{"id":266445,"date":"2025-04-28T06:44:30","date_gmt":"2025-04-27T22:44:30","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=266445"},"modified":"2025-04-27T22:45:57","modified_gmt":"2025-04-27T14:45:57","slug":"%e9%87%8d%e7%a3%85science%e7%a6%bb%e5%ad%90%e7%9b%90%e7%94%b5%e5%ad%90%e4%bc%a0%e8%be%93%e5%b1%82%e6%94%b9%e5%86%99%e8%a7%84%e5%88%99%ef%bc%9a%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=266445","title":{"rendered":"\u91cd\u78c5Science:\u79bb\u5b50\u76d0\u7535\u5b50\u4f20\u8f93\u5c42\u6539\u5199\u89c4\u5219\uff1a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6548\u738726%\u3001\u9ad8\u6e29\u8fd0\u884c\u8d852000\u5c0f\u65f6"},"content":{"rendered":"

\u3010\u4e00\u3011\u3001\u79d1\u5b66\u80cc\u666f<\/p>\n

\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u56e0\u5176\u9ad8\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u548c\u4f4e\u6210\u672c\u6f5c\u529b\u6210\u4e3a\u5149\u4f0f\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u9499\u949b\u77ff\u6750\u6599\u56e0\u5176\u9ad8\u5149\u5438\u6536\u7cfb\u6570\u3001\u53ef\u8c03\u5e26\u9699\u3001\u6eb6\u6db2\u52a0\u5de5\u6027\u7b49\u7279\u6027\uff0c\u6210\u4e3a\u7b2c\u4e09\u4ee3\u5149\u4f0f\u6280\u672f\u7684\u6838\u5fc3\u6750\u6599\u3002\u5012\u7f6e\uff08p-i-n\uff09\u7ed3\u6784\u9499\u949b\u77ff\u7535\u6c60\u56e0\u5176\u5236\u5907\u5de5\u827a\u7b80\u5355\u3001\u4f4e\u6e29\u517c\u5bb9\u6027\uff08<150\u00b0C\uff09\u4ee5\u53ca\u4e0e\u7845\u57fa\u53e0\u5c42\u7535\u6c60\u7684\u6f5c\u529b\uff0c\u88ab\u89c6\u4e3a\u5546\u4e1a\u5316\u7684\u91cd\u8981\u65b9\u5411\u3002\u7136\u800c\uff0c\u5176\u5b9e\u9645\u5e94\u7528\u53d7\u9650\u4e8e\u4e24\u5927\u95ee\u9898\uff1a\uff081\uff09\u754c\u9762\u7a33\u5b9a\u6027\u4e0d\u8db3<\/strong>\uff1a\u9499\u949b\u77ff\u4e0e\u7535\u8377\u4f20\u8f93\u5c42\uff08\u5982\u7535\u5b50\u4f20\u8f93\u5c42ETL\uff09\u7684\u754c\u9762\u6613\u53d1\u751f\u79bb\u5b50\u8fc1\u79fb\u3001\u7f3a\u9677\u6001\u79ef\u7d2f\u548c\u5316\u5b66\u964d\u89e3\uff0c\u5bfc\u81f4\u5668\u4ef6\u6548\u7387\u8870\u51cf\u3002\uff082\uff09\u957f\u671f\u8fd0\u884c\u6027\u80fd\u9000\u5316<\/strong>\uff1a\u9ad8