{"id":268012,"date":"2025-08-21T09:50:32","date_gmt":"2025-08-21T01:50:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=268012"},"modified":"2025-08-21T09:50:33","modified_gmt":"2025-08-21T01:50:33","slug":"%e5%8d%8e%e4%ba%ba%e5%ad%a6%e8%80%85%e5%91%a8%e5%85%89%e6%96%87%e6%9c%80%e6%96%b0nature%ef%bc%9a%e6%b0%a7%e5%8c%96%e7%89%a9%e8%bf%98%e5%8e%9f%e6%9c%ba%e5%88%b6%e6%96%b0%e8%a7%a3","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=268012","title":{"rendered":"\u534e\u4eba\u5b66\u8005\u5468\u5149\u6587\u6700\u65b0Nature\uff1a\u6c27\u5316\u7269\u8fd8\u539f\u673a\u5236\u65b0\u89e3"},"content":{"rendered":"\n<p>\u666f\u884c<\/p>\n\n\n\n<p><strong>\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011<\/strong><strong>&nbsp;<\/strong><\/p>\n\n\n\n<p>\u6c27\u5316\u7269\u8fd8\u539f\u8fc7\u7a0b\u5bf9\u63a8\u52a8\u91d1\u5c5e\u5236\u5907\u3001\u50ac\u5316\u53ca\u80fd\u6e90\u6280\u672f\u53d1\u5c55\u81f3\u5173\u91cd\u8981\uff0c\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\u4e0e\u6c22\u6c14\uff08H<sub>2<\/sub>\uff09\u662f\u8be5\u8fc7\u7a0b\u4e2d\u5e7f\u6cdb\u5e94\u7528\u7684\u8fd8\u539f\u5242\uff0c\u4f20\u7edf\u89c2\u70b9\u8ba4\u4e3a\u4e8c\u8005\u4f5c\u7528\u673a\u5236\u76f8\u4f3c\uff0c\u5747\u901a\u8fc7\u79fb\u9664\u6676\u683c\u6c27\u5b9e\u73b0\u8fd8\u539f\u3002\u7136\u800c\uff0c\u968f\u7740\u4ee5H<sub>2<\/sub>\u66ff\u4ee3CO\u4ee5\u964d\u4f4e\u4e8c\u6c27\u5316\u78b3\uff08CO<sub>2<\/sub>\uff09\u6392\u653e\u7684\u9700\u6c42\u65e5\u76ca\u589e\u957f\uff0c\u533a\u5206\u8fd9\u4e24\u79cd\u6c14\u4f53\u7684\u7279\u5f02\u6027\u8fd8\u539f\u8def\u5f84\u53d8\u5f97\u5c24\u4e3a\u5173\u952e\u3002\u76ee\u524d\uff0c\u5728\u53cd\u5e94\u6027\u6c14\u4f53\u6c1b\u56f4\u4e0e\u9ad8\u6e29\u6761\u4ef6\u4e0b\u6355\u83b7\u6c27\u5316\u7269\u8fd8\u539f\u7684\u539f\u5b50\u5c3a\u5ea6\u8fc7\u7a0b\u4ecd\u9762\u4e34\u6311\u6218\uff0c\u800c\u73af\u5883\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u5177\u5907\u5bf9\u6c14-\u56fa\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8fdb\u884c\u5b9e\u65f6\u3001\u539f\u5b50\u5206\u8fa8\u7387\u6210\u50cf\u7684\u80fd\u529b\uff0c\u4e3a\u76f4\u63a5\u89c2\u6d4b\u6c27\u5316\u954d\uff08NiO\uff09\u4e2d\u6c14\u4f53\u4f9d\u8d56\u6027\u7684\u8fd8\u539f\u52a8\u6001\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002<\/p>\n\n\n\n<p><strong>\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8fd1\u65e5\uff0c<strong>\u7f8e\u56fd\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5bbe\u6c49\u59c6\u987f\u5206\u6821\u5468\u5149\u6587\u8bfe\u9898\u7ec4<\/strong>\u4ee5NiO\u4e3a\u5bf9\u8c61\uff0c<strong>\u501f\u52a9\u73af\u5883\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08<\/strong><strong>ETEM<\/strong><strong>\uff09\u5b9e\u73b0\u4e86<\/strong><strong>400<\/strong><strong>\u2103<\/strong><strong>\u4e0b<\/strong><strong>CO<\/strong><strong>\u4e0e<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u6c14\u6c1b\u4e2d<\/strong><strong>NiO<\/strong><strong>\u8fd8\u539f\u8fc7\u7a0b\u7684\u5b9e\u65f6\u539f\u5b50\u5206\u8fa8\u7387\u