{"id":266553,"date":"2025-04-29T07:47:39","date_gmt":"2025-04-28T23:47:39","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=266553"},"modified":"2025-04-28T21:56:02","modified_gmt":"2025-04-28T13:56:02","slug":"%e6%97%a5%e6%9c%ac%e4%ba%ac%e9%83%bd%e5%a4%a7%e5%ad%a6susumu-kitagawa%e9%99%a2%e5%a3%ab%e5%9b%a2%e9%98%9f%e3%80%8aangew-chem-int-ed-%e3%80%8b%e6%9c%80%e6%96%b0%e7%a0%94%e7%a9%b6%ef%bc%9a%e8%b6%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=266553","title":{"rendered":"\u65e5\u672c\u4eac\u90fd\u5927\u5b66Susumu Kitagawa\u9662\u58eb\u56e2\u961f\u300aAngew. Chem. Int. Ed.\u300b\u6700\u65b0\u7814\u7a76\uff1a\u8d85\u758f\u6c34\u5200\u7247\u73af\u82ef\u7eb3\u7c73\u9631\u5b9e\u73b0\u4f4e\u538b\u9ad8\u6548\u70f7\u70c3\u5438\u9644\u5206\u79bb"},"content":{"rendered":"<p><strong><b>\u00a0<\/b><\/strong><\/p>\n<p>\u5728\u77f3\u5316\u5de5\u4e1a\u4e2d\uff0c\u8f7b\u8d28\u70ef\u70c3\uff08\u5982\u4e19\u70efC<sub>3<\/sub>H<sub>6<\/sub>\u3001\u4e59\u70efC<sub>2<\/sub>H<sub>4<\/sub>\uff09\u662f\u6781\u5176\u91cd\u8981\u7684\u57fa\u7840\u539f\u6599\uff0c\u5e7f\u6cdb\u7528\u4e8e\u5851\u6599\u3001\u5408\u6210\u6a61\u80f6\u3001\u6d82\u6599\u7b49\u4e0b\u6e38\u4ea7\u54c1\u7684\u5236\u5907\u3002\u7136\u800c\uff0c\u8f7b\u70ef\u70c3\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u907f\u514d\u5730\u4ea7\u751f\u4e19\u70f7\uff08C<sub>3<\/sub>H<sub>8<\/sub>\uff09\u3001\u4e59\u70f7\uff08C<sub>2<\/sub>H<sub>6<\/sub>\uff09\u7b49\u9971\u548c\u70f7\u70c3\u526f\u4ea7\u7269\u3002\u4e3a\u4e86\u6ee1\u8db3\u805a\u5408\u7ea7\u6807\u51c6\uff08&gt;99.5%\uff09\uff0c\u9700\u9ad8\u6548\u53bb\u9664\u70f7\u70c3\u6742\u8d28\u3002\u76ee\u524d\uff0c\u5de5\u4e1a\u4e0a\u4e3b\u8981\u4f9d\u8d56\u6df1\u51b7\u7cbe\u998f\uff0c\u4f46\u8be5\u8fc7\u7a0b\u80fd\u8017\u6781\u9ad8\u3001\u8bbe\u5907\u6295\u8d44\u5927\u3001\u64cd\u4f5c\u6761\u4ef6\u4e25\u82db\uff0c\u4e9f\u9700\u5f00\u53d1\u7eff\u8272\u4f4e\u78b3\u7684\u66ff\u4ee3\u6280\u672f\u57fa\u4e8e\u5438\u9644\u5206\u79bb\u7684\u70ef\u70c3\u7eaf\u5316\u56e0\u5176\u80fd\u8017\u4f4e\u3001\u6d41\u7a0b\u7b80\u4fbf\u7b49\u4f18\u70b9\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u7279\u522b\u662f\u901a\u8fc7\u5f00\u53d1<strong><b>\u9009\u62e9\u6027\u5438\u9644\u70f7\u70c3<\/b><\/strong>\u7684\u591a\u5b54\u6750\u6599\uff0c\u53ef\u4ee5\u5728\u4e00\u6b65\u64cd\u4f5c\u4e2d\u76f4\u63a5\u83b7\u5f97\u9ad8\u7eaf\u70ef\u70c3\uff0c\u907f\u514d\u4f20\u7edf\u65b9\u6cd5\u4e2d\u7684\u590d\u6742\u8131\u9644\u518d\u751f\u6b65\u9aa4\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u8fd1\u5e74\u6765\u51fa\u73b0\u4e86\u5927\u91cf\u65b0\u578b\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\uff08PCPs\/MOFs\uff09\uff0c\u771f\u6b63\u517c\u5177\u9ad8\u70f7\u70c3\u9009\u62e9\u6027\u4e0e\u6297\u6e7f\u6027\u7684\u5438\u9644\u5242\u4ecd\u6781\u4e3a\u7a00\u7f3a\uff0c\u4e25\u91cd\u5236\u7ea6\u4e86\u5176\u5de5\u4e1a\u5e94\u7528\u3002<\/p>\n<p>\u4e3a\u6b64\uff0c<strong><b>\u4eac\u90fd\u5927\u5b66\u5317\u5ddd<\/b><\/strong><strong><b>\u9032\uff08Susumu