{"id":264148,"date":"2024-12-25T10:27:40","date_gmt":"2024-12-25T02:27:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=264148"},"modified":"2024-12-25T10:27:40","modified_gmt":"2024-12-25T02:27:40","slug":"%e5%85%b0%e5%a4%a7%e5%91%a8%e9%87%91%e5%85%83%e6%95%99%e6%8e%88-acs-nano%ef%bc%9a%e4%b8%89%e5%90%88%e4%b8%80%e5%a4%b9%e5%b1%82%e8%ae%be%e8%ae%a1%e6%89%93%e7%a0%b4%e5%a4%9a%e9%87%8d%e9%99%90%e5%88%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=264148","title":{"rendered":"\u5170\u5927\u5468\u91d1\u5143\u6559\u6388 ACS Nano\uff1a\u4e09\u5408\u4e00\u5939\u5c42\u8bbe\u8ba1\u6253\u7834\u591a\u91cd\u9650\u5236\uff0c\u5b9e\u73b0\u9502\u786b\u7535\u6c60\u957f\u6548\u5faa\u73af\u4e0e\u9ad8\u6027\u80fd\u201d"},"content":{"rendered":"

\u3010\u6587\u7ae0\u4fe1\u606f\u3011
\n \u901a\u8fc7\u5c40\u90e8\u7535\u573a\u8c03\u63a7\u7535\u50ac\u5316\u5242\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u548c\u9502\u679d\u6676\u751f\u957f\u8bbe\u8ba1\u8d85\u9ad8\u7a33\u5b9a\u6027\u9502\u786b\u7535\u6c60
\n \u7b2c\u4e00\u4f5c\u8005\uff1a\u5b59\u56fd\u6587\uff0c\u9773\u68a6\u9759
\n \u901a\u8baf\u4f5c\u8005\uff1a\u5b59\u5e9a\u5fd7 *\uff0c\u6f58\u5b5d\u519b*\uff0cAndreu Cabot*\uff0c\u5468\u91d1\u5143*
\n \u5355\u4f4d\uff1a\u5170\u5dde\u5927\u5b66<\/p>\n

\"\"
\n \u3010\u7814\u7a76\u80cc\u666f\u3011<\/p>\n

\n \u9502\u786b\u7535\u6c60\uff08LSBs\uff09\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\uff0c\u56e0\u5176\u7406\u8bba\u5bb9\u91cf\u9ad8\u3001\u6210\u672c\u4f4e\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u591a\u786b\u5316\u7269\u7a7f\u68ad\u6548\u5e94\uff08polysulfide shuttling\uff09\u548c\u9502\u679d\u6676\u751f\u957f\uff08dendrite growth\uff09\u662f\u4e24\u5927\u4e3b\u8981\u6311\u6218\uff0c\u6781\u5927\u5730\u9650\u5236\u4e86\u5176\u7a33\u5b9a\u6027\u4e0e\u5b89\u5168\u6027\u3002<\/p>\n

