{"id":262285,"date":"2024-08-30T08:09:35","date_gmt":"2024-08-30T00:09:35","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=262285"},"modified":"2024-08-30T08:09:35","modified_gmt":"2024-08-30T00:09:35","slug":"%e4%ba%8c%e7%bb%b4%e7%81%ab%e5%b1%b1%e5%9b%be%ef%bc%9a%e6%8f%ad%e7%a7%98%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%ae%9e%e6%97%b6%e7%bb%93%e6%9e%84%e6%bc%94%e5%8f%98%e4%b8%8e%e5%85%b3%e9%94%ae%e4%b8%ad","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=262285","title":{"rendered":"\u4e8c\u7ef4\u706b\u5c71\u56fe\uff1a\u63ed\u79d8\u50ac\u5316\u5242\u7684\u5b9e\u65f6\u7ed3\u6784\u6f14\u53d8\u4e0e\u5173\u952e\u4e2d\u95f4\u4ea7\u7269"},"content":{"rendered":"<p><strong>\u4e00\u3001<\/strong><strong>\u00a0<\/strong><strong>\u3010\u5bfc\u8bfb\u3011 \u00a0<\/strong><\/p>\n<p>\u81ea\u7b2c\u4e00\u6b21\u5de5\u4e1a\u9769\u547d\u4ee5\u6765\uff0c\u5316\u77f3\u71c3\u6599\u7684\u8fc7\u5ea6\u6d88\u8017\u5bfc\u81f4\u5927\u6c14\u4e2d\u4e8c\u6c27\u5316\u78b3\u542b\u91cf\u6025\u5267\u589e\u52a0\uff0c\u52a0\u5267\u6e29\u5ba4\u6548\u5e94\u548c\u5f71\u54cd\u751f\u6001\u7cfb\u7edf\u3002\u901a\u8fc7\u6355\u83b7\u4e8c\u6c27\u5316\u78b3\u5e76\u5c06\u5176\u8fd8\u539f\u8f6c\u5316\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u6392\u653e\uff0c\u8fd8\u80fd\u4e3a\u5de5\u4e1a\u5e02\u573a\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u5316\u5b66\u539f\u6599\u3002\u5176\u4e2d\uff0c\u5f53\u78b3\u6355\u83b7\u50a8\u5b58\u6280\u672f\u548c\u53ef\u518d\u751f\u80fd\u6e90\u5982\u98ce\u80fd\u548c\u592a\u9633\u80fd\u7b49\u76f8\u7ed3\u5408\u65f6\uff0c\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u8f6c\u5316\u4e3a\u71c3\u6599\u548c\u5316\u5b66\u539f\u6599\uff0c\u662f\u5b9e\u73b0\u4e8c\u6c27\u5316\u78b3\u51c0\u51cf\u6392\u7684\u4e00\u9879\u6709\u524d\u9014\u7684\u7b56\u7565\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e8c\u3001\u3010\u6210\u679c\u63a0\u5f71\u3011<\/strong><\/p>\n<p>\u4f7f\u7528\u53ef\u518d\u751f\u80fd\u6e90\u7684\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u662f\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u7684\u4e00\u79cd\u6709\u524d\u9014\u7684\u9014\u5f84\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u5236\u5907\u7532\u9178\u76d0\u4ee3\u8868\u4e86\u4e00\u4e2a\u5546\u4e1a\u76c8\u5229\u76ee\u6807\u3002\u7136\u800c\u622a\u6b62\u81f3\u4eca\uff0c\u79d1\u7814\u4eba\u5458\u5bf9\u53cd\u5e94\u6761\u4ef6\u4e0b\u9521\u57fa\u50ac\u5316\u5242\u50ac\u5316\u673a\u7406\uff0c\u5305\u62ec\u50ac\u5316\u5242\u7684\u5b9e\u65f6\u7ed3\u6784\u6f14\u53d8\u4ee5\u53ca\u6240\u6709\u5173\u952e\u53cd\u5e94\u4e2d\u95f4\u4f53\u5728\u5f71\u54cd\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u9009\u62e9\u6027\u4e2d\u7684\u4f5c\u7528\uff0c\u4ecd\u7136\u7f3a\u4e4f\u5168\u9762\u4e86\u89e3\u3002\u672c\u5de5\u4f5c\u76ee\u524d\u7814\u7a76\u62a5\u544a\u4e86\u4e00\u4e2a\u6846\u67b6\uff0c\u8be5\u6846\u67b6\u7ed3\u5408\u7535\u5316\u5b66\u6d4b\u8bd5\u3001\u539f\u4f4d\u8868\u5f81\