{"id":262609,"date":"2024-10-07T06:30:45","date_gmt":"2024-10-06T22:30:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=262609"},"modified":"2024-10-06T22:30:54","modified_gmt":"2024-10-06T14:30:54","slug":"nature-chemistry%ef%bc%9a%e9%95%8d%e5%82%ac%e5%8c%96%e4%ba%a4%e5%8f%89%e4%ba%b2%e7%94%b5%e8%af%95%e5%89%82%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94%e7%9a%84%e9%87%8d%e8%a6%81%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=262609","title":{"rendered":"Nature Chemistry\uff1a\u954d\u50ac\u5316\u4ea4\u53c9\u4eb2\u7535\u8bd5\u5242\u5076\u8054\u53cd\u5e94\u7684\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"

\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong>\u00a0 <\/strong><\/p>\n

\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u662f\u5408\u6210\u5316\u5b66\u4e2d\u78b3-\u78b3\u952e\u5f62\u6210\u7684\u4e3b\u8981\u65b9\u6cd5\u3002\u954d\u50ac\u5316\u7684\u4ea4\u53c9\u4eb2\u7535\u8bd5\u5242\u5076\u8054\uff08XEC\uff09\u53cd\u5e94\u4f7f\u7528\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u63a5\u89e6\u5230\u66f4\u591a\u6837\u4e14\u6210\u672c\u66f4\u4f4e\u7684\u8bd5\u5242\uff0c\u56e0\u6b64\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5f00\u53d1\u548c\u5e94\u7528\u7684\u5173\u6ce8\u3002<\/p>\n

Ni\u50ac\u5316\u7684XEC\u53cd\u5e94\u9700\u8981\u4e00\u4e2a\u7535\u5b50\u6e90\u6765\u652f\u6301\u6574\u4f53\u7684\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u9700\u8981\u5c06Ni\u50ac\u5316\u5242\u8fd8\u539f\u4e3a\u4f4e\u4ef7\u4e2d\u95f4\u4f53\u4ee5\u542f\u52a8\u6c27\u5316\u52a0\u6210\u6216\u4ece\u6709\u673a\u4eb2\u7535\u4f53\u7684\u5364\u7d20\u539f\u5b50\u8f6c\u79fb\u3002\u5df2\u7ecf\u4f7f\u7528\u4e86\u5404\u79cd\u8fd8\u539f\u5242\u6765\u4fc3\u8fdb\u8fd9\u4e9b\u53cd\u5e94\u3002\u76ee\u524d\uff0c\u950c\u6216\u9530\u91d1\u5c5e\u7c89\u672b\u662f\u6700\u5e7f\u6cdb\u4f7f\u7528\u7684\u3002\u7136\u800c\uff0cZn\u548cMn\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u7684\u70ed\u529b\u5b66\u7535\u4f4d\u5c1a\u4e0d\u6e05\u695a\uff0c\u4e5f\u6ca1\u6709\u63a2\u7d22\u5728\u5178\u578b\u53cd\u5e94\u6761\u4ef6\u4e0b\u5f71\u54cd\u5b83\u4eec\u7535\u4f4d\u7684\u56e0\u7d20\u3002<\/p>\n

