{"id":263219,"date":"2024-11-07T06:24:38","date_gmt":"2024-11-06T22:24:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=263219"},"modified":"2024-11-06T22:24:55","modified_gmt":"2024-11-06T14:24:55","slug":"%e6%9d%a8%e5%9b%9b%e6%b5%b7%e6%9c%80%e6%96%b0nat-mater-%ef%bc%9a%e7%94%a8%e4%ba%8e%e7%97%95%e9%87%8f%e8%8b%af%e5%90%b8%e9%99%84%e7%9a%84mofs","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=263219","title":{"rendered":"\u6768\u56db\u6d77\u6700\u65b0Nat. Mater.\uff1a\u7528\u4e8e\u75d5\u91cf\u82ef\u5438\u9644\u7684MOFs"},"content":{"rendered":"

\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><\/p>\n

\u82ef\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u9057\u4f20\u6bd2\u6027\u81f4\u764c\u7269\u8d28\uff0c\u6ca1\u6709WHO\u5efa\u8bae\u7684\u5b89\u5168\u66b4\u9732\u6c34\u5e73\u3002\u82ef\u5728\u5ba4\u5185\u548c\u5ba4\u5916\u73af\u5883\u4e2d\u65e0\u5904\u4e0d\u5728\uff0c\u4e3a\u4fdd\u62a4\u5065\u5eb7\u548c\u73af\u5883\u800c\u6e05\u9664\u5fae\u91cf\u82ef\u5341\u5206\u6709\u5fc5\u8981\u3002\u76ee\u524d\uff0c\u6c27\u5316\u548c\u751f\u7269\u5904\u7406\u88ab\u5e7f\u6cdb\u7528\u4e8e\u82ef\u7684\u6e05\u9664\uff0c\u4f46\u6709\u5bb3\u526f\u4ea7\u7269\u7684\u5f62\u6210\u548c\u8fd9\u4e9b\u8fc7\u7a0b\u7684\u4f4e\u6548\u7387\u9650\u5236\u4e86\u5b83\u4eec\u7684\u5e94\u7528\u3002\u7531\u4e8e\u5438\u9644\u5242\u7684\u518d\u751f\u6210\u672c\u4f4e\uff0c\u82ef\u7684\u7269\u7406\u5438\u9644\u5f15\u8d77\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u4f20\u7edf\u591a\u5b54\u6750\u6599\uff08\u5982\u6d3b\u6027\u70ad\u3001\u4ecb\u5b54SiO2<\/sub>\u548c\u6cb8\u77f3\uff09\u7f3a\u4e4f\u6709\u5e8f\u6027\u548c\u7ed3\u6784\u53ef\u8c03\u6027\uff0c\u4f7f\u5f97\u7cbe\u786e\u63a7\u5236\u5b54\u7ed3\u6784\u548c\u5438\u9644\u6027\u80fd\u6781\u5176\u56f0\u96be\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u6750\u6599\u7531\u4e8e\u5176\u9ad8\u5b54\u9699\u7387\u548c\u53ef\u8c03\u8282\u7684\u5b54\u9699\u73af\u5883\u800c\u663e\u793a\u51fa\u4f5c\u4e3a\u6709\u6bd2\u6c14\u4f53\u5438\u9644\u5242\u7684\u5de8\u5927\u524d\u666f\u3002\u8bb8\u591aMOF\u8868\u73b0\u51fa\u8f83\u9ad8\u7684\u82ef\u5438\u6536\u7387\uff0c\u4f18\u4e8e\u5546\u4e1a\u5316\u7684\u5438\u9644\u5242\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u5728\u76f8\u5bf9\u9ad8\u5206\u538b\u4e0b\u7684\u5438\u6536\u5e76\u4e0d\u80fd\u4fdd\u8bc1\u5728\u4f4e\u5206\u538b\u7684\u5b9e\u9645\u6761\u4ef6\u4e0b\u7684\u6700\u4f73\u6027\u80fd\u3002\u56e0\u6b64\u6709\u6548\u63a7\u5236\u5b54\u9699\u5316\u5b66\u4ee5\u63d0\u9ad8\u75d5\u91cf\u82ef\u6355\u83b7\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