\n \u3010\u6587\u7ae0\u7b80\u4ecb\u3011<\/p>\n

\n \u8fd1\u65e5\uff0c\u5170\u5dde\u5927\u5b66\u5468\u91d1\u5143\u56e2\u961f\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u79cd\u4e09\u5408\u4e00\u5939\u5c42\u8bbe\u8ba1\u7b56\u7565\u4ee5\u5b9e\u73b0\u591a\u786b\u5316\u7269\u7684\u7a7f\u68ad\u6291\u5236\u3001Li\u2013S\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u5316\u4ee5\u53ca\u9502\u79bb\u5b50\u7684\u65e0\u679d\u6676\u6c89\u79ef\u3002\u5177\u4f53\u800c\u8a00\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u4e00\u79cd\u5305\u542b\u6781\u5316 BaTiO3 (PBTO) \u9897\u7c92\u5e76\u6d82\u6709\u4e00\u5c42 MoS2 (PBTO@PNF-MoS2) \u7684\u805a\u4e19\u70ef\u8148\u7eb3\u7c73\u7ea4\u7ef4 (PNF) \u5939\u5c42\u3002\u7406\u8bba\u8ba1\u7b97\u548c\u5b9e\u9a8c\u5de5\u4f5c\u8868\u660e\uff0c\u5c40\u57df\u7535\u573a\u4fc3\u8fdb\u4e86 Li+ \u79bb\u5b50\u7684\u5feb\u901f\u5747\u5300\u4f20\u8f93\uff0c\u6291\u5236\u4e86\u679d\u6676\u751f\u957f\u3002\u6b64\u5916\uff0c\u4ea7\u751f\u7684\u7535\u573a\u4fc3\u8fdb\u4e86 MoS2 \u5bf9 Li-S \u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u7279\u522b\u662f\u901a\u8fc7\u964d\u4f4e\u56fa\u6db2\u548c\u56fa\u56fa\u8f6c\u5316\u7684\u53cd\u5e94\u52bf\u5792\u3002\u7ed3\u679c\u663e\u793a\uff0c\u5bf9\u79f0 Li\/\/PBTO@PNF\/PP\/PBTO@PNF\/\/Li \u7535\u6c60\u5728 1200 \u5c0f\u65f6\u5185\u8868\u73b0\u51fa\u5353\u8d8a\u7684\u7a33\u5b9a\u6027\uff0c\u800c\u91c7\u7528 PP\/PBTO@PNF-MoS2 \u590d\u5408\u9694\u819c\u7684 LSB \u5728 2C \u4e0b\u7ecf\u8fc7 4000 \u6b21\u5faa\u73af\u540e\u4ecd\u80fd\u4fdd\u6301 318.3 mA h g\u20131 \u7684\u6bd4\u5bb9\u91cf\uff0c\u5bb9\u91cf\u8870\u51cf\u7387\u6781\u4f4e\uff0c\u4ec5\u4e3a 0.015%\u3002\u6b64\u5916\uff0cPBTO@PNF \u9694\u819c\u8fd8\u589e\u5f3a\u4e86\u590d\u5408\u9694\u819c\u7684\u673a\u68b0\u67d4\u97e7\u6027\u548c\u70ed\u7a33\u5b9a\u6027\u3002\u3002\u8be5\u6587\u7ae0\u4ee5\u9898\u4e3a\u201cDesign of an Ultra-Highly Stable Lithium-Sulfur Battery by Regulating the Redox Activity of Electrocatalyst and the Growth of Lithium Dendrite through Localized Electric Field\u201d\u53d1\u8868\u5728\u56fd\u9645\u671f\u520aACS Nano\u4e0a\u3002<\/p>\n

\n \u3010\u672c\u6587\u8981\u70b9\u3011<\/p>\n

\n \u8981\u70b9\u4e00\uff1a\u4e09\u5408\u4e00\u5939\u5c42\u7684\u8bbe\u8ba1<\/p>\n

\n \u56fe\u4e00\u4e2d\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u5c40\u90e8\u7535\u573a\u7684\u5939\u5c42\u7b56\u7565\uff0c\u901a\u8fc7\u540c\u65f6\u6291\u5236\u591a\u786b\u5316\u7269\u7a7f\u68ad\u3001\u6fc0\u6d3bLi-S\u53cd\u5e94\u50ac\u5316\u6d3b\u6027\u548c\u9632\u6b62\u9502\u679d\u6676\u751f\u957f\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u9502\u786b\u7535\u6c60\u7684\u6574\u4f53\u6027\u80fd\u3002\u8be5\u7b56\u7565\u521b\u65b0\u6027\u5730\u91c7\u7528\u4e86\u805a\u4e19\u70ef\u8148\uff08PNF\uff09\u7eb3\u7c73\u7ea4\u7ef4\u548c\u6781\u5316BaTiO3\uff08PBTO\uff09\u9897\u7c92\u7684\u590d\u5408\u6750\u6599\uff0c\u5e76\u4e0eMoS2\u8fdb\u884c\u590d\u5408\uff0c\u5f62\u6210\u4e86\u4e00\u4e2a\u529f\u80fd\u5316\u7684\u5939\u5c42\uff08PBTO@PNF-MoS2\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\u4e2d\u4f5c\u8005\u5bf9PBTO@PNF-MoS2\u5939\u5c42\u505a\u4e86\u8be6\u7ec6\u7684\u5f62\u8c8c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u8fdb\u4e00\u6b65\uff0c\u4f5c\u8005\u901a\u8fc7XRD\uff0cP-E\u66f2\u7ebf\uff0cAFM\u4ee5\u53caKPFM\u5bf9PBTO\u7684\u7ed3\u6784\u505a\u4e86\u8fdb\u4e00\u6b65\u8868\u5f81\uff0c\u8bc1\u5b9e\u4e86\u94c1\u7535\u76f8BTO\u7684\u5b58\u5728\u3002<\/p>\n

\"\"<\/p>\n

\u8981\u70b9\u4e09. \u5b9e\u9a8c\u7ed3\u679c\u4e0e\u6027\u80fd\u8868\u73b0<\/p>\n

