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\u00a0<\/b><\/strong><\/p>\n

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 <\/p>\n

\u56fe1 DPA-PEAI\u548c<\/b><\/strong>(DPA-PEA)<\/b><\/strong>2<\/b><\/sub><\/strong>PbI<\/b><\/strong>4<\/b><\/sub><\/strong>\u4e8c\u7ef4\u9499\u949b\u77ff<\/b><\/strong>\u7684\u5355\u6676\u548c\u8ba1\u7b97\u8868\u5f81<\/b><\/strong><\/p>\n

DPA-PEA+<\/sup>\u5177\u6709\u6bd4PEA+<\/sup>\u66f4\u5927\u7684\u5076\u6781\u77e9\uff0c\u6709\u5229\u4e8e\u4e8c\u7ef4\u9499\u949b\u77ff\u5185\u90e8\u7684\u7535\u8377\u5206\u79bb\u3002\u5728(DPA-PEA)2<\/sub>PbI4<\/sub>\u4e8c\u7ef4\u9499\u949b\u77ff\u6676\u4f53\u4e2d\uff0c\u7531\u4e8e\u4e09\u82ef\u80fa\u7279\u6b8a\u7684\u87ba\u65cb\u6868\u7ed3\u6784\uff0c\u56db\u5bf9\u9633\u79bb\u5b50\u4e4b\u95f4\u5b58\u5728\u4e5d\u5bf9\u53ef\u80fd\u7684p-p\u5806\u79ef\u76f8\u4e92\u4f5c\u7528\u3002\u901a\u8fc7\u8ba1\u7b97\u82ef\u73af\u95f4\u7684\u4e2d\u5fc3\u95f4\u8ddd\u4ee5\u53ca\u5e73\u9762\u95f4\u5939\u89d2\uff0cp-p\u76f8\u4e92\u4f5c\u7528\u5e7f\u6cdb\u5b58\u5728\u4e8e1-1\u00a2\uff0c2-2\u00a2\uff0c3-3\u00a2\u548c4-4\u00a2\u4e4b\u95f4\u6807\u8bb0\u4e3a\u84dd\u8272\u7684\u82ef\u73af\u5bf9\uff0c\u4ee5\u53ca3-2\u00a2\u4e4b\u95f4\u6807\u8bb0\u4e3a\u84dd\u8272\u7684\u82ef\u73af\u5bf9\u3002\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\u76f8\u90bb\u5c42DPA-PEA+<\/sup>\u9633\u79bb\u5b50\u4e4b\u95f4\u7684\u7ed3\u5408\u80fd\u548c\u7a7a\u7a74\u8f6c\u79fb\u79ef\u5206\u5747\u5927\u4e8ePEA+<\/sup>\u9633\u79bb\u5b50\u5bf9\u3002\u4e24\u79cd\u9633\u79bb\u5b50\u4e0e\u7a7a\u7a74\u4f20\u8f93\u5c42Spiro-OMeTAD\u4e4b\u95f4\u7684\u7ed3\u5408\u80fd\u4ee5\u53ca\u7a7a\u7a74\u8f6c\u79fb\u79ef\u5206\u7684\u8ba1\u7b97\u540c\u6837\u8bf4\u660e\u4e86DPA-PEA+<\/sup>\u4fee\u9970\u7684\u9499\u949b\u77ff\u4e0e\u7a7a\u7a74\u5c42\u4e4b\u95f4\u7684\u7a7a\u7a74\u8f6c\u79fb\u8fc7\u7a0b\u66f4\u6709\u5229\u3002<\/p>\n