6210\u50cf<\/strong>\uff0c\u5e76\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u3001\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u3001\u8fd1\u5e38\u538bX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08NAP-XPS\uff09\u53ca\u6b8b\u4f59\u6c14\u4f53\u5206\u6790\u4eea\uff08RGA\uff09\u7b49\u624b\u6bb5\uff0c<strong>\u63ed\u793a\u4e86\u4e24\u79cd\u6c14\u4f53\u8fd8\u539f<\/strong><strong>NiO<\/strong><strong>\u7684\u5dee\u5f02\u5316\u539f\u5b50\u8def\u5f84<\/strong>\u3002\u7814\u7a76\u53d1\u73b0\uff0cCO\u901a\u8fc7\u4f18\u5148\u5438\u9644\u4e8eNiO\u8868\u9762\u53f0\u9636\u8fb9\u7f18\u4e0e\u6676\u683c\u6c27\u53cd\u5e94\u751f\u6210CO<sub>2<\/sub>\uff0c\u4ea7\u751f\u7684\u6c27\u7a7a\u4f4d\uff08V<sub>o<\/sub>\uff09\u5c40\u9650\u4e8e\u8868\u9762\uff0c\u4fc3\u4f7f\u91ca\u653e\u7684Ni\u539f\u5b50\u805a\u96c6\u5f62\u6210\u91d1\u5c5eNi\u5c9b\uff0c\u6700\u7ec8\u56e0Ni\u5c42\u9694\u7edd\u6c14\u4f53\u800c\u5448\u73b0\u81ea\u9650\u6027\u8868\u9762\u91d1\u5c5e\u5316\u7279\u5f81\uff1b\u800cH<sub>2<\/sub>\u89e3\u79bb\u4ea7\u751f\u7684\u8d28\u5b50\u4f1a\u6e17\u5165NiO\u6676\u683c\uff0c\u964d\u4f4eV<sub>o<\/sub>\u8fc1\u79fb\u80fd\u5792\uff0c\u63a8\u52a8\u5176\u5411\u4f53\u76f8\u805a\u7c7b\uff0c\u89e6\u53d1\u8868\u9762-\u4f53\u76f8\u7ed3\u5408\u7684\u8f6c\u53d8\uff0c\u5b9e\u73b0\u65e0\u81ea\u9650\u6027\u7684\u4f53\u76f8\u91d1\u5c5e\u5316\uff0c\u4e14\u5b58\u5728\u7ea615\u5206\u949f\u7684Ni\u751f\u6210\u8bf1\u5bfc\u671f\u3002\u6b64\u5916\uff0c\u539f\u4f4dXRD\u3001NAP-XPS\u4e0eRGA\u5206\u522b\u4ece\u6676\u4f53\u7ed3\u6784\u3001\u8868\u9762\u5316\u5b66\u6001\u53ca\u53cd\u5e94\u4ea7\u7269\u89d2\u5ea6\u9a8c\u8bc1\u4e86\u4e0a\u8ff0\u5dee\u5f02\uff0cDFT\u8ba1\u7b97\u8fdb\u4e00\u6b65\u4ece\u80fd\u91cf\u5c42\u9762\u89e3\u91ca\u4e86H<sup>+<\/sup>\u5bf9V<sub>o<\/sub>\u8fc1\u79fb\u7684\u4fc3\u8fdb\u4f5c\u7528\u3002\u8be5\u6210\u679c\u8fd8\u8bc1\u5b9e\u6c14\u4f53\u4f9d\u8d56\u6027\u8fd8\u539f\u884c\u4e3a\u5728Cu\u3001Fe\u6c27\u5316\u7269\u4e2d\u540c\u6837\u5b58\u5728\uff0c\u4e3a\u8c03\u63a7\u6c27\u5316\u7269\u5316\u5b66\u8ba1\u91cf\u6bd4\u3001\u76f8\u7ed3\u6784\u53ca\u7f3a\u9677\u5206\u5e03\uff0c\u8fdb\u800c\u6307\u5bfc\u51b6\u91d1\u5de5\u827a\u4e0e\u50ac\u5316\u5242\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u5173\u952e\u8ba4\u8bc6\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"912\" height=\"881\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/08\/c4ca4238a0b9238-1.jpg\" alt=\"\" class=\"wp-image-268017\" \/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>1 NiO<\/strong><strong>\u5728<\/strong><strong>CO<\/strong><strong>\u4e2d\u8fd8\u539f\u52a8\u6001\u7684\u539f\u4f4d<\/strong><strong>TEM<\/strong><strong>\u89c2\u6d4b\u3002\uff08<\/strong><strong>a<\/strong><strong>\uff09\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>400<\/strong><strong>\u2103\u4e0b\u3001<\/strong><strong>CO<\/strong><strong>\u538b\u529b\u5206\u522b\u7ea6\u4e3a<\/strong><strong>0.03 Pa<\/strong><strong>\u548c<\/strong><strong>1 