{"id":261981,"date":"2024-08-15T07:29:10","date_gmt":"2024-08-14T23:29:10","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=261981"},"modified":"2024-08-14T23:37:26","modified_gmt":"2024-08-14T15:37:26","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e6%bd%98%e9%94%8b-%e6%9d%a8%e5%8d%a2%e5%a5%95%e5%9b%a2%e9%98%9fam%ef%bc%9a%e7%95%8c%e9%9d%a2%e7%bb%93%e6%9e%84%e4%b8%8e%e5%9b%ba%e6%80%81%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=261981","title":{"rendered":"\u5317\u4eac\u5927\u5b66\u6f58\u950b\/\u6768\u5362\u5955\u56e2\u961fAM\uff1a\u754c\u9762\u7ed3\u6784\u4e0e\u56fa\u6001\u7535\u6c60\u4e2d\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93"},"content":{"rendered":"

\u4e00\u3001\u3010\u7814\u7a76\u80cc\u666f\u3011<\/b><\/strong><\/p>\n

\u56fa\u6001\u9502\u79bb\u5b50\u7535\u6c60 (SSLIBs) \u56e0\u5176\u6f5c\u5728\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u9ad8\u5b89\u5168\u6027\uff0c\u5df2\u6210\u4e3a\u5f53\u524d\u7535\u6c60\u7814\u7a76\u548c\u4ea7\u4e1a\u5316\u7684\u70ed\u70b9\u3002\u56fa\u6001\u9502\u7535\u6c60\u4e0e\u6db2\u6001\u9502\u79bb\u5b50\u7535\u6c60\u7684\u4e3b\u8981\u5dee\u522b\u662f\u7528\u56fa\u6001\u7535\u89e3\u8d28\u4ee3\u66ff\u4e86\u6db2\u6001\u7535\u89e3\u8d28\uff0c\u4ece\u800c\u4ea7\u751f\u4e86\u5176\u7279\u6709\u7684\u8bb8\u591a\u7c7b\u578b\u7684\u56fa\u6001-\u56fa\u6001\u754c\u9762\u3002\u76f8\u6bd4\u4e8e\u6db2\u6001\u7535\u89e3\u8d28\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u4e0d\u5177\u6709\u6d41\u52a8\u6027\uff0c\u56e0\u6b64\u96be\u4ee5\u6e17\u900f\u5230\u6574\u4e2a\u7535\u6781\u548c\u9694\u819c\u7684\u754c\u9762\u4e2d\uff0c\u5bfc\u81f4\u4e00\u7cfb\u5217\u56fa-\u56fa\u754c\u9762\u63a5\u89e6\u4e0d\u597d\u5bfc\u81f4\u7684\u95ee\u9898\uff0c\u4f8b\u5982\u79bb\u5b50\/\u7535\u5b50\u5728\u754c\u9762\u5904\u4f20\u8f93\u7f13\u6162\u5f71\u54cd\u5145\u653e\u7535\u901f\u7387\u3001\u5f02\u8d28\u754c\u9762\u521a\u6027\u63a5\u89e6\u4f7f\u5f97\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4f53\u79ef\u81a8\u80c0\/\u7f29\u5c0f\u4e0d\u4e00\u81f4\u5f15\u53d1\u5c40\u90e8\u5e94\u529b\u4ea7\u751f\u88c2\u7f1d\u5f71\u54cd\u4e86\u7535\u6c60\u7a33\u5b9a\u6027\u3001\u5728\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u5904\u4e0d\u7406\u60f3\u7684\u7535\u5b50\u4f20\u8f93\u4f1a\u8bf1\u53d1\u5316\u5b66\u526f\u53cd\u5e94\u5f62\u6210\u949d\u5316\u7684\u4e2d\u95f4\u76f8\u5bfc\u81f4\u9ad8\u754c\u9762\u7535\u963b\u3001\u754c\u9762\u4e0d\u5747\u5300\u548c\u5c40\u90e8\u7535\u6d41\u5bc6\u5ea6\u68af\u5ea6\u5bfc\u81f4\u9502\u679d\u6676\u751f\u957f\u5f15\u53d1\u7535\u6c60\u77ed\u8def\u3002\u603b\u4e4b\uff0c\u5404\u79cd\u5404\u6837\u7684\u754c\u9762\u95ee\u9898\u4e25\u91cd\u963b\u788d\u4e86\u56fa\u6001\u9502\u7535\u6c60\u7684\u5927\u89c4\u6a21\u4ea7\u4e1a\u5316\uff08\u5982\u56fe1\u6240\u793a\uff09\u3002\u7531\u4e8eSSLIBs\u4e2d\u7684\u754c\u9762\u6d89\u53ca\u590d\u6742\u7684\u8f7d\u6d41\u5b50\uff08\u5373\u9502\u79bb\u5b50\u548c\u7535\u5b50\uff09\u4f20\u8f93\u673a\u5236\uff0c\u6df1\u5165\u4e86\u89e3\u548c\u8c03\u63a7\u754c\u9762\u7ed3\u6784\u5bf9\u4e8e\u8f7d\u6d41\u5b50\u4f20\u8f93\u7684\u5f71\u54cd\u5bf9\u4e8e\u8fdb\u4e00\u6b65\u63d0\u5347SSLIBs\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

 <\/p>\n

\u4e8c\u3001\u3010\u7814\u7a76\u8d21\u732e\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u65b0\u6750\u6599\u5b66\u9662\u6f58\u950b\/\u6768\u5362\u5955\u3001\u82f1\u56fd\u8428\u91cc\u5927\u5b66\u6768\u51ef\u3001\u6c5f\u82cf\u5927\u5b66\u5b8b\u6c38\u5229\u5408\u4f5c\uff0c\u57fa\u4e8e\u6f58\u950b\u6559\u6388\u56e2\u961f\u8fd15\u5e74\u5bf9SSLIBs\u754c\u9762\u7ed3\u6784\u548c\u6027\u80fd\u7684\u8c03\u63a7\u7814\u7a76\u53d6\u5f97\u7684\u7cfb\u7edf\u6027\u7814\u7a76\u8fdb\u5c55 (Adv. Mater<\/i><\/b><\/em><\/strong>. 2018, 30, 1704436; Nano Energy<\/i><\/b><\/em><\/strong>\u00a02019, 62, 844; Adv. Energy Mater<\/i><\/b><\/em><\/strong>. 2019, 9, 1900671; J. Mater. Chem. A<\/i><\/b><\/em><\/strong>\u00a02020, 8, 342;\u00a0Small <\/i><\/b><\/em><\/strong>2020, 16, 1906374; Mater. Today<\/i><\/b><\/em><\/strong>\u00a02021, 49, 145; Adv. Funct. Mater.<\/i><\/b><\/em><\/strong>\u00a02021, 31, 2104830; Nano Energy<\/i><\/b><\/em><\/strong>\u00a02021, 79, 105407; Nano-Micro Lett.<\/i><\/b><\/em><\/strong>\u00a02022, 14, 191; Adv. Funct. Mater.<\/i><\/b><\/em><\/strong>\u00a02023, 33, 2210845; Adv. Energy Mater.<\/i><\/b><\/em><\/strong>\u00a02024, 14, 2303422; Nano Energy<\/i><\/b><\/em><\/strong>\u00a02024, 125, 109617;\u00a0J. Am. Chem. Soc.<\/i><\/b><\/em><\/strong>\u00a02024, 146, 18535) \uff0c\u5bf9\u6b64\u8fdb\u884c\u603b\u7ed3\u4e0e\u5c55\u671b\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cTailoring Interfacial Structures to Regulate Carrier Transport in Solid-State Batteries\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials\u4e0a\u3002\u9093\u5fd7\u5eb7\u548c\u9648\u8bd7\u540d\u4e3a\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n