1.\u5939\u5c42\u4ea7\u751f\u7684\u5c40\u57df\u573a\u6709\u6548\u6291\u5236\u4e86\u591a\u786b\u5316\u9502\u7684\u7a7f\u68ad\u3002<\/p>\n

\"\"<\/p>\n

2.\u7ed3\u5408\u5b9e\u9a8c\u4e0e\u7406\u8bba\u8ba1\u7b97\uff0c\u53d1\u73b0\u5c40\u57df\u573a\u6709\u5229\u4e8eMoS2\u50ac\u5316\u6027\u80fd\u7684\u589e\u5f3a\uff0c\u50ac\u5316\u6fc0\u6d3bLi-S\u53cd\u5e94\uff1aMoS2\u6d82\u5c42\u63d0\u5347\u4e86\u5bf9Li-S\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5c24\u5176\u662f\u964d\u4f4e\u4e86\u56fa\u6db2\u8f6c\u6362\u548c\u56fa\u56fa\u8f6c\u6362\u7684\u53cd\u5e94\u969c\u788d\uff0c\u4ece\u800c\u589e\u5f3a\u4e86\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\n 3.\u9502\u79bb\u5b50\u8fd0\u8f93\u52a0\u901f\uff1a\u5c40\u90e8\u7535\u573a\u7684\u5b58\u5728\u4fc3\u8fdb\u4e86\u9502\u79bb\u5b50\u7684\u5feb\u901f\u4e14\u5747\u5300\u5730\u4f20\u8f93\uff0c\u6709\u6548\u6291\u5236\u4e86\u9502\u679d\u6676\u7684\u751f\u957f\uff0c\u540c\u65f6\uff0c\u5939\u5c42\u6291\u5236\u4e86\u56fa\u4f53Li2S\u5728\u9694\u819c\u4e0a\u7684\u6c89\u79ef\uff0c\u6709\u6548\u4fdd\u62a4\u4e86\u9694\u819c\u8868\u9762\u7684\u79bb\u5b50\u6269\u6563\u901a\u9053\u3002<\/p>\n

\"\"
\n \u8981\u70b9\u56db. \u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a<\/p>\n

\u8d85\u9ad8\u5faa\u73af\u5bff\u547d\uff1a\u914d\u5907\u8be5\u5206\u79bb\u819c\u7684\u9502\u786b\u7535\u6c60\uff0c\u57282C\u500d\u7387\u4e0b\u7ecf\u8fc74000\u6b21\u5faa\u73af\u540e\uff0c\u4ecd\u80fd\u7ef4\u6301318.3 mAh\/g\u7684\u6bd4\u5bb9\u91cf\uff0c\u4e14\u5bb9\u91cf\u8870\u51cf\u7387\u4ec5\u4e3a0.015%\u3002 \u673a\u68b0\u548c\u70ed\u7a33\u5b9a\u6027\uff1aPBTO@PNF\u819c\u4e0d\u4ec5\u63d0\u5347\u4e86\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8fd8\u663e\u8457\u589e\u5f3a\u4e86\u590d\u5408\u5206\u79bb\u819c\u7684\u673a\u68b0\u67d4\u97e7\u6027\u4e0e\u70ed\u7a33\u5b9a\u6027\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u7535\u6c60\u7684\u6574\u4f53\u53ef\u9760\u6027\u548c\u5b89\u5168\u6027\u3002<\/p>\n

\"\"<\/p>\n

\u524d\u77bb<\/p>\n

\n \u672c\u6587\u5c55\u793a\u7684\u7814\u7a76\u6210\u679c\u8868\u660e\uff0c\u901a\u8fc7\u521b\u65b0\u7684\u5206\u79bb\u819c\u8bbe\u8ba1\u548c\u5c40\u90e8\u7535\u573a\u8c03\u63a7\uff0c\u53ef\u4ee5\u6709\u6548\u89e3\u51b3\u9502\u786b\u7535\u6c60\u7684\u6838\u5fc3\u95ee\u9898\uff0c\u63d0\u5347\u5176\u7a33\u5b9a\u6027\u4e0e\u4f7f\u7528\u5bff\u547d\u3002\u8fd9\u4e0d\u4ec5\u4e3a\u9502\u786b\u7535\u6c60\u7684\u5546\u4e1a\u5316\u5e94\u7528\u94fa\u5e73\u9053\u8def\uff0c\u4e5f\u4e3a\u4e0b\u4e00\u4ee3\u7535\u6c60\u6280\u672f\u7684\u7a81\u7834\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\n \u3010\u6587\u7ae0\u94fe\u63a5\u3011
\n Guowen Sun, Mengjing Jin, Chao Yue Zhang, Dong Chen, Xi Yin Yang, Hong Ruo Ma, Yaxiong Zhang, Zhenxing Zhang, Gengzhi Sun, Xiaojun Pan, Andreu Cabot, and Jin Yuan Zhou, ACS Nano Article ASAP. DOI: 10.1021\/acsnano.4c12217<\/p>\n

