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\u666f\u884c<\/p>\n\n\n\n

\u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011  <\/strong><\/strong><\/p>\n\n\n\n

\u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08TPSCs\uff09\u4f5c\u4e3a\u65e0\u94c5\u4e14\u73af\u5883\u53cb\u597d\u7684\u5668\u4ef6\uff0c\u5df2\u6210\u4e3a\u94c5\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6f5c\u5728\u66ff\u4ee3\u65b9\u6848\uff0c\u5176\u5012\u7f6e\u7ed3\u6784\u7684\u8ba4\u8bc1\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u5df2\u8d85\u8fc716%\uff0c\u4e14\u7406\u8bba\u4e0a\u56e0\u7406\u60f3\u5e26\u9699\u652f\u6301\u8d85\u8fc733%\u7684PCE\uff0c\u4f46\u5b9e\u9645\u6027\u80fd\u4e0e\u7a33\u5b9a\u6027\u4ecd\u5927\u5e45\u843d\u540e\uff0c\u90e8\u5206\u539f\u56e0\u5728\u4e8e\u6b21\u4f18\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08HTL\uff09\u53ca\u4e0d\u826f\u7684\u57cb\u5e95\u754c\u9762\u963b\u788d\u4e86\u7a7a\u7a74\u63d0\u53d6\u3002\u5f53\u524d\u9ad8\u6027\u80fd\u5012\u7f6eTPSCs\u5e38\u91c7\u7528\u805a\uff083,4-\u4e59\u6491\u4e8c\u6c27\u567b\u5429\uff09-\u805a\u82ef\u4e59\u70ef\u78fa\u9178\u76d0\uff08PEDOT:PSS\uff09\u4f5c\u4e3aHTL\uff0c\u4f46\u5176\u5438\u6e7f\u6027\u4e0e\u9178\u6027\u4f1a\u52a0\u901f\u9521\u57fa\u9499\u949b\u77ff\u7684\u964d\u89e3\u548c\u6c27\u5316\uff0c\u4e14\u5bf9\u7d2b\u5916\u5149\u4e0e\u6e7f\u6c14\u9ad8\u5ea6\u654f\u611f\uff1b\u6c27\u5316\u954d\uff08NiOx<\/sub>\uff09\u867d\u56e0\u8f7d\u6d41\u5b50\u4f20\u8f93\u6548\u7387\u9ad8\u3001\u7a33\u5b9a\u6027\u4f18\u3001\u5236\u5907\u7b80\u4fbf\u800c\u88ab\u89c6\u4e3a\u66ff\u4ee3HTL\uff0c\u4f46\u5176\u5728\u5012\u7f6eTPSCs\u4e2d\u7684\u5e94\u7528\u53d7\u9650\u4e8e\u80fd\u7ea7\u5339\u914d\u5dee\u3001\u6c27\u7a7a\u4f4d\u53ca\u754c\u9762\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u8fd9\u4e9b\u95ee\u9898\u5747\u4f1a\u963b\u788d\u7a7a\u7a74\u63d0\u53d6\u5e76\u52a0\u901f\u9521\u57fa\u9499\u949b\u77ff\u964d\u89e3\u3002\u6b64\u5916\uff0c\u6b64\u524d\u7528\u4e8e\u4fee\u9970\u5012\u7f6e\u94c5\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08LPSCs\uff09HTL\u7684\u81ea\u7ec4\u88c5\u5206\u5b50\uff08\u59822PACz\uff09\uff0c\u5728TPSCs\u4e2d\u5b58\u5728\u57fa\u5e95\u8986\u76d6\u4e0d\u5747\u3001\u5bf9\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6db2\u6da6\u6e7f\u6027\u5dee\u7684\u95ee\u9898\uff0c\u4e14\u5176\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08HOMO\uff09\u80fd\u7ea7\uff08\u7ea6-5.6 eV\uff09\u6df1\u4e8e\u9521\u57fa\u9499\u949b\u77ff\u7684\u4ef7\u5e26\u9876\uff08VBM\uff0c\u7ea6-5.1 eV\uff09\uff0c\u9650\u5236\u7a7a\u7a74\u63d0\u53d6\uff0c\u96be\u4ee5\u9002\u914dNiOx<\/sub>\u754c\u9762\uff0c\u751a\u81f3\u53ef\u80fd\u52a0\u5267\u7a7a\u7a74\u63d0\u53d6\u80fd\u529b\u4e0d\u8db3\u4e0e\u754c\u9762\u7f3a\u9677\u95ee\u9898\u3002<\/p>\n\n\n\n

