{"id":265361,"date":"2025-03-07T07:04:38","date_gmt":"2025-03-06T23:04:38","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=265361"},"modified":"2025-03-06T22:07:41","modified_gmt":"2025-03-06T14:07:41","slug":"energy-environmental-science-n-c-%e6%8e%ba%e6%9d%82%e5%a2%9e%e5%bc%ba%e5%b1%82%e7%8a%b6bi0-4sb1-6te3%e6%9d%90%e6%96%99%e7%83%ad%e7%94%b5%e6%80%a7%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=265361","title":{"rendered":"Energy &#038; Environmental Science: N-C 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<\/b><\/strong><strong><b>\u539f\u5b50\u5c3a\u5ea6\u7ed3\u6784\u53d8\u5316<\/b><\/strong>\u3002\uff08a\uff09\u63ba\u6742\u4f53\u7cfb\u4e2d\u5206\u5e03\u7684\u5bcc\u78b3\u6676\u754c\u793a\u610f\u56fe\uff1b\uff08b\uff09TEM\u56fe\uff0c\u663e\u793a\u5d4c\u5165\u7684\u6676\u76f8\u8fb9\u754c\uff1b\uff08c\uff09STEM\u56fe\uff0c\u5bf9\u5e94\uff08b\uff09\u4e2d\u533a\u57df1\uff0c\u5c55\u793a\u5d4c\u5165\u7684\u6676\u76f8\u8fb9\u754c\uff1b\uff08d\uff09ADF-STEM\u56fe\uff0c\u5bf9\u5e94\uff08b\uff09\u4e2d\u533a\u57df2\uff0c\u6e05\u6670\u5c55\u793a\u6676\u4f53\u57fa\u4f53\u548c\u65e0\u5b9a\u5f62\u6676\u754c\u7684\u539f\u5b50\u7ed3\u6784\uff1b\uff08e\uff09\u901a\u8fc7IFFT\u5904\u7406\uff08d\uff09\u4e2d\u77e9\u5f62\u533a\u57df3\uff0c\u5c55\u793a\u65e0\u5b9a\u5f62\u6676\u754c\u4e0e\u6676\u4f53\u57fa\u4f53\u6676\u7c92\u7684\u5fae\u89c2\u7ed3\u6784\uff1b\uff08f\uff09\u7531\uff08d\uff09\u8ba1\u7b97\u7684\u5e94\u53d8\u5206\u5e03\u56fe\uff0c\u63ed\u793a\u57fa\u4f53\u4e2d\u7684\u65e0\u5b9a\u5f62\u5e94\u53d8\u76f8\uff1b\uff08g\uff09HAADF-STEM\u56fe\uff0c\u5c55\u793a\u6676\u754c\u754c\u9762\u7684\u539f\u5b50\u7ed3\u6784\uff0c\u63d2\u56fe\u4e3a\u76f8\u5e94\u7684\u5e94\u53d8\u5206\u5e03\u56fe\u3002\uff08h\uff09HAADF-STEM\u56fe\uff0c\u5c55\u793a\u63ba\u6742\u57fa\u4f53\u7684\u539f\u5b50\u7ed3\u6784\uff0c\u90e8\u5206\u533a\u57df\u5b58\u5728C\u548cN\u5bcc\u96c6\u7684\u7ed3\u6784\u7578\u53d8\uff1b\uff08i\uff09HAADF-STEM\u56fe\uff0c\u5c55\u793aBi<sub>0.4<\/sub>Sb<sub>1.6<\/sub>Te<sub>3<\/sub>\u91cf\u5b50\u5c42\u4e2d\u7531\u4e8eN\u548cC\u63ba\u6742\u800c\u5f15\u8d77\u7684\u7eb3\u7c73\u5c3a\u5ea6vdW\u7ed3\u6784\u53d8\u5316\uff1b\uff08j\uff09[100]\u65b9\u5411HAADF-STEM\u56fe\uff0c\u663e\u793a\u53d1\u751f\u7ed3\u6784\u7578\u53d8\u7684N\u548cC\u63ba\u6742\u533a\u57df\uff1b\uff08k\uff09\u901a\u8fc7IFFT\u653e\u5927\uff08j\uff09\u4e2d\u533a\u57df1\u548c4\uff0c\u5c55\u793a\u5fae\u7ed3\u6784\u7ec6\u8282\uff1b\uff08l\uff09iDPC-STEM\u56fe\uff0c\u5bf9\u5e94\uff08j\uff09\u4e2d1-4\u533a\u57df\u3002\uff08m\uff09\u539f\u5b50\u548c\u7f3a\u9677\u7684\u4f4e\u80fd\u635f\u56fe\u50cf\u548c\u9ad8\u80fd\u635f\u56fe\u50cf\uff1b\uff08n\uff09EELS\u5149\u8c31\uff1b\uff08o\uff09-\uff08p\uff09\u5206\u522b\u662fC 1s\u548cN 1s\u7684XPS\u5149\u8c31\uff1b\uff08q\uff09XRD\u7cbe\u4fee\u6570\u636e\u5206\u6790\uff1b\uff08r\uff09\u5f62\u6210\u80fd\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265365\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72473-5.png\" alt=\"\" width=\"1000\" height=\"1279\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72473-5.