{"id":265062,"date":"2025-02-19T07:07:46","date_gmt":"2025-02-18T23:07:46","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=265062"},"modified":"2025-02-18T22:15:33","modified_gmt":"2025-02-18T14:15:33","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e6%9d%8e%e7%a6%8f%e5%86%9b%e6%95%99%e6%8e%88afm%ef%bc%9a%e8%a7%a3%e7%a0%81%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e9%ab%98%e6%af%94%e8%83%bd%e7%a3%b7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=265062","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u674e\u798f\u519b\u6559\u6388AFM\uff1a\u89e3\u7801\u94a0\u79bb\u5b50\u7535\u6c60\u9ad8\u6bd4\u80fd\u78f7\u9178\u76d0\u6b63\u6781\u53ca\u5176\u591a\u7535\u5b50\u53cd\u5e94\u673a\u5236"},"content":{"rendered":"<p><strong>\u4e00\u3001<\/strong><strong>\u00a0<\/strong><strong>\u3010\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u674e\u798f\u519b\u6559\u6388\u56e2\u961f\u5728Adv. Funct. Mater.\u4e0a\u53d1\u8868\u7efc\u8ff0\u8bba\u6587\uff0c\u805a\u7126\u94a0\u79bb\u5b50\u7535\u6c60\u9ad8\u6bd4\u80fd\u78f7\u9178\u76d0\u6b63\u6781\u53ca\u5176\u591a\u7535\u5b50\u53cd\u5e94\u673a\u5236\uff0c\u4ece\u57fa\u7840\u7269\u7406\u5316\u5b66\u5165\u624b\uff0c\u7ed3\u5408\u7814\u7a76\u73b0\u72b6\uff0c\u89e3\u7801\u4e86\u78f7\u9178\u76d0\u6b63\u6781\u591a\u7535\u5b50\u53cd\u5e94\u7684\u7535\u5316\u5b66\u8fc7\u7a0b\u53ca\u8377\u8d28\u4f20\u8f93\u89c4\u5f8b\uff0c\u4e3a\u9ad8\u6bd4\u80fd\u94a0\u79bb\u5b50\u7535\u6c60\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u6307\u5bfc\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u5f20\u7b11\u94f6\u535a\u58eb<\/p>\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u674e\u798f\u519b\u6559\u6388<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u4e8c\u3001\u3010\u5185\u5bb9\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>1\u3001\u524d\u8a00<\/p>\n<p>\u94a0\u79bb\u5b50\u7535\u6c60\uff08SIBs\uff09\u56e0\u94a0\u8d44\u6e90\u4e30\u5bcc\u3001\u6210\u672c\u4f4e\uff0c\u88ab\u89c6\u4e3a\u5927\u89c4\u6a21\u50a8\u80fd\u548c\u4f4e\u901f\u7535\u52a8\u8f66\u7684\u7406\u60f3\u5019\u9009\u3002\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u6750\u6599\uff08\u5982NaTMPO\u2084\u3001Na\u2083TM\u2082(PO\u2084)\u2083\u7b49\uff09\u56e0\u5176\u9ad8\u7535\u538b\u3001\u7ed3\u6784\u7a33\u5b9a\u6027\u548c\u5b89\u5168\u6027\u5907\u53d7\u5173\u6ce8\uff0c\u4f46\u5176\u5206\u5b50\u91cf\u8f83\u5927\u5bfc\u81f4\u7406\u8bba\u5bb9\u91cf\u53d7\u9650\uff0c\u80fd\u91cf\u5bc6\u5ea6\u4f4e\u4e8e\u5546\u4e1a\u5316\u9502\u79bb\u5b50\u7535\u6c60\uff08\u5982LiFePO\u2084\uff09\u3002\u901a\u8fc7\u6fc0\u6d3b<strong><b>\u591a\u7535\u5b50\u53cd\u5e94<\/b><\/strong>\uff08\u6bcf\u4e2a\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u8d21\u732e\u591a\u4e2a\u7535\u5b50\uff09\uff0c\u53ef\u7a81\u7834\u5bb9\u91cf\u9650\u5236\uff0c\u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\uff08&gt;450 