177\u6709\u66f4\u4f4e\u7684\u52a8\u529b\u5b66\u52bf\u5792\uff0c\u80fd\u591f\u5b9e\u73b0\u66f4\u5feb\u7684\u53cd\u5e94\u901f\u7387\u3002<\/span>Ir\/C<\/span>\u548c<\/span>PNCNT@CoNiFeP<\/span>\u7535\u6781\u6750\u6599\u5728<\/span>1 A cm-2<\/sup><\/span>\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd\u663e\u793a\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u5728\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4ecd\u80fd\u6b63\u5e38\u5de5\u4f5c\uff0c\u5e76\u4e14\u6bd4<\/span>Ir\/C<\/span>\u5177\u6709\u66f4\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8bc1\u5b9e\u4e86\u5176\u5b9e\u9645\u5e94\u7528\u4ef7\u503c\u3002\u6700\u540e\u603b\u7ed3\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u548c\u5176\u4ed6\u50ac\u5316\u5242\u7684\u8fc7\u7535\u4f4d\uff0c\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u5728<\/span>OER<\/span>\u50ac\u5316\u6d3b\u6027\u65b9\u9762\u7684\u4f18\u5f02\u8868\u73b0\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/span><\/b>5.<\/span><\/b>\uff08<\/span>a<\/span>\uff09<\/span>6 M KOH+0.35 M ZnO<\/span>\u7535\u89e3\u6db2\u5728\u5e38\u538b\u548c\u5c01\u95ed\u72b6\u6001\u4e0b\u7684\u5b9e\u7269\u56fe\u3002\uff08<\/span>b<\/span>\uff09\u4e0d\u540c\u6e29\u5ea6\u4e0b<\/span>ZABs<\/span>\u5728<\/span>1 mA cm-2<\/sup><\/span>\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002\uff08<\/span>c<\/span>\uff09<\/span>ZABs<\/span>\u7684\u80fd\u91cf\u6548\u7387\u968f\u6e29\u5ea6\u53d8\u5316\u8d8b\u52bf\u3002\uff08<\/span>d<\/span>\uff09<\/span>125o<\/sup>C<\/span>\u4e0b<\/span>ZABs<\/span>\u5728<\/span>1 mA cm-2<\/sup><\/span>\u4e0b\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\u3002\uff08<\/span>e<\/span>\uff09<\/span>ZAB<\/span>\u5728<\/span>25<\/span>\u2103\u548c<\/span>125<\/span>\u2103\u65f6\u7684<\/span>EIS<\/span>\u66f2\u7ebf\u3002\uff08<\/span>f<\/span>\uff09\u80fd\u91cf\u6548\u7387\u4e0e\u5176\u4ed6\u6587\u732e\u7684\u6bd4\u8f83\u3002<\/span><\/p>\n