\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821\u7814\u7a76\u4eba\u5458\u5c55\u793a\u4e86\u5982\u4f55\u4f7f\u7528\u5f00\u8def\u7535\u4f4d\u6d4b\u91cf\u6765\u786e\u5b9a\u4e0d\u540c\u6709\u673a\u6eb6\u5242\u4e2d\u4ee5\u53ca\u5728\u5e38\u89c1\u53cd\u5e94\u6dfb\u52a0\u5242\u5b58\u5728\u4e0b\u7684Zn\u548cMn\u7684\u70ed\u529b\u5b66\u7535\u4f4d\u3002\u4f5c\u8005\u5728\u4e0eZn\u548cMn\u8fd8\u539f\u7535\u4f4d\u76f8\u5bf9\u5e94\u7684\u65bd\u52a0\u7535\u4f4d\u548c\u4f18\u5316\u4ee5\u5b9e\u73b0\u6700\u5927\u4ea7\u7387\u7684\u7535\u4f4d\u4e0b\uff0c\u6bd4\u8f83\u4e86N-\u70f7\u57fa-2,4,6-\u4e09\u82ef\u57fa\u5421\u5576\u9393\u8bd5\u5242\uff08Katritzky\u76d0\uff09\u4e0e\u82b3\u57fa\u5364\u5316\u7269\u7684Ni\u50ac\u5316\u5076\u8054\u3002\u603b\u4f53\u7ed3\u679c\u9610\u660e\u4e86\u8fd8\u539f\u5242\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5728Ni\u50ac\u5316XEC\u53cd\u5e94\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1<\/strong>\u5728\u954d\u50ac\u5316\u7684<\/strong>XEC<\/strong>\u4e2d\u4f7f\u7528\u91d1\u5c5e\u8fd8\u539f\u5242\u3002\uff08<\/strong>a<\/strong>\uff09\u954d\u50ac\u5316\u7684<\/strong>C(sp2<\/sup>)<\/strong>\u2013<\/strong>C(sp3<\/sup>) XEC<\/strong>\u53cd\u5e94\u7684\u4e00\u822c\u63cf\u8ff0\u3002\uff08<\/strong>b<\/strong>\uff09\u663e\u793a\u91d1\u5c5e\u8fd8\u539f\u5242\u5bf9\u4ea7\u7269\u4ea7\u7387\u5f71\u54cd\u7684\u954d\u50ac\u5316<\/strong>XEC<\/strong>\u53cd\u5e94\u7684\u9009\u5b9a\u4f8b\u5b50\u3002\uff08<\/strong>c<\/strong>\uff09\u950c\u548c\u9530\u5728\u6c34\u6eb6\u6db2\u4e2d\u7684<\/strong>Pourbaix<\/strong>\u56fe\u548c\u5f00\u8def\u7535\u4f4d<\/strong>\/<\/strong>\u7535\u538b\u7684\u5e38\u89c1\u5e94\u7528\u8bf4\u660e\uff0c\u8fd9\u662f\u4e00\u79cd\u53ef\u4ee5\u7528\u6765\u786e\u5b9a\u6709\u673a\u6eb6\u5242\u4e2d\u950c\u548c\u9530\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u6280\u672f\u3002\uff08<\/strong>d<\/strong>\uff09\u8bf4\u660e\u91d1\u5c5e\u8fd8\u539f\u5242\u70ed\u529b\u5b66\u7535\u4f4d<\/strong>OCP<\/strong>\u6d4b\u91cf\u7684\u793a\u610f\u56fe\u3002<\/strong>Dme<\/strong>\uff0c<\/strong>1,2-<\/strong>\u4e8c\u7532\u6c27\u57fa\u4e59\u70f7\uff1b<\/strong>bpy<\/strong>\uff0c<\/strong>2,2′-<\/strong>\u8054\u5421\u5576\uff1b<\/strong>dmbpy<\/strong>\uff0c<\/strong>5,5′-<\/strong>\u4e8c\u7532\u57fa<\/strong>-2,2′-<\/strong>\u8054\u5421\u5576\uff1b<\/strong>DMO<\/strong>\uff0c\u4e8c\u7532\u57fa\u8349\u9170\uff1b<\/strong>phen<\/strong>\uff0c<\/strong>1,10-<\/strong>\u83f2\u5570\u5549\uff1b<\/strong>dppf<\/strong>\uff0c<\/strong>1,1′-<\/strong>\u53cc<\/strong>(<\/strong>\u4e8c\u82ef\u57fa\u81a6<\/strong>)<\/strong>\u4e8c\u8302\u94c1\uff1b<\/strong>SHE<\/strong>\uff0c\u6807\u51c6\u6c22\u7535\u6781\uff1b<\/strong>Fc\/Fc+<\/sup><\/strong>\uff0c\u4e8c\u8302\u94c1<\/strong>\/<\/strong>\u4e8c\u8302\u94c1\u9633\u79bb\u5b50\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2<\/strong>\u950c\u548c\u9530\u7684\u70ed\u529b\u5b66\u7535\u4f4d\u3002\uff08<\/strong>a<\/strong>\uff09<\/strong>OCP<\/strong>\u6d4b\u91cf\u7684\u5b9e\u9a8c\u8bbe\u7f6e\u3002\uff08<\/strong>b<\/strong>\uff09\u6eb6\u5242\u5bf9\u950c\u548c\u9530\u7684\u6b63\u5f0f\u70ed\u529b\u5b66\u7535\u4f4d\u4ee5\u53ca<\/strong>[Ni(bpy)3<\/sub>]Cl2<\/sub><\/strong>\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u5f71\u54cd\u3002\uff08<\/strong>c<\/strong>\uff09\u5316\u5b66\u6cd5\u548c\u7535\u5316\u5b66\u6cd5<\/strong>Ni\/tBubpy<\/strong>\u50ac\u5316\u7684\u82c4\u6c2f\u548c\u82ef\u57fa\u7898\u5316\u7269\u5076\u8054\u53cd\u5e94\u7ed3\u679c\u7684\u6bd4\u8f83\u3002\uff08<\/strong>d<\/strong>\uff09\u6dfb\u52a0\u5242\u5bf9\u950c\u548c\u9530\u7684\u70ed\u529b\u5b66\u7535\u4f4d\u7684\u5f71\u54cd\u3002<\/strong>SM<\/strong>\uff0c\u8d77\u59cb\u6750\u6599\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