\"\" \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n

\u56fe 1. \u56fa\u6001\u9502\u7535\u6c60\u5404\u79cd\u754c\u9762\u4ee5\u53ca\u9762\u4e34\u7684\u95ee\u9898<\/p>\n

 <\/p>\n

\u4e09\u3001\u3010\u7efc\u8ff0\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

1.\u56fa\u6001\u7535\u89e3\u8d28\u5185\u90e8\u754c\u9762<\/p>\n

\u4e0d\u540c\u4e8e\u6db2\u6001\u7535\u89e3\u8d28\uff0c\u56fa\u6001\u7535\u89e3\u8d28\uff08SEs\uff09\u901a\u5e38\u662f\u975e\u5747\u8d28\u7684\uff0c\u5177\u6709\u6676\u754c\uff08GBs\uff09\uff0c\u8fd9\u4e9b\u6676\u754c\u5f80\u5f80\u8868\u73b0\u51fa\u4e0d\u7406\u60f3\u7684\u7279\u6027\uff0c\u4f8b\u5982\u4f4e\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u9ad8\u7535\u5b50\u7535\u5bfc\u7387\u548c\u8f83\u5dee\u7684\u673a\u68b0\u5f3a\u5ea6\u3002\u6676\u7c92\u4e4b\u95f4\u7684\u7a7a\u9699\u548c\u95f4\u9699\u4e3aLi+<\/sup>\u7684\u4f20\u8f93\u589e\u52a0\u4e86\u989d\u5916\u7684\u969c\u788d\uff0c\u5bfc\u81f4\u79bb\u5b50\u7535\u5bfc\u7387\u964d\u4f4e\uff0c\u5e76\u4f7fLi+<\/sup>\u5728\u8fd9\u4e9b\u8fb9\u754c\u5904\u805a\u96c6\u3002\u6b64\u5916\uff0c\u4e00\u4e9bSEs\uff08\u5982Li7<\/sub>La3<\/sub>Zr2<\/sub>O12 <\/sub>(LLZO)\uff09\u7684\u6676\u754c\u5177\u6709\u8f83\u9ad8\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u4f7f\u7535\u5b50\u6cbf\u7740\u8fb9\u754c\u4e0eLi+<\/sup>\u7ed3\u5408\uff0c\u5bfc\u81f4Li+<\/sup>\u8fd8\u539f\u4e3aLi0<\/sup>\uff0c\u4ece\u800c\u4e25\u91cd\u6270\u4e71\u7535\u5b50\u7ed3\u6784\uff0c\u5e76\u6cbf\u7740\u6676\u754c\u5f15\u53d1\u9502\u679d\u6676\u7684\u751f\u957f\u3002<\/p>\n

\"\"<\/p>\n

\u56fe 2. (A) \u5728\u6676\u754c\uff08GBs\uff09\u5904\u5f62\u6210\u7684\u4e24\u79cd\u7a7a\u95f4\u7535\u8377\u5c42\u7684\u60c5\u5f62\uff0c\u5176\u4e2d\u03a6\u8868\u793aGalvani\u7535\u4f4d\u3002 (B) \u6676\u754c\u5185\u7684\u80fd\u91cf\u5c4f\u969c\u548cLi+\u6d53\u5ea6\u7684\u53d8\u5316\u3002\u6676\u7c92\u548c\u6676\u754c\u7684\u6fc0\u6d3b\u80fd\u5206\u522b\u8868\u793a\u4e3aEa<\/sub>\u548cEGB<\/sub>\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. (A) \u6750\u6599\u5185\u90e8\u663e\u5fae\u7279\u5f81\u7684\u793a\u610f\u56fe\uff0c\u5305\u62ec\u88c2\u7eb9\u504f\u8f6c\u3001\u88c2\u7eb9\u6865\u63a5\u4ee5\u53ca\u7531\u4e8e\u4e0d\u540c\u6676\u7c92\u53d6\u5411\u5bfc\u81f4\u7684\u5f39\u6027\u5404\u5411\u5f02\u6027\u3002(B) Li2<\/sub>CO3<\/sub>\u5728\u6709\u65e0Al2<\/sub>O3<\/sub>\u60c5\u51b5\u4e0b\u5206\u89e3\u7684\u5409\u5e03\u65af\u81ea\u7531\u80fd\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u66f2\u7ebf\uff1bAl2<\/sub>O3<\/sub>\u6dfb\u52a0\u5242\u5728LLZTO\uff08Li6.5<\/sub>La3<\/sub>Zr1.5<\/sub>Ta0.5<\/sub>O12<\/sub>\uff09\u70e7\u7ed3\u8fc7\u7a0b\u4e2d\u7684\u4f5c\u7528\u793a\u610f\u56fe\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. (A) \u4e0d\u540c\u5916\u90e8\u7535\u573a\u4e0b\u6676\u754c\u5904\u7535\u5b50\u4f20\u5bfc\u7684\u793a\u610f\u56fe\u3002(B) \u91c7\u7528LPSCl\u548cx-LPSCl\u4f5c\u4e3a\u7535\u89e3\u8d28\u7684ASSLBs\u7684\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u5b83\u4eec\u5728\u6291\u5236\u9502\u679d\u6676\u3001\u81ea\u653e\u7535\u548c\u6297\u6e7f\u6027\u65b9\u9762\u7684\u4e0d\u540c\u8868\u73b0\u3002(C) LLCZN\u4e2d\u9502\u6c89\u79ef\u7684\u793a\u610f\u56fe\u53ca\u901a\u8fc7\u8868\u9762\u6d82\u5c42\u6291\u5236\u9502\u6c89\u79ef\u7684\u65b9\u5f0f\u3002(D) LLZTO\u6676\u7c92\u548c\u6676\u754c\u7684\u80fd\u5e26\u56fe\u3002(E) \u56fa\u5b9a\u95f4\u9699\u548c\u6052\u5b9a\u538b\u529b\u6761\u4ef6\u4e0b\u7535\u6c60\u5faa\u73af\u88c5\u7f6e\u7684\u793a\u610f\u56fe\u3002<\/p>\n