\u6e29\u3001\u6e7f\u5ea6\u3001\u5149\u7167\u7b49\u5916\u90e8\u5e94\u529b\u52a0\u901f\u754c\u9762\u5206\u5c42\u548c\u6750\u6599\u5206\u89e3\uff0c\u5c24\u5176\u5728\u5012\u7f6e\u7ed3\u6784\u4e2d\uff0cETL\u4e0e\u9499\u949b\u77ff\u7684\u5f31\u7ed3\u5408\uff08\u8303\u5fb7\u534e\u529b\u4e3b\u5bfc\uff09\u662f\u4e3b\u8981\u74f6\u9888\u3002\u76ee\u524d\uff0c\u5012\u7f6ePSCs\u666e\u904d\u4f7f\u7528C60\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\uff08ETL\uff09\uff0c\u4f46C60\u7684\u5206\u5b50\u6027\u8d28\u5bfc\u81f4\u5176\u4e0e\u9499\u949b\u77ff\u754c\u9762\u7ed3\u5408\u5f31\uff08\u8303\u5fb7\u534e\u529b\u4e3b\u5bfc\uff09\u3001\u673a\u68b0\u97e7\u6027\u5dee\uff0c\u4e14\u9700\u8981\u8f83\u539a\u5c42\uff08~20 nm\uff09\u4ee5\u652f\u6491\u539f\u5b50\u5c42\u6c89\u79ef\uff08ALD\uff09SnO\u2093\u6d82\u5c42\u3002\u8fd9\u4e9b\u95ee\u9898\u9650\u5236\u4e86\u5668\u4ef6\u6548\u7387\u548c\u7a33\u5b9a\u6027\uff0c\u5c24\u5176\u662f\u5728\u9ad8\u6e29\u6216\u957f\u671f\u8fd0\u884c\u6761\u4ef6\u4e0b\u3002\u9488\u5bf9C\u2086\u2080\u7684\u7f3a\u9677\uff0c\u7814\u7a76\u8005\u5c1d\u8bd5\u4e86\u591a\u79cd\u65b9\u6cd5\uff1a\uff081\uff09\u8868\u9762\u949d\u5316<\/strong>\uff1a\u5f15\u5165\u5c0f\u5206\u5b50\uff08\u5982PCBM\uff09\u6216\u4e8c\u7ef4\u6750\u6599\uff08\u5982\u77f3\u58a8\u70ef\uff09\u586b\u8865\u9499\u949b\u77ff\u8868\u9762\u7f3a\u9677\uff0c\u4f46\u672a\u89e3\u51b3C\u2086\u2080\u81ea\u8eab\u7684\u5206\u5b50\u6027\u8d28\u95ee\u9898\u3002\uff082\uff09\u754c\u9762\u4fee\u9970<\/strong>\uff1a\u901a\u8fc7\u81ea\u7ec4\u88c5\u5355\u5c42\uff08SAMs\uff09\u8c03\u6574\u80fd\u7ea7\u6392\u5217\uff0c\u4f46\u96be\u4ee5\u589e\u5f3a\u673a\u68b0\u7ed3\u5408\u529b\u3002\uff083\uff09C\u2086\u2080<\/strong>\u529f\u80fd\u5316<\/strong>\uff1a\u5c06C\u2086\u2080\u4e0e\u6781\u6027\u57fa\u56e2\u5171\u4ef7\u4fee\u9970\uff0c\u4f46\u5408\u6210\u590d\u6742\u4e14\u7535\u5b50\u4f20\u8f93\u80fd\u529b\u53ef\u80fd\u53d7\u635f\u3002\u8fd9\u4e9b\u7b56\u7565\u591a\u805a\u7126\u4e8e\u5c40\u90e8\u4f18\u5316\uff0c\u672a\u4ece\u6750\u6599\u5316\u5b66\u672c\u8d28\u4e0a\u7a81\u7834C\u2086\u2080\u7684\u5c40\u9650\u6027\u3002<\/p>\n