\n \u5f00\u8def\u7535\u4f4d\uff08OCPs\uff09\u662f\u5728\u4e0d\u901a\u8fc7\u7535\u6d41\u6216\u65bd\u52a0\u5916\u90e8\u7535\u538b\u7684\u60c5\u51b5\u4e0b\u6d4b\u91cf\u7684\uff0c\u4f5c\u8005\u901a\u8fc7\u5728\u4e0e\u954d\u50ac\u5316XEC\u53cd\u5e94\u76f8\u5173\u7684\u591a\u79cd\u6761\u4ef6\u4e0b\u6d4b\u91cf\u950c\u548c\u9530\u76f8\u5bf9\u4e8e\u53c2\u6bd4\u7535\u6781\uff08Ag\/AgNO3<\/sub>\uff09\u7684OCPs\u3002\u4f5c\u8005\u9009\u62e9\u4e86\u5728\u954d\u50ac\u5316XEC\u53cd\u5e94\u4e2d\u5e38\u7528\u7684\u516b\u79cd\u6eb6\u5242\u8fdb\u884cOCP\u6d4b\u91cf\uff0c\u4ee5\u63a2\u7a76\u6eb6\u5242\u5bf9\u950c\u548c\u9530\u8fd8\u539f\u7535\u4f4d\u7684\u5f71\u54cd\uff08\u56fe2b\uff09\uff1a\u4e8c\u7532\u57fa\u7532\u9170\u80fa\uff08DMF\uff09\u3001\u4e8c\u7532\u57fa\u4e59\u9170\u80fa\uff08DMA\uff09\u3001N-\u7532\u57fa-2-\u5421\u54af\u70f7\u916e\uff08NMP\uff09\u3001N,N’-\u4e8c\u7532\u57fa\u4e19\u70ef\u8132\uff08DMPU\uff09\u30011,3-\u4e8c\u7532\u57fa-2-\u54aa\u5511\u5549\u916e\uff08DMI\uff09\u3001\u4e8c\u7532\u57fa\u4e9a\u781c\uff08DMSO\uff09\u3001\u4e59\u8148\uff08MeCN\uff09\u548c\u56db\u6c22\u544b\u5583\uff08THF\uff09\u3002\u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\u6d4b\u91cf\u7684OCPs\u901a\u8fc7\u6821\u6b63M2+<\/sup>\u79bb\u5b50\u7684\u975e\u6807\u51c6\u72b6\u6001\u6d53\u5ea6\u8f6c\u6362\u4e3a\u76f8\u5bf9\u4e8eFc\/Fc+<\/sup>\u7684\u70ed\u529b\u5b66\u7535\u4f4d\uff08E\u00b0\u2032\uff09\u3002<\/p>\n