 <\/p>\n

    \n
  1. 2. \u7535\u6781\u5185\u90e8\u754c\u9762<\/li>\n<\/ol>\n

    SSLIBs\u7684\u590d\u5408\u7535\u6781\u901a\u5e38\u7531\u6d3b\u6027\u6750\u6599\u3001\u7535\u5b50\u5bfc\u7535\u5242\u548cSEs\u7ec4\u6210\u3002\u56fa\u4f53\u9897\u7c92\u4e4b\u95f4\u63a5\u89e6\u4e0d\u826f\u4f1a\u5bfc\u81f4\u8f7d\u6d41\u5b50\u4f20\u8f93\u963b\u6297\u589e\u5927\uff0c\u800c\u8fd9\u79cd\u963b\u6297\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7531\u4e8e\u5c40\u90e8\u5e94\u529b\u4ea7\u751f\u7684\u88c2\u7eb9\u4f1a\u8fdb\u4e00\u6b65\u52a0\u5267\u3002\u6b64\u5916\uff0cLi+<\/sup>\u5728\u6d3b\u6027\u6750\u6599\u548c\u56fa\u6001\u7535\u89e3\u8d28\u7ec4\u6210\u7684\u7f51\u7edc\u4e2d\u4f20\u8f93\uff0c\u800ce–<\/sup>\u5219\u5728\u6d3b\u6027\u6750\u6599\u548c\u5bfc\u7535\u5242\u7ec4\u6210\u7684\u7f51\u7edc\u4e2d\u4f20\u8f93\u3002\u7535\u5b50\u4f20\u8f93\u7f51\u7edc\u548c\u79bb\u5b50\u4f20\u8f93\u7f51\u7edc\u4e4b\u95f4\u7684\u95f4\u9699\u963b\u788d\u4e86\u8f7d\u6d41\u5b50\u7684\u534f\u540c\u4f20\u8f93\u3002\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u754c\u9762\u7684\u5316\u5b66\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u5c06\u5728\u4e0b\u4e00\u8282\u4e2d\u8be6\u7ec6\u8ba8\u8bba\u3002\u56e0\u6b64\uff0c\u590d\u5408\u7535\u6781\u4e2d\u7684\u5185\u90e8\u754c\u9762\u9700\u8981\u5408\u7406\u8c03\u63a7\uff0c\u4ee5\u5728\u8fd9\u4e9b\u9897\u7c92\u4e4b\u95f4\u521b\u5efa\u4e00\u4e2a\u9ad8\u6548\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u7f51\u7edc\u3002<\/p>\n

    2.1 \u6b63\u6781\u5185\u90e8\u754c\u9762<\/p>\n

    \u590d\u5408\u6b63\u6781\u4e2d\u6b63\u6781\u6d3b\u6027\u6750\u6599\uff08CAMs\uff09\u3001\u7535\u5b50\u5bfc\u7535\u78b3\u548cSEs\u7684\u5171\u5b58\u5f62\u6210\u4e86\u5927\u91cf\u7684\u56fa-\u56fa\u754c\u9762\uff08\u5373CAMs\/SEs\u754c\u9762\u3001CAMs\/\u78b3\u754c\u9762\u548cSEs\/\u78b3\u754c\u9762\uff09\uff0c\u4ece\u800c\u5bfc\u81f4\u8f83\u5927\u7684\u7535\u8377\u4f20\u8f93\u963b\u6297\uff08\u56fe3A\uff09\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u5faa\u73af\u8fc7\u7a0b\u4e2d\u76f8\u53d8\u7684\u539f\u56e0\uff0cCAMs\u548cSEs\u4e4b\u95f4\u754c\u9762\u7684\u5c40\u90e8\u5e94\u53d8\u53ef\u80fd\u5bfc\u81f4\u673a\u68b0\u6545\u969c\uff0c\u4f8b\u5982\u88c2\u7eb9\u5f62\u6210\u548c\u5206\u5c42\uff08\u56fe5B\uff09\u3002\u7279\u522b\u662f\u5728\u9ad8\u9762\u79ef\u5bb9\u91cf\uff08>5 mAh cm-2<\/sup>\uff09\u7684\u6b63\u6781\u4e2d\uff0c\u8fd9\u4e00\u95ee\u9898\u4f1a\u56e0\u9897\u7c92\u4e4b\u95f4\u7684\u70b9\u63a5\u89e6\u9020\u6210\u8f83\u5927\u7684\u63a5\u89e6\u963b\u6297\u800c\u8fdb\u4e00\u6b65\u6076\u5316\u3002\u56e0\u6b64\uff0c\u786e\u4fddCAMs\u4e0e\u8f7d\u6d41\u5b50\u5bfc\u4f53\uff08\u5982SEs\u548c\u5bfc\u7535\u78b3\uff09\u4e4b\u95f4\u7684\u7d27\u5bc6\u7269\u7406\u63a5\u89e6\u548c\u8db3\u591f\u7684\u63a5\u89e6\u9762\u79ef\u81f3\u5173\u91cd\u8981\u3002\u6b64\u5916\uff0c\u8fd8\u5fc5\u987b\u786e\u4fddCAMs\u3001SEs\u548c\u7535\u5b50\u5bfc\u7535\u78b3\u4e4b\u95f4\u7684\uff08\u7535\uff09\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5426\u5219\uff0c\u6b63\u6781\u4e2d\u53ef\u80fd\u4f1a\u53d1\u751f\u526f\u53cd\u5e94<\/p>\n

