{"id":262564,"date":"2024-09-16T07:52:42","date_gmt":"2024-09-15T23:52:42","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=262564"},"modified":"2024-09-15T23:07:39","modified_gmt":"2024-09-15T15:07:39","slug":"%e9%83%91%e5%b7%9e%e5%a4%a7%e5%ad%a6%e5%bc%a0%e4%bd%b3%e6%a5%a0-%e5%a4%8f%e4%bc%9a%e8%81%aaafm%ef%bc%9a%e6%8e%a2%e7%b4%a2%e7%94%b5%e5%ad%90%e8%87%aa%e6%97%8b%e6%9e%81%e5%8c%96%ef%bc%9a%e5%8a%a9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=262564","title":{"rendered":"\u90d1\u5dde\u5927\u5b66\u5f20\u4f73\u6960\/\u590f\u4f1a\u806aAFM\uff1a\u63a2\u7d22\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff1a\u52a9\u529b\u4e0b\u4e00\u4ee3\u53ef\u5145\u7535\u7535\u6c60\u7684\u521b\u65b0!"},"content":{"rendered":"

\u63a8\u6587\u4f5c\u8005:\u5f20\u4f73\u6960\u56e2\u961f<\/p>\n

\u7b2c\u4e00\u4f5c\u8005\uff1a\u590f\u4f1a\u806a<\/p>\n

\u901a\u8baf\u4f5c\u8005\uff1a\u590f\u4f1a\u806a \u5f20\u4f73\u6960<\/p>\n

\u901a\u8baf\u5355\u4f4d\uff1a\u90d1\u5dde\u5927\u5b66<\/p>\n

\u8bba\u6587DOI\uff1a10.1002\/adfm.202413491<\/p>\n

\"\" \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n

1\u3001 \u5168\u6587\u901f\u89c8\uff1a \u672c\u6587\u6df1\u5165\u63a2\u8ba8\u4e86\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff08ESP\uff09\u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u6f5c\u5728\u5e94\u7528\uff0c\u5206\u6790\u4e86ESP\u5982\u4f55\u901a\u8fc7\u64cd\u63a7\u7535\u5b50\u81ea\u65cb\u65b9\u5411\u6765\u4f18\u5316\u7535\u6c60\u7684\u5145\u653e\u7535\u6548\u7387\u3001\u80fd\u91cf\u5bc6\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u3002\u6587\u7ae0\u56de\u987e\u4e86ESP\u7684\u7406\u8bba\u57fa\u7840\uff0c\u7ed3\u5408\u5b9e\u9a8c\u6280\u672f\uff0c\u5c55\u793a\u4e86\u8be5\u6280\u672f\u5728\u4e0d\u540c\u7535\u6c60\u4f53\u7cfb\u4e2d\u7684\u5e94\u7528\u524d\u666f\u4e0e\u5b9e\u9645\u6311\u6218\u3002<\/p>\n

2\u3001 \u80cc\u666f\u4ecb\u7ecd\uff1a\u968f\u7740\u5168\u7403\u7535\u6c14\u5316\u548c\u53ef\u518d\u751f\u80fd\u6e90\u5e94\u7528\u7684\u4e0d\u65ad\u52a0\u901f\uff0c\u5e02\u573a\u5bf9\u6027\u80fd\u4f18\u5f02\u7684\u53ef\u5145\u7535\u7535\u6c60\u9700\u6c42\u65e5\u76ca\u589e\u52a0\u3002\u63d0\u9ad8\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u5145\u653e\u7535\u901f\u5ea6\u548c\u5faa\u73af\u5bff\u547d\u662f\u5f53\u4eca\u50a8\u80fd\u6280\u672f\u53d1\u5c55\u7684\u5173\u952e\u76ee\u6807\u3002\u7535\u5b50\u81ea\u65cb\u6781\u5316 (ESP) \u662f\u4e00\u79cd\u91cf\u5b50\u529b\u5b66\u73b0\u8c61\uff0c\u5b83\u901a\u8fc7\u64cd\u63a7\u7535\u5b50\u81ea\u65cb\u7684\u65b9\u5411\u6765\u63d0\u5347\u7535\u6c60\u6027\u80fd\u3002\u8fd1\u5e74\u6765\uff0cESP \u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u524d\u666f\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\uff0c\u7814\u7a76\u8868\u660e\u8fd9\u4e00\u6280\u672f\u6709\u671b\u6781\u5927\u5730\u63d0\u9ad8\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u5145\u653e\u7535\u6548\u7387\u53ca\u5faa\u73af\u5bff\u547d\u3002ESP \u7684\u6838\u5fc3\u662f\u901a\u8fc7\u8c03\u6574\u7535\u5b50\u7684\u81ea\u65cb\u72b6\u6001\u6765\u4f18\u5316\u7535\u6781\u6750\u6599\u4e2d\u7684\u7535\u8377\u4f20\u9012\u8fc7\u7a0b\u3002\u901a\u8fc7\u81ea\u65cb\u7684\u7cbe\u786e\u63a7\u5236\uff0c\u7814\u7a76\u4eba\u5458\u53ef\u4ee5\u6539\u5584\u7535\u6c60\u7684\u5bfc\u7535\u6027\uff0c\u52a0\u901f\u9502\u79bb\u5b50\u3001\u94a0\u79bb\u5b50\u548c\u94be\u79bb\u5b50\u7684\u4f20\u8f93\uff0c\u5e76\u51cf\u5c11\u80fd\u91cf\u635f\u5931\uff0c\u4ece\u800c\u5b9e\u73b0\u5feb\u901f\u5145\u7535\u548c\u5ef6\u957f\u7535\u6c60\u5bff\u547d\u3002<\/p>\n

ESP \u6280\u672f\u7684\u5173\u952e\u4f18\u52bf\uff1a<\/p>\n

\u63d0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff1a\u901a\u8fc7\u8c03\u6574\u7535\u5b50\u81ea\u65cb\u72b6\u6001\uff0c\u53ef\u4ee5\u4f18\u5316\u7535\u8377\u8f6c\u79fb\u8def\u5f84\uff0c\u663e\u8457\u63d0\u9ad8\u7535\u6c60\u7684\u50a8\u80fd\u80fd\u529b\u3002<\/p>\n

\u52a0\u901f\u5145\u7535\u901f\u5ea6\uff1aESP \u6280\u672f\u80fd\u591f\u51cf\u5c11\u7535\u5b50\u5728\u4f20\u5bfc\u8fc7\u7a0b\u4e2d\u7684\u963b\u529b\uff0c\u4ece\u800c\u52a0\u5feb\u5145\u7535\u901f\u5ea6\uff0c\u7f29\u77ed\u8bbe\u5907\u7684\u5145\u7535\u65f6\u95f4\u3002<\/p>\n