\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/strong><\/p>\n\n\n\n

\u8fd1\u65e5\uff0c\u590d\u65e6\u5927\u5b66\u6881\u4f73\u9752\u5e74\u7814\u7a76\u5458\u3001\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u621a\u4e9a\u51b0\u6559\u6388\u548c\u5357\u4eac\u7406\u5de5\u5927\u5b66\u5f90\u52c3\u6559\u6388<\/strong>\u7b49\u5408\u4f5c\uff0c\u9488\u5bf9\u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08TPSCs\uff09\u6027\u80fd\u4e0e\u7a33\u5b9a\u6027\u4e0d\u8db3\u7684\u95ee\u9898\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\uff08Z\uff09-3-\uff084’\uff0c5′-\u53cc\uff084-\uff08\u53cc\uff084-\u7532\u6c27\u57fa\u82ef\u57fa\uff09\u6c28\u57fa\uff09\u82ef\u57fa\uff09-[2,2′-\u8054\u567b\u5429]-5-\u57fa\uff09-2-\u6c30\u57fa\u4e19\u70ef\u9178\uff08MBC\uff09\u548c\uff08E\uff09-\uff082-\uff084’\uff0c5′-\u53cc\uff084-\uff08\u53cc\uff084-\u7532\u6c27\u57fa\u82ef\u57fa\uff09\u6c28\u57fa\uff09\u82ef\u57fa\uff09-[2,2′-\u8054\u567b\u5429]-5-\u57fa\uff09-1-\u6c30\u57fa\u4e59\u70ef\u57fa\uff09\u81a6\u9178\uff08MBP\uff09\u4e24\u79cd\u65b0\u578b\u5206\u5b50\uff0c\u7528\u4e8e\u4fee\u9970NiOx<\/sub> HTL\u4ee5\u4f18\u5316\u57cb\u5e95\u754c\u9762\u3002\u5176\u4e2dMBP\u53ef\u5f62\u6210\u5747\u5300\u754c\u9762\u5c42\uff08\u7c97\u7cd9\u5ea61.87 nm\uff0c\u8fdc\u4f4e\u4e8e\u4f20\u7edf2PACz\u76846.04 nm\uff09\uff0c\u5b9e\u73b0\u4e0e\u9521\u57fa\u9499\u949b\u77ff\u7684\u80fd\u7ea7\u7cbe\u51c6\u5339\u914d\uff08HOMO -4.95 eV\uff0c\u63a5\u8fd1\u9499\u949b\u77ffVBM -5.10 eV\uff09\uff0c\u4e14\u6784\u5efa\u8d85\u6d78\u6da6\u5e95\u5c42\uff08\u524d\u9a71\u6db2\u63a5\u89e6\u89d2<10\u00b0\uff09\uff0c\u5f15\u5bfc\u5f62\u6210\u9ad8\u8d28\u91cf\u9499\u949b\u77ff\u819c\uff0c\u51cf\u5c11\u7f3a\u9677\u4e0e\u975e\u8f90\u5c04\u590d\u5408\u3002\u57fa\u4e8e\u6b64\uff0c\u5012\u7f6e\u5c0f\u9762\u79efTPSCs\u83b717.89%\u7684PCE\uff08\u53cd\u5411\u626b\u63cf\u8ba4\u8bc117.71%\uff09\uff0c\u4e3a\u5f53\u524d\u6700\u9ad8\uff1b1 cm2<\/sup>\u5927\u9762\u79ef\u5668\u4ef6PCE\u8fbe14.40%\uff0c\u4f53\u73b0\u826f\u597d\u53ef\u6269\u5c55\u6027\u3002\u7a33\u5b9a\u6027\u65b9\u9762\uff0c\u5c01\u88c5\u5668\u4ef6\u5728\u5e38\u6e29\u50a8\u5b581344 h\u4fdd\u755995%\u4ee5\u4e0a\u521d\u59cbPCE\uff0c1-sun\u5149\u7167\u4e0b\u8fde\u7eed\u5de5\u4f5c1550 