{"id":263944,"date":"2024-12-17T06:06:28","date_gmt":"2024-12-16T22:06:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=263944"},"modified":"2024-12-17T09:25:01","modified_gmt":"2024-12-17T01:25:01","slug":"%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6%e9%b2%8d%e5%ae%97%e5%bf%85%e5%9b%a2%e9%98%9f%e3%80%8aam%e3%80%8b%e6%9c%80%e6%96%b0%e7%a0%94%e7%a9%b6%ef%bc%9a%e5%ae%a4%e6%b8%a9%e4%b8%8b%e6%b0%aa%e6%b0%94%e9%80%89","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=263944","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66\u9c8d\u5b97\u5fc5\u56e2\u961f\u300aAM\u300b\u6700\u65b0\u7814\u7a76\uff1a\u5ba4\u6e29\u4e0b\u6c2a\u6c14\u9009\u62e9\u6027\u5438\u9644\u7684\u9996\u6b3e\u78b3\u5206\u5b50\u7b5b\u95ee\u4e16\uff01"},"content":{"rendered":"

\u6c2a\u6c14\uff08Kr\uff09\u548c\u6c19\u6c14\uff08Xe\uff09\u662f\u4e24\u79cd\u91cd\u8981\u7684\u7a00\u6709\u6c14\u4f53\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7167\u660e\u3001\u533b\u7597\u6210\u50cf\u3001\u822a\u7a7a\u822a\u5929\u548c\u6838\u5de5\u4e1a\u7b49\u9886\u57df\u3002\u5c24\u5176\u5728\u6838\u5de5\u4e1a\u4e2d\uff0c\u6c2a\u6c14\u7684\u653e\u5c04\u6027\u540c\u4f4d\u7d20\uff08\u598285Kr\uff09\u662f\u6838\u5e9f\u6599\u4e2d\u9700\u91cd\u70b9\u7ba1\u7406\u7684\u7269\u8d28\u4e4b\u4e00\u3002\u5c3d\u7ba1Kr\u548cXe\u7528\u9014\u5e7f\u6cdb\uff0c\u4f46\u5b83\u4eec\u7684\u5de5\u4e1a\u5206\u79bb\u5374\u9762\u4e34\u6781\u5927\u7684\u6280\u672f\u6311\u6218\u3002Kr\u548cXe\u5728\u7269\u7406\u5316\u5b66\u6027\u8d28\u4e0a\u7684\u9ad8\u5ea6\u76f8\u4f3c\u6027\uff08\u5982\u6cb8\u70b9\u63a5\u8fd1\uff0c\u4ec5\u76f8\u5dee10\u00b0C\uff09\u5bfc\u81f4\u4f20\u7edf\u5206\u79bb\u6280\u672f\u5982\u6df1\u51b7\u84b8\u998f\u9700\u8981\u6781\u4f4e\u7684\u6e29\u5ea6\uff08\u7ea6-100\u00b0C\uff09\u548c\u9ad8\u80fd\u8017\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u65b9\u6cd5\u901a\u5e38\u66f4\u503e\u5411\u4e8e\u4f18\u5148\u5206\u79bbXe\u800c\u5ffd\u7565Kr\uff0c\u9020\u6210\u8d44\u6e90\u6d6a\u8d39\u3002\u800c\u4f18\u5148\u5438\u9644Kr\u7684\u5206\u79bb\u7b56\u7565\u4e0d\u4ec5\u53ef\u4ee5\u6709\u6548\u5206\u79bb\u4e24\u79cd\u6c14\u4f53\uff0c\u8fd8\u80fd\u76f4\u63a5\u83b7\u5f97\u9ad8\u7eafXe\uff0c\u7279\u522b\u9002\u7528\u4e8e\u6838\u5e9f\u6599\u5904\u7406\u4e2d85Kr\u7684\u9ad8\u6548\u56de\u6536\u3002<\/p>\n