    2.2 \u8d1f\u6781\u5185\u90e8\u754c\u9762<\/p>\n

    \u9502\u77ff\u4ef7\u683c\u7684\u6025\u5267\u4e0a\u5347\u548c\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u4e25\u91cd\u5b89\u5168\u95ee\u9898\u963b\u788d\u4e86SSLIBs\u7684\u53d1\u5c55\u3002\u9664\u4e86\u9502\u8d1f\u6781\uff0c\u7845\u57fa\u8d1f\u6781\u6750\u6599\u4ee5\u5176\u8d85\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff081000\u223c4200 mAh g-1<\/sup>\uff09\u3001\u4e30\u5bcc\u7684\u8d44\u6e90\uff08\u5730\u58f3\u4e2d\u542b\u91cf\u7b2c\u4e8c\u4e30\u5bcc\uff09\u548c\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3SSLIBs\u4e2d\u6709\u524d\u9014\u7684\u8d1f\u6781\u6750\u6599\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5728\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u5927\u91cf\u4f53\u79ef\u53d8\u5316\uff08100\u223c300%\uff09\uff0c\u4f1a\u5bfc\u81f4\u8d1f\u6781\u9897\u7c92\u7c89\u5316\uff08\u79f0\u4e3a\u673a\u68b0\u7c89\u5316\uff09\uff0c\u5e76\u9020\u6210\u8d1f\u6781\u6d3b\u6027\u6750\u6599\uff08AAMs\uff09\u4e2d\u7535\u5b50\/\u79bb\u5b50\u4f20\u8f93\u73af\u5883\u7684\u7834\u574f\uff08\u79f0\u4e3a\u4f20\u5bfc\u73af\u5883\u8870\u51cf\uff09\u3002\u540c\u65f6\uff0c\u8d1f\u6781\u9897\u7c92\u7684\u65b0\u9c9c\u66b4\u9732\u8868\u9762\u4f1a\u4e0e\u7535\u89e3\u8d28\uff08\u5982\u786b\u5316\u7269SEs\uff09\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u751f\u6210\u4e0d\u7a33\u5b9a\u4e14\u539a\u91cd\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u5c42\uff0c\u5e76\u5728\u78b3\u6dfb\u52a0\u5242\u7684\u4fc3\u8fdb\u4e0b\u4e0eSEs\u7ee7\u7eed\u53d1\u751f\u526f\u53cd\u5e94\uff08\u56fe3C\uff09\u3002\u6b64\u5916\uff0cAAMs\u548cSEs\u4e4b\u95f4\u7684\u63a5\u89e6\u9762\u79ef\u5728\u590d\u5408\u8d1f\u6781\u4e2d\u53d7\u5230\u9650\u5236\uff0c\u963b\u788d\u4e86\u7535\u5b50\u548c\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u3002\u56e0\u6b64\uff0c\u5728AAMs\u4e2d\u6784\u5efa\u4e00\u4e2a\u7a33\u5065\u7684\u8f7d\u6d41\u5b50\u4f20\u5bfc\u7f51\u7edc\u53ef\u4ee5\u88ab\u89c6\u4e3a\u5f25\u5408\u5b66\u672f\u7814\u7a76\u4e0e\u5b9e\u9645\u5e94\u7528\u4e4b\u95f4\u5dee\u8ddd\u7684\u6709\u6548\u7b56\u7565<\/p>\n

    \"\"<\/p>\n

    \u56fe5.\u00a0(A) \u590d\u5408\u6b63\u6781\u5fae\u89c2\u7ed3\u6784\u793a\u610f\u56fe\u3002 (B) \u590d\u5408\u6b63\u6781\u5931\u6548\u673a\u5236\u793a\u610f\u56fe\u3002 (C) \u590d\u5408\u7845\u8d1f\u6781\u5931\u6548\u673a\u5236\u793a\u610f\u56fe\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe6. (A) \u901a\u8fc7\u4f7f\u7528\u5b9a\u5236\u7684\u5177\u6709\u68d2\u72b6\u6676\u7c92\u7684\u201c\u5168\u6d53\u5ea6\u68af\u5ea6CAM\u9897\u7c92\u6765\u7f13\u89e3\u9897\u7c92\u5f00\u88c2\u3002(B) \u67b6\u6784\u548c\u7eb3\u7c73\u6da6\u6e7f\u754c\u9762\u673a\u5236\u7684\u793a\u610f\u56fe\u3002(C) TPS\u7ed3\u6784\u53ca\u5176\u5bf9CAM\/SE\u63a5\u89e6\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002(D) Si\u9897\u7c92\u5c3a\u5bf8\u548cSE\u79bb\u5b50\u7535\u5bfc\u7387\u5bf9\u8d1f\u6781\u590d\u5408\u6750\u6599\u500d\u7387\u6027\u80fd\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe7. (A) \u9502\u79bb\u5b50\u5bfc\u7535\u7f51\u7edc\u4e0e\u7535\u5b50\u5bfc\u7535\u7f51\u7edc\u4e4b\u95f4\u7684\u95f4\u9699\u3002 (B) \u590d\u5408\u7535\u6781\u4e2d\u8f7d\u6d41\u5b50\u5bfc\u7535\u7f51\u7edc\u7684\u7c98\u7ed3\u5242\u793a\u610f\u56fe\u3002<\/p>\n

    \"\"<\/p>\n

    \u56fe8. (A) \u81ea\u7531\u538b\u529b\u548c\u5916\u90e8\u538b\u529b\u6761\u4ef6\u4e0b\u7845\u9897\u7c92\u7684\u793a\u610f\u56fe\u3002 (B) \u5236\u5907\u7845\u590d\u5408\u8d1f\u6781\u7684\u4e24\u6b65\u6e7f\u6cd5\u548c\u5e72\u6cd5\u5de5\u827a\u793a\u610f\u56fe\u3002(C) \u88f8\u7845\u6216Si@MOF\u8d1f\u6781\u754c\u9762\u6f14\u53d8\u7684\u793a\u610f\u56fe\u3002<\/p>\n

     <\/p>\n

      \n
    1. 3. \u7535\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u8868\u89c2\u754c\u9762<\/li>\n<\/ol>\n

      \u5728\u4f20\u7edf\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u6db2\u6001\u7535\u89e3\u8d28\u6e17\u900f\u5230\u7535\u6781\u548c\u9694\u819c\u4e4b\u95f4\u7684\u5e73\u9762\u754c\u9762\uff0c\u5f62\u6210\u5feb\u901f\u4e14\u7a33\u5b9a\u7684Li+<\/sup>\u4f20\u8f93\u901a\u9053\u3002\u7136\u800c\uff0c\u7531\u4e8e\u5236\u9020\u6280\u672f\u7684\u9650\u5236\uff0c\u96be\u4ee5\u76f4\u63a5\u7ec4\u88c5\u4e00\u4f53\u5316\u7684SSLIBs\uff0c\u8fd9\u610f\u5473\u7740\u7535\u6781\u4e0eSEs\u754c\u9762\u7684\u56fa\u6709\u5b58\u5728\u3002\u56e0\u6b64\uff0c\u6df1\u5165\u7406\u89e3\u7535\u6781\u4e0eSEs\u4e4b\u95f4\u8868\u89c2\u754c\u9762\u7684\u8bbe\u8ba1\u5bf9\u4e8e\u6784\u5efa\u5b8c\u6574\u7684SSLIBs\u81f3\u5173\u91cd\u8981\u3002\u7535\u6781\/SE\u754c\u9762\u7684\u673a\u68b0\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u4e0d\u8db3\uff0c\u5fc5\u7136\u4f1a\u5bfc\u81f4\u4e0d\u826f\u7684\u526f\u53cd\u5e94\u6216\u7269\u7406\u63a5\u89e6\u4e0d\u826f\uff0c\u4ece\u800c\u5bfc\u81f4\u8f83\u5dee\u7684\u500d\u7387\u6027\u80fd\u548c\u5bb9\u91cf\u4fdd\u6301\u80fd\u529b\u3002<\/p>\n