Kitagawa\uff09<\/b><\/strong>\u6559\u6388\u56e2\u961f\u91c7\u7528\u521b\u65b0\u601d\u8def\uff0c\u5f00\u53d1\u4e86\u517c\u5177\u8d85\u9ad8\u70f7\u70c3\u9009\u62e9\u6027\u4e0e\u8d85\u5f3a\u6297\u6e7f\u6027\u7684\u5200\u7247\u72b6\u73af\u82ef\u7eb3\u7c73\u9631\u591a\u5b54\u6750\u6599\u3002\u8be5\u7a81\u7834\u6027\u6210\u679c\u4e0d\u4ec5\u4e3a\u70ef\u70c3\u6df1\u5ea6\u51c0\u5316\u63d0\u4f9b\u4e86\u5168\u65b0\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4e5f\u4e3a\u591a\u5b54\u6750\u6599\u5206\u5b50\u8bc6\u522b\u5206\u79bb\u5f00\u8f9f\u4e86\u65b0\u7684\u65b9\u5411\u3002\u76f8\u5173\u5de5\u4f5c\u53d1\u8868\u5728<strong><em><b><i>Angewandte Chemie International Edition<\/i><\/b><\/em><\/strong>\u4e0a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266554\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72471-43.png\" alt=\"\" width=\"1181\" height=\"303\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72471-43.png 1181w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72471-43-300x77.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72471-43-768x197.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72471-43-1024x263.png 1024w\" sizes=\"(max-width: 1181px) 100vw, 1181px\" \/>\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0<\/p>\n<p><strong><b>\u76f4\u51fb\u6311\u6218\uff1a\u517c\u987e\u70f7\u70c3\u4eb2\u548c\u529b\u4e0e\u6750\u6599\u758f\u6c34\u6027\u4ecd\u662f\u96be\u9898<\/b><\/strong><\/p>\n<p>\u73b0\u6709\u70f7\u70c3\u9009\u62e9\u6027\u6750\u6599\u7684\u8bbe\u8ba1\uff0c\u591a\u4f9d\u8d56\u4e8e\u6750\u6599\u5b54\u9053\u4e2d\u4e0e\u70f7\u70c3\u5f62\u6210\u6c22\u952e\u6216\u8303\u5fb7\u534e\u4f5c\u7528\u6765\u5b9e\u73b0\u5206\u5b50\u8bc6\u522b\u3002\u7136\u800c\uff0c\u8fd9\u7c7b\u5b54\u9053\u901a\u5e38\u4e5f\u5bb9\u6613\u5438\u9644\u6c34\u5206\u5b50\uff0c\u5bfc\u81f4\u5438\u9644\u5bb9\u91cf\u4e0b\u964d\u3001\u5206\u79bb\u6027\u80fd\u8870\u9000\uff0c\u751a\u81f3\u9020\u6210\u6750\u6599\u7ed3\u6784\u7834\u574f\u3002\u5df2\u6709\u7814\u7a76\u5c1d\u8bd5\u5f15\u5165\u82b3\u9999\u73af\u6216\u6c1f\u5316\u57fa\u56e2\u4ee5\u589e\u5f3a\u5b54\u9053\u7684\u975e\u6781\u6027\uff0c\u4ece\u800c\u63d0\u5347\u758f\u6c34\u6027\uff0c\u4f46\u5927\u591a\u6570\u6750\u6599\u4ecd\u5b58\u5728\uff1a<\/p>\n<ul>\n<li>\u5728\u9ad8\u6e7f\u73af\u5883\u4e0b\u5927\u91cf\u5438\u9644\u6c34\u5206\u5b50\uff1b<\/li>\n<li>\u70f7\u70c3\/\u70ef\u70c3\u9009\u62e9\u6027\u4e0d\u8db3\uff1b<\/li>\n<li>\u5bf9\u70f7\u70c3\u5206\u5b50\u4eb2\u548c\u529b\u5f31\uff0c\u96be\u4ee5\u5b9e\u73b0\u4f4e\u6d53\u5ea6\u70f7\u70c3\u7684\u6355\u83b7\u3002<\/li>\n<\/ul>\n<p>\u56e0\u6b64\uff0c\u4e9f\u9700\u4e00\u79cd<strong><b>\u80fd\u591f\u5728\u4f4e\u538b\u4e0b\u9ad8\u6548\u6355\u83b7\u70f7\u70c3\u3001\u540c\u65f6\u6709\u6548\u6392\u65a5\u6c34\u5206\u5b50<\/b><\/strong>\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\u4f53\u7cfb\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266555\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72472-44.png\" alt=\"\" width=\"4000\" height=\"2677\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72472-44.png 4000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72472-44-300x201.