\n \u4e3a\u4e86\u5e94\u5bf9\u4e0a\u8ff0\u6311\u6218\uff0c\u6d59\u6c5f\u5927\u5b66\u9c8d\u5b97\u5fc5\u6559\u6388\u56e2\u961f\u91c7\u7528\u521b\u65b0\u601d\u8def\uff0c\u5f00\u53d1\u4e86\u9996\u6b3e\u5ba4\u6e29\u4e0b\u5b9e\u73b0\u6c2a\u6c14\u9009\u62e9\u6027\u5438\u9644\u7684\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u3002\u8fd9\u4e00\u7a81\u7834\u6027\u6210\u679c\u4e0d\u4ec5\u4e3aKr\/Xe\u5206\u79bb\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4e5f\u4e3a\u9ad8\u6548\u5206\u79bb\u6280\u672f\u5f00\u8f9f\u4e86\u65b0\u65b9\u5411\u3002\u76f8\u5173\u5de5\u4f5c\u4ee5\u201cThe First Kr\u2010Selective Carbon Molecular Sieve for Inverse Adsorption of Krypton Over Xenon at Ambient Temperature\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u7a81\u7834\u4f20\u7edf\uff1a\u5b54\u5f84\u7cbe\u51c6\u8c03\u63a7\u5b9e\u73b0\u5ba4\u6e29\u6c2a\u6c14\u9009\u62e9\u6027\u5438\u9644<\/p>\n

\n \u56e2\u961f\u91c7\u7528\u4ee5\u8517\u7cd6\u4e3a\u539f\u6599\u7684\u6c34\u70ed\u78b3\u5316\u6280\u672f\uff0c\u8bbe\u8ba1\u5e76\u4f18\u5316\u4e86\u7cfb\u5217\u8d85\u5fae\u5b54\u78b3\u5206\u5b50\u7b5b\u3002\u57fa\u4e8e\u7cbe\u51c6\u70ed\u89e3\u7b56\u7565\u5bf9\u5bcc\u6c27\u524d\u9a71\u4f53\u8131\u6c27\u53cd\u5e94\u7a0b\u5ea6\u7cbe\u51c6\u8c03\u63a7\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u5b54\u5f84\u5728\u4e9a\u57c3\u5c3a\u5ea6\u5185\u7cbe\u51c6\u8c03\u63a7\uff0c\u5e76\u5f97\u5230\u4e86\u5b54\u5f84\u7ea6\u4e3a4.0 \u00c5\u7684\u78b3\u6846\u67b6\u2014\u2014\u6070\u597d\u4f4d\u4e8e\u6c2a\u6c14\u548c\u6c19\u6c14\u7684\u5206\u5b50\u52a8\u529b\u5b66\u76f4\u5f84\u4e4b\u95f4\u3002\u6709\u671b\u5b9e\u73b0Kr\/Xe\u5206\u5b50\u7b5b\u5206\u7684\u540c\u65f6\uff0c\u4e3a\u6838\u5e9f\u6599\u5904\u7406\u4e2d\u7684\u6c2a\u6c14\u56de\u6536\u63d0\u4f9b\u4e86\u9ad8\u6548\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\"\"<\/p>\n

\u56fe1. \u78b3\u5206\u5b50\u7b5b\u5408\u6210\u53ca\u70ed\u89e3\u8c03\u63a7\u5b9e\u73b0 Kr\/Xe\u7b5b\u5206\u5206\u79bb\u793a\u610f\u56fe<\/p>\n

\n \u7ed3\u6784\u8868\u5f81\uff1a\u70ed\u9a71\u52a8\u5b54\u5f84\u8c03\u63a7\u673a\u5236\u63a2\u7a76<\/p>\n