Wh\/kg\uff09\u3002<\/p>\n<p><strong>\u00a0<img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265063\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-19.png\" alt=\"\" width=\"1207\" height=\"794\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-19.png 1207w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-19-300x197.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-19-768x505.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72471-19-1024x674.png 1024w\" sizes=\"(max-width: 1207px) 100vw, 1207px\" \/>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0 <\/strong><\/p>\n<p><strong>\u56fe1 \u00a0\u94a0\u79bb\u5b50\u7535\u6c60\u6210\u672c\u3001\u5143\u7d20\u4e30\u5ea6\u53ca\u6b63\u6781\u80fd\u91cf\u5bc6\u5ea6<\/strong><\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<ol start=\"2\">\n<li>2. \u78f7\u9178\u76d0\u6b63\u6781\u591a\u7535\u5b50\u53cd\u5e94\u7684\u57fa\u672c\u539f\u5219<\/li>\n<\/ol>\n<p>\u672c\u8282\u7cfb\u7edf\u9610\u8ff0\u4e86\u78f7\u9178\u76d0\u57fa\u6b63\u6781\u6750\u6599\u5b9e\u73b0\u591a\u7535\u5b50\u53cd\u5e94\u7684\u6838\u5fc3\u673a\u5236\u53ca\u5176\u9762\u4e34\u7684\u9650\u5236\u3002\u591a\u7535\u5b50\u53cd\u5e94\u7684\u6838\u5fc3\u76ee\u6807\u662f\u901a\u8fc7\u6fc0\u6d3b\u6bcf\u4e2a\u8fc7\u6e21\u91d1\u5c5e\uff08TM\uff09\u79bb\u5b50\u7684\u591a\u7535\u5b50\u8f6c\u79fb\uff08\u5982\u4ece\u5355\u7535\u5b50\u53cd\u5e94\u63d0\u5347\u81f3\u53cc\u7535\u5b50\u6216\u66f4\u9ad8\uff09\uff0c\u7a81\u7834\u4f20\u7edf\u78f7\u9178\u76d0\u6750\u6599\u7684\u5bb9\u91cf\u9650\u5236\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u6bd4\u5bb9\u91cf\uff08\u5982\u8d85\u8fc7170 mAh\/g\uff09\u3002\u5b9e\u73b0\u591a\u7535\u5b50\u53cd\u5e94\u9700\u4e25\u683c\u9075\u5faa\u7535\u8377\u5b88\u6052\u4e0e\u8d28\u91cf\u5b88\u6052\u539f\u5219\u3002\u7535\u8377\u5b88\u6052\u8981\u6c42\u7535\u5b50\u8f6c\u79fb\u6570\u4e0e\u94a0\u79bb\u5b50\u8131\u5d4c\u6570\u76f8\u5339\u914d\uff0c\u4f8b\u5982\uff0c\u4e00\u4e2aTM\u00b3\u207a\u6c27\u5316\u4e3aTM\u2075\u207a\uff08\u91ca\u653e2\u4e2a\u7535\u5b50\uff09\u9700\u4f34\u968f2\u4e2aNa\u207a\u7684\u8131\u51fa\uff1b\u800c\u8d28\u91cf\u5b88\u6052\u5219\u4f9d\u8d56\u4e8e\u6750\u6599\u4e2d\u5145\u8db3\u7684\u94a0\u79bb\u5b50\u50a8\u5907\uff0c\u5982NASICON\u578b\u7ed3\u6784\u4e2d\u7684\u8fc7\u5269Na\u207a\u4f4d\u70b9\u4e3a\u591a\u7535\u5b50\u53cd\u5e94\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u6b64\u5916\uff0c\u591a\u7535\u5b50\u53cd\u5e94\u7684\u5b9e\u73b0\u9700\u5728\u5b88\u6052\u5b9a\u5f8b\u6846\u67b6\u4e0b\uff0c\u534f\u540c\u4f18\u5316\u70ed\u529b\u5b66\u5339\u914d\u4e0e\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u5e76\u9488\u5bf9\u4e0d\u540c\u78f7\u9178\u76d0\u7ed3\u6784\uff08\u5982NASICON\u578b\uff09\u8bbe\u8ba1\u9488\u5bf9\u6027\u7b56\u7565\uff0c\u4ee5\u7a81\u7834\u5bb9\u91cf\u4e0e\u80fd\u91cf\u5bc6\u5ea6\u7684\u9650\u5236\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265064\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-21.png\" alt=\"\" width=\"1163\" height=\"622\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-21.png 