\u3010\u4e8c\u3011\u3001\u79d1\u5b66\u521b\u65b0<\/p>\n

\u6700\u8fd1\u6765\u81ea\u82f1\u56fd\u7ebd\u5361\u65af\u5c14\u5927\u5b66Marina Freitag\u3001\u6258\u83b1\u591a\u5927\u5b66Yanfa Yan\u3001\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66Osman M. Bakr\u548c\u7f8e\u56fd\u56fd\u5bb6\u53ef\u518d\u751f\u80fd\u6e90\u5b9e\u9a8c\u5ba4\u6731\u51ef\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8eC60\u7684\u79bb\u5b50\u76d0\uff08CPMAC\uff09\u4f5c\u4e3a\u7535\u5b50\u4f20\u8f93\u5c42\uff0c\u7528\u4e8e\u9ad8\u6027\u80fd\u5012\u7f6e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u53ca\u6a21\u5757\u3002CPMAC\u7531C60\u4e0eN-\u7532\u57fa\u7518\u6c28\u9178\u7b49\u53cd\u5e94\u5408\u6210\uff0c\u5176\u9633\u79bb\u5b50\u4e2d\u7684CH\u2082-NH\u2083\u207a\u57fa\u56e2\u53ef\u586b\u5145\u9499\u949b\u77ff\u8868\u9762\u7684\u7532\u8112\uff08FA\u207a\uff09\u7a7a\u4f4d\u6216\u53d6\u4ee3FA\u207a\u79bb\u5b50\uff0c\u5f62\u6210\u79bb\u5b50\u952e\u7ed3\u5408\uff0c\u4ece\u800c\u589e\u5f3a\u754c\u9762\u97e7\u6027\u548c\u81f4\u5bc6\u6027\u3002\u76f8\u8f83\u4e8eC60\uff0cCPMAC\u7684\u754c\u9762\u97e7\u6027\u63d0\u9ad8\u4e86\u7ea63\u500d\uff08\u4ece0.50 J m\u207b\u00b2\u589e\u81f31.43 J m\u207b\u00b2\uff09\uff0c\u4e14\u4ec5\u9700~10 nm\u539a\u5ea6\u5373\u53ef\u652f\u6491ALD-SnO\u2093\u6d82\u5c42\u3002\u57fa\u4e8eCPMAC\u7684\u5355\u7ed3\u7535\u6c60\u5b9e\u73b0\u4e8626.1%\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\uff0c\u5e76\u572865\u00b0C\u30011\u500d\u592a\u9633\u5149\u4e0b\u8fde\u7eed\u8fd0\u884c2100\u5c0f\u65f6\u540e\u4ec5\u8870\u51cf2%\u3002\u5728\u5fae\u578b\u6a21\u5757\uff084\u4e2a\u5b50\u7535\u6c60\uff0c\u9762\u79ef6 cm\u00b2\uff09\u4e2d\uff0cCPMAC\u4f7fPCE\u8fbe\u523023.2%\uff0c\u5e76\u572855\u00b0C\u4e0b\u8fd0\u884c2200\u5c0f\u65f6\u540e\u4fdd\u630191.5%\u7684\u521d\u59cb\u6548\u7387\u3002\u8be5\u7814\u7a76\u901a\u8fc7\u79bb\u5b50\u76d0\u8bbe\u8ba1\u89e3\u51b3\u4e86C60<\/sub>\u7684\u754c\u9762\u548c\u673a\u68b0\u7a33\u5b9a\u6027\u7f3a\u9677\uff0c\u4e3a\u9499\u949b\u77ff\u5149\u4f0f\u6280\u672f\u7684\u5546\u4e1a\u5316\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cC60<\/sub>-based ionic salt electron shuttle for high-performance inverted perovskite solar modules\u201d\u4e3a\u9898\u53d1\u8868\u5728Science<\/em><\/strong>\u671f\u520a\u4e0a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>1. (A)<\/strong>\u00a0C\u2086\u2080\u4e0e\u9499\u949b\u77ff\u8868\u9762\u7684\u76f8\u4e92\u4f5c\u7528\uff08\u8303\u5fb7\u534e\u952e\u5408\uff09\u4e0eCPMAC\u7684\u5bf9\u6bd4\uff1b(B)<\/strong>\u00a04-(1′,5′-\u4e8c\u6c22-1′-\u7532\u57fa-2’H-[5,6]\u5bcc\u52d2\u70ef-C\u2086\u2080-I\u2099-[1,9-c]\u5421\u54af-2′-\u57fa)\u82ef\u7532\u80fa\u6c2f\u5316\u7269\uff08CPMAC\uff09\u7684\u5408\u6210\u8def\u5f84\u3002\u00a9 2025 AAAS<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u7ed3\u6784\u4e0e\u5149\u7535\u6027\u8d28<\/strong> \u00a9 2025 AAAS<\/strong><\/p>\n

(A)<\/strong>\u00a0\u548c\u00a0(B)<\/strong>\u00a0\u65e0\/\u6709CPMAC\u6d82\u5c42\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u5149\u81f4\u53d1\u5149\uff08PL\uff09\u6210\u50cf\uff1b
\n (C)<\/strong>\u00a0\u548c\u00a0(D)<\/strong>\u00a0\u5bf9\u7167\u7ec4\u4e0e\u76ee\u6807\u9499\u949b\u77ff\u8584\u819c\u7684\u514b\u5c14\u63a2\u9488\u529b\u663e\u5fae\u955c\uff08KPFM\uff09\u8868\u9762\u7535\u52bf\u5206\u5e03\u56fe\uff1b
\n (E)<\/strong>\u00a0C\u2086\u2080\u8584\u819c\u4e0eCPMAC\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5fae\u6ce2\u7535\u5bfc\uff08TRMC\uff09\u5bf9\u6bd4\uff1b
\n (F)<\/strong>\u00a0\u57fa\u4e8eC\u2086\u2080\u6216CPMAC\u7684\u7535\u5b50\u4f20\u8f93\u5c42\uff08ETL\uff09\u7684\u65ad\u88c2\u80fd\uff08G_c\uff09\u6bd4\u8f83\uff1b
\n (G)<\/strong>\u00a0Ag\/ALD-SnO\u2093\/CPMAC\/\u9499\u949b\u77ff\u7ed3\u6784\u7684\u6a2a\u622a\u9762\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08HAADF-STEM\uff09\u56fe\u50cf\uff1b
\n (H)<\/strong>\u00a0\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\uff08EELS\uff09\u5143\u7d20\u5206\u5e03\u5206\u6790\uff08\u94f6\u3001\u9521\u3001\u6c27\u3001\u78b3\u3001\u7898\uff09\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd<\/strong> \u00a9 2025 AAAS<\/strong><\/p>\n