Pa<\/strong><strong>\u65f6<\/strong><strong>NiO<\/strong><strong>\u8fd8\u539f\u7684\u65f6\u95f4\u5206\u8fa8<\/strong><strong>HRTEM<\/strong><strong>\u56fe\u50cf\uff0c\u6355\u6349<\/strong><strong>NiO<\/strong><strong>\u8868\u9762\u91d1\u5c5e<\/strong><strong>Ni<\/strong><strong>\u5c9b\uff08\u9752\u8272\u533a\u57df\uff09\u7684\u5f62\u6838\u4e0e\u751f\u957f\uff0c\u767d\u8272\u7bad\u5934\u8ffd\u8e2a\u539f\u5b50\u53f0\u9636\u8fb9\u7f18\u540e\u9000\uff08<\/strong><strong>0 s<\/strong><strong>\u3001<\/strong><strong>382 s<\/strong><strong>\uff09\u548c\u8868\u9762\u70b9\u8680\u65b0\u53f0\u9636\uff08<\/strong><strong>964 s<\/strong><strong>\uff09\uff0c\u7ea2\u8272\u7bad\u5934\u7a81\u51fa<\/strong><strong>Ni\/NiO<\/strong><strong>\u754c\u9762\uff08\u767d\u8272\u865a\u7ebf\uff09\u5411\u5185\u6269\u5c55\uff0c\u84dd\u8272\u201c<\/strong><strong>T<\/strong><strong>\u201d\u8868\u754c\u9762\u5931\u914d\u4f4d\u9519\uff1b\uff08<\/strong><strong>b<\/strong><strong>\uff09\uff08<\/strong><strong>d<\/strong><strong>\uff09\u5206\u522b\u5bf9\u5e94\uff08<\/strong><strong>a<\/strong><strong>\uff09\uff08<\/strong><strong>c<\/strong><strong>\uff09\u7684\u884d\u5c04\u56fe\uff0c\u663e\u793a\u4ece\u7eaf<\/strong><strong>NiO<\/strong><strong>\uff08<\/strong><strong>0 s<\/strong><strong>\uff09\u5230<\/strong><strong>CO<\/strong><strong>\u66b4\u9732\u540e<\/strong><strong>Ni<\/strong><strong>\u4e0e<\/strong><strong>NiO<\/strong><strong>\u5171\u5b58\u7684\u8f6c\u53d8\uff1b\uff08<\/strong><strong>e<\/strong><strong>\uff09\u793a\u610f\u56fe\u793a\u8868\u9762\u5f62\u6838\u548c<\/strong><strong>Ni<\/strong><strong>\u5c9b\u751f\u957f\u5f62\u6210<\/strong><strong>Ni<\/strong><strong>\u8986\u76d6\u5c42\uff0c\u5b9e\u73b0\u81ea\u9650\u6027\u8868\u9762\u91d1\u5c5e\u5316\u3002<\/strong><strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n<p>\u5728CO\u6c14\u6c1b\u4e2d\uff0cCO\u4f18\u5148\u5438\u9644\u4e8eNiO\u8868\u9762\u53f0\u9636\u8fb9\u7f18\uff0c\u4e0e\u6676\u683c\u6c27\u53cd\u5e94\u751f\u6210CO<sub>2<\/sub>\u5e76\u8131\u9644\uff0c\u540c\u65f6\u4ea7\u751f\u7684\u6c27\u7a7a\u4f4d\uff08V<sub>o<\/sub>\uff09\u4ec5\u5c40\u9650\u4e8e\u8868\u5c42\uff0c\u91ca\u653e\u7684Ni\u539f\u5b50\u5728\u8868\u9762\u805a\u96c6\u5f62\u6210\u91d1\u5c5eNi\u5c9b\uff1b\u968f\u7740Ni\u5c9b\u5408\u5e76\u5f62\u6210\u8fde\u7eed\u8868\u5c42\uff0c\u7269\u7406\u9694\u7eddCO\u4e0eNiO\u672c\u4f53\uff0c\u6700\u7ec8\u5448\u73b0\u81ea\u9650\u6027\u8868\u9762\u91d1\u5c5e\u5316\uff0c\u5373\u4f7f\u5347\u6e29\u81f3500-600\u2103\u4e5f\u65e0\u6cd5\u5b9e\u73b0NiO\u5b8c\u5168\u8fd8\u539f\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"869\" height=\"815\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/08\/1-3.jpg\" alt=\"\" class=\"wp-image-268018\" \/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>2 NiO<\/strong><strong>\u5728<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u4e2d\u8fd8\u539f\u7684\u539f\u4f4d<\/strong><strong>TEM<\/strong><strong>\u6210\u50cf\u3002\uff08<\/strong><strong>a<\/strong><strong>\uff09\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>400<\/strong><strong>\u2103\u4e0b\u3001<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u538b\u529b\u5206\u522b\u7ea6\u4e3a<\/strong><strong>0.016 