 <\/p>\n

\u56fe2 DPA-PEAI\u53caPEAI\u949d\u5316\u7684FAPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u5206\u6790\u548c\u5149\u7535\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\u901a\u8fc7X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u4ee5\u53ca\u63a0\u5165\u5c04\u5e7f\u89d2X\u5c04\u7ebf\u884d\u5c04\uff08GIWAXS\uff09\u8bc1\u660e\u4e86\u4f7f\u7528DPA-PEAI\u7898\u76d0\u4fee\u9970\u7684FAPbI3<\/sub>\u8584\u819c\u8868\u9762\u539f\u4f4d\u5f62\u6210\u4e86\u4e8c\u7ef4\u9499\u949b\u77ff\u3002\u7a33\u6001\u53d1\u5149\u5149\u8c31\uff08PL\uff09\u4ee5\u53ca\u77ac\u6001\u53d1\u5149\u5149\u8c31\uff08TRPL\uff09\u8868\u660eDPA-PEAI\u4fee\u9970\u7684\u9499\u949b\u77ff\u8584\u819c\u4e2d\u5b58\u5728\u9ad8\u6548\u7684\u8f7d\u6d41\u5b50\u63d0\u53d6\u8fc7\u7a0b\u3002\u5bfc\u7535\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08C-AFM\uff09\u548c\u7a7a\u95f4\u7535\u8377\u9650\u5236\u7535\u6d41\u6d4b\u8bd5\uff08SCLC\uff09\u8fdb\u4e00\u6b65\u8bc1\u660eDPA-PEAI\u4fee\u9970\u7684\u9499\u949b\u77ff\u8584\u819c\u5177\u6709\u66f4\u9ad8\u7684\u8868\u9762\u7535\u6d41\u548c\u66f4\u9ad8\u7684\u7a7a\u7a74\u8fc1\u79fb\u7387\u3002<\/p>\n

 <\/p>\n

\u56fe3 DPA-PEAI\u53caPEAI\u949d\u5316\u7684FAPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u9499\u949b\u77ff\u8584\u819c\u7684\u80fd\u7ea7\u8868\u5f81<\/b><\/strong><\/p>\n

\u901a\u8fc7\u7d2b\u5916\u5149\u7535\u5b50\u80fd\u8c31\uff08UPS\uff09\u548c\u5f00\u5c14\u6587\u63a2\u9488\u663e\u5fae\u955c\uff08KPFM\uff09\u786e\u5b9a\u4e86\u7898\u76d0\u4fee\u9970\u524d\u540e\u9499\u949b\u77ff\u8584\u819c\u7684\u80fd\u7ea7\u3002DPA-PEAI\u4fee\u9970\u7684\u8584\u819c\u5177\u6709\u66f4\u9ad8\u7684\u4ef7\u5e26\u9876\uff08VBM\uff09\uff0c\u4e0e\u7a7a\u7a74\u4f20\u8f93\u5c42\u7ec4\u6210\u4e86II\u578b\u5f02\u8d28\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u7a7a\u7a74\u7684\u63d0\u53d6\u4e0e\u8f6c\u79fb\u3002\u540c\u65f6\uff0c\u66f4\u5c0f\u7684\u8d39\u7c73\u80fd\u7ea7\uff08E<\/i><\/em>F<\/sub>\uff09\u4e0eVBM\u7684\u5dee\u503c\uff0c\u8868\u660eDPA-PEAI\u4fee\u9970\u7684\u9499\u949b\u77ff\u8868\u9762\u66f4p\u578b\uff0c\u6709\u5229\u4e8e\u7a7a\u7a74\u4f20\u8f93\u3002<\/p>\n

 <\/p>\n

\u56fe4 DPA-PEAI\u53caPEAI\u949d\u5316\u7684FAPbI<\/b><\/strong>3<\/b><\/sub><\/strong>\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u5149\u7535\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\u91c7\u7528DPA-PEAI\u4fee\u9970\u7684\u5668\u4ef6\u6700\u7ec8\u83b7\u5f97\u4e8625.7%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u662f\u76ee\u524d\u57fa\u4e8e\u5171\u8f6d\u94f5\u76d0\u914d\u4f53\u76842D\/3D\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6700\u9ad8\u6548\u7387\u4e4b\u4e00\u3002\u77ac\u6001\u5149\u7535\u6d41\uff08TPC\uff09\u3001\u77ac\u6001\u5149\u7535\u538b\uff08TPV\uff09\u7b49\u6d4b\u8bd5\u540c\u6837\u8bc1\u5b9e\u4e86DPA-PEAI\u4fee\u9970\u7684\u5668\u4ef6\u4e2d\u8f7d\u6d41\u5b50\u63d0\u53d6\u901f\u7387\u66f4\u5feb\uff0c\u975e\u8f90\u5c04\u590d\u5408\u4ee5\u53ca\u7f3a\u9677\u663e\u8457\u964d\u4f4e\u3002DPA-PEAI\u4fee\u9970\u7684\u5668\u4ef6\u5728\u6700\u5927\u529f\u7387\u70b9\u8ffd\u8e2a\uff08MPPT\uff09\u4e0b\uff0c\u8fde\u7eed\u5149\u71671000\u5c0f\u65f6\u540e\u4fdd\u6301\u4e86\u521d\u59cb\u6548\u7387\u768490%\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u8fd0\u884c\u7a33\u5b9a\u6027\u3002<\/p>\n