h\u4fdd\u755994%\u4ee5\u4e0a\uff0c\u4e14\u9996\u6b21\u5b9e\u73b0NiOx<\/sub>\u57faHTL\u6027\u80fd\u8d85\u8d8a\u4f20\u7edfPEDOT:PSS\uff0c\u63a8\u52a8TPSCs\u5b9e\u7528\u5316\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1\u5206\u5b50\u5747\u5300\u5206\u5e03\u4e0e\u80fd\u7ea7\u4f18\u5316\u52a9\u529b\u7a7a\u7a74\u63d0\u53d6\u548c\u4f20\u8f93\u6027\u80fd\u63d0\u5347\u3002\uff08<\/strong>a-c<\/strong>\uff09<\/strong>NiO<\/strong>x<\/sub><\/strong>\/2PACz<\/strong>\u3001<\/strong>NiO<\/strong>x<\/sub><\/strong>\/MBC<\/strong>\u548c<\/strong>NiO<\/strong>x<\/sub><\/strong>\/MBP<\/strong>\u8584\u819c\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08<\/strong>AFM<\/strong>\uff09\u5f62\u8c8c\u56fe\u3002\uff08d\uff09<\/strong>ITO<\/strong>\u3001<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u3001<\/strong>NiO\u2093\/MBP<\/strong>\u53ca\u9521\u57fa\u9499\u949b\u77ff\uff08<\/strong>Sn-PVSK<\/strong>\uff0c\u5176\u4e2d<\/strong>Sn-PVSK<\/strong>\u4ee3\u8868\u9521\u57fa\u9499\u949b\u77ff\uff09\u7684\u80fd\u7ea7\u56fe\uff1b\uff08e\uff09<\/strong>2PACz<\/strong>\u3001<\/strong>MBC<\/strong>\u548c<\/strong>MBP<\/strong>\u5206\u5b50\u7684\u8ba1\u7b97\u5076\u6781\u77e9\u3002\uff08f\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08<\/strong>HTL<\/strong>\uff09\u4e0a\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\uff08<\/strong>TRPL<\/strong>\uff09\u8870\u51cf\u66f2\u7ebf\u3002\uff08g\uff09<\/strong>2PACz<\/strong>\u3001<\/strong>MBC<\/strong>\u548c<\/strong>MBP<\/strong>\u5206\u5b50\u4e0e<\/strong>NiO\u2093<\/strong>\u8868\u9762\u76f8\u4e92\u4f5c\u7528\u7684\u8ba1\u7b97\u7535\u5b50\u5bc6\u5ea6\u5206\u5e03\u3002\u00a9<\/strong> 2025 Springer Nature<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe2\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728\u57cb\u5e95\u754c\u9762\u7684\u5f62\u8c8c\u4e0e\u7ed3\u6784\u3002\uff08a\uff09<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/2PACz<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u8584\u819c\u5bf9\u6c34\u53ca\u9521\u57fa\u9499\u949b\u77ff\uff08<\/strong>Sn-PVSK<\/strong>\uff09\u524d\u9a71\u6db2\u7684\u63a5\u89e6\u89d2\u6d4b\u8bd5\u7ed3\u679c\uff0c<\/strong>a<\/strong>\u4e2d\u7684\u63d2\u56fe\u4e3a\u9521\u57fa\u9499\u949b\u77ff\u524d\u9a71\u6db2\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/2PACz<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u8584\u819c\u4e0a\u7684\u63a5\u89e6\u89d2\u6570\u7801\u7167\u7247\uff1b\uff08<\/strong>b-d<\/strong>\uff09\u9521\u57fa\u9499\u949b\u77ff\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08<\/strong>HTL<\/strong>\uff09\u4e0a\u57cb\u5e95\u8868\u9762\u5f62\u8c8c\u7684\u5178\u578b\u9876\u89c6\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08<\/strong>SEM<\/strong>\uff09\u56fe\u50cf\u3002\uff08<\/strong>e-g<\/strong>\uff09\u9521\u57fa\u9499\u949b\u77ff\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684\u5178\u578b\u622a\u9762SEM\u56fe\u50cf\u3002\u00a9<\/strong> 2025 Springer Nature<\/strong><\/strong><\/p>\n\n\n\n