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72472-44-768x514.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72472-44-1024x685.png 1024w\" sizes=\"(max-width: 4000px) 100vw, 4000px\" \/><\/p>\n<p>\u56fe1. (a) \u57fa\u4e8e\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u7684\u70f7\u70c3\u4eb2\u548c\u529b\u4e0e\u758f\u6c34\u6027\u4e4b\u95f4\u7684\u201c\u6743\u8861\u201d\u5173\u7cfb\uff1b(b) \u901a\u8fc7\u975e\u6781\u6027\u76f8\u4e92\u4f5c\u7528\u5b9e\u73b0\u70f7\u70c3\u4eb2\u548c\u529b\u4e0e\u758f\u6c34\u6027\u7684\u534f\u540c\u63d0\u5347\u7b56\u7565\uff1b(c) \u4e0d\u540c\u70f7\u70c3\u7eb3\u7c73\u9631\u7ed3\u6784PCPs\u5bf9\u70f7\u70c3\u4e0e\u6c34\u5206\u5b50\u5171\u5438\u9644\u884c\u4e3a\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong><b>\u521b\u65b0\u8bbe\u8ba1\uff1a\u5200\u7247\u72b6\u73af\u82ef\u7eb3\u7c73\u9631\u6784\u7b51\u8d85\u758f\u6c34\u5438\u9644\u5242ZnFPCP<\/b><\/strong><\/p>\n<p>\u9488\u5bf9\u4e0a\u8ff0\u6311\u6218\uff0c\u4eac\u90fd\u5927\u5b66\u5317\u5ddd\u9032\uff08Susumu Kitagawa\uff09\u6559\u6388\u56e2\u961f\u521b\u65b0\u6027\u5730\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e00\u79cd\u5177\u6709<strong><b>\u5200\u7247\u72b6\u73af\u82ef\u7eb3\u7c73\u9631\u7ed3\u6784<\/b><\/strong>\u7684\u8d85\u758f\u6c34\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u2014<strong><b>ZnFPC<\/b><\/strong><strong><b>P<\/b><\/strong>\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266556\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72473-40.png\" alt=\"\" width=\"4004\" height=\"1535\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72473-40.png 4004w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72473-40-300x115.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72473-40-768x294.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72473-40-1024x393.png 1024w\" sizes=\"(max-width: 4004px) 100vw, 4004px\" \/><\/p>\n<p>\u56fe2. ZnFPCP\u7684\u5408\u6210\u793a\u610f\u56fe\u53ca\u5176\u5bf9\u5e94\u7ed3\u6784<\/p>\n<p>ZnFPCP\u7684\u5173\u952e\u8bbe\u8ba1\u7279\u70b9\u5305\u62ec\uff1a<\/p>\n<ul>\n<li>\u91c7\u7528V\u578b\u6c1f\u5316\u82b3\u9999\u7fa7\u9178\u914d\u4f53\uff08H<sub>2<\/sub>hfipbb\uff09\u642d\u5efa\u4e09\u7ef4\u6846\u67b6\uff1b<\/li>\n<li>\u6784\u7b51<strong><b>\u7531\u82ef\u73af\u56f4\u7ed5\u7684\u8d85\u5c0f\u5b54\u9053<\/b><\/strong>\uff0c\u5f62\u6210\u5f3a\u70c8\u975e\u6781\u6027\u73af\u5883\uff0c\u663e\u8457\u589e\u5f3a\u70f7\u70c3\u7684C\u2500H\u00b7\u00b7\u00b7\u03c0\u8bc6\u522b\u4f5c\u7528\uff1b<\/li>\n<li>\u5f15\u5165\u6c1f\u57fa\u56e2\u5c01\u95ed\u7684\u8f85\u52a9\u5b54\u9053\uff0c\u6709\u6548\u963b\u65ad\u6c34\u5206\u5b50\u7684\u4fb5\u5165\uff1b<\/li>\n<li>\u5200\u7247\u72b6\u6392\u5217\u7684\u73af\u82ef\u7eb3\u7c73\u9631\u7ed3\u6784\uff0c\u8fdb\u4e00\u6b65\u5206\u5272\u6b21\u7ea7\u5b54\u9053\u7a7a\u95f4\uff0c\u589e\u5f3a\u758f\u6c34\u5c4f\u969c\u6548\u5e94\u3002<\/li>\n<\/ul>\n<p>\u8fd9\u4e00\u72ec\u7279\u7684\u5206\u5b50\u5de5\u7a0b\u7b56\u7565\uff0c\u4f7fZnFPCP\u5728\u4fdd\u6301\u8d85\u5f3