Pa<\/strong><strong>\u548c<\/strong><strong>0.08 Pa<\/strong><strong>\u65f6<\/strong><strong>NiO<\/strong><strong>\u8fd8\u539f\u7684\u539f\u4f4d<\/strong><strong>HRTEM<\/strong><strong>\u56fe\u50cf\uff0c\u663e\u91d1\u5c5e<\/strong><strong>Ni<\/strong><strong>\uff08\u9752\u8272\u9634\u5f71\uff09\u4ece<\/strong><strong>NiO<\/strong><strong>\u4f53\u76f8\u5f62\u6210\uff0c\u767d\u8272\u7bad\u5934\u8ffd\u8e2a\u8868\u9762\u53f0\u9636\u540e\u9000\uff0c\u7d2b\u8272\u9634\u5f71\u663e\u8868\u9762\u65b0<\/strong><strong>NiO<\/strong><strong>\uff0c\u653e\u5927\u56fe\u663e\u65b0<\/strong><strong>NiO<\/strong><strong>\u4e2d\u4f4d\u9519\uff0c\u84dd\u8272\u865a\u7ebf\u8ffd<\/strong><strong>0 s NiO<\/strong><strong>\u521d\u59cb\u8868\u9762\u8f6e\u5ed3\u793a\u4f53\u79ef\u6536\u7f29\uff0c\u7ea2\u8272\u7bad\u5934\u663e<\/strong><strong>Ni\/NiO<\/strong><strong>\u754c\u9762\uff08\u767d\u8272\u865a\u7ebf\uff09\u5916\u6269\uff0c\u84dd\u8272\u201c<\/strong><strong>T<\/strong><strong>\u201d\u8868\u754c\u9762\u5931\u914d\u4f4d\u9519\uff0c\u63d2\u56fe\u4e3a\u884d\u5c04\u56fe\u663e\u7eaf<\/strong><strong>NiO<\/strong><strong>\u5230<\/strong><strong>Ni<\/strong><strong>\u4e0e<\/strong><strong>NiO<\/strong><strong>\u5171\u5b58\u7684\u8f6c\u53d8\uff1b\uff08<\/strong><strong>b<\/strong><strong>\uff09\uff08<\/strong><strong>d<\/strong><strong>\uff09\u5206\u522b\u5bf9\u5e94\uff08<\/strong><strong>a<\/strong><strong>\uff09\uff08<\/strong><strong>c<\/strong><strong>\uff09\u7684<\/strong><strong>NiO<\/strong><strong>\uff08\u51cf\u5c0f\uff09\u548c<\/strong><strong>Ni<\/strong><strong>\uff08\u589e\u5927\uff09\u6295\u5f71\u9762\u79ef\u968f\u65f6\u95f4\u53d8\u5316\u66f2\u7ebf\uff1b\uff08<\/strong><strong>e<\/strong><strong>\uff09\u793a\u610f\u56fe\u793a<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u8bf1\u5bfc<\/strong><strong>NiO<\/strong><strong>\u8fd8\u539f\u5173\u952e\u6b65\u9aa4\uff0c\u4ece<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u5438\u9644\u9a71\u52a8\u53f0\u9636\u540e\u9000\u5230\u6676\u683c\u6c27\u518d\u6c27\u5316<\/strong><strong>Ni<\/strong><strong>\u5438\u9644\u539f\u5b50\u3001<\/strong><strong>V<sub>o<\/sub><\/strong><strong>\u878d\u5165\u4f53\u76f8\uff0c\u6700\u7ec8\u5b9e\u73b0\u4f53\u76f8\u91d1\u5c5e\u5316\u3002<\/strong><strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n<p>\u800c\u5728H<sub>2<\/sub>\u6c14\u6c1b\u4e2d\uff0cH<sub>2<\/sub>\u89e3\u79bb\u4ea7\u751f\u7684\u8d28\u5b50\u4f1a\u6e17\u5165NiO\u6676\u683c\uff0c\u663e\u8457\u964d\u4f4eV\u2092\u8fc1\u79fb\u80fd\u5792\uff08\u4ece\u65e0H\u65f6\u76843.03 eV\u964d\u81f31.81 