{"id":262794,"date":"2024-09-26T06:47:17","date_gmt":"2024-09-25T22:47:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=262794"},"modified":"2024-09-25T21:53:30","modified_gmt":"2024-09-25T13:53:30","slug":"%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e9%82%93%e5%85%b5-%e8%8e%b1%e6%96%af%e5%a4%a7%e5%ad%a6james-tour%e5%90%88%e4%bd%9cnature-chemical-engineering-%e7%94%b5%e7%83%ad%e6%b0%af%e5%8c%96%e6%b3%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=262794","title":{"rendered":"\u6e05\u534e\u5927\u5b66\u9093\u5175\/\u83b1\u65af\u5927\u5b66James Tour\u5408\u4f5cNature Chemical Engineering: \u7535\u70ed\u6c2f\u5316\u6cd5\u5b9e\u73b0\u6218\u7565\u5173\u952e\u91d1\u5c5e\u5feb\u901f\u5206\u79bb\u56de\u6536"},"content":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u9093\u5175\uff0c\u8bb8\u4e16\u81e3<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u9093\u5175\uff0cJames M. Tour<\/p>\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u6e05\u534e\u5927\u5b66\uff0c\u83b1\u65af\u5927\u5b66<\/p>\n<p>\u8bba\u6587\u94fe\u63a5\uff1ahttps:\/\/www.nature.com\/articles\/s44286-024-00125-2<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262796\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72471-16.png\" alt=\"\" width=\"554\" height=\"241\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72471-16.png 554w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72471-16-300x131.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p>\u3010\u5de5\u4f5c\u7b80\u4ecb\u3011<\/p>\n<p>\u91d1\u5c5e\u56de\u6536\u5bf9\u4e8e\u7f13\u89e3\u5173\u952e\u91d1\u5c5e\u8d44\u6e90\u77ed\u7f3a\u548c\u51cf\u5c11\u5bf9\u539f\u59cb\u91c7\u77ff\u7684\u4f9d\u8d56\u65b9\u9762\u53d1\u6325\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u4f20\u7edf\u7684\u7684\u6e7f\u6cd5\u51b6\u91d1\u5de5\u827a\u8017\u8d39\u5927\u91cf\u6c34\u548c\u5316\u5b66\u54c1\uff0c\u5e76\u4ea7\u751f\u4e8c\u6b21\u5e9f\u7269\u6d41\uff0c\u800c\u706b\u6cd5\u51b6\u91d1\u7f3a\u4e4f\u9009\u62e9\u6027\u4e14\u9700\u8981\u5927\u91cf\u80fd\u91cf\u8f93\u5165\u3002\u9488\u5bf9\u8fd9\u4e2a\u95ee\u9898\uff0c<strong>\u6e05\u534e\u5927\u5b66\u9093\u5175\u8bfe\u9898\u7ec4\u548c\u83b1\u65af\u5927\u5b66<\/strong><strong>James