\u672c\u7814\u7a76\u53d1\u5c55\u4e86\u4e00\u79cd\u5177\u6709\u7a7a\u7a74\u4f20\u8f93\u529f\u80fd\u7684\u4e09\u82ef\u80fa\u7c7b\u914d\u4f53\u7528\u4e8e2D\/3D FAPbI3<\/sub>\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u3002DPA-PEAI\u95f4\u9694\u9633\u79bb\u5b50\u4e4b\u95f4\u4ee5\u53caDPA-PEAI\u4e0e\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u663e\u8457\u589e\u5f3a\uff0c\u540c\u65f6\u4fc3\u8fdb\u4e862D\u9499\u949b\u77ff\u5185\u90e8\u548c3D\u9499\u949b\u77ff\/\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e4b\u95f4\u7684\u8f7d\u6d41\u5b50\u8f93\u8fd0\uff0c\u4e3a\u53d1\u5c55\u9ad8\u6548\u7a33\u5b9a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5f88\u597d\u7684\u601d\u8def\u3002\u4e09\u82ef\u80fa\u7ed3\u6784\u7684\u6613\u4fee\u9970\u6027\uff0c\u6709\u671b\u8fdb\u4e00\u6b65\u63d0\u5347\u9633\u79bb\u5b50\u914d\u4f53\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u4ee5\u53ca\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u540c\u65f6\uff0cDPA-PEAI\u8868\u73b0\u51fa\u7684\u534a\u5bfc\u4f53\u6027\u80fd\u4f7f\u5176\u5728\u5176\u5b83\u57fa\u4e8e2D\u62162D\/3D\u9499\u949b\u77ff\u7684\u5149\u7535\u5668\u4ef6\u4e2d\uff0c\u4f8b\u5982\u51c6\u9499\u949b\u77ff\/\u53e0\u5c42\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u3001\u53d1\u5149\u4e8c\u6781\u7ba1\u3001\u5149\u7535\u63a2\u6d4b\u5668\u7b49\u6709\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

 <\/p>\n

\u8bba\u6587\u4fe1\u606f\uff1a<\/p>\n

Triphenylamine-Based Hole-Transporting Ligands for 2D\/3D FAPbI3<\/sub>\u00a0Perovskite Solar Cells<\/p>\n

Huaiman Cao, Tianshu Li, Liangyu Zhao, Yue Qiang, Xufan Zheng, Shouye Dai, Yulong Chen, Yong Zhu, Liang Zhao, Rui Cai, Zhiguang Sun, Fei Li, Yingguo Yang, Lijun Zhang*, Hin-Lap Yip*, and Ze Yu*<\/p>\n

\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u66f9\u6000\u6ee1\uff08\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u8054\u5408\u57f9\u517b\uff09\u548c\u5409\u6797\u5927\u5b66\u5df2\u6bd5\u4e1a\u535a\u58eb\u674e\u5929\u59dd\uff08\u76ee\u524d\u4e3a\u82f1\u56fd\u5e1d\u56fd\u7406\u5de5\u5b66\u9662\u535a\u58eb\u540e\uff09\u3002\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u4e3a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u4e8e\u6cfd\u6559\u6388\u3001\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u53f6\u8f69\u7acb\u6559\u6388\u548c\u5409\u6797\u5927\u5b66\u5f20\u7acb\u519b\u6559\u6388\u3002<\/p>\n

ACS Energy Letters<\/em><\/p>\n

DOI: 10.1021\/acsenergylett.5c00471<\/p>\n","protected":false},"excerpt":{"rendered":"

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