1163w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-21-300x160.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-21-768x411.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72472-21-1024x548.png 1024w\" sizes=\"(max-width: 1163px) 100vw, 1163px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>2<\/strong><strong>\u00a0\u00a0\u94a0\u79bb\u5b50\u7535\u6c60\u5e38\u89c1\u78f7\u9178\u76d0\u6b63\u6781\u7ed3\u6784\u3001\u53cd\u5e94\u65b9\u7a0b\u5f0f\u53ca\u6bd4\u5bb9\u91cf<\/strong><\/p>\n<p>&nbsp;<\/p>\n<ol start=\"3\">\n<li>3. \u70ed\u529b\u5b66\u5206\u6790<\/li>\n<\/ol>\n<p>\u672c\u8282\u6df1\u5165\u63a2\u8ba8\u4e86\u78f7\u9178\u76d0\u57fa\u6b63\u6781\u6750\u6599\u4e2d\u591a\u7535\u5b50\u53cd\u5e94\u7684\u70ed\u529b\u5b66\u53ef\u884c\u6027\u53ca\u5176\u6838\u5fc3\u5f71\u54cd\u56e0\u7d20\u3002\u70ed\u529b\u5b66\u5206\u6790\u7684\u6838\u5fc3\u5728\u4e8e\u8bc4\u4f30\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u5e73\u8861\u7535\u4f4d\u662f\u5426\u5904\u4e8e\u7535\u89e3\u6db2\u7684\u7a33\u5b9a\u7535\u538b\u7a97\u53e3\u5185\uff0c\u4ece\u800c\u786e\u4fdd\u53cd\u5e94\u7684\u53ef\u9006\u6027\u4e0e\u5b89\u5168\u6027\u3002\u7814\u7a76\u6307\u51fa\uff0c\u78f7\u9178\u76d0\u57fa\u56e2\uff08\u5982PO\u2084\u548cP\u2082O\u2087\uff09\u7684\u5f3a\u5438\u7535\u5b50\u6548\u5e94\u80fd\u591f\u663e\u8457\u63d0\u5347\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff0c\u4f8b\u5982V\u2074\u207a\/V\u2075\u207a\u548cMn\u00b3\u207a\/Mn\u2074\u207a\u7b49\u9ad8\u4ef7\u6001\u5bf9\u7684\u7535\u538b\uff0c\u4f46\u8fd9\u4e00\u7279\u6027\u53ef\u80fd\u5bfc\u81f4\u5176\u7535\u4f4d\u8d85\u51fa\u5e38\u89c4\u7535\u89e3\u6db2\u7684\u8010\u53d7\u8303\u56f4\uff08\u901a\u5e38&lt;4.3 V\uff09\uff0c\u8fdb\u800c\u5f15\u53d1\u7535\u89e3\u6db2\u5206\u89e3\u7b49\u526f\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u6750\u6599\u8bbe\u8ba1\u4e2d\u9700\u5728\u63d0\u5347\u5bb9\u91cf\u4e0e\u6291\u5236\u9ad8\u7535\u538b\u526f\u4f5c\u7528\u4e4b\u95f4\u5bfb\u6c42\u5e73\u8861\u3002<\/p>\n<p>\u4e0d\u540c\u78f7\u9178\u76d0\u7ed3\u6784\u5bf9\u6c27\u5316\u8fd8\u539f\u7535\u538b\u7684\u5f71\u54cd\u5b58\u5728\u663e\u8457\u5dee\u5f02\u3002NASICON\u578b\u6750\u6599\uff08\u5982Na\u2083TM\u2082(PO\u2084)\u2083\uff09\u5176\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u7535\u538b\u5206\u5e03\u66f4\u6613\u4e0e\u7535\u89e3\u6db2\u7a97\u53e3\u5339\u914d\uff0c\u6210\u4e3a\u5b9