M. Tour<\/strong><strong>\u8bfe\u9898\u7ec4<\/strong>\u5408\u4f5c\u5f00\u53d1\u4e86\u4e00\u79cd\u7535\u70ed\u6c2f\u5316\u548c\u78b3\u6c2f\u5316\u5de5\u827a\uff0c\u5e76\u8bbe\u8ba1\u4e86\u76f8\u5e94\u7684\u53cd\u5e94\u5668\uff0c\u5b9e\u73b0\u4e86\u4ece\u7535\u5b50\u5e9f\u6599\u4e2d\u9009\u62e9\u6027\u5206\u79bb\u5173\u952e\u91d1\u5c5e\u3002\u7535\u70ed\u6c2f\u5316\u65b9\u6cd5\u91c7\u7528\u95ea\u901f\u7126\u8033\u70ed\u52a0\u70ed\u6280\u672f\uff0c\u901a\u8fc7\u53ef\u7f16\u7a0b\u7684\u8109\u51b2\u7535\u6d41\u8f93\u5165\uff0c\u5b9e\u73b0\u4e86\u5bf9\u5e7f\u6cdb\u6e29\u5ea6\u8303\u56f4\uff08\u4ece\u5ba4\u6e29\u52302400 \u00b0C\uff09\u7684\u7cbe\u786e\u63a7\u5236\uff0c\u53cd\u5e94\u6301\u7eed\u65f6\u95f4\u4ec5\u4e3a\u6570\u79d2\uff0c\u4e14\u5728\u8fc7\u7a0b\u4e2d\u53ef\u5b9e\u73b0\u5feb\u901f\u52a0\u70ed\/\u51b7\u5374\u901f\u7387\uff08\u6bcf\u79d210<sup>3 <\/sup>\u00b0C\uff09\u3002\u5229\u7528\u6c2f\u5316\u8fc7\u7a0b\u91d1\u5c5e\u6c2f\u5316\u7269\u5f62\u6210\u81ea\u7531\u80fd\u7684\u5dee\u5f02\uff0c\u4e00\u65e6\u8f6c\u5316\u4e3a\u7279\u5b9a\u7684\u91d1\u5c5e\u6c2f\u5316\u7269\uff0c\u8be5\u5316\u5408\u7269\u53ef\u5728\u6570\u79d2\u5185\u4ece\u6df7\u5408\u7269\u4e2d\u84b8\u998f\u51fa\u6765\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u5173\u952e\u91d1\u5c5e\u7684\u8d85\u5feb\u901f\u5206\u79bb\uff0c\u5177\u6709\u91cd\u8981\u7684\u73b0\u5b9e\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<p>\u8fd1\u65e5\uff0c\u8be5\u5de5\u4f5c\u4ee5\u201cFlash separation of metals by electrothermal chlorination\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8e\u300aNature Chemical Engineering\u300b\u3002\u6e05\u534e\u5927\u5b66\u73af\u5883\u5b66\u9662\u7279\u522b\u7814\u7a76\u5458\u9093\u5175\u548c\u7f8e\u56fd\u5de5\u7a0b\u9662\u9662\u58eb\u3001\u83b1\u65af\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388James M. Tour\u4e3a\u8be5\u5de5\u4f5c\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff0c\u9093\u5175\u548c\u83b1\u65af\u5927\u5b66\u535a\u58eb\u540e\u8bb8\u4e16\u81e3\u4e3a\u8be5\u8bba\u6587\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002<\/p>\n<p>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/p>\n<p>\u968f\u7740\u7535\u5b50\u5e94\u7528\u3001\u8d85\u7ea7\u5408\u91d1\u548c\u53ef\u518d\u751f\u80fd\u6e90\u7cfb\u7edf\u5bf9\u91d1\u5c5e\u9700\u6c42\u7684\u589e\u957f\uff0c\u5173\u952e\u91d1\u5c5e\u53d8\u5f97\u8d8a\u6765\u8d8a\u96be\u83b7\u53d6\uff0c\u5a01\u80c1\u5230\u4f9b\u5e94