a\u70f7\u70c3\u4eb2\u548c\u529b\u7684\u540c\u65f6\uff0c\u517c\u5177\u4e86\u4f18\u5f02\u7684\u6297\u6e7f\u6027\u548c\u7ed3\u6784\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong><b>\u5b9e\u9a8c\u9a8c\u8bc1\uff1a\u4f4e\u538b\u4e0b\u5b9e\u73b0\u521b\u7eaa\u5f55\u70f7\u70c3\u5438\u9644\u4e0e\u9ad8\u6548\u5206\u79bb<\/b><\/strong><\/p>\n<p>\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u4e00\u7cfb\u5217\u5b9e\u9a8c\u7cfb\u7edf\u9a8c\u8bc1\u4e86ZnFPCP\u7684\u6027\u80fd\uff1a<\/p>\n<ul>\n<li><strong><b>\u6c34\u6c7d\u5438\u9644\u6d4b\u8bd5<\/b><\/strong>\u8868\u660e\uff1a\u5373\u4f7f\u572890%\u76f8\u5bf9\u6e7f\u5ea6\u4e0b\uff0cZnFPCP\u7684\u6c34\u5438\u9644\u91cf\u4ecd\u4f4e\u81f30.01 g\/g\uff0c\u8fdc\u4f18\u4e8eFDMOF-2\u3001PCP-IPA\u7b49\u5178\u578b\u70f7\u70c3\u9009\u62e9\u6027\u6750\u6599\u3002<\/li>\n<li><strong><b>\u6c14\u4f53\u5438\u9644\u7b49\u6e29\u7ebf<\/b><\/strong>\u6d4b\u8bd5\u7ed3\u679c\u663e\u793a\uff0c\u5728\u6781\u4f4e\u538b\u529b\uff08&lt;0.1 kPa\uff09\u4e0b\uff0cZnFPCP\u5bf9\u4e19\u70f7\u548c\u4e59\u70f7\u7684\u5438\u9644\u91cf\u8fdc\u8d85\u5176\u4ed6\u62a5\u9053\u6750\u6599\uff0c\u4f53\u73b0\u51fa\u5f3a\u5927\u7684\u4f4e\u538b\u6355\u83b7\u80fd\u529b\u3002<\/li>\n<li><strong><b>IAST\u7406\u8bba\u9009\u62e9\u6027\u8ba1\u7b97<\/b><\/strong>\u8868\u660e\uff1aZnFPCP\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5b9e\u73b0\u4e86C<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\u9009\u62e9\u60272.08\uff0cC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\u9009\u62e9\u60272.93\uff0c\u5747\u4f4d\u5c45\u524d\u5217\u3002<\/li>\n<\/ul>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266557\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72474-35.png\" alt=\"\" width=\"2101\" height=\"913\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72474-35.png 2101w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72474-35-300x130.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72474-35-768x334.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72474-35-1024x445.png 1024w\" sizes=\"(max-width: 2101px) 100vw, 2101px\" \/><\/p>\n<p>\u56fe3. (a) ZnFPCP\u5bf9\u6c34\u7684\u84b8\u6c7d\u5438\u9644\u66f2\u7ebf\u4ee5\u53ca\u4e0e\u6c34\u7684\u63a5\u89e6\u89d2\uff1b(b)\u00a0\u5178\u578b\u70f7\u70c3\u6355\u83b7\u6750\u6599\u7684\u6c34\u5438\u9644\u91cf\u5bf9\u6bd4<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266558\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72475-33.png\" alt=\"\" width=\"2783\" height=\"1730\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72475-33.png 2783w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72475-33-300x186.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72475-33-768x477.