\u5ef6\u957f\u5faa\u73af\u5bff\u547d\uff1a\u901a\u8fc7\u6291\u5236\u5bfc\u81f4\u7535\u6c60\u5bb9\u91cf\u8870\u51cf\u7684\u526f\u53cd\u5e94\uff0cESP \u6709\u52a9\u4e8e\u51cf\u7f13\u6750\u6599\u964d\u89e3\uff0c\u5ef6\u957f\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

\u5145\u7535\u7535\u6c60\u4e2dESP\u7684\u57fa\u672c\u539f\u7406<\/b><\/strong><\/p>\n

\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff08ESP\uff09\u662f\u5f71\u54cd\u6750\u6599\u78c1\u6027\u3001\u81ea\u65cb\u7535\u5b50\u5b66\u548c\u78c1\u6027\u6570\u636e\u5b58\u50a8\u7b49\u591a\u9886\u57df\u7684\u57fa\u672c\u73b0\u8c61\u3002\u79d1\u5b66\u5bb6\u4eec\u901a\u8fc7\u5404\u79cd\u5b9e\u9a8c\u6280\u672f\u548c\u7406\u8bba\u6a21\u578b\u6765\u7814\u7a76\u548c\u8868\u5f81ESP\u3002\u8fd9\u4e9b\u6280\u672f\u5305\u62ec\u7a46\u65af\u5821\u5c14\u8c31\u5b66\u3001\u632f\u52a8\u6837\u54c1\u78c1\u5f3a\u8ba1\uff08VSM\uff09\u3001\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\u8c31\u5b66\u3001\u91d1\u5c5eL\u8fb9X\u5c04\u7ebf\u5438\u6536\u8c31\u5b66\u53ca\u7406\u8bba\u8ba1\u7b97\u7b49\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u80fd\u591f\u6df1\u523b\u63ed\u793aESP\u7684\u590d\u6742\u673a\u5236\u3002\u4f8b\u5982\uff0c\u7a46\u65af\u5821\u5c14\u8c31\u5b66\u53ef\u901a\u8fc7\u6838\u81ea\u65cb\u4e0e\u7535\u5b50\u81ea\u65cb\u76f8\u4e92\u4f5c\u7528\u63d0\u4f9b\u6709\u5173ESP\u7684\u8be6\u7ec6\u4fe1\u606f\uff0cEPR\u548cVSM\u5219\u7528\u4e8e\u5206\u6790\u6750\u6599\u5728\u4e0d\u540c\u78c1\u573a\u5f3a\u5ea6\u4e0b\u7684\u78c1\u7279\u6027\u3002\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\uff0c\u7814\u7a76\u4eba\u5458\u80fd\u591f\u6a21\u62df\u78c1\u573a\u5bf9\u7535\u5b50\u81ea\u65cb\u7684\u5f71\u54cd\uff0c\u4e3a\u5b9e\u9a8c\u63d0\u4f9b\u7406\u8bba\u652f\u6301\u3002\u8fd9\u4e9b\u65b9\u6cd5\u5e2e\u52a9\u79d1\u5b66\u5bb6\u7406\u89e3ESP\u7684\u57fa\u672c\u673a\u5236\uff0c\u5e76\u6269\u5c55\u5176\u5728\u6750\u6599\u79d1\u5b66\u3001\u81ea\u65cb\u7535\u5b50\u5b66\u548c\u78c1\u5b58\u50a8\u4e2d\u7684\u5e94\u7528\u3002\u6b64\u5916\uff0c\u7814\u7a76\u8fd8\u53d1\u5c55\u4e86\u591a\u79cd\u63a7\u5236ESP\u7684\u7b56\u7565\uff0c\u5982\u78c1\u573a\u8c03\u63a7\u3001\u81ea\u65cb\u6ce8\u5165\u3001\u81ea\u65cb\u8f68\u9053\u8026\u5408\u3001\u81ea\u65cb\u4ea4\u6362\u4f5c\u7528\u548c\u81ea\u65cb\u5171\u632f\u7b49\u3002\u8fd9\u4e9b\u7b56\u7565\u4e0d\u4ec5\u589e\u5f3a\u4e86\u6211\u4eec\u5bf9ESP\u7684\u7406\u89e3\uff0c\u8fd8\u63a8\u52a8\u4e86\u5176\u5728\u73b0\u4ee3\u6280\u672f\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u65bd\u52a0\u5916\u90e8\u78c1\u573a\u6216\u5f15\u5165\u7535\u6d41\uff0cESP\u53ef\u4ee5\u88ab\u6fc0\u6d3b\u548c\u63a7\u5236\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6c60\u6548\u7387\u3001\u589e\u5f3a\u50ac\u5316\u53cd\u5e94\u7b49\u3002ESP \u7684\u63a7\u5236\u5728\u50a8\u80fd\u3001\u4fe1\u606f\u5904\u7406\u7b49\u9886\u57df\u5c55\u73b0\u4e86\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\"\"<\/p>\n

\u793a\u610f\u56fe. \u7535\u5b50\u81ea\u65cb\u6781\u5316\u7684\u4e3b\u8981\u7c7b\u578b<\/p>\n

ESP\u7279\u6027\u548c\u8c03\u8282\u7b56\u7565<\/b><\/strong><\/p>\n

\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff08ESP\uff09\u662f\u4e00\u79cd\u5728\u591a\u4e2a\u9886\u57df\u4e2d\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u7684\u57fa\u672c\u73b0\u8c61\uff0c\u6db5\u76d6\u4e86\u6750\u6599\u78c1\u6027\u3001\u81ea\u65cb\u7535\u5b50\u5b66\u548c\u78c1\u5b58\u50a8\u7b49\u65b9\u9762\u3002\u4e3a\u4e86\u63ed\u793aESP\u7684\u590d\u6742\u6027\uff0c\u79d1\u5b66\u5bb6\u4eec\u91c7\u7528\u4e86\u591a\u79cd\u5b9e\u9a8c\u6280\u672f\u548c\u7406\u8bba\u6a21\u578b\uff0c\u5305\u62ec\u7a46\u65af\u5821\u5c14\u8c31\u5b66\uff08M\u00f6ssbauer spectroscopy\uff09\u3001\u632f\u52a8\u6837\u54c1\u78c1\u5f3a\u8ba1\uff08VSM\uff09\u3001\u7535\u5b50\u987a\u78c1\u5171\u632f\u8c31\uff08EPR\uff09\u4ee5\u53ca\u91d1\u5c5eL\u8fb9X\u5c04\u7ebf\u5438\u6536\u8c31\u5b66\uff08L-edge X-ray absorption spectroscopy\uff09\uff0c\u5e76\u7ed3\u5408\u7406\u8bba\u8ba1\u7b97\u6765\u6df1\u5165\u63a2\u8ba8\u3002<\/p>\n