\n \u901a\u8fc7\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u89c2\u5bdf\uff0c\u8bc1\u5b9e\u5236\u5907\u7684\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u5177\u6709\u5747\u4e00\u7684\u7c92\u5f84\u5206\u5e03\uff0c\u8fd9\u79cd\u7279\u6027\u6709\u52a9\u4e8e\u5176\u4f5c\u4e3a\u56fa\u5b9a\u5e8a\u586b\u6599\u7684\u5e94\u7528\u3002\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u5206\u6790\u663e\u793a\uff0c\u6750\u6599\u4e2d\u7684\u90e8\u5206\u65e0\u5b9a\u5f62\u7ed3\u6784\u5df2\u8f6c\u53d8\u4e3a\u77f3\u58a8\u5fae\u6676\u7ed3\u6784\uff0c\u8fd9\u4e00\u7ed3\u679c\u4e0eX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u56fe\u8c31\u548c\u62c9\u66fc\u5149\u8c31\u7684\u5206\u6790\u4e00\u81f4\uff0c\u5747\u8868\u660e\u6750\u6599\u5728\u70ed\u89e3\u6e29\u5ea6\u4e0b\u53d1\u751f\u4e86\u90e8\u5206\u77f3\u58a8\u5316\u3002\u901a\u8fc7CO2\u5728195 K\u4e0b\u7684\u5438\u9644\u6d4b\u8bd5\uff0c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u78b3\u5206\u5b50\u7b5b\u53d1\u8fbe\u7684\u5b54\u9699\u7387\uff0c\u4e3a\u6c14\u4f53\u7684\u9ad8\u6548\u5438\u9644\u5206\u79bb\u63d0\u4f9b\u4e86\u6709\u529b\u652f\u6301\u3002<\/p>\n

\"\"<\/p>\n

\u56fe2. (a) \u6c34\u70ed\u78b3\u5316\u7269\u548c (b, c) C-Suc-750 \u7684SEM\u56fe\uff1b(d) \u6c34\u70ed\u78b3\u5316\u7269\u548c (e, f) C-Suc-750 \u7684TEM\u56fe\uff1b(g) \u6c34\u70ed\u78b3\u5316\u7269\u548c (h) C-Suc-750 \u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b(i) PXRD\u56fe\u8c31\uff0c(j) \u62c9\u66fc\u5149\u8c31\uff0c(k) \u4e0d\u540c\u70ed\u89e3\u6e29\u5ea6\u4e0b\u78b3\u5206\u5b50\u7b5b\u5728195 K\u7684CO2\u5438\u9644\u7b49\u6e29\u7ebf<\/p>\n

