{"id":262967,"date":"2024-10-27T06:11:13","date_gmt":"2024-10-26T22:11:13","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=262967"},"modified":"2024-10-26T21:11:40","modified_gmt":"2024-10-26T13:11:40","slug":"%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6nature-synthesis%ef%bc%9a%e5%a4%9a%e5%85%83%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e7%ac%bc%e7%9a%84%e5%8f%af%e6%8e%a7%e5%90%88%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=262967","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66Nature Synthesis\uff1a\u591a\u5143\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u53ef\u63a7\u5408\u6210"},"content":{"rendered":"<p><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n<p>\u4f5c\u4e3a\u4e00\u7c7b\u7531\u5468\u671f\u6027\u8fde\u63a5\u7684\u65e0\u673a\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673alinker\u7ec4\u6210\u7684\u6676\u4f53\u591a\u5b54\u6750\u6599\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u5df2\u88ab\u5f00\u53d1\u7528\u4e8e\u5e94\u5bf9\u4e0e\u80fd\u6e90\u548c\u73af\u5883\u76f8\u5173\u7684\u5168\u7403\u6311\u6218\u3002\u9ad8\u5ea6\u591a\u5b54\u7684MOF\u56e0\u5176\u660e\u786e\u7684\u9aa8\u67b6\u7ed3\u6784\u800c\u8868\u73b0\u51fa\u8d85\u9ad8\u7684\u5b54\u9699\u7387\u548c\u8868\u9762\u79ef\uff0c\u662f\u5929\u7136\u6c14\u548c\u6c22\u6c14\u53ef\u9006\u548c\u9ad8\u5bb9\u91cf\u50a8\u5b58\u7684\u6709\u524d\u666f\u7684\u5019\u9009\u6750\u6599\u3002\u5b9e\u73b0\u7cbe\u51c6\u5408\u6210\u62d3\u6251\u7f51\u7edc\u7ed3\u6784\u5bf9MOF\u7684\u5bfc\u5411\u6027\u5408\u6210\u5177\u6709\u91cd\u8981\u6307\u5bfc\u610f\u4e49\u3002\u8d85\u5206\u5b50\u6784\u7b51\u6a21\u5757\u7b56\u7565\uff08SBBs\uff09\u901a\u8fc7\u5c06\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\uff08MOPs\uff09\u4f5c\u4e3a\u6784\u7b51\u57fa\u5143\uff0c\u4e3a\u53d1\u5c55\u9ad8\u8fde\u63a5\u7f51\u7edc\u7ed3\u6784\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u6307\u5bfc\u3002\u57fa\u4e8e\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u4e86\u4e00\u7cfb\u5217\u53cc\u5143\u7684\u9ad8\u8fde\u63a5\u7f51\u7edc\u7ed3\u6784\uff0c\u598212-\u8fde\u63a5\u7684fcu\u7f51\u7edc\u30014,12-\u8fde\u63a5\u7684ftw\u7f51\u7edc\u4ee5\u53ca3,24-\u8fde\u63a5\u7684rht\u7f51\u7edc\u3002\u76f8\u8f83\u4e8e\u4f4e\u8fde\u63a5\u7f51\u7edc\uff0c\u9ad8\u8fde\u63a5\u7f51\u7edc\u7ed3\u6784\u901a\u5e38\u6709\u66f4\u597d\u7684\u53ef\u8bbe\u8ba1\u6027\u548c\u53ef\u9884\u6d4b\u6027\u3002\u4f46\u4e0a\u8ff0SBB\u7b56\u7565\u5728\u4e09\u5143\u7f51\u7edc\u7ed3\u6784\u4e2d\u8fd8\u672a\u66fe\u5b9e\u73b0\u3002<\/p>\n<p><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c<strong>\u6d59\u6c5f\u5927\u5b66\u9648\u5fd7\u6770\u7814\u7a76\u5458<\/strong>\u56e2\u961f\u5728<strong><em>Nature Synthesis<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>A hetero-supermolecular-building-block strategy for the assembly of porous (3,12,24)-connected uru metal\u2013organic frameworks<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u63d0\u51fa\u4e86\u5f02\u8d28\u5316\u8d85\u5206\u5b50\u6784\u7b51\u6a21\u5757\u7b56\u7565\uff08Hetero-SBBs\uff09\uff0c\u5373\u5728\u7f51\u7edc\u7ed3\u6784\u4e2d\u540c\u65f6\u5f15\u5165\u4e24\u79cd\u91d1\u5c5e\u6709\u673a\u591a\u9762\u4f53\u4f5c\u4e3a\u6784\u7b51\u57fa\u5143\uff0c\u4ece\u800c\u521b\u5efa\u4e86\u9ad8\u8fde\u63a5\u7684\u4e09\u5143\u7f51\u7edc\u7ed3\u6784\uff1a3,12,24-\u8fde\u63a5uru\u7f51\u7edc\u3002\u7814\u7a76\u4eba\u5458\u91c7\u7528\u4e00\u79cd\u7075\u6d3b\u7684\u8fde\u63a5\u5242\u2014\u57fa\u4e8e\u6709\u673a\u7b3c\u7684\u7fa7\u9178\u76d0\uff0c\u6210\u529f\u5730\u5c06\u57fa\u4e8eCu-\u6868\u8f6e\u7684\u7acb\u65b9\u516b\u9762\u4f53\uff08cuo\uff09\u548c\u83f1\u5f62\u516b\u9762\u4f53\uff08rco\uff09MOPs\u7ec4\u88c5\u6210\u4e00\u4e2a\u4e09\u7ef4\u7684uru\u9aa8\u67b6\u3002\u6240\u5f97\u5230\u7684uru-MOF-1\u5177\u6709\u5206\u5c42\u7684\u5fae\u5b54\u548c\u4ecb\u5b54\u7b3c\uff0c\u5c55\u73b0\u51faBET\u9762\u79ef\u4e3a3170 