       <\/p>\n

      3.1 \u590d\u5408\u6b63\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u8868\u89c2\u754c\u9762<\/p>\n

      \u754c\u9762\u7a33\u5b9a\u6027\u95ee\u9898\u4f1a\u5bfc\u81f4CAMs\u548c\u56fa\u6001\u7535\u89e3\u8d28\u5728\u9ad8\u7535\u538b\u4e0b\u53d1\u751f\u5206\u89e3\u3002\u590d\u5408\u6b63\u6781\/SEs\u754c\u9762\u95f4\u4e0d\u826f\u7684\u7535\u5b50\u4f20\u8f93\u4f1a\u5f15\u53d1\u5316\u5b66\u53cd\u5e94\uff0c\u5f62\u6210\u4e0d\u6d3b\u8dc3\u7684\u5206\u89e3\u4e2d\u95f4\u5c42\uff08\u5982La2<\/sub>O3<\/sub>\u548cLi2<\/sub>S\uff09\uff0c\u751a\u81f3\u5bfc\u81f4CAMs\u7684\u76f8\u53d8\u548c\u7ed3\u6784\u7d0a\u4e71\uff0c\u8fd9\u4e9b\u90fd\u5c06\u589e\u52a0\u754c\u9762\u7535\u963b\uff08\u56fe4A\uff09\u3002\u56e0\u6b64\uff0c\u590d\u5408\u6b63\u6781\u4e0eSEs\u4e4b\u95f4\u7a33\u5b9a\u4e14\u6709\u5e8f\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u754c\u9762\u5bf9SSLIBs\u83b7\u5f97\u4f18\u5f02\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

      \"\"<\/p>\n

      \u56fe9. (A) \u590d\u5408\u6b63\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\uff08SEs\uff09\u4e4b\u95f4\u754c\u9762\u95ee\u9898\u7684\u793a\u610f\u56fe\u3002 (B) \u9502\u91d1\u5c5e\u8d1f\u6781\u4e0eSEs\u4e4b\u95f4\u754c\u9762\u95ee\u9898\u7684\u793a\u610f\u56fe\u3002 (C) \u590d\u5408\u7845\u8d1f\u6781\u4e0eSEs\u4e4b\u95f4\u754c\u9762\u95ee\u9898\u7684\u793a\u610f\u56fe\u3002 (D) \u7535\u6781\u4e0eSEs\u4e4b\u95f4\u7406\u60f3\u754c\u9762\u7684\u793a\u610f\u56fe\u3002<\/p>\n

      3.1 \u590d\u5408\u8d1f\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u8868\u89c2\u754c\u9762<\/p>\n

      \u4e0e\u6b63\u6781\u6750\u6599\u4e0d\u540c\uff0c\u9664\u4e86\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u5916\uff0c\u590d\u5408\u8d1f\u6781\/SEs\u754c\u9762\u7684\u673a\u68b0\u6027\u80fd\u5c24\u4e3a\u91cd\u8981\u3002\u4e00\u65b9\u9762\uff0c\u5408\u91d1\u578b\u8d1f\u6781\uff08\u5982\u7845\u548c\u9521\uff09\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u4f1a\u4f34\u968f\u5de8\u5927\u7684\u5404\u5411\u5f02\u6027\u81a8\u80c0\uff0c\u5bfc\u81f4\u754c\u9762\u4e0a\u7684\u5e94\u529b\u6f14\u53d8\u548c\u65ad\u88c2\uff0c\u6700\u7ec8\u5f15\u8d77\u79bb\u5b50\u4f20\u5bfc\u7f51\u7edc\u7684\u9000\u5316\uff08\u56fe4B\uff09\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u754c\u9762\u63a5\u89e6\u4e0d\u7a33\u5b9a\u3001\u9502\u679d\u6676\u7684\u751f\u957f\u4ee5\u53ca\u4e0eSEs\u7684\u5267\u70c8\u526f\u53cd\u5e94\u4f1a\u7f29\u77ed\u57fa\u4e8eSSLIBs\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5bff\u547d\uff08\u56fe4C\uff09\u3002\u672c\u8d28\u4e0a\uff0cLi+<\/sup>\u7684\u4f20\u8f93\u548c\u9502\u6c89\u79ef\u8fc7\u7a0b\u53d1\u751f\u5728\u5faa\u73af\u671f\u95f4\u7684\u9502\/SEs\u754c\u9762\u4e0a\uff0c\u8fd9\u9700\u8981\u6df1\u5165\u7406\u89e3\u5176\u52a8\u529b\u5b66\u548c\u5931\u6548\u673a\u5236\u3002\u7406\u60f3\u7684\u590d\u5408\u7535\u6781\u4e0eSEs\u4e4b\u95f4\u7684\u8868\u89c2\u754c\u9762\uff08\u56fe4D\uff09\u9700\u8981\u5408\u7406\u8c03\u63a7\uff0c\u4ee5\u521b\u5efa\u9009\u62e9\u6027\u8f7d\u6d41\u5b50\u4f20\u8f93\u7f51\u7edc\uff0c\u6291\u5236\u7535\u5b50\u4f20\u8f93\u5e76\u52a0\u901f\u9502\u79bb\u5b50\u4f20\u8f93\u3002<\/p>\n

      \"\"<\/p>\n

      \u56fe10. (A) Li10<\/sub>GeP2<\/sub>S12<\/sub>\u3001Li6<\/sub>PS5<\/sub>Cl\u3001Li2<\/sub>ZrCl6<\/sub>\u3001Li3<\/sub>InCl6<\/sub>\u548cLZCO\u51b7\u538b\u9897\u7c92\u7684SEM\u56fe\u50cf\u3002\u6240\u6709\u9897\u7c92\u5747\u5728300\u2009MPa\u4e0b\u5236\u5907\u3002(B) SSLIBs\u4e2d\u5e26\u7f3a\u9677PEO\u7684LLZTO\u5de5\u4f5c\u673a\u5236\u793a\u610f\u56fe\u3002<\/p>\n