\n \u7531\u4e8e\u78b3\u5206\u5b50\u7b5b\u5177\u6709\u590d\u6742\u7684\u5b54\u9053\u7ed3\u6784\uff0cN2\u548cAr\u5728\u4e34\u754c\u6e29\u5ea6\u4e0b\u6269\u6563\u901f\u7387\u8f83\u4f4e\uff0c\u56e0\u6b64\u96be\u4ee5\u51c6\u786e\u63cf\u8ff0\u6750\u6599\u7684\u5b54\u9699\u7279\u5f81\u3002\u5373\u4f7f\u662f\u52a8\u529b\u5b66\u76f4\u5f84\u66f4\u5c0f\u7684CO2\u5206\u5b50\uff0c\u4e5f\u96be\u4ee5\u7cbe\u786e\u8868\u5f81\u6750\u6599\u7684\u8d85\u5fae\u5b54\u90e8\u5206\u3002\u4e3a\u6b64\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u201c\u5206\u5b50\u622a\u65ad\u6cd5\u201d\u8868\u5f81\u6750\u6599\u5b54\u5f84\u7684\u7b56\u7565\uff08\u56fe3a-b\uff09\uff0c\u5373\u91c7\u7528\u5177\u6709\u4e0d\u540c\u5c3a\u5bf8\u5927\u5c0f\u7684\u6c14\u4f53\u5206\u5b50\u4f5c\u4e3a\u63a2\u9488\uff0c\u6d4b\u8bd5\u4e0d\u540c\u6e29\u5ea6\u6761\u4ef6\u4e0b\u5236\u5907\u7684\u78b3\u5206\u5b50\u7b5b\u5bf9\u5176\u7684\u5b9e\u9645\u5438\u9644\u60c5\u51b5\uff0c\u4ee5\u6b64\u786e\u5b9a\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u7684\u201c\u6709\u6548\u5fae\u5b54\u5b54\u5f84\u201d\u3002\u6b64\u65b9\u6cd5\u786e\u5b9a\u7684\u5fae\u5b54\u5b54\u5f84\u5bf9\u4e8e\u5b9e\u9645\u6c14\u4f53\u5438\u9644\u5206\u79bb\u7684\u5e94\u7528\u66f4\u5177\u4ef7\u503c\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63a2\u7a76\u6750\u6599\u5b54\u5f84\u53d8\u5316\u4e0e\u70ed\u89e3\u7119\u70e7\u6e29\u5ea6\u95f4\u7684\u89c4\u5f8b\uff0c\u4f5c\u8005\u901a\u8fc7FT-IR\u4ee5\u53caTPD-MS\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u5b9e\u4e86\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u4e3b\u8981\u662f\u524d\u9a71\u4f53\u4e2d\u542b\u6c27\u5b98\u80fd\u56e2\u7684\u8131\u6c27\u53cd\u5e94\u3002\u968f\u7740\u70ed\u89e3\u7119\u70e7\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u7684\u5b54\u5f84\u5448\u73b0\u5148\u589e\u5927\u540e\u51cf\u5c0f\u7684\u8d8b\u52bf\u3002\u524d\u671f\u5b54\u5f84\u7684\u589e\u5927\u4e3b\u8981\u7531\u4e8eCO\u3001CO2\u548cH2O\u7b49\u5c0f\u5206\u5b50\u4ece\u6750\u6599\u4e2d\u9038\u51fa\uff0c\u800c\u540e\u671f\u968f\u7740\u6e29\u5ea6\u8fdb\u4e00\u6b65\u5347\u9ad8\uff0cH2\u5c0f\u5206\u5b50\u7684\u9038\u51fa\u4f7f\u6750\u6599\u7ed3\u6784\u53d8\u5f97\u66f4\u52a0\u81f4\u5bc6\uff0c\u5bfc\u81f4\u5b54\u5f84\u51cf\u5c0f\u3002\u8fd9\u4e00\u89c4\u5f8b\u4e3a\u78b3\u5206\u5b50\u7b5b\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5236\u5907\u63d0\u4f9b\u4e86\u91cd\u8981\u53c2\u8003\u3002\u6b64\u5916\uff0c\u6750\u6599\u4e2d\u6b8b\u7559\u7684\u7a33\u5b9a\u542b\u6c27\u5b98\u80fd\u56e2\u4e3a\u6c14\u4f53\u5206\u5b50\u63d0\u4f9b\u4e86\u6781\u6027\u5438\u9644\u4f4d\u70b9\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3. (a, b) \u201c\u5206\u5b50\u622a\u65ad\u201d\u6cd5\u793a\u610f\u56fe\uff1b(c) \u4e0d\u540c\u6e29\u5ea6\u4e0b\u6c34\u70ed\u78b3\u5316\u7269\u548c\u78b3\u5206\u5b50\u7b5b\u7684FT-IR\u5149\u8c31\uff1b(d) \u6c34\u70ed\u78b3\u5316\u7269\u5728TPD-MS\u5206\u6790\u4e2d\u7684\u6c14\u4f53\u91ca\u653e\u66f2\u7ebf\uff1b(e, g) \u6c34\u70ed\u78b3\u5316\u7269\u548c (f, h) C-Suc-750 \u7684CO\u548cCO2\u91ca\u653e\u66f2\u7ebf<\/p>\n

\u6027\u80fd\u9a8c\u8bc1\uff1a\u5353\u8d8a\u7684\u5438\u9644\u5206\u79bb\u80fd\u529b\u4e0e\u6297\u8f90\u5c04\u7a33\u5b9a\u6027<\/p>\n