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u6765\u7814\u7a76\u9521\u57fa\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u504f\u597d\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u63ba\u6742\u7b2c\u4e8c\u79cd\u91d1\u5c5e\uff08Co\u3001Ni\u3001Ag\u3001Zn\u3001Ga\u3001Bi\uff09\u5bf9\u5f71\u54cd\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u6027\u80fd\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u8be5\u5de5\u4f5c\u901a\u8fc7\u539f\u4f4d X \u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7f18\u7ed3\u6784\u6d4b\u91cf\u63ed\u793a\u4e86\u4e0d\u540c\u6b21\u751f\u91d1\u5c5e\u5f15\u8d77\u7684 Sn \u4ef7\u6001\u7684\u52a8\u6001\u6f14\u5316\u3002\u4e8c\u7ef4\u706b\u5c71\u56fe\u4ece\u591a\u5c42\u9762\u63ed\u793a\u4e86\u6d89\u53ca\u6240\u6709\u5173\u952e\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u591a\u7ef4\u63cf\u8ff0\u7b26\uff0c\u4ee5\u8bc4\u4f30\u751f\u6210\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u3002\u8fd9\u5de5\u4f5c\u7814\u7a76\u4e86\u50ac\u5316\u5242\u7684\u5b9e\u65f6\u7ed3\u6784\u6f14\u5316\u548c\u6240\u6709\u6d89\u53ca\u7684\u5173\u952e\u4e2d\u95f4\u4ea7\u7269\uff0c\u4e3a\u7406\u89e3\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u9009\u62e9\u6027\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u6548\u7684\u6846\u67b6\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u00a0\u4e09\u3001\u3010\u6838\u5fc3\u521b\u65b0\u70b9\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u7ed3\u5408\u7535\u5316\u5b66\u6d4b\u8bd5\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u8be5\u7814\u7a76\u63ed\u793a\u4e86Sn\u57fa\u50ac\u5316\u5242\u5bf9\u4e0d\u540c\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u4e0d\u540c\u7684\u539f\u56e0\u3002\u901a\u8fc7\u8ba1\u7b97CO\u548c\u7532\u9178\u76d0\u4e2d\u95f4\u4ea7\u7269HOCO*\u548cHCOO*\u4e0e\u50ac\u5316\u5242\u7ed3\u5408\u80fd\u4e4b\u5dee\u0394<em><i>E<\/i><\/em><sub>(bind_HOCO)<\/sub>\u00a0\u2212 \u0394<em><i>E<\/i><\/em><sub>(bind_HCOO)<\/sub>\u00a0\u4ee5\u53ca\u6c22\u6c14\u4e2d\u95f4\u4ea7\u7269*H\u4e0e\u50ac\u5316\u5242\u7684\u7ed3\u5408\u80fd \u0394<em><i>E<\/i><\/em><sub>(bind_H)<\/sub>\uff0c\u7814\u7a76\u8868\u660e\uff1a1\uff09\u5f53Sn-M\uff08M = Co\u3001Ni\uff09\u7684\u0394E<sub>(bind_HOCO)<\/sub>\u00a0&#8211; \u0394E<sub>(bind_HCOO)<\/sub>\u00a0\u503c\u4f4e\uff08&lt;0.7eV\uff09\uff0c\u0394E<sub>(bind_H)<\/sub>\u00a0\u503c\u4e3a\u4e2d\u7b49\u8d1f\u503c\uff08\u223c-0.4 eV\uff09\uff0c\u6709\u5229\u4e8e\u6c22\u6c14\u4ea7\u751f\uff1b2\uff09\u0394E<sub>(bind_HOCO)<\/sub>-\u0394E<sub>(bind_HCOO)<\/sub>\u503c\u4f4e\u4e8e 0.7 eV\uff0c\u8868\u660e\u5f62\u6210\u7532\u9178\u76d0\u548c CO \u4ea7\u7269\u6240\u9700\u7684\u5173\u952e\u76f8\u4e92\u4f5c\u7528\u7684\u533a\u522b\u5f88\u5c0f\uff1b3\uff09\u5f53 \u0394E<sub>(bind_H) <\/sub>\u63a5\u8fd1 -0.4 eV\uff08\u76f8\u5f53\u4e8e \u0394G<sub>H*<\/sub>\u00a0\u63a5\u8fd1\u96f6\uff09\u65f6\uff0c\u53cd\u5e94\u66f4\u503e\u5411\u4e8e\u4ea7\u751f H<sub>2<\/sub>\uff1b4\uff09Sn-M\uff08M = Bi\u3001Ga\u3001Ag \u548c Sn\uff09\u7684\u0394E<sub>\uff08bind_HOCO\uff09<\/sub>&#8211; \u0394E<sub>\uff08bind_HCOO\uff09<\/sub>\u503c\u9ad8\uff08&gt;1.2 eV\uff09\uff0c\u0394E<sub>\uff08bind_H\uff09<\/sub>\u503c\u975e\u5e38\u8d1f\/\u6b63\uff08\u223c-0.7 eV \u548c&gt;0 eV\uff09\u65f6\uff0c\u53cd\u5e94\u66f4\u503e\u5411\u751f\u6210\u7532\u9178\u76d0\u3002\uff08\u56fe3\uff09<\/p>\n<p>\u9664\u6b64\u4ee5\u5916\uff0c\u8be5\u7814\u7a76\u901a\u8fc7\u4e0d\u540c\u7535\u4f4d\u4e0b SnZn \u7684 \u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6027\u80fd\u548c\u7ed3\u6784\u6f14\u53d8\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u6240\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u6846\u67b6\u3002\u539f\u4f4dXANES\u7ed3\u679c\u8868\u660e\uff0c\u5728 -0.7 V \u81f3 -1.1 V \u7684\u8d1f\u7535\u4f4d\u6761\u4ef6\u4e0b\uff0cSnZn \u50ac\u5316\u5242\u4e2d Zn \u548c Sn \u7684\u4ef7\u6001\u4f1a\u964d\u4f4e\uff08\u56fe2\uff09\uff0c\u56e0\u6b64\u5728\u9ad8\u8d1f\u7535\u4f4d\u4e0b\uff0c\u50ac\u5316\u5242\u6676\u80de\u6a21\u578b\u8bbe\u7f6e\u4e3aSn<sub>1<\/sub>O<sub>1<\/sub>\u00a0\u56e2\u7c07\u9644\u7740\u5728Zn(0001) \u6676\u9762\u4e0a\uff08SnO\/Zn(0001)\uff09\uff1b\u800c\u4f4e\u8d1f\u7535\u4f4d\u4e0b\uff0c\u6676\u80de\u6a21\u578b\u8bbe\u7f6e\u4e3aSnO<sub>2<\/sub>\/ZnO(0001)_Ov\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff1a\u9ad8\u8d1f\u7535\u4f4d\u4e0b\uff0cSnO\/Zn(0001)\u7684\u0394E<sub>(bind_HOCO)<\/sub>\u00a0&#8211; \u0394E<sub>(bind_HCOO)<\/sub>\u503c\uff081.723 eV\uff09\u8d85\u8fc7\u4e86\u5728 SnO<sub>2<\/sub>\/ZnO(0001)_Ov \u4e0a\u89c2\u5bdf\u5230\u7684\u0394E<sub>(bind_HOCO)<\/sub>\u00a0&#8211; \u0394E<sub>(bind_HCOO)<\/sub>\u503c\uff081.393 eV\uff09\uff0c\u8bf4\u660e\u5bf9\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u66f4\u9ad8\u3002\u8be5\u53d1\u73b0\u4e0e\u5b9e\u9a8c\u7ed3\u679c\u4e00\u81f4\uff1a\u5373\u968f\u7740\u65bd\u52a0\u7535\u4f4d\u8d8a\u8d1f\uff0cSnZn \u50ac\u5316\u5242\u5bf9\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u589e\u52a0\uff08\u56fe1\uff09\uff0c\u8bc1\u660e\u0394E<sub>(bind_HOCO)<\/sub>\u00a0&#8211; \u0394E<sub>(bind_HCOO)<\/sub>\u00a0\u89e3\u91ca\u7532\u9178\u9009\u62e9\u6027\u7684\u6709\u6548\u6027\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u56db\u3001\u3010\u6570\u636e\u6982\u89c8\u3011 <\/strong><\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-262286 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72471-20.png\" alt=\"\" width=\"912\" height=\"740\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72471-20.png 912w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72471-20-300x243.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72471-20-768x623.png 768w\" sizes=\"(max-width: 912px) 100vw, 912px\" \/> \u00a0<\/strong><\/p>\n<p>\u56fe1 \u00a0\u9521\u57fa\u50ac\u5316\u5242\u7684\u7535\u6d41\u4ee5\u53ca\u5bf9\u4e0d\u540c\u4ea7\u7269\u5728\u4e0d\u540c\u7535\u538b\u4e0b\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-262287 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72472-21.png\" alt=\"\" width=\"903\" height=\"1152\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72472-21.png 903w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72472-21-235x300.png 235w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72472-21-768x980.