e\u73b0\u591a\u7535\u5b50\u53cd\u5e94\u7684\u7406\u60f3\u8f7d\u4f53\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u7126\u78f7\u9178\u76d0\uff08Na\u2082TMP\u2082O\u2087\uff09\u548c\u6df7\u5408\u78f7\u9178\u76d0\uff08Na\u2084TM\u2083(PO\u2084)\u2082(P\u2082O\u2087)\uff09\u4e2dP\u2082O\u2087\u57fa\u56e2\u7684\u5438\u7535\u5b50\u6548\u5e94\u66f4\u5f3a\uff0c\u8fdb\u4e00\u6b65\u63a8\u5347\u9ad8\u6c27\u5316\u6001\uff08\u5982Fe\u2074\u207a\uff09\u7684\u7535\u538b\uff0c\u4f7f\u5176\u66f4\u6613\u8d85\u51fa\u7535\u89e3\u6db2\u7a33\u5b9a\u4e0a\u9650\uff0c\u540c\u65f6\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u963b\u529b\u589e\u5927\uff0c\u9650\u5236\u4e86\u591a\u7535\u5b50\u53cd\u5e94\u7684\u6fc0\u6d3b\u3002\u6b64\u5916\uff0c\u6807\u51c6\u7535\u6781\u7535\u4f4d\u6570\u636e\uff08\u57fa\u4e8e\u6c34\u6eb6\u6db2\u4f53\u7cfb\uff09\u867d\u4e3a\u8bc4\u4f30\u975e\u6c34\u4f53\u7cfb\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u884c\u4e3a\u63d0\u4f9b\u4e86\u53c2\u8003\uff0c\u4f46\u5176\u76f4\u63a5\u9002\u7528\u6027\u4ecd\u9700\u7ed3\u5408\u6750\u6599\u5b9e\u9645\u7ed3\u6784\u8fdb\u884c\u4fee\u6b63\u3002\u70ed\u529b\u5b66\u5206\u6790\u8868\u660e\uff0c\u591a\u7535\u5b50\u53cd\u5e94\u7684\u6210\u529f\u5b9e\u73b0\u4e0d\u4ec5\u4f9d\u8d56\u4e8e\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u56fa\u6709\u7279\u6027\uff0c\u66f4\u9700\u901a\u8fc7\u6750\u6599\u5316\u5b66\u8bbe\u8ba1\u5b9e\u73b0\u7535\u538b\u3001\u5bb9\u91cf\u4e0e\u7a33\u5b9a\u6027\u7684\u534f\u540c\u4f18\u5316\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265065\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-18.png\" alt=\"\" width=\"1166\" height=\"796\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-18.png 1166w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-18-300x205.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-18-768x524.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72473-18-1024x699.png 1024w\" sizes=\"(max-width: 1166px) 100vw, 1166px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>3<\/strong><strong>\u00a0\u00a0\u94a0\u79bb\u5b50\u7535\u6c60\u5e38\u89c1\u78f7\u9178\u76d0\u6b63\u6781\u6c27\u5316\u8fd8\u539f\u5bf9\u7535\u52bf\u5206\u5e03\u53ca\u78f7\u9178\u76d0\u7c7b\u57fa\u56e2\u63d0\u5347\u7535\u538b\u7684\u4f5c\u7528\u673a\u5236<\/strong><\/p>\n<p>&nbsp;<\/p>\n<ol start=\"4\">\n<li>4. \u52a8\u529b\u5b66\u5206\u6790<\/li>\n<\/ol>\n<p>\u672c\u8282\u7cfb\u7edf\u89e3\u6790\u4e86\u78f7\u9178\u76d0\u57fa\u6b63\u6781\u6750\u6599\u4e2d\u591a\u7535\u5b50\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u9650\u5236\u56e0\u7d20\uff0c\u805a\u7126\u4e8e\u7535\u5b50\u4f20\u5bfc\u3001\u79bb\u5b50\u6269\u6563\u4e0e\u7535\u8377\u8f6c\u79fb\u4e09\u5927\u6838\u5fc3\u73af\u8282\u3002\u52a8\u529b\u5b66\u8fc7\u7a0b\u76f4\u63a5\