1\u3001\u7a46\u65af\u5821\u5c14\u8c31\u5b66\u901a\u8fc7\u63a2\u6d4b\u6838\u81ea\u65cb\u548c\u7535\u5b50\u81ea\u65cb\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u5206\u6790\u6750\u6599\u4e2d\u7684\u6838\u80fd\u7ea7\u5206\u88c2\u60c5\u51b5\uff0c\u4ece\u800c\u63ed\u793aESP\u73b0\u8c61\u3002\u901a\u8fc7\u8be5\u6280\u672f\u53ef\u4ee5\u533a\u5206\u5e76\u91cf\u5316\u6837\u54c1\u4e2d\u7684\u4e0d\u540c\u94c1\u7269\u79cd\uff0c\u5e76\u8bc4\u4f30\u5176\u5728\u4e0d\u540c\u73af\u5883\u6761\u4ef6\u4e0b\u7684\u7535\u5b50\u81ea\u65cb\u884c\u4e3a\u3002<\/p>\n

2\u3001\u632f\u52a8\u6837\u54c1\u78c1\u5f3a\u8ba1\u7528\u4e8e\u7814\u7a76\u6750\u6599\u5728\u5916\u52a0\u78c1\u573a\u4e0b\u7684\u78c1\u6027\u54cd\u5e94\u3002\u5b83\u901a\u8fc7\u673a\u68b0\u632f\u52a8\u8bb0\u5f55\u6750\u6599\u7684\u78c1\u5316\u5f3a\u5ea6\uff0c\u80fd\u591f\u5206\u6790\u6837\u54c1\u5728\u4e0d\u540c\u78c1\u573a\u5f3a\u5ea6\u4e0b\u7684\u81ea\u65cb\u6781\u5316\u7279\u6027\u3002\u7814\u7a76\u8005\u8fd8\u901a\u8fc7\u6e29\u5ea6\u4f9d\u8d56\u7684\u78c1\u5316\u66f2\u7ebf\uff08M-T\u66f2\u7ebf\uff09\u63a2\u8ba8\u4e86\u4e0d\u540cFe-Co\u6bd4\u7387\u7684\u6837\u54c1\u5728\u6e29\u5ea6\u53d8\u5316\u4e0b\u7684\u81ea\u65cb\u6781\u5316\u5f71\u54cd\u3002<\/p>\n

3\u3001EPR\u8c31\u5b66\u7528\u4e8e\u6d4b\u91cf\u987a\u78c1\u6750\u6599\u5728\u5fae\u6ce2\u8f90\u5c04\u4e0b\u7684\u5438\u6536\u548c\u53d1\u5c04\uff0c\u901a\u8fc7\u8c03\u8282\u78c1\u573a\u5f3a\u5ea6\u548c\u9891\u7387\uff0c\u80fd\u591f\u89e3\u6790\u6750\u6599\u4e2d\u7535\u5b50\u81ea\u65cb\u7684\u80fd\u7ea7\u7ed3\u6784\u548c\u52a8\u6001\u884c\u4e3a\u3002EPR\u7ed3\u679c\u663e\u793a\u4e86Fe-Co\u6bd4\u7387\u5bf9\u6750\u6599\u81ea\u65cb\u6781\u5316\u7a0b\u5ea6\u7684\u5f71\u54cd\uff0c\u968f\u7740\u94c1\u542b\u91cf\u7684\u589e\u52a0\uff0c\u81ea\u65cb\u6781\u5316\u589e\u5f3a\u3002<\/p>\n

4\u3001\u91d1\u5c5eL\u8fb9X\u5c04\u7ebf\u5438\u6536\u8c31\u5b66\u7528\u4e8e\u63a2\u6d4b\u91d1\u5c5e\u4e2d\u7684\u7535\u5b50\u7ed3\u6784\u548cESP\uff0c\u901a\u8fc7\u9ad8\u80fdX\u5c04\u7ebf\u6765\u5206\u6790L\u8fb9\u7535\u5b50\u7684\u5438\u6536\u5149\u8c31\uff0c\u5f97\u51fa\u7535\u5b50\u81ea\u65cb\u548c\u8f68\u9053\u914d\u7f6e\u7684\u8be6\u7ec6\u4fe1\u606f\u3002\u4f8b\u5982\uff0cCo L\u8fb9\u8c31\u63ed\u793a\u4e86Co\u4e2d\u672a\u5360\u636e\u7684\u7535\u5b50\u8f68\u9053\u7279\u6027\uff0c\u5e76\u901a\u8fc7\u5206\u6790L3\/L2\u8fb9\u7684\u5f3a\u5ea6\u6bd4\u8fdb\u4e00\u6b65\u7406\u89e3\u4e86Co\u7684\u4f4e\u81ea\u65cb\u72b6\u6001\u3002<\/p>\n

5\u3001\u7406\u8bba\u8ba1\u7b97\u901a\u8fc7\u91cf\u5b50\u529b\u5b66\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u7b49\u65b9\u6cd5\uff0c\u6a21\u62df\u78c1\u573a\u5bf9\u6750\u6599\u4e2d\u7535\u5b50\u81ea\u65cb\u7684\u5f71\u54cd\uff0c\u4ece\u800c\u9884\u6d4b\u6709\u6548\u78c1\u77e9\u3002\u901a\u8fc7\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u94c1\u542b\u91cf\u589e\u52a0\u65f6\uff0c\u5421\u5576\u6c2e\u7684\u78c1\u77e9\u5448\u6b63\u76f8\u5173\u5173\u7cfb\uff0c\u8fd9\u79cd\u53d8\u5316\u4e0e\u50ac\u5316\u6d3b\u6027\u7684\u5173\u7cfb\u5f97\u5230\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u3002<\/p>\n

\u8fd9\u4e9b\u65b9\u6cd5\u4e3aESP\u7684\u8868\u5f81\u63d0\u4f9b\u4e86\u591a\u79cd\u9014\u5f84\uff0c\u6df1\u5316\u4e86\u5bf9\u5176\u673a\u5236\u7684\u7406\u89e3\uff0c\u5e76\u6269\u5c55\u4e86\u5176\u5728\u6750\u6599\u79d1\u5b66\u3001\u78c1\u5b58\u50a8\u548c\u81ea\u65cb\u7535\u5b50\u5b66\u7b49\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