      \"\"<\/p>\n

      \u56fe11. (A) SEs\u4e2d\u9502\u7ed3\u6676\u7684\u591a\u6b65\u8def\u5f84\u3002(B) Li2<\/sub>CO3<\/sub>\u5c42\u5bf9\u754c\u9762\u7535\u963b\u5f71\u54cd\u7684\u793a\u610f\u56fe\u3002 (C) \u539f\u4f4dMoS2<\/sub>\u4fdd\u62a4\u673a\u5236\u53ca\u5176\u5728\u6781\u5316\u8fc7\u7a0b\u4e2d\u7684\u5316\u5b66\u6f14\u53d8\u793a\u610f\u56fe\u3002<\/p>\n

      \"\"<\/p>\n

      \u56fe12. (A) \u4fdd\u62a4\u5c42\u7a33\u5b9a\u754c\u9762\u7684\u793a\u610f\u56fe\u3002 (B) SSLIBs\u4e2d\u5404\u79cd\u8d1f\u6781\u7684\u5316\u5b66\u548c\u7ed3\u6784\u6f14\u53d8\u793a\u610f\u56fe\u3002(C) \u9502\u91d1\u5c5e\u4e0e\u56fa\u6001\u9502\u79bb\u5b50\u5bfc\u4f53\u4e4b\u95f4\u7684\u4e09\u79cd\u754c\u9762\u7c7b\u578b\u3002<\/p>\n

       <\/p>\n

      4.\u3010\u603b\u7ed3\u548c\u5c55\u671b\u3011<\/p>\n

      \u4e0e\u4f20\u7edf\u6db2\u6001\u9502\u79bb\u5b50\u7535\u6c60\u76f8\u6bd4\uff0cSSLIBs\u56e0\u5176\u6f5c\u5728\u7684\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u5353\u8d8a\u7684\u5b89\u5168\u6027\u800c\u8131\u9896\u800c\u51fa\u3002\u6b63\u5982\u524d\u6587\u6240\u8ff0\uff0c\u591a\u5c3a\u5ea6\u7684\u56fa-\u56fa\u754c\u9762\u5728SSLIBs\u4e2d\u8d77\u7740\u5173\u952e\u4f5c\u7528\uff0c\u63a7\u5236\u7740\u8f7d\u6d41\u5b50\u7684\u4f20\u8f93\u3002\u8fd9\u4e9b\u56fa-\u56fa\u754c\u9762\u5305\u62ec\u4e09\u4e2a\u5185\u90e8\u754c\u9762\uff08\u590d\u5408\u6b63\u6781\u3001\u56fa\u6001\u7535\u89e3\u8d28\u548c\u590d\u5408\u8d1f\u6781\uff09\u548c\u4e24\u4e2a\u590d\u5408\u6b63\u6781\/\u8d1f\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u8868\u89c2\u754c\u9762\uff0c\u5e38\u5e38\u6210\u4e3a\u6574\u4f53\u8f7d\u6d41\u5b50\u4f20\u8f93\u7684\u74f6\u9888\uff0c\u5176\u7279\u6027\u4e0e\u6e17\u900f\u6027\u6db2-\u56fa\u754c\u9762\u6709\u5f88\u5927\u4e0d\u540c\u3002\u4f8b\u5982\uff0c\u56fa\u6001\u7535\u89e3\u8d28\u4e2d\u7684GBs\u901a\u5e38\u4f1a\u963b\u788d\u9502\u79bb\u5b50\u7684\u4f20\u8f93\uff0c\u751a\u81f3\u5bfc\u81f4\u673a\u68b0\u6027\u80fd\u4e0b\u964d\u3002\u56fa-\u56fa\u754c\u9762\u7684\u4e0d\u7a33\u5b9a\u70b9\u63a5\u89e6\u4f1a\u5bfc\u81f4\u8f83\u5927\u7684\u754c\u9762\u7535\u963b\u548c\u663e\u8457\u7684\u5bb9\u91cf\u635f\u5931\u3002\u5728\u7406\u60f3\u7684\u5185\u90e8\u754c\u9762\u4e2d\uff0c\u9502\u79bb\u5b50\u548c\u7535\u5b50\u5728\u590d\u5408\u7535\u6781\u4e2d\u534f\u540c\u4f20\u8f93\u3002\u76f8\u53cd\uff0c\u7406\u60f3\u7684\u56fa\u6001\u7535\u89e3\u8d28\u5e94\u8868\u73b0\u51fa\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u6781\u4f4e\u7684\u7535\u5b50\u7535\u5bfc\u7387\uff0c\u751a\u81f3\u7edd\u7f18\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5e94\u5728\u7535\u6781\/\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u5904\u6291\u5236\u7535\u5b50\u4f20\u8f93\u4ee5\u907f\u514d\u526f\u53cd\u5e94\u3002\u901a\u8fc7\u754c\u9762\u5de5\u7a0b\u5728SSLIBs\u4e2d\u5b9a\u5236\u548c\u6784\u5efa\u7a33\u5065\u7684\u8f7d\u6d41\u5b50\u4f20\u5bfc\u7f51\u7edc\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

      \u5c3d\u7ba1\u5728\u754c\u9762\u95ee\u9898\u4e0a\u5df2\u7ecf\u53d6\u5f97\u4e86\u663e\u8457\u6210\u5c31\uff0c\u4f46SSLIBs\u7684\u5546\u4e1a\u5316\u4e4b\u8def\u4ecd\u7136\u5d0e\u5c96\u4e0d\u5e73\u3002\u7efc\u5408\u4e0a\u8ff0\u5185\u5bb9\uff0c\u56fe5\u603b\u7ed3\u4e86SSLIBs\u7684\u4f18\u5316\u7b56\u7565\u548c\u8bbe\u8ba1\u539f\u5219\u3002\u6700\u57fa\u672c\u7684\u662f\uff0c\u6bcf\u4e2a\u56fa\u4f53\u7ec4\u4ef6\uff08\u5982\u6d3b\u6027\u6750\u6599\u9897\u7c92\u3001\u7535\u5b50\u5bfc\u7535\u5242\u548c\u56fa\u6001\u7535\u89e3\u8d28\uff09\u4e4b\u95f4\u5145\u8db3\u7684\u7269\u7406\u63a5\u89e6\u662f\u8f7d\u6d41\u5b50\u4f20\u8f93\u548c\u7535\u6c60\u8fd0\u884c\u7684\u57fa\u77f3\u3002\u5176\u6b21\uff0c\u5728\u591a\u5c3a\u5ea6\u56fa-\u56fa\u754c\u9762\u4e4b\u95f4\u6784\u5efa\u7a33\u56fa\u7684\u5316\u5b66\u951a\u5b9a\u4ee5\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u7269\u7406\u63a5\u89e6\uff0c\u5bf9\u4e8e\u7279\u522b\u662f\u5177\u6709\u5927\u4f53\u79ef\u53d8\u5316\u7684\u7535\u6c60\u7cfb\u7edf\u81f3\u5173\u91cd\u8981\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u6df1\u5165\u7406\u89e3\u9502\u79bb\u5b50\u548c\u7535\u5b50\u7684\u4f20\u8f93\uff0c\u5e76\u5728\u6574\u4e2aSSLIBs\u4e2d\u5b9a\u5236\u9009\u62e9\u6027\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u7f51\u7edc\uff0c\u5bf9\u4e8e\u89e3\u51b3\u4e0e\u754c\u9762\u76f8\u5173\u7684\u666e\u904d\u95ee\u9898\u81f3\u5173\u91cd\u8981\uff0c\u8fd9\u4e9b\u95ee\u9898\u6d89\u53ca\u590d\u6742\u7684\u7269\u7406\u3001\uff08\u7535\uff09\u5316\u5b66\u548c\u7535\u5316\u5b66-\u673a\u68b0\u8fc7\u7a0b\u3002\u63a5\u4e0b\u6765\u7684\u6bb5\u843d\u5c06\u63cf\u8ff0\u52a0\u901fSSLIBs\u5b9e\u9645\u5e94\u7528\u6240\u9700\u7684\u672a\u6765\u6311\u6218\u548c\u7814\u7a76\u65b9\u5411\u3002<\/p>\n