u51b3\u5b9a\u53cd\u5e94\u7a0b\u5ea6\u4e0e\u7535\u5316\u5b66\u6027\u80fd\u8868\u73b0\uff0c\u5176\u4f18\u5316\u662f\u5b9e\u73b0\u9ad8\u5bb9\u91cf\u4e0e\u9ad8\u500d\u7387\u6027\u80fd\u7684\u5173\u952e\u3002\u7814\u7a76\u6307\u51fa\uff0c\u78f7\u9178\u76d0\u6750\u6599\u56fa\u6709\u4f4e\u7535\u5b50\u7535\u5bfc\u7387\uff0810\u207b\u2078\u201310\u207b\u00b9\u2070\u00a0S\/cm\uff09\u5bfc\u81f4\u663e\u8457\u7684\u6b27\u59c6\u6781\u5316\uff0c\u9700\u901a\u8fc7\u78b3\u5305\u8986\uff08\u5982\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\uff09\u6784\u5efa\u8868\u9762\u5bfc\u7535\u7f51\u7edc\uff0c\u6216\u5f15\u5165\u8fc7\u6e21\u91d1\u5c5e\u63ba\u6742\uff08\u5982Fe\u3001Cr\uff09\u8c03\u63a7\u80fd\u5e26\u7ed3\u6784\uff0c\u63d0\u5347\u672c\u5f81\u7535\u5bfc\u7387\u3002\u7136\u800c\uff0c\u78b3\u5305\u8986\u4ec5\u6539\u5584\u8868\u9762\u5bfc\u7535\u6027\uff0c\u6750\u6599\u4f53\u76f8\u5185\u90e8\u7684\u7535\u5b50\u4f20\u8f93\u4ecd\u9700\u4f9d\u8d56\u7ed3\u6784\u8bbe\u8ba1\uff08\u5982\u9ad8\u71b5\u63ba\u6742\uff09\u5b9e\u73b0\u5747\u5300\u5316\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265066\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-20.png\" alt=\"\" width=\"1169\" height=\"528\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-20.png 1169w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-20-300x136.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-20-768x347.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72474-20-1024x463.png 1024w\" sizes=\"(max-width: 1169px) 100vw, 1169px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>4<\/strong><strong>\u00a0\u00a0\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u6b27\u59c6\u6781\u5316\u793a\u610f\u56fe<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u94a0\u79bb\u5b50\u6269\u6563\u7684\u52a8\u529b\u5b66\u9650\u5236\u4f53\u73b0\u4e8e\u56fa\u76f8\u8fc1\u79fb\u8def\u5f84\u4e0e\u80fd\u5792\u3002\u901a\u8fc7\u6676\u4f53\u7ed3\u6784\u89e3\u6790\u4e0e\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0\uff0cNASICON\u578b\u6750\u6599\uff08\u5982Na\u2083V\u2082(PO\u2084)\u2083\uff09\u4e2d\u94a0\u79bb\u5b50\u7684\u4f18\u5148\u8131\u5d4c\u4f4d\u70b9\uff08\u5982Na2\u4f4d\u70b9\uff09\u53ca\u4f4e\u80fd\u5792\u6269\u6563\u901a\u9053\uff08&lt;0.5 eV\uff09\u4e3a\u5176\u591a\u7535\u5b50\u53cd\u5e94\u63d0\u4f9b\u4e86\u57fa\u7840\uff0c\u800c\u7126\u78f7\u9178\u76d0\uff08Na\u2082TMP\u2082O\u2087\uff09\u4e2d\u94a0\u79bb\u5b50\u7684\u591a\u7ef4\u6269\u6563\u8def\u5f84\u867d\u4e30\u5bcc\uff0c\u4f46\u90e8\u5206\u4f4d\u70b9\u7684\u9ad8\u80fd\u5792\uff08\u5982Na4\u4f4d\u70b9\uff09\u4ecd\u9650\u5236\u53cd\u5e94\u6df1\u5ea6\u3002\u63ba\u6742\u7b56\u7565\uff08\u5982Al\u00b3\u207a\u53d6\u4ee3Fe\u00b2\u207a\uff09\u53ef\u91cd\u6784\u94a0\u7a7a\u4f4d\u5206\u5e03\uff0c\u964d\u4f4e\u8