\u94fe\u5b89\u5168\u3002\u5728\u7535\u5b50\u884c\u4e1a\u4e2d\uff0c\u94df\uff08In\uff09\u3001\u9553\uff08Ga\uff09\u548c\u94bd\uff08Ta\uff09\u662f\u4e3b\u8981\u7684\u5173\u952e\u91d1\u5c5e\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u663e\u793a\u5668\u3001\u534a\u5bfc\u4f53\u3001\u7167\u660e\u548c\u7535\u5bb9\u5668\u3002\u4f8b\u5982\uff0c\u94df\u4e3b\u8981\u4ece\u94dc\u548c\u950c\u7684\u526f\u4ea7\u54c1\u4e2d\u56de\u6536\uff0c\u7528\u4e8e\u751f\u4ea7\u6c27\u5316\u94df\u9521\uff08ITO\uff09\u8584\u819c\uff0c\u8fd9\u662f\u663e\u793a\u5668\u548c\u89e6\u6478\u5c4f\u4e2d\u7684\u5173\u952e\u6750\u6599\u3002\u9553\u4f5c\u4e3a\u5546\u54c1\u91d1\u5c5e\u751f\u4ea7\u7684\u526f\u4ea7\u54c1\uff0c\u7528\u4e8e\u7837\u5316\u9553\uff08GaAs\uff09\u548c\u6c2e\u5316\u9553\uff08GaN\uff09\u7b49\u534a\u5bfc\u4f53\u3002\u94bd\u5e7f\u6cdb\u7528\u4e8e\u624b\u673a\u548c\u7535\u8111\u7535\u5bb9\u5668\u4e2d\uff0c\u5360\u603b\u6d88\u8d39\u91cf\u768434%\u3002\u968f\u7740\u4e2a\u4eba\u7535\u5b50\u8bbe\u5907\u9700\u6c42\u7684\u589e\u52a0\uff0c\u5173\u952e\u91d1\u5c5e\u6d88\u8017\u5927\u5e45\u4e0a\u5347\uff0c\u4f9b\u5e94\u94fe\u9762\u4e34\u6311\u6218\u3002\u5c3d\u7ba1\u91d1\u5c5e\u7406\u8bba\u4e0a\u53ef\u4ee5\u65e0\u9650\u6b21\u56de\u6536\uff0c\u4f46\u7531\u4e8e\u4ea7\u54c1\u8bbe\u8ba1\u590d\u6742\u548c\u6280\u672f\u9650\u5236\uff0c\u5f53\u524d\u56de\u6536\u6548\u7387\u4e0d\u9ad8\u3002\u4f20\u7edf\u6e7f\u6cd5\u51b6\u91d1\u5de5\u827a\u6d88\u8017\u5927\u91cf\u6c34\u548c\u5316\u5b66\u54c1\uff0c\u4ea7\u751f\u4e8c\u6b21\u5e9f\u6c34\uff0c\u800c\u706b\u6cd5\u51b6\u91d1\u7f3a\u4e4f\u9009\u62e9\u6027\uff0c\u5bb9\u6613\u5bfc\u81f4\u91d1\u5c5e\u964d\u7ea7\u3002\u6700\u8fd1\uff0c\u9009\u62e9\u6027\u786b\u5316\u6280\u672f\u88ab\u7528\u4e8e\u4ece\u6df7\u5408\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u5206\u79bb\u91d1\u5c5e\u3002<\/p>\n<p>\u6c2f\u5316\u5de5\u827a\u5728\u51b6\u91d1\u4e2d\u5e38\u7528\u4e8e\u5206\u79bb\u91d1\u5c5e\uff0c\u5c24\u5176\u662f\u5728\u5de5\u4e1a\u4e0a\u7528\u4e8e\u4ece\u77ff\u77f3\u4e2d\u63d0\u53d6\u949b\u3002\u7136\u800c\uff0c\u5e38\u89c4\u6c2f\u5316\u5de5\u827a\u56e0\u6e29\u5ea6\u8303\u56f4\uff08900-1300\u00b0C\uff09\u7684\u9650\u5236\uff0c\u5e94\u7528\u8303\u56f4\u6709\u9650\uff0c\u4e14\u901a\u5e38\u901a\u8fc7\u95f4\u63a5\u52a0\u70ed\u65b9\u5f0f\u8fdb\u884c\uff0c\u5904\u7406\u65f6\u95f4\u957