ESP\u63a7\u5236\u7b56\u7565\u5bf9\u81ea\u65cb\u78c1\u77e9\u7684\u64cd\u63a7\u81f3\u5173\u91cd\u8981\uff0c\u5177\u6709\u91cd\u8981\u7684\u5b9e\u9645\u5e94\u7528\u3002\u4e3b\u8981\u63a7\u5236\u7b56\u7565\u5305\u62ec\uff1a<\/p>\n

1\u3001\u78c1\u573a\u8c03\u63a7\uff1a\u901a\u8fc7\u5916\u52a0\u78c1\u573a\u8c03\u8282\u81ea\u65cb\u7684\u65b9\u5411\u548c\u5f3a\u5ea6\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u78c1\u5b58\u50a8\u548c\u78c1\u5171\u632f\u6210\u50cf\u7b49\u9886\u57df\u3002\u4f8b\u5982\uff0c\u5728\u78c1\u5b58\u50a8\u6280\u672f\u4e2d\uff0c\u901a\u8fc7\u8c03\u8282\u78c1\u6027\u6750\u6599\u7684\u81ea\u65cb\u65b9\u5411\u53ef\u4ee5\u5b9e\u73b0\u6570\u636e\u7684\u7f16\u7801\u548c\u8bfb\u53d6\u3002\u6b64\u5916\uff0c\u7814\u7a76\u8fd8\u8868\u660e\uff0c\u901a\u8fc7\u5728CsPbBr3<\/sub>\u7eb3\u7c73\u7247\u4e2d\u63ba\u5165\u9530\u5e76\u65bd\u52a0\u78c1\u573a\uff0c\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u7684\u6548\u7387\u3002<\/p>\n

2\u3001\u81ea\u65cb\u6ce8\u5165\uff1a\u901a\u8fc7\u5f15\u5165\u7535\u6d41\u6216\u5149\u7167\u6fc0\u53d1\u6750\u6599\u4e2d\u7684\u81ea\u65cb\u6781\u5316\uff0c\u81ea\u65cb\u6ce8\u5165\u65b9\u6cd5\u5728\u81ea\u65cb\u7535\u5b50\u5668\u4ef6\u4e2d\u81f3\u5173\u91cd\u8981\uff0c\u4f8b\u5982\u901a\u8fc7\u81ea\u65cb\u6781\u5316\u7535\u6d41\u7cbe\u786e\u4f20\u9012\u548c\u64cd\u63a7\u81ea\u65cb\u3002\u8fd9\u79cd\u65b9\u6cd5\u8fd8\u7528\u4e8e\u9502\u5bcc\u96c6\u6b63\u6781\u6750\u6599\u4e2d\uff0c\u901a\u8fc7\u8c03\u8282\u9634\u79bb\u5b50\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u964d\u4f4e\u7535\u6c60\u4e2d\u7684\u7535\u538b\u6ede\u540e\u73b0\u8c61\u3002<\/p>\n

3\u3001\u81ea\u65cb\u8f68\u9053\u8026\u5408\uff1a\u8be5\u73b0\u8c61\u662f\u81ea\u65cb\u4e0e\u8f68\u9053\u89d2\u52a8\u91cf\u4e4b\u95f4\u7684\u8f6c\u6362\u673a\u5236\uff0c\u53ef\u901a\u8fc7\u6750\u6599\u7684\u6676\u4f53\u7ed3\u6784\u3001\u5bf9\u79f0\u6027\u548c\u7535\u573a\u53c2\u6570\u8fdb\u884c\u8c03\u8282\u3002\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u81ea\u65cb\u8f68\u9053\u8026\u5408\u53ef\u4ee5\u4f18\u5316\u7535\u5b50\u7ed3\u6784\uff0c\u589e\u5f3a\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

4\u3001\u81ea\u65cb\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528\uff1a\u8fd9\u79cd\u76f8\u4e92\u4f5c\u7528\u51b3\u5b9a\u4e86\u6750\u6599\u5185\u90e8\u81ea\u65cb\u4f20\u9012\u548c\u4f20\u64ad\u7684\u52a8\u529b\u5b66\u3002\u901a\u8fc7\u8c03\u6574\u81ea\u65cb\u4ea4\u6362\u52a8\u6001\uff0c\u53ef\u4ee5\u589e\u5f3a\u81ea\u65cb\u4fe1\u606f\u5904\u7406\u7684\u80fd\u529b\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u57285Co0.5-MOF\u4e2d\u5f15\u5165\u8d85\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528\uff0c\u52a0\u901f\u6c27\u6790\u51fa\u53cd\u5e94\u7684\u81ea\u65cb\u4f9d\u8d56\u53cd\u5e94\u52a8\u529b\u5b66\u3002<\/p>\n

5\u3001\u81ea\u65cb\u5171\u632f\uff1a\u81ea\u65cb\u5171\u632f\u6280\u672f\uff0c\u5305\u62ec\u6838\u78c1\u5171\u632f\uff08NMR\uff09\u548c\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\uff0c\u53ef\u4ee5\u7cbe\u786e\u63a7\u5236ESP\u3002NMR\u901a\u8fc7\u6838\u81ea\u65cb\u7ed3\u5408\u5916\u52a0\u78c1\u573a\u6765\u5206\u6790\u6750\u6599\u7ed3\u6784\uff0c\u800cEPR\u5219\u63a2\u6d4b\u987a\u78c1\u6750\u6599\u4e2d\u7684\u7535\u5b50\u81ea\u65cb\u7279\u6027\u3002<\/p>\n

\u8fd9\u4e9b\u7b56\u7565\u4e0d\u4ec5\u52a0\u6df1\u4e86\u5bf9ESP\u7684\u7406\u89e3\uff0c\u8fd8\u63d0\u5347\u4e86\u5176\u5728\u591a\u4e2a\u79d1\u5b66\u9886\u57df\u7684\u5b9e\u9645\u5e94\u7528\uff0c\u8868\u660e\u81ea\u65cb\u73b0\u8c61\u7684\u8c03\u63a7\u5728\u73b0\u4ee3\u6280\u672f\u548c\u79d1\u5b66\u8fdb\u6b65\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5f71\u54cd\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. \u7535\u5b50\u81ea\u65cb\u6781\u5316\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u56fe2. \u7535\u5b50\u81ea\u65cb\u6781\u5316\u63a7\u5236\u7b56\u7565<\/p>\n

 <\/p>\n

\u53ef\u5145\u7535\u7535\u6c60\u6750\u6599\u4e2d\u7684ESP\u7b56\u7565<\/b><\/strong><\/p>\n