eV\uff09\uff0c\u63a8\u52a8V<sub>o<\/sub>\u5411\u4f53\u76f8\u805a\u7c7b\u5e76\u89e6\u53d1\u4f53\u76f8\u5185Ni<sup>2+<\/sup>\u5411Ni<sup>o<\/sup>\u7684\u8f6c\u53d8\uff0c\u4f34\u968fNiO\u6676\u7c92\u56e0\u4f53\u79ef\u6536\u7f29\u53d1\u751f\u503e\u659c\uff1b\u8be5\u8fc7\u7a0b\u5b58\u5728\u7ea615\u5206\u949f\u7684Ni\u751f\u6210\u8bf1\u5bfc\u671f\uff0c\u4e14\u65e0\u81ea\u9650\u6027\uff0c\u6700\u7ec8\u53ef\u5b9e\u73b0NiO\u5b8c\u5168\u4f53\u76f8\u91d1\u5c5e\u5316\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"951\" height=\"897\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/08\/3-1.png\" alt=\"\" class=\"wp-image-268019\" \/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>3 NiO<\/strong><strong>\u8fd8\u539f\u7684\u539f\u4f4d<\/strong><strong>XRD<\/strong><strong>\u3001<\/strong><strong>NAP-XPS<\/strong><strong>\u4e0e<\/strong><strong>RGA<\/strong><strong>\u8868\u5f81\uff08<\/strong><strong>400<\/strong><strong>\u2103\uff09\u3002\uff08<\/strong><strong>a<\/strong><strong>\uff09<\/strong><strong>NiO<\/strong><strong>\u5728<\/strong><strong>5% CO\/He<\/strong><strong>\uff08<\/strong><strong>CO<\/strong><strong>\u7ea6<\/strong><strong>5\u00d710<sup>3<\/sup> Pa<\/strong><strong>\uff09\u4e0b\u8fd8\u539f\u7684\u539f\u4f4d\u540c\u6b65\u8f90\u5c04<\/strong><strong>XRD<\/strong><strong>\u56fe\uff08\u6ce2\u957f<\/strong><strong>0.6199 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Pa<\/strong><strong>\uff09\u4e0b\u8fd8\u539f\u7684\u65f6\u95f4\u5206\u8fa8<\/strong><strong>XRD<\/strong><strong>\u56fe\uff0c\u663e\u793a\u8bf1\u5bfc\u671f\u540e<\/strong><strong>Ni<\/strong><strong>\uff08<\/strong><strong>111<\/strong><strong>\uff09\u3001\uff08<\/strong><strong>200<\/strong><strong>\uff09\u3001\uff08<\/strong><strong>220<\/strong><strong>\uff09\u5cf0\u5feb\u901f\u589e\u5f3a\uff1b\uff08<\/strong><strong>c<\/strong><strong>\uff09<\/strong><strong>NiO<\/strong><strong>\uff08<\/strong><strong>111<\/strong><strong>\uff09\u5cf0\u5f3a\u5ea6\u5728<\/strong><strong>CO<\/strong><strong>\u548c<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u4e0b\u7684\u5f52\u4e00\u5316\u65f6\u95f4\u53d8\u5316\uff1b\uff08<\/strong><strong>d<\/strong><strong>\uff09\uff08<\/strong><strong>e<\/strong><strong>\uff09<\/strong><strong>NiO<\/strong><strong>\u5728\u7ea6<\/strong><strong>13 Pa CO<\/strong><strong>\u4e2d\u8fd8\u539f\u65f6<\/strong><strong>O 1s<\/strong><strong>\u3001<\/strong><strong>Ni 2p<\/strong><strong>\u7684<\/strong><strong>NAP-XPS<\/strong><strong>\u65f6\u95f4\u6f14\u5316\uff1b\uff08<\/strong><strong>f<\/strong><strong>\uff09\uff08<\/strong><strong>g<\/strong><strong>\uff09<\/strong><strong>NiO<\/strong><strong>\u5728\u7ea6<\/strong><strong>13 Pa H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u4e2d\u8fd8\u539f\u65f6<\/strong><strong>O 1s<\/strong><strong>\u3001<\/strong><strong>Ni 2p<\/strong><strong>\u7684<\/strong><strong>NAP-XPS<\/strong><strong>\u65f6\u95f4\u6f14\u5316\uff1b\uff08<\/strong><strong>h<\/strong><strong>\uff09<\/strong><strong>CO<\/strong><strong>\u548c<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>\u4e0b<\/strong><strong>Ni<sup>2+<\/sup><\/strong><strong>\u3001<\/strong><strong>Ni<sup>0<\/sup><\/strong><strong>\u3001\u6676\u683c\u6c27\u53ca<\/strong><strong>OH<\/strong><strong>\u4fe1\u53f7\u7684\u65f6\u95f4\u53d8\u5316\uff08<\/strong><strong>Ni 