f\uff0c\u80fd\u6548\u4f4e\uff0c\u7ecf\u6d4e\u6548\u76ca\u8f83\u5dee\u3002\u4f8b\u5982\uff0c\u7528\u6c2f\u5316\u94f5\u4ece\u5e9f\u6599\u4e2d\u56de\u6536\u94df\u548c\u9553\u65f6\uff0c\u52a0\u70ed\u548c\u51b7\u5374\u901f\u5ea6\u6162\uff0c\u964d\u4f4e\u4e86\u751f\u4ea7\u7387\u3002\u4e3a\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u4f5c\u8005\u5f15\u5165\u4e86\u76f4\u63a5\u7535\u52a0\u70ed\u6216\u95ea\u901f\u52a0\u70ed\u6280\u672f\uff0c\u79f0\u4e3a\u7535\u70ed\u6c2f\u5316\uff08ETC\uff09\uff0c\u5f53\u4f7f\u7528\u78b3\u4f5c\u4e3a\u8fd8\u539f\u5242\u65f6\u79f0\u4e3a\u7535\u70ed\u78b3\u6c2f\u5316\uff08ETCC\uff09\u3002\u8fd9\u79cd\u65b9\u6cd5\u5177\u5907\u8d85\u5feb\u901f\u52a0\u70ed\/\u51b7\u5374\u3001\u5feb\u901f\u5904\u7406\u548c\u5e7f\u6cdb\u7684\u6e29\u5ea6\u8c03\u8282\u80fd\u529b\uff0c\u6781\u5927\u63d0\u5347\u4e86\u91d1\u5c5e\u56de\u6536\u6548\u7387\uff0c\u964d\u4f4e\u4e86\u80fd\u8017\uff0c\u5e76\u6210\u529f\u5b9e\u73b0\u4ece\u7535\u5b50\u5e9f\u6599\u4e2d\u9ad8\u4ea7\u7387\u3001\u9ad8\u7eaf\u5ea6\u56de\u6536\u94df\u3001\u9553\u548c\u94bd\u3002<\/p>\n<p>\u3010\u4e3b\u8981\u5185\u5bb9\u3011<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262797\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72472-17.png\" alt=\"\" width=\"600\" height=\"485\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72472-17.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72472-17-300x243.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1. ETC\/ETCC<\/strong><strong>\u5de5\u827a\u7684\u70ed\u529b\u5b66\u5206\u6790\u4e0e\u88c5\u7f6e\u3002<\/strong>(a) \u5404\u79cd\u91d1\u5c5e\u6c27\u5316\u7269\u6c2f\u5316\u548c\u78b3\u6c2f\u5316\u7684\u8ba1\u7b97\u4e34\u754c\u53cd\u5e94\u6e29\u5ea6\uff08T<sub>crit<\/sub>\uff09\u3002\u865a\u7ebf\u8868\u793a400 \u2103\u548c2400 \u2103\u7684\u6e29\u5ea6\u3002(b) ETC\/ETCC\u5de5\u827a\u793a\u610f\u56fe\uff0c\u663e\u793a\u91d1\u5c5e\u6c2f\u5316\u7269\u84b8\u53d1\u5e76\u6c89\u79ef\u5728\u5468\u56f4\u7684\u77f3\u82f1\u7ba1\u4e0a\u3002(c) \u572860 