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72475-33-1024x637.png 1024w\" sizes=\"(max-width: 2783px) 100vw, 2783px\" \/><\/p>\n<p>\u56fe4. (a, b) ZnFPCP\u5728298 K\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\u3001C<sub>3<\/sub>H<sub>6<\/sub>\u3001C<sub>2<\/sub>H<sub>6<\/sub>\u548cC<sub>2<\/sub>H<sub>4<\/sub>\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff08\u538b\u529b\u8303\u56f4\u5206\u522b\u4e3a0\u2013100 kPa\u548c0\u20131.0 kPa\uff09\uff1b(f, g) \u5178\u578b\u6750\u6599\u4e2dC<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\u548cC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\u7684Henry\u9009\u62e9\u6027\u53ca\u4f4e\u538b\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\u3001C<sub>2<\/sub>H<sub>6<\/sub>\u5438\u9644\u91cf\u7684\u5bf9\u6bd4\uff1b(e, f) \u5178\u578b\u6750\u6599\u4e2dC<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\u548cC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\u6df7\u5408\u6c14\uff0850\/50, v\/v\uff09IAST\u9009\u62e9\u6027\u7684\u5bf9\u6bd4<\/p>\n<p><strong><b>\u673a\u7406\u89e3\u6790\uff1a\u5200\u7247\u72b6\u7ed3\u6784\u52a9\u529b\u6c34\u6c7d\u6392\u65a5\u4e0e\u70f7\u70c3\u4f18\u5148\u8bc6\u522b<\/b><\/strong><\/p>\n<p>\u4e3a\u4e86\u6df1\u5165\u7406\u89e3ZnFPCP\u4f18\u5f02\u6027\u80fd\u7684\u6765\u6e90\uff0c\u7814\u7a76\u56e2\u961f\u7ed3\u5408\u4e86\u591a\u79cd\u7406\u8bba\u4e0e\u8868\u5f81\u624b\u6bb5\uff1a<\/p>\n<ul>\n<li><strong><b>GCMC\u5206\u5b50\u6a21\u62df<\/b><\/strong>\u63ed\u793a\uff1a\u5728\u8d85\u4f4e\u538b\u4e0b\u70f7\u70c3\u4f18\u5148\u586b\u5145\u7531\u82ef\u73af\u73af\u7ed5\u7684\u5c0f\u5b54\uff08SP\u901a\u9053\uff09\uff0c\u800c\u6c34\u5206\u5b50\u5219\u88ab\u6709\u6548\u6392\u65a5\u5728\u5916\u3002<\/li>\n<li><strong><b>\u539f\u4f4d\u7ea2\u5916\u5149\u8c31\uff08FT-IR\uff09\u6d4b\u8bd5<\/b><\/strong>\u8bc1\u5b9e\uff1a\u70f7\u70c3\u5438\u9644\u521d\u671f\u5e76\u4e0d\u4f1a\u663e\u8457\u6270\u52a8\u6c1f\u57fa\u56e2\uff0c\u53ea\u6709\u5728\u9ad8\u8d1f\u8f7d\u65f6\u624d\u53d1\u751f\u5f31\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\uff0c\u8bf4\u660e\u5c0f\u5b54\u4f18\u5148\u6355\u83b7\u673a\u5236\u4e3b\u5bfc\u3002<\/li>\n<li><strong><b>DFTB\u8ba1\u7b97<\/b><\/strong>\u8868\u660e\uff1a\u70f7\u70c3\u5728\u5c0f\u5b54\u4e2d\u5f62\u6210\u591a\u4e2aC\u2500H\u00b7\u00b7\u00b7\u03c0\u76f8\u4e92\u4f5c\u7528\uff0c\u663e\u8457\u4f18\u4e8e\u70ef\u70c3\uff0c\u6709\u6548\u89e3\u91ca\u4e86\u6750\u6599\u7684\u9ad8\u9009\u62e9\u6027\u6765\u6e90\uff1b\u5927\u5b54\u4e2d-CF<sub>3<\/sub>\u57fa\u56e2\u4e0e\u70f7\u70c3\u5206\u5b50\u95f4\u5f62\u6210\u7684C\u2500H\u00b7\u00b7\u00b7F\u5f31\u76f8\u4e92\u4f5c\u7528\u4e5f\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u4fc3\u8fdb\u4e86\u6750\u6599\u5bf9\u70f7\u70c3\u7684\u4f18\u5148\u5438\u9644\u3002<\/li>\n<\/ul>\n<p>\u8fd9\u4e00\u7cfb\u5217\u673a\u5236\u7814\u7a76\u6e05\u6670\u5730\u9610\u91ca\u4e86ZnFPCP\u540c\u65f6\u5b9e\u73b0\u9ad8\u70f7\u70c3\u9009\u62e9\u6027\u548c\u8d85\u5f3a\u6297\u6e7f\u6027\u7684\u5185\u5728\u539f\u56e0\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266559\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72476-29.png\" alt=\"\" width=\"4000\" height=\"2959\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72476-29.png 4000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72476-29-300x222.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72476-29-768x568.