\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u968f\u7740\u6e29\u5ea6\u9010\u6e10\u5347\u9ad8\uff0c<\/span>ZABs<\/span>\u7684\u80fd\u91cf\u6548\u7387\u5728<\/span>50o<\/sup>C<\/span>\u65f6\u9996\u6b21\u663e\u8457\u63d0\u5347\u5e76\u7a33\u5b9a\u5728<\/span>85o<\/sup>C<\/span>\u3002\u5f53\u6e29\u5ea6\u7ee7\u7eed\u5347\u9ad8\u65f6\uff0c\u5728<\/span>100o<\/sup>C<\/span>\u65f6\u53d1\u751f\u7b2c\u4e8c\u6b21\u8dc3\u5347\u3002\u5f53\u6e29\u5ea6\u8fbe\u5230<\/span>125o<\/sup>C<\/span>\u65f6\uff0c\u7535\u538b\u95f4\u9699\u964d\u81f3\u6781\u4f4e<\/span>0.194 V<\/span>\uff0c\u80fd\u91cf\u6548\u7387\u8fbe\u5230\u6700\u9ad8<\/span>88.1%<\/span>\u3002\u540c\u65f6\uff0c\u5728<\/span>100 mA cm-2<\/sup><\/span>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u80fd\u91cf\u6548\u7387\u4ecd\u9ad8\u8fbe<\/span>62.7%<\/span>\u3002\u7ecf\u8fc7<\/span>150<\/span>\u6b21\u5faa\u73af\uff0c\u8870\u51cf\u7387\u4ec5\u4e3a<\/span>0.0068%<\/span>\uff0c\u4e14\u80fd\u91cf\u6548\u7387\u4ecd\u9ad8\u8fbe<\/span>87.2%<\/span>\uff0c\u663e\u8457\u9ad8\u4e8e\u6700\u8fd1\u62a5\u9053\u7684<\/span>ZABs<\/span>\u3002<\/span>EIS<\/span>\u66f2\u7ebf\u663e\u793a\u4e86\u7535\u5316\u5b66\u8f6c\u79fb\u963b\u6297\u7684\u964d\u4f4e\uff0c<\/span>ZABs<\/span>\u5728\u9ad8\u6e29\u4e0b\u7684\u5faa\u73af\u80fd\u529b\u4e5f\u4f18\u4e8e<\/span>Ir\/C<\/span>\u3002<\/span>PNCNT@CoNiFeP<\/span>\u652f\u6301\u7684<\/span>ZABs<\/span>\u5728<\/span>20 mA cm-2<\/sup><\/span>\u4e0b\u6bd4\u5546\u4e1a<\/span>Ir\/C<\/span>\u652f\u6301\u7684<\/span>ZABs<\/span>\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\u6548\u7387\uff0c\u5e76\u5728<\/span>10 mA cm-2<\/sup><\/span>\u548c<\/span>5 mA cm-2<\/sup><\/span>\u4e0b\u8868\u73b0\u51fa\u51fa\u8272\u7684\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u8003\u8651\u5e76\u8ba1\u7b97\u4e86<\/span>125o<\/sup>C<\/span>\u65f6\u7684\u80fd\u8017\uff0c\u7ed3\u679c\u8868\u660e\uff1a<\/span>25o<\/sup>C<\/span>\u65f6\u5206\u89e3<\/span>1 mol Zn2+<\/sup><\/span>\u6240\u9700\u80fd\u91cf\u4e3a<\/span>351.26 kJ, 125o<\/sup>C<\/span>\u65f6\u5206\u89e3\u80fd\u91cf\u4e3a<\/span>312.66 kJ<\/span>\uff0c\u52a0\u70ed\u80fd\u91cf\u4e3a<\/span>3.38 kJ<\/span>\uff0c\u5171<\/span>316.04 kJ<\/span>\uff0c\u5c0f\u4e8e<\/span>25o<\/sup>C<\/span>\u65f6\u7684\u80fd\u8017\u3002<\/span><\/p>\n

\"\"<\/p>\n

\u56fe<\/span><\/b>6.<\/span><\/b> 25o<\/sup>C<\/span>\u5faa\u73af\u540e<\/span>PNCNT@CoNiFeP<\/span>\u7684\uff08<\/span>a<\/span>\uff09<\/span>TEM<\/span>\uff0c\uff08<\/span>b<\/span>\uff09<\/span>HR-TEM<\/span>\uff0c\u548c\uff08<\/span>c<\/span>\uff09<\/span>EDS<\/span>\u5206\u6790\u3002<\/span>125o<\/sup>C<\/span>\u5faa\u73af\u540e<\/span>PNCNT@CoNiFeP<\/span>\u7684\uff08<\/span>d<\/span>\uff09<\/span>TEM<\/span>\uff0c\uff08<\/span>e<\/span>\uff09<\/span>HR-TEM<\/span>\uff0c\u548c\uff08<\/span>f<\/span>\uff09<\/span>EDS<\/span>\u5206\u6790\u3002\uff08<\/span>g<\/span>\uff09<\/span>O 1s<\/span>\uff0c\uff08<\/span>h<\/span>\uff09<\/span>Co 2p<\/span>\uff0c\uff08<\/span>i<\/span>\uff09<\/span>Ni 2p<\/span>\uff0c\uff08<\/span>j<\/span>\uff09<\/span>Fe 2p<\/span>\u5728\u521d\u59cb\u3001<\/span>25o<\/sup>C<\/span>\u5faa\u73af\u548c<\/span>125o<\/sup>C<\/span>\u5faa\u73af\u540e\u7684<\/span>XPS<\/span>\u5149\u8c31\u3002<\/span><\/p>\n