\u4f5c\u8005\u901a\u8fc7\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u3001\u5f00\u5c14\u6587\u63a2\u9488\u529b\u663e\u5fae\u955c\uff08KPFM\uff09\u53ca\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff0c\u5bf9\u6bd4NiO\u2093\/2PACz\u3001NiO\u2093\/MBC\u3001NiO\u2093\/MBP\u7684\u754c\u9762\u7279\u6027\uff0c\u53d1\u73b0MBP\u5728NiO\u2093\u8868\u9762\u5f62\u6210\u6700\u5747\u5300\u754c\u9762\u5c42\uff08\u7c97\u7cd9\u5ea61.87 nm\uff0c\u8fdc\u4f4e\u4e8e2PACz\u76846.04 nm\uff09\uff1b\u7ed3\u5408\u7d2b\u5916\u5149\u7535\u5b50\u80fd\u8c31\uff08UPS\uff09\uff0cMBP\u7684\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053\uff08HOMO\uff0c-4.95 eV\uff09\u4e0e\u9521\u57fa\u9499\u949b\u77ff\u4ef7\u5e26\u9876\uff08VBM\uff0c-5.10 eV\uff09\u80fd\u7ea7\u5339\u914d\u6700\u4f18\uff0c\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\uff08TRPL\uff09\u548c\u83ab\u7279-\u8096\u7279\u57fa\u5206\u6790\u9a8c\u8bc1\u5176\u7a7a\u7a74\u63d0\u53d6\u6548\u7387\u63d0\u5347\uff0c\u7535\u5b50\u5bc6\u5ea6\u5206\u5e03\u53ca\u5438\u9644\u80fd\uff08-2.71 eV\uff09\u4e5f\u8868\u660eMBP\u4e0eNiO\u2093\u76f8\u4e92\u4f5c\u7528\u6700\u5f3a\u3002\u901a\u8fc7\u63a5\u89e6\u89d2\u6d4b\u8bd5\uff0c\u663e\u793aMBP\u4fee\u9970\u5c42\u517c\u5177\u9ad8\u6c34\u63a5\u89e6\u89d2\uff08\u9632\u6e7f\u6c14\uff09\u4e0e\u4f4e\u9499\u949b\u77ff\u524d\u9a71\u6db2\u63a5\u89e6\u89d2\uff08<10\u00b0\uff0c\u8d85\u6d78\u6da6\uff09\uff1b\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u89c2\u5bdf\u5230\uff0cNiO\u2093\u4e0a\u9521\u9499\u949b\u77ff\u57cb\u5e95\u8868\u9762\u6709\u9488\u5b54\uff0c\u800cMBP\/MBC\u4fee\u9970\u540e\u65e0\u9488\u5b54\u4e14\u622a\u9762\u7ed3\u6784\u5747\u5300\uff1bGIXRD\u7ed3\u679c\u8868\u660e\uff0cMBP\u4f7f\u9499\u949b\u77ff\u6b8b\u4f59\u538b\u5e94\u529b\u6700\u5c0f\uff0c\u53ef\u7f13\u89e3\u7f3a\u9677\u4e0e\u964d\u89e3\u98ce\u9669\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe3\u9ad8\u7269\u76f8\u7eaf\u5ea6\u964d\u4f4e\u754c\u9762\u80fd\u91cf\u635f\u5931\u3002\uff08<\/strong>a-c<\/strong>\uff09\u4ece<\/strong>PEN\/ITO\/<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08<\/strong>HTL<\/strong>\uff09<\/strong>\/<\/strong>\u9521\u57fa\u9499\u949b\u77ff\u80cc\u9762\u83b7\u53d6\u7684\u63a0\u5165\u5c04\u5e7f\u89d2<\/strong>X<\/strong>\u5c04\u7ebf\u6563\u5c04\uff08<\/strong>GIWAXS<\/strong>\uff09\u56fe\u8c31\uff0c\u5176\u4e2d\u7a7a\u7a74\u4f20\u8f93\u5c42\u5206\u522b\u4e3a<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u3002\uff08d\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684<\/strong>X<\/strong>\u5c04\u7ebf\u884d\u5c04\uff08<\/strong>XRD<\/strong>\uff09\u56fe\u8c31\uff08\u4ece\u5e95\u9762\u4fa7\u6d4b\u91cf\uff09\uff1b\uff08e\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a<\/strong>Sn 