\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff08ESP\uff09\u901a\u8fc7\u591a\u79cd\u624b\u6bb5\u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u5f97\u5230\u4e86\u6709\u6548\u7684\u8bf1\u5bfc\u548c\u64cd\u63a7\uff0c\u4e3b\u8981\u624b\u6bb5\u5305\u62ec\u78c1\u6027\u6750\u6599\u3001\u5916\u52a0\u78c1\u573a\u3001\u81ea\u65cb\u6781\u5316\u7535\u89e3\u8d28\u4ee5\u53ca\u5c16\u7aef\u5149\u8c31\u6280\u672f\u3002\u901a\u8fc7\u8fd9\u4e9b\u65b9\u6cd5\uff0cESP\u80fd\u591f\u8c03\u63a7\u7535\u6781\u5185\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347\u7535\u6c60\u6027\u80fd\u3002<\/p>\n

1\u3001\u78c1\u6027\u6750\u6599\uff1a\u78c1\u6027\u6750\u6599\uff0c\u5c24\u5176\u662f\u94c1\uff08Fe\uff09\u3001\u94b4\uff08Co\uff09\u548c\u954d\uff08Ni\uff09\u7b49\u94c1\u78c1\u5143\u7d20\uff0c\u901a\u8fc7\u5176\u81ea\u65cb\u5bf9\u9f50\u5f62\u6210\u7684\u51c0\u78c1\u77e9\uff0c\u80fd\u591f\u5728\u7535\u6c60\u7535\u6781\u4e2d\u8c03\u63a7ESP\uff0c\u4ece\u800c\u6539\u5584\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u3002\u4f8b\u5982\uff0c\u5e94\u7528\u78c1\u6027\u8584\u819c\u5230\u7535\u6c60\u7535\u6781\u53ef\u4ee5\u589e\u5f3a\u5176\u78c1\u6027\u80fd\uff0c\u5e76\u63d0\u9ad8\u7535\u8377\u8f6c\u79fb\u901f\u7387\u3002<\/p>\n

2\u3001\u5916\u52a0\u78c1\u573a\uff1a\u5916\u52a0\u78c1\u573a\u5728\u63a7\u5236\u7535\u6c60\u4e2d\u7684ESP\u65b9\u9762\u4e5f\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u901a\u8fc7\u78c1\u573a\u4f7fESP\u6cbf\u9884\u5b9a\u65b9\u5411\u5bf9\u9f50\uff0c\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u7535\u8377\u8f6c\u79fb\u6548\u7387\u3002\u7814\u7a76\u8868\u660e\uff0c\u8109\u51b2\u78c1\u573a\u6709\u52a9\u4e8e\u589e\u5f3a\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u7684\u5bb9\u91cf\u548c\u5faa\u73af\u5bff\u547d\u7b49\u6027\u80fd\u6307\u6807\u3002<\/p>\n

3\u3001\u81ea\u65cb\u6781\u5316\u7535\u89e3\u8d28\uff1a\u4f7f\u7528\u81ea\u65cb\u6781\u5316\u7535\u89e3\u8d28\u8fdb\u4e00\u6b65\u6269\u5c55\u4e86ESP\u7684\u63a7\u5236\u7ef4\u5ea6\u3002\u5728\u8fd9\u4e9b\u7cfb\u7edf\u4e2d\uff0c\u7535\u89e3\u8d28\u4e2d\u7684\u79bb\u5b50\u8868\u73b0\u51fa\u504f\u5411\u7684\u81ea\u65cb\u53d6\u5411\uff0c\u76f4\u63a5\u5f71\u54cd\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7684\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u3002\u4f18\u5316\u7535\u89e3\u8d28\u7684ESP\u53ef\u4ee5\u663e\u8457\u63d0\u5347\u7535\u8377\u8f6c\u79fb\u6548\u7387\u4ee5\u53ca\u7535\u6c60\u7684\u6574\u4f53\u80fd\u91cf\u5b58\u50a8\u5bb9\u91cf\u3002<\/p>\n

4\u3001\u5148\u8fdb\u5149\u8c31\u6280\u672f\uff1a\u7535\u5b50\u81ea\u65cb\u5171\u632f\uff08ESR\uff09\u5149\u8c31\u7b49\u6280\u672f\u5bf9\u8868\u5f81\u548c\u91cf\u5316\u7535\u6c60\u7cfb\u7edf\u4e2d\u7684ESP\u81f3\u5173\u91cd\u8981\u3002ESR\u5149\u8c31\u63d0\u4f9b\u4e86\u6709\u5173\u7535\u6c60\u6750\u6599\u4e2dESP\u7279\u5f81\u7684\u8be6\u7ec6\u4fe1\u606f\uff0c\u63ed\u793a\u4e86\u9a71\u52a8\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u7684\u673a\u5236\u3002\u7ed3\u5408X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u548c\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u7b49\u5de5\u5177\uff0c\u80fd\u591f\u66f4\u5168\u9762\u5730\u7406\u89e3ESP\u4e0e\u7535\u6c60\u6027\u80fd\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u3002<\/p>\n

\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u63a2\u7d22\u4e86\u4e00\u4e9b\u56fa\u6709ESP\u7279\u6027\u7684\u6750\u6599\u548c\u7ed3\u6784\uff0c\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u78c1\u6027\u7eb3\u7c73\u9897\u7c92\u548c\u6709\u673a\u81ea\u7531\u57fa\u3002\u8fd9\u4e9b\u6750\u6599\u5177\u6709\u6f5c\u529b\u5e94\u7528\u4e8e\u53ef\u5145\u7535\u7535\u6c60\uff0c\u4f5c\u4e3a\u7535\u6781\u3001\u7535\u89e3\u8d28\u6216\u6027\u80fd\u589e\u5f3a\u6dfb\u52a0\u5242\u3002\u4f8b\u5982\uff0c\u50cfLiCoO2<\/sub>\u3001LiNiO2<\/sub>\u548cLiMn2<\/sub>O4<\/sub>\u7b49\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7535\u5b50\u7ed3\u6784\u548c\u78c1\u6027\u5c5e\u6027\uff0c\u8868\u73b0\u51fa\u663e\u8457\u7684ESP\u7279\u6027\uff0c\u901a\u8fc7\u63ba\u6742\u548c\u8c03\u8282\u4ef7\u6001\u53ef\u4ee5\u8fdb\u4e00\u6b65\u4f18\u5316\u5176ESP\u5c5e\u6027\uff0c\u4ece\u800c\u63d0\u9ad8\u7535\u6c60\u6027\u80fd\u3002\u78c1\u6027\u7eb3\u7c73\u9897\u7c92\u5982Fe3<\/sub>O4<\/sub>\u548cCoO\u56e0\u5176\u56fa\u6709\u7684\u78c1\u6027\u5c5e\u6027\uff0c\u80fd\u591f\u4fc3\u8fdb\u9ad8\u6548\u7535\u8377\u8f6c\u79fb\u548c\u80fd\u91cf\u5b58\u50a8\u3002\u901a\u8fc7\u529f\u80fd\u5316\u5904\u7406\uff0c\u8fd9\u4e9b\u7eb3\u7c73\u9897\u7c92\u88ab\u8ba4\u4e3a\u662f\u4e0b\u4e00\u4ee3\u7535\u6c60\u6280\u672f\u7684\u6709\u529b\u5019\u9009\u8005\u3002\u6709\u673a\u81ea\u7531\u57fa\u5982\u6c2e\u6c27\u81ea\u7531\u57fa\u7b49\uff0c\u5df2\u88ab\u63a2\u7d22\u4f5c\u4e3a\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\uff0c\u80fd\u591f\u8bf1\u5bfcESP\uff0c\u4f18\u5316\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u5e76\u63d0\u5347\u7535\u6c60\u6027\u80fd\u3002<\/p>\n