V\u3001\u52a0\u70ed\u5668\u7535\u963b\u7ea6\u4e3a1\u03a9\u3001\u8109\u51b2\u5360\u7a7a\u6bd4\u4e3a10%\u65f6\u7684\u7535\u6d41\u66f2\u7ebf\u3002\u63d2\u56fe\u4e3a\u7ea2\u8272\u77e9\u5f62\u5185\u653e\u5927\u7684\u7535\u6d41\u66f2\u7ebf\u3002(d) \u52a0\u70ed\u5668\u7535\u52a0\u70ed\u524d\uff08\u4e0a\uff09\u548c\u52a0\u70ed\u671f\u95f4\uff08\u4e0b\uff09\u7684\u7167\u7247\u3002(e) \u5728\u4e0d\u540c\u7535\u538b\u8f93\u5165\u4e0b\u52a0\u70ed\u5668\u7684\u6e29\u5ea6\u66f2\u7ebf\u3002(f) \u4e0d\u540c\u7535\u538b\u8f93\u5165\u4e0b\u52a0\u70ed\u5668\u7684\u6700\u9ad8\u6e29\u5ea6\uff08Tmax\uff09\u53ca\u52a0\u70ed\/\u51b7\u5374\u901f\u7387\u3002(g) \u6837\u54c1\u548c\u6c14\u4f53\u7684\u6a21\u62df\u6e29\u5ea6\u66f2\u7ebf\u3002\u6837\u54c1\u6e29\u5ea6\u5b9a\u4e49\u4e3a\u5176\u5e73\u5747\u6e29\u5ea6\uff0c\u6c14\u4f53\u6e29\u5ea6\u5b9a\u4e49\u4e3a\u78b3\u7eb8\u52a0\u70ed\u5668\u5bbd\u5ea6\u8303\u56f4\u5185\u6c14\u4f53\u7684\u5e73\u5747\u6e29\u5ea6\uff0c\u8003\u8651\u5230\u53ea\u6709\u9760\u8fd1\u6837\u54c1\u7684\u6c14\u4f53\u4f1a\u53d1\u751f\u53cd\u5e94\u3002\u865a\u7ebf\u8868\u793a\u52a0\u70ed\u5668\u6e29\u5ea6\uff0c\u56fa\u5b9a\u57281141 \u2103\uff0c\u5bf9\u5e9460 V\u8f93\u5165\u4e0b\u7684\u6700\u9ad8\u6e29\u5ea6\u3002\u63d2\u56fe\u4e3at = 0.6\u79d2\u548c4\u79d2\u65f6\u7684\u6a21\u62df\u6a2a\u622a\u9762\u6e29\u5ea6\u5206\u5e03\u3002(h) \u6a21\u62df\u7684\u6837\u54c1\u548c\u6c14\u4f53\u6e29\u5ea6\u4e0e\u52a0\u70ed\u5668\u6e29\u5ea6\uff08T<sub>heater<\/sub>\uff09\u4e4b\u95f4\u7684\u5173\u7cfb\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262798\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72473-15.png\" alt=\"\" width=\"600\" height=\"498\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72473-15.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72473-15-300x249.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u4ece\u542b<\/strong><strong>ITO<\/strong><strong>\u5e9f\u6599\u4e2d\u9009\u62e9\u6027\u56de\u6536\u94df\u3002<\/strong>(a) \u8ba1\u7b97\u7684In<sub>2<\/sub>O<sub>3<\/sub>\u548cSnO<sub>2<\/sub>\u6c2f\u5316\u53cd\u5e94\u7684\u0394G\u968f\u6e29\u5ea6\u53d8\u5316\u3002\u865a\u7ebf\u8868\u793a\u0394G = 0 kJ mol<sup>-1<\/sup>\u3002(b) \u78b3\u7eb8\u52a0\u70ed\u5668\u5728\u5360\u7a7a\u6bd4\u4e3a5%\u65f6\u7684\u6700\u5927\u6e29\u5ea6\uff08Tmax\uff09\u968f\u7535\u538b\u8f93\u5165\u53d8\u5316\u3002\u5e95\u90e8\u548c\u9876\u90e8\u865a\u7ebf\u5206\u522b\u8868\u793aT = 