fc1\u79fb\u80fd\u5792\u5e76\u62d3\u5bbd\u6269\u6563\u901a\u9053\uff0c\u540c\u65f6\u9ad8\u71b5\u8bbe\u8ba1\u901a\u8fc7\u5f15\u5165\u591a\u5143\u7d20\u534f\u540c\u6548\u5e94\uff0c\u8fdb\u4e00\u6b65\u52a0\u901f\u79bb\u5b50\u4f20\u8f93\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265067\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-16.png\" alt=\"\" width=\"991\" height=\"705\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-16.png 991w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-16-300x213.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72475-16-768x546.png 768w\" sizes=\"(max-width: 991px) 100vw, 991px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>5<\/strong><strong>\u00a0\u00a0\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u6d53\u5dee\u6781\u5316\u53ca\u5e38\u89c1\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u94a0\u79bb\u5b50\u6269\u6563\u8def\u5f84\u793a\u610f\u56fe<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u7535\u8377\u8f6c\u79fb\u4f5c\u4e3a\u6700\u7ec8\u53cd\u5e94\u6b65\u9aa4\uff0c\u5176\u80fd\u5792\u7531\u91cd\u7ec4\u80fd\uff08\u03bb\uff09\u4e3b\u5bfc\u3002Marcus\u7406\u8bba\u8868\u660e\uff0c\u8fc7\u6e21\u91d1\u5c5e\u9ad8\u4ef7\u6001\uff08\u5982V\u2075\u207a\u3001Mn\u2074\u207a\uff09\u7684\u7535\u8377\u8f6c\u79fb\u9700\u514b\u670d\u8f83\u9ad8\u80fd\u91cf\u58c1\u5792\u3002\u78f7\u9178\u76d0\u6846\u67b6\u7684\u5f3a\u5171\u4ef7\u952e\u7f51\u7edc\u901a\u8fc7\u6291\u5236Jahn-Teller\u7578\u53d8\uff08\u5982Mn\u00b3\u207a\u7684\u516b\u9762\u4f53\u626d\u66f2\uff09\u548c\u6784\u5efa\u201c\u72b6\u6001\u68af\u201d\u80fd\u7ea7\u7ed3\u6784\uff08\u591a\u6b65\u6c27\u5316\u8fd8\u539f\u8026\u5408\uff09\uff0c\u53ef\u6709\u6548\u964d\u4f4e\u91cd\u7ec4\u80fd\u3002\u4f8b\u5982\uff0cNa\u2083.\u2085V\u2080.\u2085Mn\u2080.\u2085Fe\u2080.\u2085Ti\u2080.\u2085(PO\u2084)\u2083\u4e2d\u591a\u6d3b\u6027\u5143\u7d20\u7684\u534f\u540c\u4f5c\u7528\uff0c\u4f7f\u7535\u8377\u8f6c\u79fb\u5206\u6b65\u8fdb\u884c\uff0c\u663e\u8457\u63d0\u5347\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u7126\u78f7\u9178\u76d0\u4e0e\u6df7\u5408\u78f7\u9178\u76d0\u4e2d\u8fc7\u9ad8\u7684\u6c27\u5316\u7535\u4f4d\u4ecd\u5bfc\u81f4\u7535\u8377\u8f6c\u79fb\u4e0e\u7535\u89e3\u6db2\u7a33\u5b9a\u6027\u4e4b\u95f4\u7684\u77db\u76fe\uff0c\u9700\u901a\u8fc7\u754c\u9762\u5de5\u7a0b\uff08\u5982\u9ad8\u538b\u7535\u89e3\u6db2\u5f00\u53d1\uff09\u4e0e\u6750\u6599\u6539\u6027\uff08\u5982Zr\u2074\u207a\u63ba\u6742\u6291\u5236\u76f8\u53d8\uff09\u534f\u540c\u89e3\u51b3\u3002\u603b\u4f53\u800c\u8a00\uff0c\u52a8\u529b\u5b66\u4f18\u5316\u9700\u517c\u987e\u7535\u5b50-\u79bb\u5b50\u4f20\u5bfc\u7f51\u7edc\u7684\u5747\u8861\u6027\u4e0e\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u7684\u80fd\u91cf\u5339\u914d\uff0c\u4e3a\u591a\u7535\u5b50\u53cd\u5e94\u7684\u9ad8\u6548\u63a8\u8fdb\u63d0\u4f9b\u4fdd\u969c\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265068\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-11.png\" alt=\"\" width=\"987\" height=\"525\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-11.png 987w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-11-300x160.