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72473-5-235x300.png 235w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72473-5-768x982.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72473-5-801x1024.png 801w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>3<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>vdW\u5c42\u7684\u539f\u5b50\u5c3a\u5ea6\u8868\u9762\u91cd\u6784<\/b><\/strong>\u3002\uff08a\uff09\u548c\uff08b\uff09\u5c55\u793a\u4e86Bi<sub>0.4<\/sub>Sb<sub>1.6<\/sub>Te<sub>3<\/sub>\u4f53\u7cfb\u4e0eN-C\u63ba\u6742\u4f53\u7cfb\u7684\u539f\u5b50\u6392\u5e03\uff1b\uff08c\uff09\u7406\u8bba\u6676\u754c\u7ed3\u6784\u548cC\u63d2\u5c42\u4e0eN\u95f4\u9699\u63ba\u6742\u4e0b\u7684\u53ef\u80fd\u6a21\u578b\uff1b\uff08d\uff09c\u4e2d\u5bf9\u5e94\u7684\u6a21\u578b\u5728\u5355\u4e2a\u6676\u80de\u5185\u7684\u6a21\u578b\uff1b\uff08e\uff09\u548c\uff08f\uff09HAADF-STEM\u56fe\u50cf\uff1b\uff08g\uff09\u7531\uff08f\uff09\u4e2d\u6807\u8bb0\u7684\u533a\u57df1\u548c2\u7684HAADF-STEM\u56fe\u50cf\uff0c\u663e\u793a\u6b63\u5e38QLs\u548c\u5012\u7f6e\u7684QLs\u3002\uff08h\uff09\u548c\uff08i\uff09HAADF-STEM\u56fe\uff0c\u5206\u522b\u5c55\u793a\u5c42\u95f4\u548c\u5c42\u5185\u533a\u57df\u7684\u7ed3\u6784\u53d8\u5316\uff1b\uff08j\uff09\u03bb<sub>PD<\/sub>\u503c\u4e0e\u5c42\u95f4\u539f\u5b50\u8ddd\u79bb\u7684\u63ba\u6742\u4f9d\u8d56\u6027\u3002\uff08k\uff09N-C\u63ba\u6742\u4f53\u7cfb\u4e2d\uff0c\u7531C\u63d2\u5c42\u9a71\u52a8\u7684\u5c42\u95f4-\u5c42\u5185\u7578\u53d8\u76f8\u5173\u884c\u4e3a\uff1b\uff08l\uff09QLs\u5185\u90e8\u7684\u63ba\u6742\u4f9d\u8d56\u6027\u4ee5\u53ca\u952e\u957f\u53d8\u5316\uff1b\uff08m\uff09\u8ba1\u7b97\u7684\u5f3a\u5ea6\u6bd4\uff1b\uff08n\uff09\u5f62\u6210\u80fd\u8ba1\u7b97\u7ed3\u679c\u3002\u00a0<\/p>\n<p>\u7814\u7a76\u4e86\u5236\u5907\u7684Bi<sub>0.4<\/sub>Sb<sub>1.6<\/sub>Te<sub>3<\/sub>\u7684\u8f7d\u6d41\u5b50\u8f93\u8fd0\u6027\u80fd\uff0c\u4ece\u7406\u8bba\u548c\u5b9e\u9a8c\u89d2\u5ea6\u5bf9\u6bd4\u5206\u6790\u4e86N-C\u63ba\u6742\u540eBi<sub>0.4<\/sub>Sb<sub>1.6<\/sub>Te<sub>3<\/sub>\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\uff0c\u5f62\u6210\u80fd\uff0c\u80fd\u5e26\u7ed3\u6784\u7684\u53d8\u5316\u4ee5\u53ca\u5176\u5bf9\u7535\u5bfc\u7387\u548c\u585e\u8d1d\u514b\u7cfb\u6570\u7684\u8c03\u8282\u4f5c\u7528\uff08\u56fe4\u548c\u56fe5\uff09\u3002\u6839\u636e\u70ed\u5bfc\u7387\u5b9e\u9a8c\u6d4b\u91cf\u7ed3\u679c\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\uff0c\u5206\u6790\u63ba\u6742\u5bf9\u58f0\u5b50\u6563\u5c04\u7684\u5f71\u54cd\u3002\u901a\u8fc7Peierls\u7578\u53d8\u53c2\u6570\u7684\u8ba1\u7b97\uff0c\u8bc1\u660eN-C\u63ba\u6742\u5bf9\u964d\u4f4eBi<sub>0.4<\/sub>Sb<sub>1.6<\/sub>Te<sub>3<\/sub>\u6676\u683c\u70ed\u5bfc\u7387\u7684\u4f5c\u7528\uff08\u56fe6\uff09\u3002\u540c\u65f6\uff0c\u672c\u7814\u7a76\u5236\u5907\u7684\u9ad8\u6548\u70ed\u7535\u5668\u4ef6\u5728200 