\u56fe<\/span>6<\/span>\u5c55\u793a\u4e86<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u7684\u7a33\u5b9a\u6027\u7814\u7a76\u3002\u5728<\/span>25o<\/sup>C<\/span>\u548c<\/span>125o<\/sup>C<\/span>\u4e0b\u5206\u522b\u8fdb\u884c<\/span>300<\/span>\u5c0f\u65f6\u7684\u5faa\u73af\u6d4b\u8bd5\u540e\uff0c<\/span>TEM<\/span>\u548c<\/span>Mapping<\/span>\u56fe\u50cf\u663e\u793a\u50ac\u5316\u5242\u4fdd\u6301\u4e86\u539f\u59cb\u7684\u516d\u68f1\u67f1\u7ed3\u6784\u548c\u5747\u5300\u7684\u5143\u7d20\u5206\u5e03\uff0c\u8868\u9762\u7eb3\u7c73\u9897\u7c92\u672a\u53d1\u751f\u56e2\u805a\u3002\u5728<\/span>125o<\/sup>C<\/span>\u5faa\u73af\u540e\uff0c\u8868\u9762\u7eb3\u7c73\u9897\u7c92\u66b4\u9732\u51fa\u66f4\u591a\u7684<\/span>Co<\/span>\u4f4d\u70b9\uff0c\u5982<\/span>NiCoP<\/span>\u3001<\/span>Co2<\/sub>P<\/span>\u7b49\uff0c\u8fd9\u53ef\u80fd\u4e0e<\/span>OER<\/span>\u8fc7\u7a0b\u7684\u9ad8\u6e29\u91cd\u6784\u6709\u5173\uff0c\u5bfc\u81f4\u66f4\u591a\u7684<\/span>Co<\/span>\u4f4d\u70b9\u66b4\u9732\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684<\/span>OER<\/span>\u6d3b\u6027\u3002\u6b64\u5916\uff0c<\/span>EDS<\/span>\u6570\u636e\u8868\u660e\uff0c<\/span>125o<\/sup>C<\/span>\u5faa\u73af\u540e\u7684\u50ac\u5316\u5242\u8868\u9762<\/span>O<\/span>\u542b\u91cf\u4f4e\u4e8e<\/span>25o<\/sup>C<\/span>\u5faa\u73af\u7684\u50ac\u5316\u5242\uff0c<\/span>XPS<\/span>\u5149\u8c31\u5f3a\u5ea6\u4e5f\u95f4\u63a5\u8bc1\u660e\u4e86\u9ad8\u6e29\u66b4\u9732\u4e86\u50ac\u5316\u5242\u8868\u9762\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u964d\u4f4e\u4e86\u53cd\u5e94\u52bf\u5792\uff0c\u52a0\u901f\u4e86<\/span>O<\/span>\u539f\u5b50\u7684\u89e3\u5438\u8fc7\u7a0b\u3002<\/span>XPS<\/span>\u5149\u8c31\u8fd8\u663e\u793a\uff0c\u5faa\u73af\u540e<\/span>Co<\/span>\u3001<\/span>Ni<\/span>\u548c<\/span>Fe<\/span>\u5143\u7d20\u7684\u7ed3\u5408\u80fd\u5411\u8d1f\u65b9\u5411\u79fb\u52a8\uff0c\u8868\u660e\u7535\u5b50\u4ece\u91d1\u5c5e\u5143\u7d20\u8f6c\u79fb\u5230<\/span>P<\/span>\u5143\u7d20\uff0c\u589e\u5f3a\u4e86\u91d1\u5c5e\u79bb\u5b50\u7684\u6b63\u7535\u8377\uff0c\u4ece\u800c\u66f4\u6709\u6548\u5730\u5438\u9644\u6c27\u4e2d\u95f4\u4f53\uff0c\u4fc3\u8fdb<\/span>OER<\/span>\u53cd\u5e94\u3002\u8fd9\u4e9b\u7ed3\u679c\u5171\u540c\u8868\u660e\uff0c<\/span>PNCNT@CoNiFeP<\/span>\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u4fdd\u6301\u4e86\u826f\u597d\u7684\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\uff0c\u4e3a\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u53ef\u9760\u7684\u6750\u6599\u57fa\u7840\u3002<\/span><\/p>\n