\n \u901a\u8fc7\u9759\u6001\u5438\u9644\u6d4b\u8bd5\uff0c\u8bc1\u5b9e\u4e86\u4f18\u9009\u7684\u78b3\u5206\u5b50\u7b5b\u6750\u6599\uff08C-Suc-750\uff09\u53ef\u4ee5\u57fa\u4e8e\u5c3a\u5bf8\u5dee\u5f02\u5b9e\u73b0Kr\/Xe\u5728\u5ba4\u6e29\u4e0b\u7684\u5206\u5b50\u7b5b\u5206\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8fd9\u662f\u9996\u4f8b\u5728\u5ba4\u6e29\u4e0b\u4f18\u5148\u5438\u9644Kr\u7684\u5438\u9644\u5242\u6750\u6599\u3002\u5728298 K\u3001100 kPa\u4e0b\uff0c\u6750\u6599\u5bf9Kr\/Xe\u7684\u5438\u9644\u91cf\u6bd4\u503c\u9ad8\u8fbe39.3\uff0c\u5728Kr\/Xe\u5206\u79bb\u9886\u57df\u6811\u7acb\u4e86\u5168\u65b0\u7684\u6807\u6746\u3002\u540c\u65f6\uff0c\u5bf9\u4e8e\u5b9e\u9645\u6838\u5e9f\u6599\u5c3e\u6c14\u4e2d\u7684\u5404\u79cd\u6c14\u4f53\uff0c\u6750\u6599\u4e5f\u53ef\u4ee5\u5b9e\u73b0\u5bf9Kr\u7684\u4f18\u5148\u5438\u9644\u3002\u56fa\u5b9a\u5e8a\u7a7f\u900f\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u6750\u6599\u4f18\u5f02\u7684Kr\/Xe\u5206\u79bb\u4ee5\u53ca\u5bf9\u6838\u5e9f\u6599\u5c3e\u6c14\u4e2dKr\u7684\u7279\u5f02\u6027\u6355\u83b7\u7684\u4f18\u5f02\u6027\u80fd\u3002\u6700\u4e3a\u91cd\u8981\u7684\u662f\uff0c\u6750\u6599\u5177\u6709\u8fdc\u8d85\u4e8e\u5e38\u89c4MOFs\u6750\u6599\u7684\u4f18\u5f02\u6297\u8f90\u5c04\u7a33\u5b9a\u6027\uff0c\u5373\u4f7f\u5728\u03b3\u5c04\u7ebf\u9ad8\u5242\u91cf\u8f90\u5c04\u4e0b\uff0cC-Suc-750\u4ecd\u80fd\u4fdd\u6301\u4f18\u5f02\u6027\u80fd\uff0c\u663e\u73b0\u51fa\u957f\u671f\u5de5\u4e1a\u5e94\u7528\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4. (a) C-Suc-750\u5728298 K\u4e0b\u5bf9Xe\u3001Kr\u3001N2\u3001O2\u548cAr\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1b(b) 298 K\u30011.0 bar\u6761\u4ef6\u4e0b\u4e0d\u540c\u5438\u9644\u5242\u7684Xe\/Kr\u6216Kr\/Xe\u5438\u9644\u6bd4\u5bf9\u6bd4\uff1b(c) Xe\/Kr\uff0820\/80\uff09\u6df7\u5408\u6c14\u548c (e) \u6a21\u62df\u6838\u5e9f\u6599\u6c14\u5728298 K\u30011.0 bar\u4e0b\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(d) C-Suc-750\u5728423 K\u30011.0 bar\u6761\u4ef6\u4e0b\u4ee55 mL\/min He\u6c14\u8131\u9644\u7684Xe\u548cKr\u66f2\u7ebf\uff1b(f, h) C-Suc-750\u7ecf\u03b3\u5c04\u7ebf\u8f90\u7167\u524d\u540e\u5728298 K\u4e0b\u7684Xe\u3001Kr\u5438\u9644\u7b49\u6e29\u7ebf\u53ca195 K\u4e0b\u7684CO2\u5438\u9644\u7b49\u6e29\u7ebf\uff1b(g) Xe\/Kr\uff0820\/80, v\/v\uff09\u5728298 K\u30011.0 bar\u4e0b\u7684\u5faa\u73af\u7a81\u7834\u5b9e\u9a8c\u66f2\u7ebf<\/p>\n