m<sup>2<\/sup> g<sup>-1<\/sup>\uff0c\u5b9e\u9a8c\u5b54\u4f53\u79ef\uff08PV\uff09\u4e3a1.38 cm<sup>3<\/sup> g<sup>-1<\/sup>\u7684\u4f18\u5f02\u5b54\u9699\u5ea6\u3002\u7814\u7a76\u7ed3\u679c\u663e\u793a\uff0curu-MOF-1\u5728159 K\u548c10 bar\u6761\u4ef6\u4e0b\u7684\u7532\u70f7\u5438\u6536\u91cf\u8fbe\u5230339.6 cm<sup>3<\/sup> (STP) cm<sup>-3<\/sup>\uff0c\u4f7f\u5176\u6210\u4e3a\u4e00\u79cd\u6781\u5177\u6f5c\u529b\u7684\u4f4e\u6e29\u7532\u70f7\u50a8\u5b58\u6750\u6599\u3002\u6b64\u5916\uff0c\u57286 bar\u3001159 K\u548c5 bar\u3001298 K\u4e4b\u95f4\u7684\u5de5\u4f5c\u5bb9\u91cf\u4e3a309.4 cm<sup>3<\/sup> (STP) cm<sup>-3<\/sup>\u3002\u901a\u8fc7\u5408\u6210\u7684MOPs\u5e93\uff0c\u5229\u7528\u5f02\u6784SBB\u7b56\u7565\u4e3a\u8bbe\u8ba1\u5408\u6210\u9ad8\u8fde\u63a5MOF\u94fa\u5e73\u4e86\u9053\u8def\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262968\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/0-2.png\" alt=\"\" width=\"600\" height=\"311\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/0-2.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/0-2-300x156.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p>\u5728\u524d\u671f\u7814\u7a76\u5de5\u4f5c\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5728\u7b3c\u72b6\u516d\u8fde\u63a5\u7fa7\u9178\u914d\u4f53\u4e2d\u5f15\u5165\u53d6\u4ee3\u57fa\u56e2\uff0c\u4f7f\u5f97\u5b83\u5728\u4e0eCu<sup>2+<\/sup>\u7ec4\u88c5\u4e2d\u5f62\u6210\u4e86\u84dd\u8272\u7684\u5757\u72b6\u5355\u6676\u3002\u5355\u6676XRD\u663e\u793a\u8be5\u5316\u5408\u7269\u5177\u6709\u7acb\u65b9\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u6676\u80de\u4f53\u79ef\u8fbe\u523068000 \u00c5<sup>3<\/sup>\u3002\u62d3\u6251\u5206\u6790\u663e\u793a\u8be5\u5316\u5408\u7269\u5177\u67093,12,24-\u8fde\u63a5\u7684uru\u7f51\u7edc\u7ed3\u6784\uff0c\u8fd9\u4e5f\u662f\u76ee\u524d\u62a5\u9053\u7684\u5177\u6709\u6700\u9ad8\u8fde\u63a5\u6570\u7684MOF\u7ed3\u6784\u4e4b\u4e00\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262969\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/1-3.png\" alt=\"\" width=\"600\" height=\"492\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/1-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/1-3-300x246.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>1\u00a0 <\/strong><strong>uru<\/strong><strong>\u7f51\u7edc\u7684\u4ea7\u751f\u4e0e\u89e3\u6784<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262970\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/2-3.png\" alt=\"\" width=\"600\" height=\"663\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/2-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/2-3-271x300.png 271w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>2\u00a0 <\/strong><strong>\u5f02\u8d28\u5316<\/strong><strong>SBB<\/strong><strong>\u7b56\u7565\u7528\u4e8e\u5408\u6210<\/strong><strong>uru-MOF \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262971\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/3-3.png\" alt=\"\" width=\"600\" height=\"690\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/3-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/3-3-261x300.png 261w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>3\u00a0 uru-MOF<\/strong><strong>\u7684\u7f51\u683c\u5316\u5408\u6210<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-262972\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/4-3.png\" alt=\"\" width=\"600\" height=\"487\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/4-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2024\/10\/4-3-300x244.