\u950c\u548c\u9530\u7684\u8fd8\u539f\u7535\u4f4d\u5728\u4e00\u7cfb\u5217\u9170\u80fa\u548c\u5c3f\u7d20\u6eb6\u5242\uff08DMF\u3001DMA\u3001NMP\u3001DMPU\u548cDMI\uff09\u4e2d\u663e\u793a\u51fa\u9002\u5ea6\u53d8\u5316\uff1aZn\u7684\u0394E\u00b0\u2032\u226450 mV\uff0cMn\u7684\u0394E\u00b0\u2032\u226480 mV\u3002DMSO\u548cTHF\u4e2d\u7684Mn\u7535\u4f4d\u4e0e\u5728\u9170\u80fa\u6eb6\u5242\u4e2d\u89c2\u5bdf\u5230\u7684\u76f8\u5e94\u7535\u4f4d\u76f8\u4f3c\u3002\u76f8\u5bf9\u4e8e\u9170\u80fa\u6eb6\u5242\u4e2d\u7684\u76f8\u5e94\u7535\u4f4d\uff0cDMSO\u4e2d\u7684Zn\u7535\u4f4d\u66f4\u8d1f\uff0cTHF\u4e2d\u7684Zn\u7535\u4f4d\u66f4\u6b63\u3002\u5728MeCN\u4e2d\uff0cZn\u548cMn\u7684\u7535\u4f4d\u53d1\u751f\u4e86\u663e\u8457\u53d8\u5316\uff0c\u4e0e\u5728DMSO\u548c\u9170\u80fa\u6eb6\u5242\u4e2d\u6d4b\u91cf\u7684\u7535\u4f4d\u76f8\u6bd4\uff0c\u589e\u52a0\u4e86\u9ad8\u8fbe260-370 mV\u3002Zn\u548cMn\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u6bd4[Ni(bpy)3<\/sub>]Cl2<\/sub>\u7684\u7535\u4f4d\u66f4\u6b63\uff0c\u5c3d\u7ba1\u5728DMSO\u548c\u9170\u80fa\u6eb6\u5242\u4e2dMn\u7684\u5dee\u5f02\u76f8\u5f53\u5c0f\uff08\u0394E\u00b0\u2032\u226490 mV\uff09\u3002\u5728\u8fd9\u4e9b\u6eb6\u5242\u4e2d\uff0cZn\u7684\u5dee\u5f02\u66f4\u5927\uff08\u0394E\u00b0\u2032\u2264270 mV\uff09\u3002<\/p>\n