3d<\/strong>\u2085<\/strong>\/<\/strong>\u2082<\/strong>\u548c<\/strong>Sn 3d<\/strong>\u2083<\/strong>\/<\/strong>\u2082<\/strong>\u80fd\u7ea7\u533a\u57df\u7684<\/strong>Sn\u2074<\/strong>\u207a<\/strong>\/Sn<\/strong>\u00b2<\/strong>\u207a<\/strong>\u6bd4\u503c\uff1b\uff08f\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08<\/strong>PLQY<\/strong>\uff09\u3002\uff08g\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728\u4e0a\u8ff0\u4e09\u79cd\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684\u4f30\u7b97\u51c6\u8d39\u7c73\u80fd\u7ea7\u5206\u88c2\uff08<\/strong>QFLS<\/strong>\uff09\u4e0e\u5f00\u8def\u7535\u538b\uff08<\/strong>V<\/strong>oc<\/sub><\/strong>\uff09\uff1b\uff08h\uff09\u9521\u57fa\u9499\u949b\u77ff\u5728<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684\u5178\u578b\u9876\u89c6<\/strong>SEM<\/strong>\u5f62\u8c8c\u56fe\uff1b\uff08i\uff09\u9521\u57fa\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u4e0a\u7684\u5149\u81f4\u53d1\u5149\uff08<\/strong>PL<\/strong>\uff09\u56fe\u3002\u00a9<\/strong> 2025 Springer Nature<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe<\/strong>4<\/strong> TPSCs\u7684\u5149\u4f0f\u6027\u80fd\u3002\uff08a\uff09<\/strong>TPSCs<\/strong>\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff0c\u5176\u7ed3\u6784\u4e3a<\/strong>ITO\/<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08<\/strong>HTL<\/strong>\uff09<\/strong>\/<\/strong>\u9521\u57fa\u9499\u949b\u77ff<\/strong>\/ICBA\/BCP\/Ag<\/strong>\uff1b\uff08b\uff09<\/strong>NiO\u2093<\/strong>\u3001<\/strong>NiO\u2093\/MBC<\/strong>\u548c<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u5bf9\u5e94\u7684<\/strong>TPSCs<\/strong>\u5728\u6b63\u5411\u548c\u53cd\u5411\u626b\u63cf\u6a21\u5f0f\u4e0b\u7684\u7535\u6d41<\/strong>–<\/strong>\u7535\u538b\uff08<\/strong>J-V<\/strong>\uff09\u66f2\u7ebf\uff1b\uff08c\uff09<\/strong>NiO\u2093\/MBP<\/strong>\u7a7a\u7a74\u4f20\u8f93\u5c42\u5bf9\u5e94\u7684<\/strong>TPSCs<\/strong>\u5728\u6b63\u5411\u548c\u53cd\u5411\u626b\u63cf\u6a21\u5f0f\u4e0b\u7684\u8ba4\u8bc1<\/strong>J-V<\/strong>\u66f2\u7ebf\uff1b\uff08d\uff09\u672c\u7814\u7a76\u4e0e\u6b64\u524d\u62a5\u9053\u7684\u5012\u7f6e<\/strong>TPSCs<\/strong>\u7684\u8ba4\u8bc1\