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe<\/strong><strong>4\u00a0 <\/strong><strong>\u6c14\u4f53\u5438\u9644\u8bd5\u9a8c<\/strong><strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n<p>\u7efc\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u63d0\u51fa\u4e86\u8d85\u8d8a\u4f20\u7edf\u7684\u5f02\u8d28\u5316\u8d85\u5206\u5b50\u6784\u7b51\u6a21\u5757\u6982\u5ff5\uff0c\u5e76\u7528\u4e8e\u53ef\u63a7\u5408\u6210\u57fa\u4e8e\u591a\u5143\u91d1\u5c5e\u6709\u673a\u7b3c\u7684\u9ad8\u8fde\u63a5\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u3002\u5408\u6210\u7684\u9ad8\u5ea6\u591a\u5b54\u7684uru-MOF-1\u5177\u6709\u5206\u7ea7\u5fae\u5b54\u548c\u4e2d\u5b54\u7b3c\uff0c\u88ab\u8ba4\u4e3a\u662f\u7532\u70f7\u50a8\u5b58\u548c\u6db2\u5316\u5929\u7136\u6c14\u2014\u5929\u7136\u6c14\u5e94\u7528\u7684\u6709\u524d\u666f\u7684\u6750\u6599\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5f02\u8d28SBB\u7b56\u7565\u5728\u6269\u5c55MOF\u6676\u4f53\u5316\u5b66\u4e2d\u9ad8\u8fde\u63a5\u6027\u7f51\u7edc\u7684\u8fb9\u754c\u65b9\u9762\u662f\u6709\u6548\u7684\u3002\u8fd9\u9879\u7814\u7a76\u4e0d\u4ec5\u62d3\u5c55\u4e86\u7f51\u683c\u5316\u5b66\u4e0e\u8d85\u5206\u5b50\u6784\u7b51\u5757\u7b56\u7565\u7406\u8bba\uff0c\u800c\u4e14\u4e3a\u53d1\u5c55\u4e0b\u4e00\u4ee3\u9ad8\u5b54\u6027\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7684\u53ef\u63a7\u5408\u6210\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u7814\u7a76\u601d\u8def\u3002<\/p>\n<p>\u539f\u6587\u8be6\u60c5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s44160-024-00622-5\" target=\"_blank\" rel=\"noopener\">A hetero-supermolecular-building-block strategy for the assembly of porous (3,12,24)-connected uru metal\u2013organic frameworks<\/a> (<em>Nature Synthesis<\/em> <strong>2024<\/strong>, DOI: 10.1038\/s44160-024-00622-5)<\/p>\n<p>\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011 \u4f5c\u4e3a\u4e00\u7c7b\u7531\u5468\u671f\u6027\u8fde\u63a5\u7684\u65e0\u673a\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673alinker\u7ec4\u6210\u7684\u6676\u4f53\u591a\u5b54\u6750\u6599\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOF\uff09\u5df2\u88ab\u5f00\u53d1\u7528\u4e8e\u5e94\u5bf9\u4e0e\u80fd\u6e90\u548c\u73af\u5883\u76f8\u5173\u7684\u5168\u7403\u6311\u6218\u3002\u9ad8\u5ea6&#8230;<\/p>\n","protected":false},"author":1004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[5134],"class_list":["post-262967","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-mof"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262967"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=262967"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262967\/revisions"}],"predecessor-version":[{"id":262976,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/262967\/revisions\/262976"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=262967"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=262967"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=262967"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}