(A)<\/strong>\u00a0\u548c\u00a0(B)<\/strong>\u00a0\u4e0d\u540c\u5668\u4ef6\u7ed3\u6784\uff08FTO\/HTL\/\u9499\u949b\u77ff\/C\u2086\u2080\/ALD-SnO\u2093\/Ag\u00a0(A)<\/strong>\u00a0\u548c FTO\/HTL\/\u9499\u949b\u77ff\/CPMAC\/ALD-SnO\u2093\/Ag\u00a0(B)<\/strong>\uff09\u7684\u7535\u6d41\u5bc6\u5ea6-\u7535\u538b\uff08J-V\uff09\u66f2\u7ebf\u53ca\u6a21\u62dfAM 1.5 G\u5149\u7167\u4e0b\u7684\u5149\u4f0f\u53c2\u6570\uff08\u63d2\u56fe\u4e3a\u5177\u4f53\u6570\u503c\uff09\u3002\u5668\u4ef6\u6709\u6548\u9762\u79ef\u4e3a0.059 cm\u00b2\uff08\u901a\u8fc7\u91d1\u5c5e\u5b54\u5f84\u5b9a\u4e49\uff09\uff1b
\n (C)<\/strong>\u00a0\u57fa\u4e8eISOS-L-1\u534f\u8bae\u7684\u5668\u4ef6\u8fd0\u884c\u7a33\u5b9a\u6027\u5bf9\u6bd4\uff0865\u00b0C\uff0c\u6c2e\u6c14\u73af\u5883\uff0c1\u500d\u592a\u9633\u5149\u6700\u5927\u529f\u7387\u70b9\u8ffd\u8e2a\uff09\u3002HTL\u4e3aMeO-2PACZ\/Me-4PACZ\u6df7\u5408\u7269\u3002C\u2086\u2080\u4e0eCPMAC\u5668\u4ef6\u7684\u521d\u59cbPCE\u5206\u522b\u4e3a24.9%\u548c25.8%\uff1b
\n (D)<\/strong>\u00a0\u672a\u5c01\u88c5\u5668\u4ef6\u572885\u00b0C\u3001\u6c2e\u6c14\u73af\u5883\u4e0b\u7684\u8fd0\u884c\u7a33\u5b9a\u6027\u5bf9\u6bd4\uff08\u6301\u7eed1\u500d\u592a\u9633\u5149\u7167\u5c04\uff09\u3002\u6b64\u6d4b\u8bd5\u4e2d\uff0cHTL\u4e3aPTAA\u3002C\u2086\u2080\u4e0eCPMAC\u5668\u4ef6\u7684\u521d\u59cbPCE\u5206\u522b\u4e3a24.3%\u548c25.5%\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 \u9499\u949b\u77ff\u592a\u9633\u80fd\u6a21\u5757\u6027\u80fd<\/strong> \u00a9 2025 AAAS<\/strong><\/p>\n

(A)<\/strong>\u00a0\u9499\u949b\u77ff\u8584\u819c\u5200\u7247\u6d82\u8986\u5de5\u827a\u793a\u610f\u56fe\uff1b
\n (B)<\/strong>\u00a0\u5178\u578b\u9499\u949b\u77ff\u592a\u9633\u80fd\u6a21\u5757\uff08PSM\uff09\u7684J-V\u66f2\u7ebf\uff08\u63d2\u56fe\u4e3a\u6a21\u5757\u5b9e\u7269\u56fe\uff09\uff1b
\n (C)<\/strong>\u00a0\u7f8e\u56fd\u56fd\u5bb6\u53ef\u518d\u751f\u80fd\u6e90\u5b9e\u9a8c\u5ba4\uff08NREL\uff09\u5149\u4f0f\u6027\u80fd\u7ec4\u6d4b\u91cf\u7684CPMAC\u5668\u4ef6\u7684\u51c6\u7a33\u6001\uff08QSS\uff09\u4e0eJ-V\u7ed3\u679c\uff1b
\n (D)<\/strong>\u00a0\u5c01\u88c5\u6a21\u5757\u5728~55\u00b0C\u300140%~60%\u76f8\u5bf9\u6e7f\u5ea6\u7a7a\u6c14\u4e2d\u7684\u8fd0\u884c\u7a33\u5b9a\u6027\uff08\u57fa\u4e8eISOS-L-1\u534f\u8bae\uff09\u3002C\u2086\u2080\u4e0eCPMAC\u5668\u4ef6\u7684\u521d\u59cbPCE\u5206\u522b\u4e3a20.2%\u548c21.5%\u3002<\/p>\n

\u3010\u4e09\u3011\u3001\u79d1\u5b66\u542f\u793a<\/p>\n

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