\n \u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/p>\n

\u5468\u91d1\u5143\uff0c\u7537\uff0c\u6c49\u65cf\uff0c\u6e56\u5317\u9ec4\u5188\u4eba\u3002\u4e2d\u5171\u515a\u5458\uff0c\u535a\u58eb\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022002\u5e74\uff0c\u6bd5\u4e1a\u4e8e\u5170\u5dde\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\uff0c\u83b7\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff08\u7269\u7406\u5b66\uff09\uff0c\u5bfc\u5e08\u5f20\u798f\u7532\u6559\u6388\uff1b\u6bd5\u4e1a\u540e\u5728\u5170\u5dde\u533b\u5b66\u9662\u533b\u5b66\u5de5\u7a0b\u7cfb\uff082004\u5e74\u5e76\u5165\u5170\u5dde\u5927\u5b66\uff09\u4efb\u6559\u30022010\u5e74\uff0c\u6bd5\u4e1a\u4e8e\u5170\u5dde\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u9662\uff0c\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff08\u51dd\u805a\u6001\u7269\u7406\uff09\uff0c\u5bfc\u5e08\u8c22\u4e8c\u5e86\u6559\u6388\u30022010\u5e74-2012\u5e74\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u822a\u5929\u4e0e\u673a\u68b0\u5de5\u7a0b\u5b66\u9662\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08Lianxi Zheng\u6559\u6388\u30022016\u5e74\uff0c\u664b\u5347\u4e3a\u6559\u6388\u30022021\u5e74\uff0c\u589e\u9009\u4e3a\u6750\u6599\u4e0e\u5316\u5de5\u4e13\u4e1a\u5b66\u4f4d\u7814\u7a76\u751f\u6559\u80b2\u6307\u5bfc\u59d4\u5458\u4f1a\u59d4\u5458\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u4e3b\u6301\u548c\u53c2\u4e0e\u7701\u90e8\u7ea7\u9879\u76ee6\u9879\uff0c\u5df2\u5728Sci. Adv.\u3001J. Am. Chem. Soc.\u3001Adv. Mater.\u3001 Angew. Chem. Int. Edit.\u3001Adv. Funct. Mater.\u3001ACS Nano\u3001eScience\u3001Energy Storage Mater.\u3001Sensor Actuat. B-Chem.\u3001Appl. Phys. Lett.\u7b49\u56fd\u9645\u77e5\u540dSCI\u671f\u520a\u6742\u5fd7\u4e0a\u53d1\u8868\u4e86200\u4f59\u7bc7\u5b66\u672f\u8bba\u6587\uff0c\u603b\u5f15\u7528\u6b21\u6570\u4e3a9100\u4f59\u6b21\uff0cH-index\u4e3a55\uff08WOS\u7edf\u8ba1\uff0c2024.10.\uff09 \u4e3b\u8981\u7814\u7a76\u65b9\u5411\uff1a
\n 1\uff09\u534a\u5bfc\u4f53\u7eb3\u7c73\u6750\u6599\u7684\u5236\u5907\u53ca\u6c14\u654f\u6027\u80fd\u7814\u7a76
\n 2\uff09\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\u3001\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u7b49\u5fae\u7eb3\u7ed3\u6784\u5728\u50a8\u80fd\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u3002<\/p>\n

\n \u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/p>\n

\u5b59\u56fd\u6587\uff08\u5170\u5dde\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u6280\u672f\u5b66\u96622021\u7ea7\u535a\u58eb\uff09\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u80fd\u6e90\u50a8\u5b58\u4e0e\u8f6c\u6362\u3002\u4ee5\u7b2c\u4e00\u6216\u5171\u4e00\u4f5c\u8005\u5728ACS Nano\uff0cEnSM\uff0cCEJ\uff0cSmall\u7b49\u671f\u520a\u53d1\u8868\u8bba\u65877\u7bc7\uff0c\u5176\u4ed6\u4f5c\u8005\u53d1\u8868\u8bba\u658713\u7bc7\u3002\u4e3b\u6301\u7518\u8083\u7701\u201c\u521b\u65b0\u4e4b\u661f\u201d\u9879\u76ee\u4e00\u9879,\u4e2d\u592e\u9ad8\u6821\u57fa\u7840\u79d1\u7814\u4e1a\u52a1\u8d39\u4e00\u9879\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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