 <\/p>\n

ESP\u5bf9\u53ef\u5145\u7535\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u590d\u6742\uff0c\u5e76\u4e14\u6df1\u53d7\u6750\u6599\u548c\u7ed3\u6784\u914d\u7f6e\u7684\u5f71\u54cd\u3002\u7136\u800c\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u8868\u660e\uff0c\u4f18\u5316ESP\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u7535\u6c60\u7684\u591a\u4e2a\u6027\u80fd\u6307\u6807\u3002\u901a\u8fc7\u5728\u7535\u6781\u5185\u4f18\u5316ESP\uff0c\u53ef\u4ee5\u63d0\u9ad8\u7535\u6c60\u5bb9\u91cf\uff0c\u52a0\u901f\u5145\u653e\u7535\u901f\u7387\uff0c\u51cf\u5c11\u526f\u53cd\u5e94\u5e76\u5ef6\u957f\u7535\u6c60\u5faa\u73af\u5bff\u547d\u3002\u4f8b\u5982\uff0c\u5728\u7535\u89e3\u8d28\u4e2d\u5f15\u5165\u6709\u673a\u81ea\u7531\u57fa\u5df2\u88ab\u8bc1\u660e\u80fd\u51cf\u5c11\u6b63\u6781\u7684\u964d\u89e3\uff0c\u4ece\u800c\u5ef6\u957f\u7535\u6c60\u5bff\u547d\u3002\u6b64\u5916\uff0cESP\u8fd8\u53ef\u4ee5\u4fc3\u8fdb\u53ef\u518d\u751f\u80fd\u6e90\u4e0e\u7535\u7f51\u7684\u96c6\u6210\uff0c\u63d0\u5347\u80fd\u91cf\u5b58\u50a8\u548c\u8f6c\u6362\u6548\u7387\u3002<\/p>\n

\u603b\u7684\u6765\u8bf4\uff0cESP\u4e3a\u63d0\u5347\u53ef\u5145\u7535\u7535\u6c60\u6280\u672f\u63d0\u4f9b\u4e86\u6709\u529b\u7684\u7814\u7a76\u65b9\u5411\u3002\u901a\u8fc7\u5229\u7528\u7535\u5b50\u81ea\u65cb\u7684\u72ec\u7279\u7279\u6027\uff0c\u7814\u7a76\u4eba\u5458\u80fd\u591f\u4f18\u5316\u7535\u6c60\u7535\u6781\u4e2d\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u5c3d\u7ba1\u9762\u4e34\u4e00\u4e9b\u5b9e\u9645\u5b9e\u65bd\u7684\u6311\u6218\uff0c\u4f46ESP\u4ecd\u7136\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u6f5c\u5728\u6548\u76ca\u3002\u968f\u7740\u8be5\u9886\u57df\u7684\u7814\u7a76\u4e0d\u65ad\u6df1\u5165\uff0cESP\u9884\u8ba1\u5c06\u5728\u5f00\u53d1\u66f4\u9ad8\u6548\u3001\u66f4\u53ef\u9760\u7684\u80fd\u6e90\u5b58\u50a8\u89e3\u51b3\u65b9\u6848\u4e2d\u53d1\u6325\u5173\u952e\u4f5c\u7528\uff0c\u4fc3\u8fdb\u53ef\u6301\u7eed\u80fd\u6e90\u7684\u672a\u6765\u53d1\u5c55\u3002<\/p>\n

 <\/p>\n

\u53ef\u5145\u7535\u7535\u6c60ESP\u7684\u5e94\u7528\u4e0e\u8fdb\u5c55<\/b><\/strong><\/p>\n

\u7535\u5b50\u81ea\u65cb\u6781\u5316\uff08ESP\uff09\u5728\u7535\u6c60\u6280\u672f\u4e2d\u7684\u5e94\u7528\u662f\u4e00\u79cd\u524d\u6cbf\u7684\u521b\u65b0\u65b9\u6cd5\uff0c\u57fa\u4e8e\u7535\u5b50\u7684\u78c1\u6027\u6765\u63d0\u5347\u7535\u6c60\u6027\u80fd\u3002ESP\u901a\u8fc7\u8c03\u63a7\u7535\u6781\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u79fb\u52a8\u8def\u5f84\uff0c\u51cf\u5c11\u79bb\u5b50\u79fb\u52a8\u7684\u963b\u529b\uff0c\u63d0\u5347\u7535\u5bfc\u7387\uff0c\u4ece\u800c\u52a0\u5feb\u5145\u7535\u901f\u5ea6\uff0c\u5e76\u80fd\u5ef6\u957f\u7535\u6c60\u7684\u5faa\u73af\u5bff\u547d\u3002\u7814\u7a76\u8868\u660e\uff0cESP\u80fd\u591f\u901a\u8fc7\u964d\u4f4e\u79bb\u5b50\u63d2\u5165\u548c\u63d0\u53d6\u7684\u80fd\u91cf\u969c\u788d\uff0c\u589e\u5f3a\u7535\u6c60\u5bb9\u91cf\u548c\u7a33\u5b9a\u6027\uff0c\u6539\u5584\u53ef\u5145\u7535\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u76ee\u524d\uff0cESP\u5728\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u4e3b\u8981\u96c6\u4e2d\u4e8e\u78c1\u6027\u6750\u6599\u7684\u4f7f\u7528\uff0c\u4f8b\u5982\u94c1\u3001\u94b4\u3001\u954d\u7b49\u6750\u6599\uff0c\u8fd9\u4e9b\u6750\u6599\u80fd\u591f\u901a\u8fc7\u81ea\u65cb\u6781\u5316\u7279\u6027\u63d0\u5347\u7535\u6c60\u7684\u7535\u8377\u8f6c\u79fb\u6548\u7387\u3002\u6b64\u5916\uff0c\u5916\u52a0\u78c1\u573a\u4e5f\u662f\u4e00\u79cd\u5e38\u7528\u7684\u8bf1\u5bfcESP\u7684\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u5728\u65e5\u5e38\u7535\u6c60\u7cfb\u7edf\u4e2d\u4f7f\u7528\u5916\u52a0\u78c1\u573a\u7684\u53ef\u884c\u6027\u4ecd\u9762\u4e34\u6311\u6218\uff0c\u5f53\u524d\u7684\u7814\u7a76\u4e3b\u8981\u5904\u4e8e\u5b9e\u9a8c\u5ba4\u9636\u6bb5\uff0c\u4f46\u5176\u6f5c\u5728\u7684\u4f18\u52bf\u4f7f\u5176\u6210\u4e3a\u672a\u6765\u7814\u7a76\u7684\u70ed\u70b9\u3002<\/p>\n