K\u6e29\u5dee\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e866.1%\u7684\u80fd\u91cf\u8f6c\u5316\u6548\u7387\uff0c\u663e\u8457\u4f18\u4e8e\u73b0\u6709\u7684Bi-Sb-Te\u4f53\u7cfb\u7684\u70ed\u7535\u6a21\u5757\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265366\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72474-5.png\" alt=\"\" width=\"1000\" height=\"815\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72474-5.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72474-5-300x245.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72474-5-768x626.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u8f93\u8fd0\u884c\u4e3a\u4e0e\u7535\u5b50\u80fd\u5e26\u7ed3\u6784<\/b><\/strong>\u3002\uff08a\uff09\u8f7d\u6d41\u5b50\u6d53\u5ea6\u53d8\u5316\u8d8b\u52bf\uff1b\uff08b\uff09\u5f62\u53d8\u52bf\u80fd\u53d8\u5316\u8d8b\u52bf\uff1b\uff08c\uff09SPB\u6a21\u578b\u8ba1\u7b97\u7684\u7535\u5bfc\u7387\u4e0e\u8f7d\u6d41\u5b50\u6d53\u5ea6\u5173\u7cfb\u3002\uff08d\uff09\u6e29\u5ea6\u76f8\u5173\u7684\u8fc1\u79fb\u7387\u4ee5\u53ca\u57fa\u4e8eDFT\u8ba1\u7b97\u7684\u4e0d\u540c\u8f7d\u6d41\u5b50\u6d53\u5ea6\u4e0b\u7684\u7535\u5bfc\u7387\/\u5f1b\u8c6b\u65f6\u95f4\u6bd4\u503c\uff1b\uff08e\uff09\u6001\u5bc6\u5ea6\uff1b\uff08f\uff09\u6001\u5bc6\u5ea6\u5bf9\u6bd4\uff1b\uff08g\uff09\u80fd\u5e26\u95f4\u9699\u53d8\u5316\u4e0e\u6742\u8d28\u6001\u7684\u5f62\u6210\uff1b\uff08h\uff09\u4ef7\u6001\u6536\u655b\u6027\u4e3a\u5bf9\u6bd4\uff1b\uff08i\uff09\u63ba\u6742\u4f53\u7cfbVBM\u548cCBM\u53d8\u5316\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265367\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72475-4.png\" alt=\"\" width=\"1000\" height=\"1079\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72475-4.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72475-4-278x300.png 278w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72475-4-768x829.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72475-4-949x1024.png 949w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>5<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u6676\u9762\u6676\u754c\u548c\u70ed\u7535\u6027\u80fd\u7684\u8c03\u63a7<\/b><\/strong>\u3002\uff08a\uff09\u57fa\u4e8e\u80fd\u91cf\u8fc7\u6ee4\u6548\u5e94\u7684\u7406\u8bba\u6a21\u578b\u3002\uff08b\uff09\u8ba1\u7b97\u7684\u754c\u9762\u585e\u8d1d\u514b\u7cfb\u6570\u4e0e\u5b9e\u9a8c\u585e\u8d1d\u514b\u7cfb\u6570\u5bf9\u6bd4\uff1b\uff08c\uff09\u5b9e\u9a8c\u585e\u8d1d\u514b\u7cfb\u6570\u4ee5\u53ca\u57fa\u4e8eDFT\u8ba1\u7b97\u7684\u7406\u8bba\u585e\u8d1d\u514b\u7cfb\u6570\uff1b\uff08d\uff09SPB \u6a21\u578b\u4e0b\u585e\u8d1d\u514b\u7cfb\u6570\u5bf9\u8f7d\u6d41\u5b50\u6d53\u5ea6\u7684\u4f9d\u8d56\u6027\uff1b\uff08e\uff09\u6709\u6548\u8d28\u91cf\u53d8\u5316\uff1b\uff08f\uff09\u5b9e\u9a8c\u529f\u7387\u56e0\u5b50\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\u4ee5\u53ca\u8f7d\u6d41\u5b50\u6d53\u5ea6\u4f9d\u8d56\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-265368\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72476-4.png\" alt=\"\" width=\"1000\" height=\"921\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72476-4.png 1000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72476-4-300x276.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72476-4-768x707.png 768w\" sizes=\"(max-width: 1000px) 100vw, 1000px\" \/><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>6<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\u7ed3\u6784\u7578\u53d8\u548c\u70ed\u8f93\u8fd0\u884c\u4e3a<\/b><\/strong>\u3002\uff08a\uff09\u603b\u70ed\u5bfc\u7387\u53d8\u5316\u8d8b\u52bf\uff1b\uff08b\uff09\u5b9e\u9a8c\u6d4b\u5f97\u6676\u683c\u70ed\u5bfc\u7387\u4e0e\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u5bf9\u6bd4\uff1b\uff08c\uff09\u5404\u6563\u5c04\u673a\u5236\u4e0b\u6a21\u62df\u7684\u6676\u683c\u70ed\u5bfc\u7387\uff1b\uff08d\uff09\u7406\u8bba\u8ba1\u7b97\u7684Ks\u503c\uff1b\uff08e\uff09\u5e73\u5747\u58f0\u901f\u548cGruneisen 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srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72478-1.png 314w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/03\/\u56fe\u72478-1-287x300.png 287w\" sizes=\"(max-width: 314px) 100vw, 314px\" \/><\/p>\n<p>Bushra Jabar\u535a\u58eb\uff0c\u5fb7\u56fd\u83b1\u5e03\u5c3c\u8328\u56fa\u4f53\u6750\u6599\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u6d2a\u5821\u5956\u5b66\u91d1\u83b7\u5f97\u8005\uff082023\uff09\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u535a\u58eb\uff0c\u6df1\u5733\u5927\u5b66\u535a\u58eb\u540e\u3002\u957f\u671f\u4ece\u4e8b\u5148\u8fdb\u80fd\u6e90\u6750\u6599\u7684\u5f00\u53d1\uff08\u6bd4\u5982\u70ed\u7535\u6750\u6599\uff09\u4ee5\u53ca\u80fd\u6e90\u5b58\u50a8\u4e0e\u4e8c\u7ef4\u6750\u6599\u7684\u7814\u7a76\u3002\u5df2\u5728Energy &amp; Environmental Science\u3001Nature Communications\u3001Advanced Functional Materials\u3001Nano 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Communication\u3001Energy &amp; Environmental Science\u7b49\u671f\u520a\u4e0a\u53d1\u8868\u5b66\u672f\u8bba\u6587200\u4f59\u7bc7\uff0cSCI\u603b\u5f15\u75288000\u4f59\u6b21\uff0cH\u6307\u657048\uff1b\u83b7\u7f8e\u56fd\u548c\u65e5\u672c\u7b49\u56fd\u5bb6\u6388\u6743\u53d1\u660e\u4e13\u52297\u9879\uff0c\u56fd\u5185\u53d1\u660e\u4e13\u5229\u6388\u674310\u4f59\u9879\uff0c\u83b7\u5e7f\u4e1c\u7701\u79d1\u5b66\u6280\u672f\u5956\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong><b>\u5168\u6587\u94fe\u63a5<\/b><\/strong>\uff1ahttps:\/\/doi.org\/10.1039\/d4ee04930f<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5bfc\u8bfb 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