630\u00b0C\u548c1240\u00b0C\u3002(c) ITO\u539f\u6750\u6599\uff08\u4e0b\uff09\u3001\u6325\u53d1\u7269\uff08\u4e2d\uff09\u548c\u6b8b\u7559\u7269\uff08\u4e0a\uff09\u7684\u7167\u7247\u3002(d) ITO\u539f\u6750\u6599\u3001InCl<sub>3<\/sub>\u6325\u53d1\u4ea7\u7269\u548cSnO<sub>2<\/sub>\u6b8b\u7559\u7269\u7684\u62c9\u66fc\u5149\u8c31\u3002(e) ITO\u539f\u6750\u6599\uff08PDF#01-089-4597\uff09\u3001InCl<sub>3<\/sub>\u6325\u53d1\u4ea7\u7269\uff08PDF#01-0170\uff09\u548cSnO2\u6b8b\u7559\u7269\uff08PDF#00-021-1250\uff09\u7684XRD\u56fe\u8c31\u300226.3\u00b0\u5904\u7684\u5bbd\u5cf0\u5f52\u56e0\u4e8e\u7528\u4e8e\u5bc6\u5c01InCl3\u6837\u54c1\u4ee5\u51cf\u7f13\u5176\u6f6e\u89e3\u7684Kapton\u80f6\u5e26\u3002(f) \u4ea7\u54c1\u7eaf\u5ea6\u548c\u4ea7\u7387\u968f\u7535\u538b\u8f93\u5165\u53d8\u5316\u3002\u63d2\u56fe\u4e3a\u83b7\u5f97\u7684InCl3\u7167\u7247\u3002(g) TCE\u5e9f\u6599\u4e2d\u7684\u4e3b\u8981\u91d1\u5c5e\u6210\u5206\u3002(h) TCE\u5e9f\u6599\u4e2d\u4e3b\u8981\u6210\u5206\u7684\u6c2f\u5316\u53cd\u5e94\u0394G\u968f\u6e29\u5ea6\u53d8\u5316\uff0c\u5305\u62ecIn<sub>2<\/sub>O<sub>3<\/sub>\u3001MnO\u3001SnO<sub>2<\/sub>\u3001Au\u548cCr<sub>2<\/sub>O<sub>3<\/sub>\u3002\u865a\u7ebf\u8868\u793a\u0394G = 0 kJ mol<sup>-1<\/sup>\u3002(i) \u4eceTCE\u5e9f\u6599\u4e2d\u56de\u6536\u94df\u7684\u4ea7\u7387\u548c\u7eaf\u5ea6\u3002\u56fef\u3001g\u548ci\u4e2d\u7684\u8bef\u5dee\u7ebf\u8868\u793a\u6d4b\u91cf\u7684\u6807\u51c6\u504f\u5dee\uff0cN = 3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262799\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72474-15.png\" alt=\"\" width=\"600\" height=\"506\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72474-15.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72474-15-300x253.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3. <\/strong><strong>\u4ece\u94bd\u7535\u5bb9\u5e9f\u6599\u4e2d\u9009\u62e9\u6027\u56de\u6536\u94bd<\/strong>\u3002(a) \u94bd\u7535\u5bb9\u5e9f\u6599\u4e2d\u7684\u4e3b\u8981\u91d1\u5c5e\u6210\u5206\u3002(b) \u94bd\u7535\u5bb9\u5e9f\u6599\u4e2d\u4e3b\u8981\u91d1\u5c5e\u7684\u6c2f\u5316\u53cd\u5e94\u0394G\u968f\u6e29\u5ea6\u53d8\u5316\uff0c\u5305\u62ecTa<sub>2<\/sub>O<sub>5<\/sub>\u3001SiO<sub>2<\/sub>\u3001CuO\u3001Fe<sub>2<\/sub>O<sub>3<\/sub>\u3001NiO\u548cMnO\u3002\u865a\u7ebf\u8868\u793a\u0394G = 0 kJ mol<sup>-1<\/sup>\u3002(c) Ta<sub>2<\/sub>O<sub>5<\/sub>\u548cSiO<sub>2<\/sub>\u78b3\u6c2f\u5316\u53cd\u5e94\u7684\u0394G\u968f\u6e29\u5ea6\u53d8\u5316\u3002\u865a\u7ebf\u8868\u793a\u0394G = 0 kJ mol-1\u3002(d) Ta<sub>2<\/sub>O<sub>5<\/sub>\u548cSiO<sub>2<\/sub>\u78b3\u6c2f\u5316\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u3002\u62df\u5408\u66f2\u7ebf\u7684\u659c\u7387\u4f9d\u636e\u963f\u4f26\u5c3c\u4e4c\u65af\u65b9\u7a0b\uff0c\u5176\u4e2dSiO2\u7684\u6d3b\u5316\u80fd\u4e3a53.6 kJ mol<sup>-1<\/sup>\uff0cTa<sub>2<\/sub>O<sub>5<\/sub>\u4e3a31.6 kJ mol<sup>-1<\/sup>\u3002(e) \u7b2c\u4e00\u6b65\u6325\u53d1\u7269\uff08\u4e0b\uff09\u548c\u7b2c\u4e8c\u6b65\u6325\u53d1\u7269\uff08\u4e0a\uff09\u7684EDS\u5149\u8c31\u3002\u63d2\u56fe\u4e3a\u77f3\u82f1\u7ba1\u4e0a\u51dd\u7ed3\u7684\u6325\u53d1\u7269\u7167\u7247\uff0c\u5de6\u4e0b\u89d2\u4e3a\u6b65\u9aa41\u6c2f\u5316\u6325\u53d1\u7269\uff0c\u53f3\u4e0a\u89d2\u4e3a\u6b65\u9aa42\u78b3\u6c2f\u5316\u6325\u53d1\u7269\u3002(f) \u94bd\u7535\u5bb9\u539f\u6750\u6599\u3001\u6b65\u9aa41\u6c2f\u5316\u6325\u53d1\u7269\u53ca\u6b8b\u7559\u7269\u3001\u6b65\u9aa42\u78b3\u6c2f\u5316\u6325\u53d1\u7269\u53ca\u6b8b\u7559\u7269\u4e2d\u7684\u91d1\u5c5e\u542b\u91cf\u767e\u5206\u6bd4\u3002(g) \u4e0d\u540c\u7535\u70ed\u6c2f\u5316\u6761\u4ef6\u4e0b\u7684\u4ea7\u54c1\u7eaf\u5ea6\u548c\u4ea7\u7387\u3002x\u8f74\u7684\u7b2c\u4e00\u884c\u8868\u793a\u7b2c\u4e00\u6b65ETC\u53c2\u6570\uff0c\u7b2c\u4e8c\u884c\u8868\u793a\u7b2c\u4e8c\u6b65ETCC\u53c2\u6570\u3002(h) \u6c89\u79ef\u6325\u53d1\u7269\u53ca\u7145\u70e7\u540e\u7684XRD\u56fe\u8c31\uff0c\u53c2\u8003PDF\u4e3aTa<sub>2<\/sub>O<sub>5<\/sub>\uff0801-082-9637\uff09\u3002(i) Ta<sub>2<\/sub>O<sub>5<\/sub>\u539f\u6750\u6599\u3001\u6c89\u79ef\u6325\u53d1\u7269\u53ca\u7145\u70e7\u540e\u7684\u62c9\u66fc\u5149\u8c31\u3002\u56fea\u548cg\u4e2d\u7684\u8bef\u5dee\u7ebf\u8868\u793a\u6807\u51c6\u504f\u5dee\uff0c\u6d4b\u91cf\u91cd\u590d\u6b21\u6570\u4e3aN = 3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262800\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72475-13.png\" alt=\"\" width=\"600\" height=\"494\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72475-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/09\/\u56fe\u72475-13-300x247.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u53ef\u6269\u5c55\u6027\u3001\u6280\u672f\u7ecf\u6d4e\u548c\u53ef\u6301\u7eed\u6027\u8003\u8651<\/strong>\u3002(a) \u5728\u76f8\u540c\u7535\u538b\u8f93\u5165100 V\u4e0b\uff0c\u78b3\u7eb8\u52a0\u70ed\u5668\u7684\u7167\u7247\uff0c\u5c3a\u5bf8\u5206\u522b\u4e3a 2 \u00d7 6 cm\u00b2\u30013 \u00d7 9 