DMF\u662fXEC\u53cd\u5e94\u4e2d\u6700\u5e38\u7528\u7684\u6eb6\u5242\u4e4b\u4e00\u3002\u6dfb\u52a0\u5242\uff0c\u5982LiCl\u548cLiBr\u7b49\uff0c\u901a\u5e38\u5305\u542b\u5728\u53cd\u5e94\u6df7\u5408\u7269\u4e2d\u3002\u5728DMF\u4e2d\u5b58\u5728\u5404\u79cd\u6dfb\u52a0\u5242\uff08200 mM\uff09\u65f6\uff0c\u5bf9Zn\u548cMn\u7684OCP\u6d4b\u91cf\u8868\u660e\uff0cZn\u548cMn\u7684\u8fd8\u539f\u7535\u4f4d\u53ef\u4ee5\u53d8\u5316\u8fd1300 mV\uff0c\u5177\u4f53\u53d6\u51b3\u4e8e\u6dfb\u52a0\u5242\u3002\u5364\u7d20\u79bb\u5b50\uff0c\u7279\u522b\u662f\u6c2f\u5316\u7269\u76d0\uff0c\u5c06Zn\u548cMn\u7684\u8fd8\u539f\u7535\u4f4d\u76f8\u5bf9\u4e8e\u5728\u5f31\u914d\u4f4d\u9634\u79bb\u5b50\u5b58\u5728\u65f6\u8bb0\u5f55\u7684\u503c\u8f6c\u79fb\u5230\u66f4\u8d1f\u7684\u503c\u3002\u5728MeCN\u548cTHF\u4e2d\u8fdb\u4e00\u6b65\u63a2\u7a76\u4e86\u5364\u7d20\u79bb\u5b50\u7684\u5f71\u54cd\uff0c\u89c2\u5bdf\u5230\u4e86\u7c7b\u4f3c\u7684\u73b0\u8c61\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3<\/strong>\u950c\u548c\u9530\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4e0e\u954d\u50ac\u5316<\/strong>XEC<\/strong>\u4e2d\u57fa\u4e8e\u954d\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u7684\u76f8\u5173\u6027\u3002\uff08<\/strong>a<\/strong>\uff09<\/strong> \u4f7f\u7528<\/strong>Ni\/dmbpy<\/strong>\u50ac\u5316\u5242\uff08<\/strong>dmbpy<\/strong>\uff0c<\/strong>5,5′-<\/strong>\u4e8c\u7532\u57fa<\/strong>-2,2′-<\/strong>\u8054\u5421\u5576\uff09\u5c06\u82ef\u4e59\u70ef\u57fa\u4e59\u9178\u916f\u4e0e\u70f7\u57fa\u6eb4\u5316\u7269\u8fdb\u884c\u8fd8\u539f\u6027\u4ea4\u53c9\u5076\u8054\u3002\uff08<\/strong>b<\/strong>\uff09\u4f7f\u7528<\/strong>DMO<\/strong>\u6d3b\u5316\u9187\uff0c\u5e76\u901a\u8fc7<\/strong>Ni\/<\/strong>\u6df7\u5408\u914d\u4f53\u50ac\u5316\u5242\u4f53\u7cfb\uff08\u914d\u4f53\uff1a<\/strong>phen<\/strong>\uff0c<\/strong>1,10-<\/strong>\u83f2\u5570\u5549\uff1b<\/strong>dppf<\/strong>\uff0c<\/strong>1,1′-<\/strong>\u53cc<\/strong>(<\/strong>\u4e8c\u82ef\u57fa\u81a6<\/strong>)<\/strong>\u4e8c\u8302\u94c1\uff09\u5b9e\u73b0\u82c4\u9187\u4e0e\u82b3\u57fa\u4e09\u6c1f\u7532\u78fa\u9178\u916f\u7684\u51c0\u4ea4\u53c9\u5076\u8054\u3002\uff08<\/strong>c<\/strong>\uff09\u5728\u5e95\u7269\u5b58\u5728\u548c\u4e0d\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u5bf9<\/strong>Ni\/dmbpy<\/strong>\u8fdb\u884c<\/strong>CV<\/strong>\u5206\u6790\u3002\uff08<\/strong>d<\/strong>\uff09\u5728\u5e95\u7269\u5b58\u5728\u548c\u4e0d\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\u5bf9<\/strong>Ni\/dppf\/phen<\/strong>\u8fdb\u884c<\/strong>CV<\/strong>\u5206\u6790\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4<\/strong>\u70f7\u57fa<\/strong>Katritzky<\/strong>\u76d0\u4e0e\u82b3\u57fa\u6eb4\u5316\u7269\u7684<\/strong>XEC<\/strong>\u53cd\u5e94\u3002\u53cd\u5e94\u4ee5\u70ed\u5316\u5b66\u65b9\u5f0f\u8fdb\u884c\uff0c\u4f7f\u7528\u950c\u6216\u9530\u4f5c\u4e3a\u8fd8\u539f\u5242\uff0c\u6216\u5728\u53d8\u5316\u7684\u65bd\u52a0\u7535\u4f4d\u4e0b\u8fdb\u884c\u7535\u5316\u5b66\u53cd\u5e94\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n