1) \u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09<\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u662f\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u57fa\u7840\uff0c\u4f46\u5b83\u4eec\u7684\u6027\u80fd\u53d7\u9650\u4e8e\u9502\u79bb\u5b50\u6269\u6563\u901f\u7387\u548c\u7535\u6781\u6750\u6599\u4e2d\u7684\u7535\u5b50\u8f6c\u79fb\u901f\u5ea6\u3002\u901a\u8fc7ESP\u8c03\u63a7\u7535\u6781\u4e2d\u7684\u7535\u5b50\u81ea\u65cb\u72b6\u6001\uff0c\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u5bfc\u7535\u6027\u548c\u9502\u79bb\u5b50\u7684\u4f20\u8f93\u901f\u7387\uff0c\u964d\u4f4e\u9502\u79bb\u5b50\u8fc1\u79fb\u7684\u80fd\u91cf\u969c\u788d\uff0c\u4ece\u800c\u52a0\u901f\u7535\u6c60\u7684\u5145\u653e\u7535\u901f\u5ea6\u3001\u63d0\u9ad8\u5bb9\u91cf\uff0c\u5e76\u5ef6\u957f\u5faa\u73af\u5bff\u547d\u3002<\/p>\n

 <\/p>\n

\u7814\u7a76\u8868\u660e\uff0c\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u6781\u4e2d\u7684\u50a8\u80fd\u5bb9\u91cf\u8d85\u8fc7\u9884\u671f\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8eESP\u6240\u4ea7\u751f\u7684\u5f3a\u8868\u9762\u7535\u5bb9\u6548\u5e94\u3002\u6b64\u5916\uff0c\u78c1\u6027\u7eb3\u7c73\u9897\u7c92\u548c\u8fc7\u6e21\u91d1\u5c5e\u6c1f\u5316\u7269\uff0c\u5982FeF2<\/sub>\uff0c\u901a\u8fc7ESP\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u5347\u7535\u8377\u4f20\u8f93\u80fd\u529b\u3002<\/p>\n

2) \u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09<\/p>\n

\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u7531\u4e8e\u94a0\u8d44\u6e90\u4e30\u5bcc\u4e14\u6210\u672c\u8f83\u4f4e\uff0c\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u66ff\u4ee3\u54c1\u9010\u6e10\u53d7\u5230\u5173\u6ce8\u3002ESP\u5728SIBs\u4e2d\u7684\u5e94\u7528\u80fd\u591f\u901a\u8fc7\u78c1\u6027\u76f8\u4e92\u4f5c\u7528\u6765\u4f18\u5316\u7535\u6781\u6750\u6599\u4e2d\u7684\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\uff0c\u5e76\u63d0\u9ad8\u94a0\u79bb\u5b50\u7684\u6269\u6563\u901f\u7387\uff0c\u4ece\u800c\u63d0\u5347\u7535\u6c60\u7684\u6027\u80fd\u3002\u7814\u7a76\u8868\u660e\uff0c\u5229\u7528Fe3<\/sub>O4<\/sub>\u6d82\u5c42\u6765\u589e\u5f3a\u7535\u6781\u754c\u9762\u7684\u79bb\u5b50\u6269\u6563\u901f\u5ea6\u548c\u5747\u5300\u6027\uff0c\u53ef\u663e\u8457\u6539\u5584\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u6574\u4f53\u6027\u80fd\u3002<\/p>\n

3) \u94be\u79bb\u5b50\u7535\u6c60\uff08PIBs\uff09<\/p>\n

\u94be\u79bb\u5b50\u7535\u6c60\uff08PIBs\uff09\u56e0\u94be\u8d44\u6e90\u7684\u4e30\u5bcc\u548c\u6210\u672c\u4f4e\u5ec9\uff0c\u5177\u6709\u5927\u89c4\u6a21\u80fd\u91cf\u50a8\u5b58\u5e94\u7528\u7684\u6f5c\u529b\u3002\u7136\u800c\uff0c\u94be\u79bb\u5b50\u7535\u6c60\u5728\u80fd\u91cf\u5bc6\u5ea6\u548c\u5145\u653e\u7535\u901f\u7387\u65b9\u9762\u4ecd\u5b58\u5728\u6311\u6218\u3002\u901a\u8fc7ESP\uff0c\u80fd\u591f\u63d0\u9ad8\u94be\u79bb\u5b50\u7684\u4f20\u8f93\u6548\u7387\uff0c\u51cf\u5c11\u7535\u8377\u8f6c\u79fb\u963b\u529b\uff0c\u8fdb\u4e00\u6b65\u63d0\u5347\u94be\u79bb\u5b50\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u6b64\u5916\uff0cESP\u8fd8\u80fd\u591f\u901a\u8fc7\u7a33\u5b9a\u7535\u6781\u6750\u6599\u7684\u81ea\u65cb\u73af\u5883\uff0c\u51cf\u5c11\u4e0e\u7535\u89e3\u8d28\u7684\u526f\u53cd\u5e94\uff0c\u4ece\u800c\u5ef6\u957f\u7535\u6c60\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