cm\u00b2 \u548c 4 \u00d7 12 cm\u00b2\uff08\u5bbd \u00d7 \u957f\uff09\u3002(b) \u52a0\u70ed\u5668\u6e29\u5ea6\u56fe\u4e0e\u7535\u538b\u8f93\u5165\u548c\u52a0\u70ed\u5668\u957f\u5ea6\u7684\u5173\u7cfb\u3002\u52a0\u70ed\u5668\u539a\u5ea6\u4fdd\u6301\u4e0d\u53d8\uff0c\u5176\u7eb5\u6a2a\u6bd4\uff08L\/W\uff09\u56fa\u5b9a\u4e3a3\u3002(c) \u4e0d\u540c\u52a0\u70ed\u5668\u89c4\u6a21\uff08S\uff09\u4e0b\u6837\u54c1\u7684\u6a21\u62df\u5e73\u5747\u6e29\u5ea6\u5206\u5e03\uff0cS = 1 \u8868\u793a 1 \u00d7 3 cm\u00b2\u3002\u52a0\u70ed\u5668\u6e29\u5ea6\u56fa\u5b9a\u4e3a1200 \u00b0C\u3002\u63d2\u56fe\u663e\u793a\u4e86 S = 2 \u548c S = 4 \u7684\u6a21\u62df\u6e29\u5ea6\u5206\u5e03\u3002(d) T99\u7684\u65f6\u95f4\u548c\u5f52\u4e00\u5316\u6837\u54c1\u8d28\u91cf\u968f\u52a0\u70ed\u5668\u89c4\u6a21\u53d8\u5316\u3002\u6837\u54c1\u8d28\u91cf\u5728S = 1\u7684\u89c4\u6a21\u4e0b\u5b9a\u4e49\u4e3a1\u3002(e) \u653e\u7f6e\u5728\u5c3a\u5bf8\u4e3a 3 \u00d7 9 cm\u00b2 \u78b3\u52a0\u70ed\u5668\u4e0a\u7684\u539f\u59cbTCW\u7167\u7247\uff08\u4e0a\u56fe\uff09\u53ca\u7b2c\u4e8c\u6b65ETCC\u53cd\u5e94\u540e\u6c89\u79ef\u5728\u77f3\u82f1\u7ba1\u5185\u7684\u6325\u53d1\u7269\u7167\u7247\uff08\u4e0b\u56fe\uff09\u3002(f) \u4ece1.0 g\u653e\u5927\u6279\u6b21\u4e2d\u56de\u6536\u7684\u94bd\u4ea7\u54c1\u7684\u7eaf\u5ea6\u548c\u4ea7\u7387\u3002(g) \u4f7f\u7528\u7535\u70ed\u6c2f\u5316\uff08\u6709\u78b3\u548c\u65e0\u78b3\uff09\u4e0e\u6e7f\u6cd5\u51b6\u91d1\u5de5\u827a\uff08\u9178\u6d78\u548c\u78b1\u6d88\u5316\uff09\u5206\u79bb\u4e8c\u5143\u91d1\u5c5e\u6c27\u5316\u7269\u65f6\u7684\u5bb9\u91cf\u4f9d\u8d56\u6027\u8d44\u672c\u652f\u51fa\uff08CAPEX\uff09\u3002(h) \u57281\u5428\u5904\u7406\u91cf\u4e0b\uff0c\u4f7f\u7528\u7535\u70ed\u6c2f\u5316\u6216\u6e7f\u6cd5\u51b6\u91d1\u5de5\u827a\u5206\u79bb\u4e8c\u5143\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u8fd0\u8425\u652f\u51fa\uff08OPEX\uff09\u3002(i) \u57281\u5428\u5904\u7406\u91cf\u4e0b\uff0c\u4f7f\u7528\u7535\u70ed\u6c2f\u5316\u6216\u6e7f\u6cd5\u51b6\u91d1\u5de5\u827a\u5206\u79bb\u4e8c\u5143\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u5168\u7403\u53d8\u6696\u6f5c\u529b\uff08GWP\uff09\u3002\u56feg\u3001h\u548ci\u4e2d\u7684\u8bef\u5dee\u6761\u8868\u793a\u901a\u8fc7\u8499\u7279\u5361\u6d1b\u4e0d\u786e\u5b9a\u6027\u5206\u6790\uff08N = 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