2p<\/strong><strong>\u3001<\/strong><strong>O 1s<\/strong><strong>\u4fe1\u53f7\u5f52\u4e00\u5316\u81f3\u80cc\u666f\uff09\uff1b\uff08<\/strong><strong>i<\/strong><strong>\uff09\u4ea7\u7269\u6c14<\/strong><strong>CO<\/strong><strong><sub>2<\/sub><\/strong><strong>\u548c<\/strong><strong>H<\/strong><strong><sub>2<\/sub><\/strong><strong>O<\/strong><strong>\u6d53\u5ea6\u7684\u65f6\u95f4\u53d8\u5316\uff0c\u7531\u4e0e<\/strong><strong>XRD<\/strong><strong>\u540c\u6b65\u7684<\/strong><strong>RGA<\/strong><strong>\u5b9a\u91cf\uff0c<\/strong><strong>cps<\/strong><strong>\u4e3a\u8ba1\u6570\u6bcf\u79d2\u3002<\/strong><strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n<figure class=\"wp-block-gallery has-nested-images columns-default is-cropped wp-block-gallery-1 is-layout-flex wp-block-gallery-is-layout-flex\">\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"1323\" height=\"760\" data-id=\"268020\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/08\/4-2.png\" alt=\"\" class=\"wp-image-268020\" 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2025 Springer Nature<\/strong><\/p>\n\n\n\n<p>\u6b64\u5916\uff0c\u539f\u4f4dXRD\u663e\u793aCO\u8fd8\u539f\u65f6Ni\u7279\u5f81\u5cf0\u5f31\u4e14\u4e0d\u589e\u957f\u3001NiO\u5cf0\u65e0\u660e\u663e\u4e0b\u964d\uff0c\u800cH<sub>2<\/sub>\u8fd8\u539f\u65f6Ni\u5cf0\u5ef6\u8fdf\u51fa\u73b0\u540e\u6301\u7eed\u589e\u5f3a\u3001NiO\u5cf0\u9010\u6e10\u6d88\u5931\uff1bNAP-XPS\u4e0eRGA\u5206\u522b\u4ece\u8868\u9762\u5316\u5b66\u6001\uff08O 1s\u3001Ni 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X., Wang, J., Patel, S.B. et al. Atomic dynamics of gas-dependent oxide reducibility. Nature (2025). https:\/\/doi.org\/10.1038\/s41586-025-09394-0<\/p>\n\n\n\n<p><strong>\u672c\u6587\u7531\u666f\u884c\u64b0\u7a3f<\/strong><strong><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u666f\u884c \u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011&nbsp; \u6c27\u5316\u7269\u8fd8\u539f\u8fc7\u7a0b\u5bf9\u63a8\u52a8\u91d1\u5c5e\u5236\u5907\u3001\u50ac\u5316\u53ca\u80fd\u6e90\u6280\u672f\u53d1\u5c55\u81f3\u5173\u91cd\u8981\uff0c\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\u4e0e\u6c22\u6c14\uff08H2\uff09\u662f\u8be5\u8fc7\u7a0b\u4e2d\u5e7f\u6cdb\u5e94\u7528\u7684\u8fd8\u539f\u5242\uff0c\u4f20\u7edf\u89c2\u70b9&#8230;<\/p>\n","protected":false},"author":36004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-268012","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268012"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=268012"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268012\/revisions"}],"predecessor-version":[{"id":268022,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268012\/revisions\/268022"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=268012"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=268012"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=268012"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}