4) \u9502\u786b\u7535\u6c60\uff08LSBs\uff09<\/p>\n

\u9502\u786b\u7535\u6c60\uff08LSBs\uff09\u56e0\u5176\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u5907\u53d7\u77a9\u76ee\uff0c\u4f46\u5b9e\u9645\u5e94\u7528\u53d7\u9650\u4e8e\u786b\u7684\u5bfc\u7535\u6027\u5dee\u548c\u9502\u591a\u786b\u5316\u7269\uff08LiPS\uff09\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u3002ESP\u7b56\u7565\u901a\u8fc7\u8c03\u63a7\u7535\u6781\u754c\u9762\u4e0a\u7684\u7535\u5b50\u81ea\u65cb\u72b6\u6001\uff0c\u63d0\u5347\u7535\u5b50\u5bfc\u7535\u6027\u5e76\u4fc3\u8fdb\u66f4\u9ad8\u6548\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u3002\u5229\u7528ESP\u53ef\u4ee5\u589e\u5f3a\u786b\u57fa\u6750\u6599\u4e0eLiPS\u7684\u7ed3\u5408\uff0c\u6291\u5236\u5176\u6eb6\u89e3\uff0c\u663e\u8457\u63d0\u9ad8\u9502\u786b\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u5728\u9502\u786b\u7535\u6c60\u4e2d\uff0c\u7814\u7a76\u8868\u660eESP\u80fd\u591f\u589e\u5f3a\u7535\u6781\u6750\u6599\u7684\u50ac\u5316\u6027\u80fd\uff0c\u901a\u8fc7\u4f18\u5316\u81ea\u65cb\u5bc6\u5ea6\uff0c\u663e\u8457\u63d0\u5347\u9502\u786b\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u5e76\u589e\u5f3a\u5145\u653e\u7535\u6027\u80fd\u3002\u6b64\u5916\uff0cESP\u5728\u5355\u539f\u5b50\u50ac\u5316\u5242\u4e2d\u8fd8\u53ef\u4ee5\u4fc3\u8fdbLi2<\/sub>S2<\/sub>\u5411Li2<\/sub>S\u7684\u8fd8\u539f\u8fc7\u7a0b\uff0c\u8fdb\u4e00\u6b65\u5ef6\u957f\u7535\u6c60\u5bff\u547d\u3002<\/p>\n

\u603b\u7ed3\uff0cESP\u4e3a\u53ef\u5145\u7535\u7535\u6c60\u6280\u672f\u7684\u53d1\u5c55\u5e26\u6765\u4e86\u6781\u5927\u7684\u6f5c\u529b\u3002\u901a\u8fc7\u7cbe\u786e\u8c03\u63a7\u7535\u6781\u6750\u6599\u7684\u81ea\u65cb\u7279\u6027\uff0cESP\u80fd\u591f\u63d0\u9ad8\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3001\u5145\u653e\u7535\u901f\u7387\u548c\u5faa\u73af\u5bff\u547d\u3002\u968f\u7740ESP\u7814\u7a76\u7684\u4e0d\u65ad\u6df1\u5165\uff0c\u672a\u6765\u6709\u671b\u5f00\u53d1\u51fa\u66f4\u52a0\u9ad8\u6548\u3001\u53ef\u9760\u7684\u50a8\u80fd\u89e3\u51b3\u65b9\u6848\uff0c\u63a8\u52a8\u53ef\u6301\u7eed\u80fd\u6e90\u7684\u53d1\u5c55\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. \u7535\u5316\u5b66\u7cfb\u7edf\u4e2d\u81ea\u65cb\u6781\u5316\u7535\u5b50\u7684\u793a\u610f\u56fe\u548c\u78c1\u529b\u8ba1\u5206\u6790<\/p>\n

\"\"<\/p>\n

\u56fe4. \u9ad8\u538bLiCoO2<\/sub>\u548c\u8fc7\u6e21\u91d1\u5c5e\u9897\u7c92\u7535\u6781\u7684\u673a\u5236\u4e0e\u81ea\u65cb\u6781\u5316\u54cd\u5e94<\/p>\n

\"\"<\/p>\n

\u56fe5.\u00a0\u94a0\u79bb\u5b50\u7535\u6c60\u4e2d\u81ea\u65cb\u6781\u5316Na+\u6269\u6563\u4e0eFe3<\/sub>O4<\/sub>\u7ed3\u6784\u5206\u6790<\/p>\n

\"\"<\/p>\n

\u56fe6.\u00a0\u94c1\u548cMoS2<\/sub>\u7535\u6781\u4e2d\u7684\u81ea\u65cb\u8dc3\u8fc1\u4e0e\u53ef\u9006\u5145\u653e\u7535\u673a\u5236<\/p>\n

\"\"<\/p>\n

\u56fe7.\u00a0\u94be\u79bb\u5b50\u7535\u6c60\u4e2dCo\u63ba\u6742\u94c1\u6c30\u5316\u7269\u7684\u81ea\u65cb\u6781\u5316K+<\/sup>\u5438\u9644\u4e0e\u7535\u5316\u5b66\u8fc7\u7a0b<\/p>\n

\"\"<\/p>\n

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 <\/p>\n

    \n
  1. \u7ed3\u8bba\u4e0e\u5c55\u671b<\/b><\/strong><\/li>\n<\/ol>\n

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    \u8de8\u5b66\u79d1\u5408\u4f5c\u7684\u91cd\u8981\u6027\uff1aESP\u6280\u672f\u7684\u8fdb\u6b65\u4f9d\u8d56\u4e8e\u7535\u5316\u5b66\u3001\u7eb3\u7c73\u6280\u672f\u548c\u6750\u6599\u79d1\u5b66\u7b49\u591a\u9886\u57df\u7684\u534f\u540c\u5408\u4f5c\u3002\u5b66\u672f\u754c\u3001\u4ea7\u4e1a\u754c\u548c\u76d1\u7ba1\u90e8\u95e8\u4e4b\u95f4\u7684\u5408\u4f5c\u5c06\u52a0\u901f\u521b\u65b0\uff0c\u540c\u65f6\u786e\u4fdd\u5236\u5b9a\u5b89\u5168\u6807\u51c6\u3001\u6cd5\u89c4\u548c\u6700\u4f73\u5b9e\u8df5\uff0c\u4ee5\u63a8\u52a8\u81ea\u65cb\u6781\u5316\u7535\u6c60\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n

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    \"\"<\/p>\n

    \u4f5c\u8005\u4ecb\u7ecd\uff1a<\/b><\/strong><\/p>\n

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     <\/p>\n

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     <\/p>\n

    \u53c2\u8003\u6587\u732e\uff1a<\/b><\/strong><\/p>\n

      \n
    1. Xia, Y. Hu, Z. Li, H. Lan, J. Zhang, Electron Spin Polarization in Rechargeable Batteries: Theoretical Foundation and Practical Applications. Adv. Funct. Mater. 2024, 2413491.<\/li>\n<\/ol>\n

      https:\/\/doi.org\/10.1002\/adfm.202413491<\/p>\n","protected":false},"excerpt":{"rendered":"

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