 <\/p>\n

\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/p>\n

\u8fd1\u671f\uff0c\u5317\u4eac\u5927\u5b66<\/strong>\/<\/strong>\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u6768\u56db\u6d77\u6559\u6388<\/strong>\u5728Nature Materials<\/em><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cTrace benzene capture by decoration of structural defects in metal-organic framework materials<\/strong>\u201d\u7684\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u901a\u8fc7\u5f15\u5165\u4e8c\u4ef7\u5355\u539f\u5b50\u4f4d\u70b9\u6765\u4fee\u9970MIL-125-\u7f3a\u9677\u4e2d\u7684\u7ed3\u6784\u7f3a\u9677\uff08\u7f3a\u5931\u7684\u91d1\u5c5e\u4e2d\u5fc3\uff09\uff0c\u4ee5\u83b7\u5f97\u4e00\u7cfb\u5217\u53cc\u91d1\u5c5e\u6750\u6599MIL-125-X\uff08X=Mn\u3001Fe\u3001Co\u3001Ni\u3001Cu\u3001Zn\uff09\u6765\u63a7\u5236\u5b54\u9699\u5316\u5b66\u3002\u5728298 K\u65f6\uff0cMIL-125-Zn\u57281.2 mbar\u548c0.12 mbar\u4e0b\u7684\u82ef\u5438\u6536\u7387\u5206\u522b\u4e3a7.63 mmol g-1<\/sup>\u548c5.33 mmol g-1<\/sup>\uff0c\u5bf9\u591a\u5b54\u56fa\u4f53\u5177\u6709\u660e\u786e\u7684\u5438\u9644\u4f5c\u7528\u3002\u7a81\u7834\u6027\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5373\u4f7f\u66b4\u9732\u5728\u6f6e\u6e7f\u73af\u5883\u4e2d\uff0c\u4e5f\u80fd\u4ece\u7a7a\u6c14\u4e2d\u53bb\u9664\u75d5\u91cf\u82ef\uff08\u4ece5 ppm\u964d\u81f3 < 0.5 ppm\uff09\u3002\u901a\u8fc7\u884d\u5c04\u3001\u6563\u5c04\u548c\u5149\u8c31\u5206\u6790\uff0c\u53ef\u4ee5\u89c2\u5bdf\u5230\u4f4e\u538b\u4e0b\u82ef\u4e0e\u7f3a\u9677\u548c\u5f00\u653eZn\uff08II\uff09\u4f4d\u70b9\u7684\u7ed3\u5408\u3002\u8fd9\u9879\u7814\u7a76\u5f3a\u8c03\u4e86\u7cbe\u786e\u8c03\u63a7\u5b54\u9699\u5316\u5b66\u5bf9\u4e8e\u8bbe\u8ba1\u9ad8\u6548\u53bb\u9664\u7a7a\u6c14\u6c61\u67d3\u7269\u7684\u5438\u9644\u5242\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u00a0\"\"<\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1\u00a0 <\/strong>MIL-125<\/strong>\u7f3a\u9677\u4e2d\u5355\u539f\u5b50<\/strong>Zn(II)<\/strong>\u4f4d\u70b9\u7f3a\u9677\u4fee\u9970\u793a\u610f\u56fe<\/strong>\u00a9 2024 Springer Nature<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2\u00a0 <\/strong>\u82ef\u5438\u9644\u548c\u7a81\u7834\u6027\u6570\u636e<\/strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n