\n \u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff1a\u78b3\u5206\u5b50\u7b5b\u5b9e\u73b0Kr\/Xe\u7b5b\u5206\u5206\u79bb\u7684\u52a8\u6001\u673a\u5236<\/p>\n

\n \u7814\u7a76\u56e2\u961f\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\uff08MD\uff09\u6a21\u62df\uff0c\u76f4\u89c2\u5c55\u793a\u4e86C-Suc-750\u78b3\u5206\u5b50\u7b5b\u5728Kr\/Xe\u5206\u79bb\u4e2d\u7684\u72ec\u7279\u7b5b\u5206\u673a\u5236\u3002\u5728298 K\u6761\u4ef6\u4e0b\uff0cKr\/Xe\uff0880\/20, v\/v\uff09\u6df7\u5408\u6c14\u4f53\u9996\u5148\u88ab\u7f6e\u4e8e\u8fdb\u6599\u4ed3\u5185\uff0c\u968f\u7740\u65f6\u95f4\u63a8\u8fdb\uff0cKr\u5206\u5b50\u80fd\u591f\u5feb\u901f\u901a\u8fc7\u5b54\u5f84\u4e3a4.0 \u00c5\u7684\u72ed\u7a84\u5b54\u9053\uff0c\u800c\u4f53\u79ef\u66f4\u5927\u7684Xe\u5206\u5b50\u96be\u4ee5\u8fdb\u5165\u5b54\u9053\u30020-10000 ps\u65f6\u95f4\u8303\u56f4\u5185Kr\u5206\u5b50\u5df2\u5f00\u59cb\u663e\u8457\u6269\u6563\uff0c\u800c\u5728\u5ef6\u957f\u81f3100000 ps\u540e\uff0c\u51e0\u4e4e\u6240\u6709Kr\u5206\u5b50\u5747\u7a7f\u8fc7\u5b54\u9053\uff0c\u800cXe\u5206\u5b50\u4f9d\u7136\u65e0\u6cd5\u901a\u8fc7\u3002\u8fd9\u8868\u660e\uff0cC-Suc-750\u7684\u72ed\u7a84\u5b54\u9053\u5728Kr\u4e0eXe\u7684\u5206\u79bb\u4e2d\u8d77\u5230\u5173\u952e\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u5206\u5b50\u6a21\u62df\u5feb\u7167\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86\u6c14\u4f53\u6269\u6563\u7684\u52a8\u6001\u8fc7\u7a0b\uff0c\u76f4\u89c2\u5730\u5448\u73b0\u4e86\u5b54\u9053\u5185Kr\u5206\u5b50\u9010\u6b65\u6269\u6563\u7684\u884c\u4e3a\u3002\u901a\u8fc7\u8fd9\u4e9b\u6a21\u62df\u6570\u636e\uff0c\u660e\u786e\u4e86\u5c3a\u5bf8\u7b5b\u5206\u4e0e\u5b54\u5f84\u8c03\u63a7\u5bf9Kr\/Xe\u5206\u79bb\u6027\u80fd\u7684\u91cd\u8981\u8d21\u732e\uff0c\u4e3a\u9ad8\u6548\u7a00\u6709\u6c14\u4f53\u5206\u79bb\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u7406\u8bba\u652f\u6301\u3002<\/p>\n