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72476-29-1024x758.png 1024w\" sizes=\"(max-width: 4000px) 100vw, 4000px\" \/><\/p>\n<p>\u56fe5. (a) ZnFPCP\u5728233 K\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\u548cC<sub>3<\/sub>H<sub>6<\/sub>\u7684\u5438\u9644\u7b49\u6e29\u7ebf\uff1b(b, c) ZnFPCP\u5728233 K\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\u548cC<sub>3<\/sub>H<sub>6<\/sub>\u5438\u9644\u8fc7\u7a0b\u4e2d\u7684\u539f\u4f4dFT-IR\u5149\u8c31\uff1b(d\u2013i) GCMC\u6a21\u62df\u5f97\u5230\u7684\u4e0d\u540c\u538b\u529b\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\u7684\u5438\u9644\u7ed3\u6784\uff1a\uff08d\uff090.001 kPa\uff0c(e) 0.01 kPa\uff0c(f) 0.1 kPa\uff0c(g) 1.0 kPa\uff0c(h) 10.0 kPa\uff0c(i) 100.0 kPa\u3002\u6ce8\uff1a\u56fe\u4e2d\u672a\u663e\u793aC<sub>3<\/sub>H<sub>8<\/sub>\u5206\u5b50\u4e2d\u7684\u6c22\u539f\u5b50<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266560\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72477-16.png\" alt=\"\" width=\"4000\" height=\"2861\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72477-16.png 4000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72477-16-300x215.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72477-16-768x549.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72477-16-1024x732.png 1024w\" sizes=\"(max-width: 4000px) 100vw, 4000px\" \/><\/p>\n<p>\u56fe6. (a, b) ZnFPCP\u4e2dC<sub>3<\/sub>H<sub>8<\/sub>\u5728SP\u548cLP\u4e2d\u7684DFTB\u8ba1\u7b97\u5438\u9644\u7ed3\u6784\uff1b(c, d) ZnFPCP\u4e2dC<sub>3<\/sub>H<sub>6<\/sub>\u5728SP\u548cLP\u4e2d\u7684\u5438\u9644\u7ed3\u6784\uff1b(e, f) ZnFPCP\u4e2dC<sub>2<\/sub>H<sub>6<\/sub>\u5728SP\u548cLP\u4e2d\u7684\u5438\u9644\u7ed3\u6784\uff1b(g, h) ZnFPCP\u4e2dC<sub>2<\/sub>H<sub>4<\/sub>\u5728SP\u548cLP\u4e2d\u7684\u5438\u9644\u7ed3\u6784\u3002\u6ce8\uff1a<sup>a<\/sup>\u6c14\u4f53\u5206\u5b50\u4e2d\u6c22\u539f\u5b50\u4e0e\u6700\u8fd1\u03c0\u4f53\u7cfb\u4e2d\u5fc3\u4e4b\u95f4\u7684\u8ddd\u79bb\uff08\u5355\u4f4d\uff1a\u00c5\uff09\uff1b\u84dd\u8272\u548c\u7c89\u8272\u5206\u522b\u6807\u6ce8C\u2013H\u00b7\u00b7\u00b7\u03c0\u548cC\u2013H\u00b7\u00b7\u00b7F\u76f8\u4e92\u4f5c\u7528\uff1b<sup>b<\/sup>\u56fe\u4e2d\u6570\u5b57\u8868\u793a\u76f8\u4e92\u4f5c\u7528\u7684\u6570\u91cf\uff1b<sup>c<\/sup>\u56fe\u4e2d\u6807\u6ce8\u4e86\u5ba2\u4f53\u5206\u5b50\u4e0e\u6846\u67b6\u4e4b\u95f4\u7684DFTB\u8ba1\u7b97\u7ed3\u5408\u80fd\u3002C\u3001H\u3001F\u3001O\u3001Zn\u5143\u7d20\u5206\u522b\u4ee5\u7070\u8272\u3001\u767d\u8272\u3001\u9752\u8272\u3001\u7ea2\u8272\u548c\u7d2b\u8272\u8868\u793a\uff0c\u6c14\u4f53\u5206\u5b50\u4e2d\u7684\u78b3\u539f\u5b50\u7528\u6d45\u84dd\u8272\u663e\u793a<\/p>\n<p><strong><b>\u5de5\u4e1a\u6f5c\u529b\uff1a\u5206\u79bb\u6027\u80fd\u4f18\u5f02\uff0c\u8010\u6e7f\u6027\u51fa\u8272<\/b><\/strong><\/p>\n<p>\u52a8\u6001\u7a81\u7834\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u4e86\u6750\u6599\u7684\u5b9e\u9645\u5206\u79bb\u6027\u80fd\uff0c\u4e19\u70ef\u548c\u4e59\u70ef\u7684\u7eaf\u5ea6\u5747\u53ef\u8fbe\u523099.99%\uff0c\u4e14\u751f\u4ea7\u7387\u5206\u522b\u9ad8\u8fbe39.93 