\u91d1\u5c5e\u950c\u548c\u9530\u662f\u8bb8\u591a\u8fd8\u539f\u6027\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u6709\u6548\u8fd8\u539f\u5242\uff0c\u4f46\u5b83\u4eec\u7684\u5404\u81ea\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5e76\u4e0d\u4e00\u5b9a\u9002\u5408\u6bcf\u79cd\u53cd\u5e94\uff0c\u800c\u7535\u5316\u5b66\u7535\u4f4d\u53ef\u4ee5\u5728\u5f88\u5bbd\u7684\u8303\u56f4\u5185\u8fde\u7eed\u8c03\u8282\u3002\u672c\u6587\u6982\u8ff0\u7684\u5f00\u8def\u7535\u4f4d\uff08OCP\uff09\u6d4b\u91cf\u4f7f\u5f97\u80fd\u591f\u5728\u53cd\u5e94\u6761\u4ef6\u4e0b\u76f4\u63a5\u6bd4\u8f83\u5316\u5b66\u548c\u7535\u5316\u5b66\u954d\u50ac\u5316XEC\u53cd\u5e94\u5728\u950c\u548c\u9530\u7684\u8fd8\u539f\u7535\u4f4d\uff0c\u5e76\u4e14\u8fd9\u4e9b\u7ed3\u679c\u53ef\u4ee5\u4e0e\u5176\u4ed6\u65bd\u52a0\u7535\u4f4d\u4e0b\u8fdb\u884c\u7684\u7535\u5316\u5b66\u53cd\u5e94\u8fdb\u884c\u6bd4\u8f83\u3002\u4f7f\u7528N-\u70f7\u57fa-2,4,6-\u4e09\u82ef\u57fa\u5421\u5576\u76d0\uff08Katritzky\u76d0\uff09\u7684\u53cd\u5e94\u662f\u63a2\u7d22\u8fd9\u4e9b\u95ee\u9898\u7684\u4e00\u4e2a\u91cd\u8981\u76ee\u6807\uff0c\u56e0\u4e3a\u5f53\u4f7f\u7528\u5177\u6709\u4e0d\u540c\u8fd8\u539f\u7535\u4f4d\u7684\u5747\u76f8\u6709\u673a\u8fd8\u539f\u5242\u65f6\uff0c\u5b83\u4eec\u5728\u954d\u50ac\u5316XEC\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u53ef\u53d8\u7684\u6027\u80fd\u3002\u56fe4\u4e2d\u7684\u7ed3\u679c\u5bf9\u954d\u50ac\u5316XEC\u53cd\u5e94\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u4f7f\u7528\u5316\u5b66\u8fd8\u539f\u5242\u7684\u8fd9\u4e9b\u53cd\u5e94\u7684\u5927\u89c4\u6a21\u5e94\u7528\u5df2\u7ecf\u56e0\u4e3a\u4f7f\u7528\u91d1\u5c5e\u7c89\u672b\u8bd5\u5242\uff08\u975e\u5747\u5300\u7684\u9897\u7c92\u5c5e\u6027\u548c\u53cd\u5e94\u6027\uff0c\u60ac\u6d6e\u5728\u53cd\u5e94\u5668\u4e2d\u7684\u5bc6\u96c6\u7c89\u672b\u7684\u56f0\u96be\uff09\u6216\u7a7a\u6c14\u654f\u611f\u7684\u6709\u673a\u8fd8\u539f\u5242\u7684\u6311\u6218\u800c\u53d8\u5f97\u590d\u6742\u3002\u56fe4\u4e2d\u7684\u6570\u636e\u8868\u660e\uff0c\u5316\u5b66\u8fd8\u539f\u5242\u7684\u91cf\u5316\/\u4e0d\u53ef\u8c03\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5c06\u9650\u5236\u4f18\u5316\u53cd\u5e94\u6027\u80fd\u7684\u673a\u4f1a\u3002\u8fd9\u4e9b\u6311\u6218\u53ef\u4ee5\u901a\u8fc7\u4f7f\u7528\u7535\u5316\u5b66\u6765\u63d0\u4f9b\u53cd\u5e94\u4e2d\u6240\u9700\u7684\u7535\u5b50\u6765\u89e3\u51b3\u3002<\/p>\n

\u8be5\u7814\u7a76\u9996\u6b21\u786e\u5b9a\u4e0d\u540c\u6709\u673a\u6eb6\u5242\u4e2d\u4ee5\u53ca\u5728\u5e38\u89c1\u53cd\u5e94\u6dfb\u52a0\u5242\u5b58\u5728\u4e0b\u7684Zn\u548cMn\u7684\u70ed\u529b\u5b66\u7535\u4f4d\u53ca\u5f71\u54cd\u5b83\u4eec\u7535\u4f4d\u7684\u56e0\u7d20\uff0c\u4ee5\u201cZinc and manganese redox potentials in organic solvents and their influence on nickel-catalysed cross-electrophile coupling<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature Chemistry<\/strong>\u4e0a\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u5e7f\u6cdb\u5173\u6ce8\u3002<\/p>\n

\"\"<\/p>\n

\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u8bb0\u5f55\u4e86\u6709\u673a\u6eb6\u6db2\u4e2dZn\u548cMn\u8fd8\u539f\u5242\u7684\u70ed\u529b\u5b66\u7535\u4f4d\uff0c\u63ed\u793a\u4e86\u4e0d\u540c\u6eb6\u5242\u548c\u6dfb\u52a0\u5242\u5bf9\u8fd8\u539f\u7535\u4f4d\u7684\u5f71\u54cd\u3002\u8fd9\u4e9b\u6570\u636e\u4e0e\u5faa\u73af\u4f0f\u5b89\u6cd5\u7814\u7a76\u5b8c\u7f8e\u642d\u914d\uff0c\u53ef\u4ee5\u6df1\u5165\u4e86\u89e3\u8fd8\u539f\u5242\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u4e0e\u53cd\u5e94\u4e2d\u5173\u952e\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u8fd9\u91cc\u4f7f\u7528\u7684\u65b9\u6cd5\u5f88\u5bb9\u6613\u9002\u5e94\u5176\u4ed6\u8fd8\u539f\u548c\u8fd8\u539f\u5076\u8054\u53cd\u5e94\uff0c\u5305\u62ec\u90a3\u4e9b\u4f7f\u7528\u4e0d\u540c\u91d1\u5c5e\u8fd8\u539f\u5242\u3001\u6eb6\u5242\u548c\u53cd\u5e94\u6761\u4ef6\u7684\u53cd\u5e94\u3002\u7ed3\u679c\u5f3a\u8c03\u4e86\u5728\u4f18\u5316Ni\u50ac\u5316XEC\uff0c\u4ee5\u53ca\u53ef\u80fd\u7684\u5176\u4ed6\u8fd8\u539f\u5076\u8054\u53cd\u5e94\u65f6\u8c03\u6574\u8fd8\u539f\u5242\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u7684\u91cd\u8981\u6027\u3002<\/p>\n

 <\/p>\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aSu, ZM., Deng, R. & Stahl, S.S. Zinc and manganese redox potentials in organic solvents and their influence on nickel-catalysed cross-electrophile coupling. Nat. Chem. (2024). https:\/\/doi.org\/10.1038\/s41557-024-01627-5<\/p>\n

 <\/p>\n

\u672c\u6587\u7531\u666f\u884c\u64b0\u7a3f<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011\u00a0 \u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u662f\u5408\u6210\u5316\u5b66\u4e2d\u78b3-\u78b3\u952e\u5f62\u6210\u7684\u4e3b\u8981\u65b9\u6cd5\u3002\u954d\u50ac\u5316\u7684\u4ea4\u53c9\u4eb2\u7535\u8bd5\u5242\u5076\u8054\uff08XEC\uff09\u53cd\u5e94\u4f7f\u7528\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u53ef\u4ee5\u63a5\u89e6\u5230\u66f4\u591a\u6837\u4e14\u6210\u672c\u66f4…<\/p>\n","protected":false},"author":36004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-262609","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262609"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=262609"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262609\/revisions"}],"predecessor-version":[{"id":262618,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262609\/revisions\/262618"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=262609"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=262609"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=262609"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}