\"\"<\/p>\n

\n \u56fe5. (a) 0-10000 ps\u548c (b) 0-100000 ps\u5185\u901a\u8fc7\u5b54\u9053\u7684\u6c14\u4f53\u5206\u5b50\u6570\u91cf\u53d8\u5316\uff1b(c) \u4e0d\u540c\u65f6\u95f4\u4e0b\u5165\u53e3\u6c14\u4f53\u4e2d\u5269\u4f59\u5206\u5b50\u6570\u91cf\uff1b(d-f) Kr\/Xe\uff0880\/20, v\/v\uff09\u6df7\u5408\u6c14\u5728298 K\u4e0b\u7684\u78b3\u5206\u5b50\u7b5b\u6a21\u578b\u5438\u9644\u8fc7\u7a0b\u7684MD\u6a21\u62df\u5feb\u7167\uff0c\u5206\u522b\u4e3a1 ps\u300110000 ps\u548c50000 ps\u65f6\u7684\u60c5\u51b5\u3002\u521d\u59cb\u65f6\u6df7\u5408\u6c14\u5728\u8fdb\u6599\u4ed3\u5185\uff0c\u968f\u540e\u6c14\u4f53\u5206\u5b50\u6269\u6563\u5230\u78b3\u5c42\u5b54\u9053\u4e2d\u3002\u7070\u8272\u3001\u7ea2\u8272\u3001\u767d\u8272\u3001\u9752\u8272\u548c\u7d2b\u8272\u7403\u5206\u522b\u8868\u793aC\u3001O\u3001H\u3001Kr\u548cXe\u5206\u5b50
\n \u6b64\u6b21\u7814\u7a76\u4e0d\u4f46\u63d0\u51fa\u4e86\u4e00\u79cd\u524d\u6240\u672a\u6709\u7684\u6c2a\u6c14\u4f18\u5148\u5206\u79bb\u7b56\u7565\uff0c\u8fd8\u4e3a\u7cbe\u5bc6\u5206\u5b50\u7b5b\u6750\u6599\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002C-Suc-750\u5c55\u73b0\u51fa\u7684\u9ad8\u9009\u62e9\u6027\u3001\u53ef\u91cd\u590d\u6027\u53ca\u5de5\u4e1a\u7a33\u5b9a\u6027\uff0c\u6807\u5fd7\u7740\u5438\u9644\u5206\u79bb\u6280\u672f\u7684\u53c8\u4e00\u91cc\u7a0b\u7891\u3002\u672a\u6765\uff0c\u8fd9\u4e00\u6750\u6599\u5728\u6838\u5e9f\u6599\u5904\u7406\u3001\u7a00\u6709\u6c14\u4f53\u63d0\u53d6\u7b49\u9886\u57df\u5c06\u5927\u6709\u53ef\u4e3a\uff0c\u4e3a\u7eff\u8272\u5316\u5de5\u548c\u8d44\u6e90\u9ad8\u6548\u5229\u7528\u6ce8\u5165\u65b0\u7684\u52a8\u529b\u3002
\n \u2003
\n \u4f5c\u8005\u7b80\u4ecb<\/p>\n