L\/L\uff08C\u2083H\u2086\uff09\u548c35.12 L\/L\uff08C\u2082H\u2084\uff09\uff0c\u521b\u9020\u4e86\u65b0\u7eaa\u5f55\u3002\u8003\u8651\u5230\u5b9e\u9645\u5de5\u51b5\u4e2d\u4e0d\u53ef\u907f\u514d\u5b58\u5728\u6c34\u6c7d\uff0c\u7814\u7a76\u56e2\u961f\u5bf9ZnFPCP\u5728\u6e7f\u6da6\u73af\u5883\u4e0b\u8fdb\u884c\u4e86\u591a\u8f6e\u52a8\u6001\u7a81\u7834\u6d4b\u8bd5\u3002\u7ed3\u679c\u8868\u660e\uff0c\u572870%\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0cZnFPCP\u7684\u5206\u79bb\u6027\u80fd\u51e0\u4e4e\u65e0\u8870\u51cf\uff0c\u4e14\u591a\u8f6e\u5faa\u73af\u540e\u4fdd\u6301\u7a33\u5b9a\uff0c\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u8010\u6e7f\u6027\u4e0e\u957f\u671f\u8fd0\u884c\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-266561\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72478-15.png\" alt=\"\" width=\"4000\" height=\"3458\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72478-15.png 4000w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72478-15-300x259.png 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72478-15-768x664.png 768w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/04\/\u56fe\u72478-15-1024x885.png 1024w\" sizes=\"(max-width: 4000px) 100vw, 4000px\" \/><\/b><\/strong><\/p>\n<p>\u56fe7. (a) ZnFPCP\u5728298 K\u30011.0 bar\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\uff0850\/50\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(b) C<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\uff085\/95, v\/v\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(e) \u6e7f\u6da6\u73af\u5883\u4e0bC<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\uff085\/95, v\/v\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(c) ZnFPCP\u5728298 K\u30011.0 bar\u4e0bC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\uff0850\/50\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(d) C<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\uff085\/95, v\/v\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(f) \u6e7f\u6da6\u73af\u5883\u4e0bC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4 <\/sub>\uff0810\/90, v\/v\uff09\u6df7\u5408\u6c14\u7684\u7a81\u7834\u66f2\u7ebf\uff1b(g) ZnFPCP\u4e0e\u5df2\u62a5\u9053\u6750\u6599\u5728C<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\u5206\u79bb\u4e2d\u9ad8\u7eaf\u70ef\u70c3\u4ea7\u7387\u7684\u5bf9\u6bd4\uff1b(h) ZnFPCP\u4e0e\u5df2\u62a5\u9053\u6750\u6599\u5728C<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\u5206\u79bb\u4e2d\u9ad8\u7eaf\u70ef\u70c3\u4ea7\u7387\u7684\u5bf9\u6bd4\uff1b(i) ZnFPCP\u5728298 K\u30011.0 bar\u4e0b\u8fdb\u884cC<sub>3<\/sub>H<sub>8<\/sub>\/C<sub>3<\/sub>H<sub>6<\/sub>\uff0850\/50, v\/v, 2.0 mL\/min\uff09\u53caC<sub>2<\/sub>H<sub>6<\/sub>\/C<sub>2<\/sub>H<sub>4<\/sub>\uff0850\/50, v\/v, 2.0 