      (1) \u901a\u8fc7\u5408\u7406\u7684\u7535\u6781\u8bbe\u8ba1\u589e\u52a0\u5b9e\u9645\u7535\u6c60\u4e2d\u6d3b\u6027\u6750\u6599\u7684\u6bd4\u4f8b\uff0c\u663e\u793a\u51fa\u5b9e\u73b0SSLIBs\u66f4\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u5de8\u5927\u6f5c\u529b\u3002\u7136\u800c\uff0c\u589e\u52a0\u7535\u6781\u539a\u5ea6\u4f1a\u5bfc\u81f4\u8f7d\u6d41\u5b50\u4f20\u8f93\u8ddd\u79bb\u53d8\u957f\uff0c\u4ece\u800c\u5bfc\u81f4\u8f83\u5dee\u7684\u5145\u653e\u7535\u52a8\u529b\u5b66\u548c\u6cbf\u7eb5\u8f74\u7684\u79bb\u5b50\u6d53\u5ea6\u68af\u5ea6\u3002\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\u3001\u5e94\u7528\u591a\u7ef4\u5bfc\u7535\u6dfb\u52a0\u5242\uff08\u5982\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\uff09\u4ee5\u53ca\u5339\u914d\u6b63\u6781\u6750\u6599\u548c\u7535\u89e3\u8d28\u7684\u5c3a\u5bf8\u6765\u6539\u5584\u8fd9\u4e00\u95ee\u9898\u3002<\/p>\n

      (2) \u53ef\u6269\u5c55\u4e14\u7ecf\u6d4e\u7684\u5236\u9020\u6280\u672f\u5bf9\u4e8eSSLIBs\u7684\u5546\u4e1a\u5316\u81f3\u5173\u91cd\u8981\u3002\u4f20\u7edf\u7684\u6d46\u6599\u6d47\u6ce8\u7535\u6781\u5236\u9020\u6280\u672f\u5f80\u5f80\u5bfc\u81f4\u539a\u7535\u6781\u7684\u5f00\u88c2\u6216\u5206\u5c42\uff0c\u5e76\u7531\u4e8e\u9897\u7c92\u7684\u968f\u673a\u6392\u5217\u800c\u5bfc\u81f4\u8f83\u9ad8\u7684\u66f2\u6298\u5ea6\uff0c\u963b\u788d\u4e86\u5feb\u901f\u8f7d\u6d41\u5b50\u4f20\u8f93\u3002\u4e00\u4e2a\u6709\u6548\u7684\u89e3\u51b3\u65b9\u6848\u662f\u901a\u8fc7\u6a21\u677f\u6cd5\u6216\u81ea\u7ec4\u88c5\u7b56\u7565\u6784\u5efa\u5177\u6709\u5782\u76f4\u901a\u9053\u7684\u539a\u7535\u6781\uff0c\u51cf\u5c11Li+<\/sup>\/e–<\/sup>\u7684\u4f20\u8f93\u8ddd\u79bb\u3002\u6b64\u5916\uff0c\u6eb6\u5242\u81ea\u7531\u5e72\u819c\u6280\u672f\uff08\u5982\u7c89\u672b\u55b7\u6d82\u548c\u7c98\u7ed3\u5242\u7ea4\u7ef4\u5316\uff09\u5728\u672a\u6765\u503c\u5f97\u66f4\u591a\u5173\u6ce8\u3002\u8fd9\u4e9b\u65b9\u6cd5\u4e0d\u53d7\u7535\u6781\u539a\u5ea6\u7684\u9650\u5236\uff0c\u80fd\u591f\u6291\u5236\u5404\u79cd\u7535\u6781\u7ec4\u4ef6\u7684\u5206\u5c42\uff0c\u6784\u5efa\u6709\u5229\u7684\u4f20\u8f93\u7f51\u7edc\u3002\u8bbe\u8ba1\u7a33\u5065\u7684\u591a\u7ef4\u7535\u6d41\u6536\u96c6\u5668\u662f\u6539\u5584Li+<\/sup>\u4f20\u8f93\u901a\u91cf\u7684\u53e6\u4e00\u9014\u5f84\u3002<\/p>\n

      (3) \u8bbe\u8ba1\u548c\u5408\u6210\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5bbd\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7684SEs\u5bf9\u4e8e\u9ad8\u6027\u80fdSSLIBs\u7684\u53d1\u5c55\u81f3\u5173\u91cd\u8981\u3002\u57fa\u4e8e\u6c27\u5316\u7269\u7684SEs\u9762\u4e34\u7740\u9ad8GB\u7535\u963b\u548c\u6750\u6599\u56fa\u6709\u7684\u8fc7\u786c\u7279\u6027\u6240\u5e26\u6765\u7684\u6311\u6218\uff0c\u5bfc\u81f4\u63a5\u89e6\u4e0d\u826f\u3002\u5728\u8fd9\u65b9\u9762\uff0c\u57fa\u4e8e\u5364\u5316\u7269\u548c\u786b\u5316\u7269\u7684SEs\u66f4\u5177\u524d\u666f\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u66f4\u597d\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u5ef6\u5c55\u6027\u3002\u6b64\u5916\uff0c\u5f00\u53d1\u8584\u7535\u89e3\u8d28\u5236\u9020\u6280\u672f\u5bf9\u4e8e\u5b9e\u9645SSLIBs\u7684\u5236\u9020\u4e5f\u975e\u5e38\u91cd\u8981\u3002<\/p>\n