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72476-11-768x409.png 768w\" sizes=\"(max-width: 987px) 100vw, 987px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>6<\/strong><strong>\u00a0\u00a0\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u7535\u5316\u5b66\u6781\u5316\u793a\u610f\u56fe<\/strong><\/p>\n<p>&nbsp;<\/p>\n<ol start=\"5\">\n<li>5. \u9ad8\u6bd4\u80fd\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u4f18\u5316\u7b56\u7565<\/li>\n<\/ol>\n<p>\u672c\u8282\u603b\u7ed3\u4e86\u901a\u8fc7\u591a\u7ef4\u5ea6\u6750\u6599\u8bbe\u8ba1\u6fc0\u6d3b\u591a\u7535\u5b50\u53cd\u5e94\u3001\u63d0\u5347\u80fd\u91cf\u5bc6\u5ea6\u7684\u6838\u5fc3\u8def\u5f84\u3002\u805a\u7126\u4e8e\u7535\u5b50\u4f20\u5bfc\u4f18\u5316\u3001\u79bb\u5b50\u6269\u6563\u8c03\u63a7\u4e0e\u9ad8\u4ef7\u6c27\u5316\u8fd8\u539f\u5bf9\u6fc0\u6d3b\u4e09\u5927\u65b9\u5411\uff0c\u5e76\u7ed3\u5408\u5b9e\u9645\u6848\u4f8b\u9610\u660e\u4e86\u7b56\u7565\u7684\u6709\u6548\u6027\u3002\u9488\u5bf9\u78f7\u9178\u76d0\u672c\u5f81\u7535\u5bfc\u7387\u4f4e\u7684\u7f3a\u9677\uff0c\u78b3\u5305\u8986\uff08\u5982\u77f3\u58a8\u70ef\u3001\u78b3\u7eb3\u7c73\u7ba1\uff09\u88ab\u5e7f\u6cdb\u7528\u4e8e\u6784\u5efa\u8868\u9762\u5bfc\u7535\u7f51\u7edc\uff0c\u800c\u8fc7\u6e21\u91d1\u5c5e\u63ba\u6742\uff08\u5982Fe\u3001Cr\uff09\u4e0e\u9634\u79bb\u5b50\u53d6\u4ee3\uff08\u5982Si\u66ff\u4ee3P\uff09\u5219\u901a\u8fc7\u80fd\u5e26\u7ed3\u6784\u8c03\u6574\u63d0\u5347\u4f53\u76f8\u5bfc\u7535\u6027\u3002\u9ad8\u71b5\u8bbe\u8ba1\u8fdb\u4e00\u6b65\u5f15\u5165\u591a\u5143\u7d20\u534f\u540c\u6548\u5e94\uff08\u5982Na\u2083V\u2081.\u2088(CrMnFeZnAl)\u2080.\u2082(PO\u2084)\u2083\uff09\uff0c\u5728\u65e0\u5e8f\u7ed3\u6784\u4e2d\u5f62\u6210\u201c\u8d5d\u7535\u5bb9\u201d\u7279\u6027\uff0c\u5b9e\u73b0\u65e0\u78b3\u6d82\u5c42\u4e0b\u7684\u9ad8\u500d\u7387\u6027\u80fd\uff08\u598250C\u5bb9\u91cf\u4fdd\u6301\u7387&gt;80%\uff09\uff0c\u7a81\u7834\u4e86\u4f20\u7edf\u78b3\u4f9d\u8d56\u7684\u5c40\u9650\u6027\u3002<\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265069\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477.png\" alt=\"\" width=\"991\" height=\"558\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477.png 991w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-300x169.