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72472-21-803x1024.png 803w\" sizes=\"(max-width: 903px) 100vw, 903px\" \/><\/strong><\/p>\n<p>\u56fe2 \u00a0\u539f\u4f4dXANES \u53cd\u5e94\u5668\u53caSnZn\u548cSnBi\u7684\u539f\u4f4dXANES\u8c31\u56fe\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-262288 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72473-20.png\" alt=\"\" width=\"1099\" height=\"792\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72473-20.png 1099w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72473-20-300x216.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72473-20-768x553.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/08\/\u56fe\u72473-20-1024x738.png 1024w\" sizes=\"(max-width: 1099px) 100vw, 1099px\" \/><\/strong><\/p>\n<p>\u56fe3 \u00a0\u9521\u57fa\u50ac\u5316\u5242\u4e0e\u4e0d\u540c\u53cd\u5e94\u4e2d\u95f4\u4ea7\u7269\u7684\u4e8c\u7ef4\u706b\u5c71\u56fe\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e94\u3001\u3010\u6210\u679c\u542f\u793a\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u7ed3\u5408\u7535\u5316\u5b66\u6027\u80fd\u8d8b\u52bf\u3001\u539f\u4f4d\u8868\u5f81\u548c DFT \u8ba1\u7b97\uff0c\u7814\u7a76\u5c55\u793a\u4e86Sn-M \u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u6027\u80fd\uff0c\u7279\u522b\u662f\u5f15\u5165\u8f85\u52a9\u5143\u7d20\uff08Co\u3001Ni\u3001Ag\u3001Zn\u3001Ga\u3001Bi\uff09\u5982\u4f55\u5f71\u54cd\u5176\u7535\u50ac\u5316\u6027\u80fd\u3002\u4e0eSn \u50ac\u5316\u5242\u76f8\u6bd4\uff0cSnNi \u548c SnCo \u50ac\u5316\u5242\u5bf9 H2 \u7684\u9009\u62e9\u6027\u66f4\u9ad8\uff0c\u800c\u5728 Sn \u4e2d\u52a0\u5165 Bi\u3001Ga\u3001Ag \u548c Zn \u5219\u4f1a\u63d0\u9ad8\u5bf9\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u3002\u5177\u4f53\u800c\u8a00\uff0c\u5728\u8d1f\u7535\u4f4d\u8f83\u9ad8\u7684\u60c5\u51b5\u4e0b\uff0cSnBi \u7684\u7532\u9178\u916f\u9009\u62e9\u6027\u6700\u9ad8\uff0c\u8fbe\u5230 90%\u3002\u539f\u4f4d XANES \u7ed3\u679c\u8868\u660e\u9521\u4ef7\u6001\u5728\u7535\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53d1\u751f\u53d8\u5316\uff0c\u8bf4\u660e\u63ba\u6742\u8f85\u52a9\u91d1\u5c5e\u5f71\u54cd\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\u3002\u57fa\u4e8e\u6b64\uff0c\u8be5\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u540c\u65f6\u6d89\u53ca HCOO*\u3001HOCO* \u548c H* \u5438\u9644\u7684\u591a\u7ef4\u63cf\u8ff0\u56e0\u5b50\uff08\u0394E<sub>(bind_HOCO)<\/sub>\u00a0&#8211; \u0394E<sub>(bind_HCOO)<\/sub>\u548c \u0394E<sub>(bind_H)\uff09<\/sub>\u3002\u901a\u8fc7\u4e8c\u7ef4\u6d3b\u6027\u706b\u5c71\u56fe\u8bc4\u4f30\u4e0d\u540c\u50ac\u5316\u5242\u5bf9\u7532\u9178\u76d0\u7684\u9009\u62e9\u6027\u3002\u540c\u65f6\u7814\u7a76SnZn\u5728\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u671f\u95f4\u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u7ed3\u6784\u6f14\u53d8\uff0c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u8be5\u63cf\u8ff0\u56e0\u5b50\u7684\u6b63\u786e\u6027\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u52a0\u6df1\u4e86\u6211\u4eec\u5bf9\u7528\u4e8e\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u53cd\u5e94\u7684 Sn-M \u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u673a\u7406\u7684\u7406\u89e3\uff0c\u8fd8\u5f3a\u8c03\u4e86\u50ac\u5316\u5242\u5728\u53cd\u5e94\u4e2d\u7684\u7ed3\u6784\u6f14\u53d8\u548c\u53cd\u5e94\u4e2d\u95f4\u4ea7\u7269\u7528\u4e8e\u89e3\u91ca\u4ea7\u7269\u9009\u62e9\u7387\u7684\u91cd\u8981\u6027\u3002<\/p>\n<p><strong>\u516d\u3001\u3010\u8bfe\u9898\u7ec4\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u5e38\u4e54\u5a49\u535a\u58eb2023\u52a0\u5165\u534e\u76db\u987f\u5dde\u7acb\u5927\u5b66\u6210\u4e3a\u5316\u5b66\u5de5\u7a0b\u7cfb\u52a9\u7406\u6559\u6388\u3002\u5979\u5728\u54e5\u4f26\u6bd4\u4e9a\u5927\u5b66\u7684\u9648\u7ecf\u5e7f\u6559\u6388\u548cAlissa Park\u6559\u6388\u8bfe\u9898\u7ec4\u8fdb\u884c\u535a\u58eb\u540e\u7814\u7a76\u3002\u5979\u5728\u52a0\u5dde\u5927\u5b66\u5723\u5730\u4e9a\u54e5\u5206\u6821\u83b7\u5f97\u5316\u5b66\u5de5\u7a0b\u535a\u58eb\u5b66\u4f4d\uff0c\u5bfc\u5e08\u662f\u9648\u653f\u6559\u6388\u3002\u8bfe\u9898\u7ec4\u7814\u7a76\u91cd\u70b9\u4e3a\u7535\u50ac\u5316\u5242\u8bbe\u8ba1\u548c\u901a\u8fc7\u539f\u4f4d\u8868\u5f81\u8fdb\u884c\u7535\u50ac\u5316\u53cd\u5e94\u673a\u5236\u7814\u7a76\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u539f\u6587\u8be6\u60c5<\/strong>\uff1ahttps:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2024\/ta\/d4ta02315c<\/p>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531XXX\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u00a0\u3010\u5bfc\u8bfb\u3011 \u00a0 \u81ea\u7b2c\u4e00\u6b21\u5de5\u4e1a\u9769\u547d\u4ee5\u6765\uff0c\u5316\u77f3\u71c3\u6599\u7684\u8fc7\u5ea6\u6d88\u8017\u5bfc\u81f4\u5927\u6c14\u4e2d\u4e8c\u6c27\u5316\u78b3\u542b\u91cf\u6025\u5267\u589e\u52a0\uff0c\u52a0\u5267\u6e29\u5ba4\u6548\u5e94\u548c\u5f71\u54cd\u751f\u6001\u7cfb\u7edf\u3002\u901a\u8fc7\u6355\u83b7\u4e8c\u6c27\u5316\u78b3\u5e76\u5c06\u5176\u8fd8\u539f\u8f6c\u5316\uff0c\u4e0d\u4ec5\u53ef\u4ee5&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-262285","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262285"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=262285"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262285\/revisions"}],"predecessor-version":[{"id":262289,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262285\/revisions\/262289"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=262285"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=262285"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=262285"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}