\u00a0<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3\u00a0 MIL-125-<\/strong>\u7f3a\u9677\u548c<\/strong>MIL-125-Zn<\/strong>\u4e2d\u82ef<\/strong>–d<\/em>6<\/sub><\/strong>\u5438\u9644\u57df\u7684\u7ed3\u6784\u6a21\u578b<\/strong>\u00a9 2024 Springer Nature<\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4\u00a0 MIL-125-<\/strong>\u7f3a\u9677\u548c<\/strong>MIL-125-Zn<\/strong>\u7684\u539f\u4f4d<\/strong>FTIR<\/strong>\u3001\u56fa\u6001<\/strong>NMR<\/strong>\u548c<\/strong>INS<\/strong>\u5149\u8c31\u8868\u5f81<\/strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n

 <\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5\u00a0 MIL-125<\/strong>\u548c<\/strong>MIL-125-Zn<\/strong>\u4e2d\u5438\u9644\u82ef\u5206\u5b50\u7684<\/strong>QENS<\/strong>\u5206\u6790<\/strong> \u00a9 2024 Springer Nature<\/strong><\/p>\n

 <\/p>\n

\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n

\u7efc\u4e0a\uff0c\u672c\u7814\u7a76\u901a\u8fc7\u7528\u5355\u539f\u5b50\u4f4d\u70b9\u88c5\u9970MIL-125\u7f3a\u9677\u4e2d\u7684\u7ed3\u6784\u7f3a\u9677\u6765\u589e\u5f3a\u5bf9\u75d5\u91cf\u82ef\u7684\u6355\u83b7\uff0c\u662f\u4e00\u79cd\u5f88\u6709\u524d\u666f\u7684\u89e3\u51b3\u7a7a\u6c14\u6c61\u67d3\u95ee\u9898\u7684\u7b56\u7565\u3002\u5728\u73af\u5883\u6761\u4ef6\u4e0b\uff0cMIL-125-Zn\u5bf9\u75d5\u91cf\u82ef\u7684\u9ad8\u6548\u53bb\u9664\u51f8\u663e\u4e86\u5176\u5728\u5b9e\u9645\u5ba4\u5185\u7a7a\u6c14\u8d28\u91cf\u7ba1\u7406\u4e2d\u7684\u6f5c\u529b\u3002\u7f3a\u9677\u5de5\u7a0b\u548c\u5355\u539f\u5b50\u4f4d\u70b9\u88c5\u9970\u7684\u539f\u7406\u53ef\u4ee5\u6269\u5c55\u5230\u82ef\u6355\u83b7\u4e4b\u5916\uff0c\u4e3a\u9488\u5bf9\u5176\u4ed6\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\u548c\u6c14\u6001\u6c61\u67d3\u7269\u63d0\u4f9b\u9002\u5e94\u6027\u3002\u6b64\u5916\uff0c\u8fd9\u9879\u7814\u7a76\u4e2d\u7684\u591a\u65b9\u9762\u8868\u5f81\u4e3a\u63a2\u6d4b\u591a\u5b54\u6750\u6599\u4e2d\u7684\u4e3b\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5b9d\u8d35\u7684\u6846\u67b6\uff0c\u6709\u53ef\u80fd\u52a0\u901f\u53d1\u73b0\u548c\u4f18\u5316\u7528\u4e8e\u5404\u79cd\u73af\u5883\u548c\u5de5\u4e1a\u5e94\u7528\u7684\u5438\u9644\u5242\u3002\u8fd9\u9879\u5de5\u4f5c\u51f8\u663e\u4e86\u5fae\u8c03\u5b54\u9699\u5316\u5b66\u5728\u8bbe\u8ba1\u53ef\u884c\u3001\u9ad8\u6548\u5438\u9644\u5242\u65b9\u9762\u7684\u6781\u7aef\u91cd\u8981\u6027\u3002<\/p>\n

\u539f\u6587\u8be6\u60c5\uff1aTrace benzene capture by decoration of structural defects in metal-organic framework materials<\/a> (Nature Materials, <\/em>2024<\/strong>, 23, 1531-1538)<\/p>\n

\u672c\u6587\u7531\u5927\u5175\u54e5\u4f9b\u7a3f\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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