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/02\/\u56fe\u72477-768x432.png 768w\" sizes=\"(max-width: 991px) 100vw, 991px\" \/><\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>7<\/strong><strong>\u00a0\u00a0\u78f7\u9178\u76d0\u7c7b\u6b63\u6781\u7535\u5b50\u4f20\u5bfc\u53ca\u79bb\u5b50\u6269\u6563\u6539\u8fdb\u7684\u7b56\u7565<\/strong><\/p>\n<p>\u94a0\u79bb\u5b50\u6269\u6563\u52a8\u529b\u5b66\u7684\u4f18\u5316\u4f9d\u8d56\u4e8e\u6676\u4f53\u7ed3\u6784\u8c03\u63a7\u4e0e\u7f3a\u9677\u5de5\u7a0b\u3002\u901a\u8fc7Al\u00b3\u207a\u3001Zr\u2074\u207a\u7b49\u63ba\u6742\u91cd\u6784\u94a0\u7a7a\u4f4d\u5206\u5e03\uff0c\u53ef\u964d\u4f4e\u6269\u6563\u80fd\u5792\uff08\u5982Na\u2084Fe\u2082.\u2089Al\u2080.\u2081(PO\u2084)\u2082(P\u2082O\u2087)\u7684\u8fc1\u79fb\u80fd\u964d\u4f4e30%\uff09\uff0c\u540c\u65f6\u9ad8\u71b5\u8bbe\u8ba1\u6269\u5c55\u94a0\u79bb\u5b50\u901a\u9053\uff0c\u63d0\u5347\u56fa\u76f8\u6269\u6563\u901f\u7387\u3002\u6838\u58f3\u7ed3\u6784\uff08\u5982\u4e2d\u7a7aNa\u2084Fe\u2082.\u2084Ni\u2080.\u2086(PO\u2084)\u2082(P\u2082O\u2087)\uff09\u4e0e\u8868\u9762\u7f3a\u9677\u5de5\u7a0b\uff08\u5982\u78b3\u5c42\u5bcc\u7f3a\u9677\u8bbe\u8ba1\uff09\u5219\u901a\u8fc7\u7f29\u77ed\u6269\u6563\u8def\u5f84\u4e0e\u589e\u52a0\u6d3b\u6027\u4f4d\u70b9\uff0c\u534f\u540c\u63d0\u5347\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u6b64\u5916\uff0c\u7535\u89e3\u6db2\u4f18\u5316\uff08\u5982\u919a\u7c7b\u6eb6\u5242\u964d\u4f4e\u8131\u6eb6\u5242\u5316\u80fd\uff09\u4e0e\u754c\u9762\u7a33\u5b9a\u5316\uff08\u5982\u78f7\u9178\u4e09\uff082,2,2-\u4e09\u6c1f\u4e59\u57fa\uff09\u916f\u8c03\u63a7CEI\u6210\u819c\uff09\u8fdb\u4e00\u6b65\u52a0\u901f\u94a0\u79bb\u5b50\u8de8\u754c\u9762\u4f20\u8f93\uff0c\u652f\u6491\u4f4e\u6e29\uff08-20\u00b0C\uff09\u4e0e\u9ad8\u500d\u7387\uff084C\uff09\u4e0b\u7684\u7a33\u5b9a\u5faa\u73af\u3002<\/p>\n<p>\u9ad8\u4ef7\u6c27\u5316\u8fd8\u539f\u5bf9\u7684\u6fc0\u6d3b\u662f\u7a81\u7834\u5bb9\u91cf\u4e0a\u9650\u7684\u6838\u5fc3\u3002NASICON\u578b\u6750\u6599\uff08\u5982Na\u2083.\u2085MnCr(PO\u2084)\u2083\uff09\u901a\u8fc7\u5f15\u5165\u591a\u6d3b\u6027\u5143\u7d20\uff08Mn\u00b2\u207a\/\u00b3\u207a\/\u2074\u207a\u3001Cr\u00b3\u207a\/\u2074\u207a\uff09\u5b9e\u73b0\u4e09\u7535\u5b50\u53cd\u5e94\uff0c\u5bb9\u91cf\u8fbe160.5 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Zhang; B. Lian; H. Shen; S. Cheng; F. Li, Challenges and Strategies for Multi\u2010Electron Reactions in High\u2010Energy Phosphate\u2010Based Cathodes for Sodium\u2010Ion Batteries. <em><i>Adv. Funct. Mater. <\/i><\/em><strong><b>2025, <\/b><\/strong>2420864. DOI: 10.1002\/adfm.202420864.<\/p>\n<p>\u672c\u6587\u7531\u5c0f\u9ed1\u4eba\u4e0d\u9ed1\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u00a0\u3010\u5bfc\u8bfb\u3011 \u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u5316\u5b66\u5b66\u9662\u674e\u798f\u519b\u6559\u6388\u56e2\u961f\u5728Adv. Funct. 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