\n \u7b2c\u4e00\u4f5c\u8005\uff1a\u9648\u5bcc\u5f3a\uff0c\u535a\u58eb\uff0c2022\u5e7412\u6708\u4e8e\u6d59\u6c5f\u5927\u5b66\u83b7\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6d59\u6c5f\u5927\u5b66\u4efb\u5176\u9f99\u9662\u58eb\u548c\u9c8d\u5b97\u5fc5\u6559\u6388\u30022023\u5e742\u6708\u81f3\u4eca\u4e8e\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c\u5e08\u4eceSusumu Kitagawa\uff08\u5317\u5ddd\u9032\uff09\u9662\u58eb\uff0c\u5e76\u5165\u9009\u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\uff08JSPS\uff09\u7814\u7a76\u5458\u3002\u4e3b\u8981\u4ece\u4e8b\u591a\u5b54\u78b3\u5438\u9644\u5242\u53ca\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOFs\uff09\u7684\u7ed3\u6784\u8c03\u63a7\u4ee5\u53ca\u6c14\u4f53\u5438\u9644\u5206\u79bb\u6027\u80fd\u7814\u7a76\u3002\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u5728J. Am. Chem. Soc., Angew. Chem. Int. Ed., Adv. Mater., ACS Cent. Sci., Small, Engineering\u7b49\u9ad8\u6c34\u5e73\u671f\u520a\u53d1\u8868SCI\u8bba\u658716\u7bc7\uff0c\u5e76\u7533\u8bf7\u56fd\u5185\u56fd\u9645\u53d1\u660e\u4e13\u522912\u9879\uff0c\u5df2\u6388\u67438\u9879\u3002\u83b7\u5f97\u6d59\u6c5f\u7701\u4f18\u79c0\u535a\u58eb\u8bba\u6587\u3001\u6d59\u6c5f\u5927\u5b66\u4f18\u79c0\u535a\u58eb\u5b66\u4f4d\u8bba\u6587\u3001ACS Excellent Postdoctor in the Leadership of Promoting Mentoring\u7b49\u8363\u8a89\u3002\u62c5\u4efbChem. Eng. J.\u4ee5\u53caSep. Purif. Technol.\u7b49\u56fd\u9645\u671f\u520a\u72ec\u7acb\u5ba1\u7a3f\u4eba\u3002<\/p>\n

\n \u901a\u8baf\u4f5c\u8005\uff1a\u9c8d\u5b97\u5fc5\uff0c\u6d59\u6c5f\u5927\u5b66\u6c42\u662f\u7279\u8058\u6559\u6388\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005(2022\u5e74)\u3001\u56fd\u5bb6\u4f18\u79c0\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005(2017\u5e74)\u3001\u6d59\u6c5f\u7701\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005(2016\u5e74)\uff0c\u6d59\u6c5f\u7701\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u9752\u5e74\u62d4\u5c16\u4eba\u624d(2019\u5e74)\u3002\u4e3b\u8981\u4ece\u4e8b\u5316\u5de5\u5206\u79bb\u6280\u672f\u3001\u591a\u5b54\u5438\u9644\u5206\u79bb\u6750\u6599\u53ca\u9ad8\u7eaf\u5316\u5b66\u54c1\u5206\u79bb\u5236\u5907\u7814\u7a76\uff0c\u5728Science\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001Adv. Mater.\u3001Nat. Commun.\u3001Sci. Adv.\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587250\u4f59\u7bc7\uff0c\u83b7\u6388\u6743\u53d1\u660e\u4e13\u522960\u4f59\u4ef6\u3002\u4f5c\u4e3a\u4e3b\u8981\u5b8c\u6210\u4eba\u83b7\u5f97\u56fd\u5bb6\u6280\u672f\u53d1\u660e\u5956\u4e8c\u7b49\u5956\u3001\u6d59\u6c5f\u7701\u79d1\u6280\u8fdb\u6b65\u4e00\u7b49\u5956\u3001\u9752\u5c71\u79d1\u6280\u5956\u3001\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u5b66\u6280\u672f\u521b\u65b0\u5956\u7b49\u8363\u8a89\u3002\u73b0\u4efb\u751f\u7269\u8d28\u5316\u5de5\u6559\u80b2\u90e8\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u526f\u4e3b\u4efb\u3001\u6d59\u6c5f\u5927\u5b66\u8862\u5dde\u7814\u7a76\u9662\u7535\u5b50\u5316\u5b66\u54c1\u7814\u7a76\u6240\u6240\u957f\u3002\u517c\u4efb\u4e2d\u56fd\u5316\u5de5\u5b66\u4f1a\u8d85\u4e34\u754c\u6d41\u4f53\u4e13\u59d4\u4f1a\u79d8\u4e66\u957f\u3001\u300a\u5316\u5de5\u8fdb\u5c55\u300b\u671f\u520a\u7f16\u59d4\u3001\u56fd\u9645\u671f\u520a\u300aSeparation and Purification Technology\u300b\u526f\u4e3b\u7f16\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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