\u603b\u7ed3<\/span><\/b><\/p>\n

\u672c\u6587\u63d0\u51fa<\/span>MIL-68<\/span>\uff08<\/span>In<\/span>\uff09\u884d\u751f\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u7ba1\u8d1f\u8f7d<\/span>CoNiFeP<\/span>\u5f02\u8d28\u5171\u8f6d\u5408\u91d1\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u3001\u9ad8\u6548\u7684<\/span>OER<\/span>\u50ac\u5316\u5242\uff0c\u5728\u8fc7\u6cb8\u70b9\u5904\u6784\u5efa\u5177\u6709\u8d85\u9ad8\u80fd\u6548\u548c\u8010\u4e45\u6027\u7684\u65b0\u578b<\/span>ZABs<\/span>\u3002\u6d4b\u8bd5\u548c<\/span>DFT<\/span>\u8ba1\u7b97\u8bc1\u5b9e\uff0c\u8be5\u50ac\u5316\u5242\u5728\u5ba4\u6e29\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684<\/span>194 mV@10 mA cm-2<\/sup><\/span>\u8fc7\u7535\u4f4d\uff0c\u5728<\/span>125o<\/sup>C<\/span>\u4e0b\u8868\u73b0\u51fa<\/span>110 mV@10 mA cm-2<\/sup><\/span>\u7684\u8d85\u4f4e\u8fc7\u7535\u4f4d\u3002\u7ed3\u679c\u8868\u660e\uff0c\u9ad8\u6e29\u6709\u5229\u4e8e<\/span>O<\/span>\u539f\u5b50\u7684\u8131\u9644\u3001<\/span>O-H<\/span>\u548c\u6c22\u952e\u7684\u89e3\u79bb\u4ee5\u53ca\u50ac\u5316\u5242\u4e0a\u6d3b\u6027\u4f4d\u70b9\u7684\u66b4\u9732\uff0c\u4ece\u800c\u663e\u8457\u63d0\u9ad8\u4e86\u50ac\u5316\u5242\u7684<\/span>OER<\/span>\u6027\u80fd\u3002\u7ed3\u5408\u65b0\u578b\u50ac\u5316\u5242\u548c\u8fc7\u6cb8\u70b9\u7535\u89e3\u8d28\u7684\u8d21\u732e\uff0c\u7ec4\u88c5\u7684<\/span>ZABs<\/span>\u5728<\/span>150<\/span>\u6b21\u5faa\u73af\u540e\u5b9e\u73b0\u4e86\u9ad8\u8fbe<\/span>88.1%<\/span>\u7684\u8d85\u9ad8\u80fd\u91cf\u6548\u7387\u548c<\/span>0.194V<\/span>\u7684\u8d85\u7a84\u5145\u653e\u7535\u7535\u538b\u95f4\u9699\uff0c\u4ee5\u53ca\u6781\u4f4e\u7684<\/span>0.0068%<\/span>\u7684\u80fd\u6548\u8870\u51cf\u7387\u3002\u8fd9\u9879\u5de5\u4f5c\u7a81\u7834\u4e86\u4f20\u7edf\u7684\u5728\u4f4e\u4e8e<\/span>100o<\/sup>C<\/span>\u7684\u6c34\u4e2d\u5de5\u4f5c\u7684<\/span>ZABs<\/span>\uff0c\u4e3a\u6784\u5efa\u9ad8\u6548\u7684\u4e8c\u6b21\u91d1\u5c5e<\/span>–<\/span>\u7a7a\u6c14\u7535\u6c60\u63d0\u4f9b\u4e86\u65b0\u7684\u901a\u7528\u7b56\u7565\u3002<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"

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