      (4) \u5728\u6b63\u6781\u65b9\u9762\uff0c\u4e25\u91cd\u7684\u7269\u7406\u63a5\u89e6\u95ee\u9898\u548c\u9ad8\u7535\u538b\u4e0d\u7a33\u5b9a\u6761\u4ef6\u662f\u9700\u8981\u8fdb\u4e00\u6b65\u8003\u8651\u7684\u91cd\u5927\u95ee\u9898\u3002\u5f00\u53d1\u67d4\u8f6f\u4e14\u5bfc\u7535\u7684\u6d82\u5c42\u7528\u4e8eCAMs\uff0c\u5e76\u8c03\u8282\u7535\u6781\u76843D\u7ed3\u6784\uff0c\u53ef\u80fd\u4f1a\u7f13\u89e3\u8fd9\u4e9b\u95ee\u9898\u3002\u5bf9\u4e8e\u8d1f\u6781\uff0c\u5e94\u66f4\u591a\u5173\u6ce8\u5982\u4f55\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\u548c\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6291\u5236\u4f53\u79ef\u53d8\u5316\u3002\u6784\u5efa\u591a\u5c42\u4e14\u52a8\u6001\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u91c7\u7528\u81ea\u6108\u548c\u79bb\u5b50-\u7535\u5b50\u5bfc\u7535\u7684\u7c98\u7ed3\u5242\uff0c\u4ee5\u53ca\u4e3a\u8f6f\u5305\u7535\u6c60\u8bbe\u8ba1\u5916\u90e8\u65bd\u538b\u88c5\u7f6e\uff0c\u6709\u6f5c\u529b\u89e3\u51b3\u8fd9\u4e9b\u6311\u6218\u3002<\/p>\n

      (5) \u5e94\u5f00\u53d1\u5148\u8fdb\u7684\u539f\u4f4d\u8868\u5f81\u6280\u672f\uff08\u5982\u539f\u4f4dX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u3001\u539f\u4f4dNMR\u5149\u8c31\u548c\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff09\u4ee5\u6df1\u5165\u4e86\u89e3\u754c\u9762\u6210\u5206\u548c\u7ed3\u6784\u7684\u590d\u6742\u6f14\u53d8\u673a\u5236\uff0c\u6307\u5bfcSSLIBs\u754c\u9762\u7ed3\u6784\u7684\u5408\u7406\u8bbe\u8ba1\u3002\u4f8b\u5982\uff0c\u64cd\u4f5c\u4e2d\u7684X\u5c04\u7ebf\u8ba1\u7b97\u673a\u65ad\u5c42\u626b\u63cf\u5df2\u88ab\u7528\u6765\u5b9e\u65f6\u89c2\u5bdf\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u5148\u8fdb\u7684\u8868\u5f81\u7b56\u7565\u53ea\u5bf9\u6709\u9650\u6570\u91cf\u7684\u7535\u6781\u6750\u6599\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u5e76\u4e14\u9700\u8981\u7279\u5b9a\u7684\u5b9e\u9a8c\u8bbe\u5907\u3002<\/p>\n

      (6) \u7406\u8bba\u8ba1\u7b97\u548c\u6a21\u62df\uff08\u5982\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u3001\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u548c\u6709\u9650\u5143\u6a21\u62df\uff09\u662f\u7b5b\u9009\u6709\u524d\u666f\u7684SEs\u548c\u5206\u6790SSLIBs\u4e2d\u7269\u7406\u5316\u5b66\u8fc7\u7a0b\u7684\u6709\u529b\u5de5\u5177\u3002\u901a\u8fc7\u8ba1\u7b97SEs\u7684\u6027\u8d28\uff08\u5982\u7535\u5316\u5b66\u7a97\u53e3\u548c\u79bb\u5b50\u4f20\u8f93\uff09\uff0c\u53ef\u4ee5\u5efa\u7acb\u5927\u578b\u7684\u8ba1\u7b97\u6750\u6599\u6570\u636e\u5e93\u3002\u6b64\u5916\uff0c\u5f00\u53d1\u591a\u5c3a\u5ea6\u6a21\u62df\u6a21\u578b\uff08\u4ece\u6750\u6599\u5230\u7535\u6c60\uff09\u975e\u5e38\u91cd\u8981\uff0c\u7528\u4e8e\u9884\u6d4bSSLIBs\u4e2d\u7684\u7535\u5316\u5b66\u884c\u4e3a\u548c\u5e94\u529b\u5206\u5e03\u3002<\/p>\n

      \u00a0\"\"<\/b><\/strong><\/p>\n

      \u56fe 13.\u00a0\u5bf9\u672a\u6765SSLIBs\u8bbe\u8ba1\u6307\u5357\u7684\u5c55\u671b\u3002<\/p>\n

      \u901a\u8fc7\u8fd9\u7bc7\u7efc\u8ff0\uff0c\u6211\u4eec\u5e0c\u671b\u80fd\u591f\u5728\u8fd9\u4e9b\u7814\u7a76\u65b9\u5411\u4e0a\u63d0\u4f9b\u4e00\u5b9a\u7684\u542f\u53d1\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u63a8\u52a8\u9ad8\u6027\u80fdSSLIBs\u7684\u53d1\u5c55\u3002\u4e00\u65e6\u5728\u6574\u4e2a\u56fa\u6001\u7535\u6c60\u4e2d\u5efa\u7acb\u8d77\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u7684\u8f7d\u6d41\u5b50\u4f20\u8f93\u7f51\u7edc\uff0cSSLIBs\u7684\u5546\u4e1a\u5316\u5c06\u6307\u65e5\u53ef\u5f85\u3002<\/b><\/strong><\/p>\n

      \u00a0<\/b><\/strong><\/p>\n

      \u8bba\u6587\u5730\u5740<\/b><\/strong><\/p>\n

      https:\/\/doi.org\/10.1002\/adma.202407923<\/p>\n

       <\/p>\n

      \u4e94\u3001\u3010\u9879\u76ee\u652f\u6301\u3011<\/b><\/strong><\/p>\n

      Pan acknowledges the support from International joint Research Center for Electric Vehicle Power Battery and Materials (No.2015B01015), Guangdong Key Laboratory of Design and calculation of New Energy Materials (No. 2017B030301013) and the Shenzhen Key Laboratory of New Energy Resources Genome Preparation and Testing (No. ZDSYS201707281026184). L. Yang acknowledges the support from Shenzhen Science and Technology Planning Project (JSGG20220831095604008). Y. Song acknowledges the support from the National Natural Science Foundation of China (No. 52102200).<\/p>\n

       <\/p>\n","protected":false},"excerpt":{"rendered":"

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