mL\/min\uff09\u5206\u79bb\u7684\u5faa\u73af\u7a81\u7834\u6d4b\u8bd5<\/p>\n<p><strong><b>\u603b\u7ed3\u5c55\u671b<\/b><\/strong><\/p>\n<p>\u672c\u5de5\u4f5c\u901a\u8fc7\u7cbe\u5999\u8bbe\u8ba1\u5200\u7247\u72b6\u73af\u82ef\u7eb3\u7c73\u9631\uff0c\u6210\u529f\u6784\u7b51\u51fa\u4e00\u79cd\u517c\u5177<strong><b>\u9ad8\u70f7\u70c3\u9009\u62e9\u6027\u3001\u8d85\u758f\u6c34\u6027\u3001\u4f4e\u538b\u9ad8\u6548\u5438\u9644\u3001\u4f18\u5f02\u5faa\u73af\u7a33\u5b9a\u6027<\/b><\/strong>\u7684\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269ZnFPCP\uff0c\u5f00\u8f9f\u4e86\u8f7b\u70ef\u70c3\u7eff\u8272\u5206\u79bb\u65b0\u8def\u5f84\u3002\u8fd9\u4e00\u6210\u679c\u4e0d\u4ec5\u4e3a\u5de5\u4e1a\u4e0a\u5b9e\u73b0<strong><b>\u4f4e\u80fd\u8017\u3001\u4f4e\u78b3\u6392\u3001\u9ad8\u6548\u7387<\/b><\/strong>\u7684\u70ef\u70c3\u63d0\u7eaf\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u4e5f\u4e3a\u672a\u6765\u5f00\u53d1\u9002\u5e94\u6781\u7aef\u73af\u5883\u7684\u65b0\u578b\u6c14\u4f53\u5206\u79bb\u6750\u6599\u63d0\u4f9b\u4e86\u91cd\u8981\u542f\u793a\u3002<\/p>\n<p>\u76f8\u5173\u5de5\u4f5c\u4ee5\u201c<strong><b>Benchmark Paraffin Adsorption in a Super-Hydrophobic Porous Coordination Polymer with Blade-like Circular Phenyl Nanotraps<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u5c16\u671f\u520a<strong><em><b><i>Angewandte Chemie International Edition<\/i><\/b><\/em><\/strong>\u4e0a\uff0c\u5e76\u5165\u9009\u671f\u520aVIP\u8bba\u6587\u3002\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a\u65e5\u672c\u5b66\u672f\u632f\u5174\u4f1a\uff08JSPS\uff09\u7814\u7a76\u5458\u4eac\u90fd\u5927\u5b66<strong><b>\u9648\u5bcc\u5f3a<\/b><\/strong>\u535a\u58eb\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u4e3a\u4eac\u90fd\u5927\u5b66<strong><b>\u5317\u5ddd\u9032\uff08Susumu Kitagawa\uff09<\/b><\/strong>\u9662\u58eb\u548c<strong><b>\u5927\u7af9\u7814\u4e00\uff08Ken-ichi Otake\uff09<\/b><\/strong>\u7279\u5b9a\u526f\u6559\u6388\u3002\u8bba\u6587\u94fe\u63a5\uff1a<a href=\"https:\/\/doi.org\/10.1002\/anie.202423371\">https:\/\/doi.org\/10.1002\/anie.202423371<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u00a0 \u5728\u77f3\u5316\u5de5\u4e1a\u4e2d\uff0c\u8f7b\u8d28\u70ef\u70c3\uff08\u5982\u4e19\u70efC3H6\u3001\u4e59\u70efC2H4\uff09\u662f\u6781\u5176\u91cd\u8981\u7684\u57fa\u7840\u539f\u6599\uff0c\u5e7f\u6cdb\u7528\u4e8e\u5851\u6599\u3001\u5408\u6210\u6a61\u80f6\u3001\u6d82\u6599\u7b49\u4e0b\u6e38\u4ea7\u54c1\u7684\u5236\u5907\u3002\u7136\u800c\uff0c\u8f7b\u70ef\u70c3\u751f\u4ea7\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u907f\u514d\u5730\u4ea7&#8230;<\/p>\n","protected":false},"author":14360,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-266553","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/266553"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/14360"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=266553"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/266553\/revisions"}],"predecessor-version":[{"id":266562,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/266553\/revisions\/266562"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=266553"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=266553"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=266553"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}