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08<\/strong>PCE<\/strong>\uff09\u5bf9\u6bd4\uff1b\uff08e\uff09\u4e09\u79cd\u7a7a\u7a74\u4f20\u8f93\u5c42\u5bf9\u5e94\u7684<\/strong>TPSCs<\/strong>\u7684\u5165\u5c04\u5149<\/strong>–<\/strong>\u7535\u6d41\u8f6c\u6362\u6548\u7387\uff08<\/strong>IPCE<\/strong>\uff09\u5149\u8c31\u53ca\u79ef\u5206\u77ed\u8def\u7535\u6d41\u5bc6\u5ea6\uff08<\/strong>J<\/strong>\u209b<\/strong>c<\/strong>\uff09\u503c\uff1b\uff08f\uff09\u4e09\u79cd\u7a7a\u7a74\u4f20\u8f93\u5c42\u5bf9\u5e94\u7684<\/strong>TPSCs<\/strong>\u7684\u5948\u594e\u65af\u7279\u56fe\uff1b\uff08g\uff09\u5c01\u88c5\u540e\u7684<\/strong>TPSCs<\/strong>\u5728\u73af\u5883\u5927\u6c14\u4e2d\u50a8\u5b58<\/strong>1344 h<\/strong>\u4ee5\u4e0a\u7684\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u6bcf\u7ec4<\/strong>7<\/strong>\u4e2a\u5668\u4ef6\u7684\u521d\u59cb\u5e73\u5747<\/strong>PCE<\/strong>\u5206\u522b\u4e3a<\/strong>16.48%<\/strong>\u3001<\/strong>15.2%<\/strong>\u548c<\/strong>11.23%<\/strong>\uff1b\uff08h\uff09\u5c01\u88c5\u540e\u7684<\/strong>TPSCs<\/strong>\u5728\u8fde\u7eed<\/strong>1<\/strong>\u500d\u592a\u9633\u7b49\u6548\u767d\u5149<\/strong>LED<\/strong>\u7167\u5c04\u4e0b\u7684\u5de5\u4f5c\u7a33\u5b9a\u6027<\/strong>\u3002<\/strong>\u00a9<\/strong> 2025 Springer Nature<\/strong><\/strong><\/p>\n\n\n\n

\u4f5c\u8005\u901a\u8fc7\u63a0\u5165\u5c04\u5e7f\u89d2X\u5c04\u7ebf\u6563\u5c04\uff08GIWAXS\uff09\u548cX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u53d1\u73b0\uff0cNiO\u2093\/MBP\u4fee\u9970\u4e0b\u7684\u9499\u949b\u77ffBragg\u6591\u70b9\u6700\u5c16\u9510\u3001XRD\u5cf0\u6700\u5f3a\uff0c\u7269\u76f8\u7eaf\u5ea6\u6700\u9ad8\uff1bX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u663e\u793a\u5176Sn4+<\/sup>\/Sn2+<\/sup>\u6bd4\u503c\u6700\u4f4e\uff0c\u6709\u6548\u6291\u5236\u7a7a\u4f4d\u7f3a\u9677\uff1b\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08PLQY\uff0c4.5%\uff09\u548c\u51c6\u8d39\u7c73\u80fd\u7ea7\u5206\u88c2\uff08QFLS\uff0c1.02 eV\uff09\u6700\u4f18\uff0c\u51cf\u5c11\u975e\u8f90\u5c04\u590d\u5408\uff0c\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u548c\u5149\u81f4\u53d1\u5149\uff08PL\uff09mapping\u4e5f\u8bc1\u660e\u5176\u819c\u5c42\u66f4\u5747\u5300\u3002\u4f5c\u8005\u5bf9\u5668\u4ef6\u5149\u4f0f\u6027\u80fd\u8fdb\u884c\u8868\u5f81\u3002J-V\u66f2\u7ebf\u663e\u793aNiO\u2093\/MBP\u5c0f\u9762\u79efTPSCs\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u8fbe17.89%\uff08\u53cd\u5411\u626b\u63cf\u8ba4\u8bc117.71%\uff09\uff0c1 cm2<\/sup>\u5927\u9762\u79ef\u5668\u4ef6PCE\u8fbe14.40%\uff1b\u5165\u5c04\u5149-\u7535\u6d41\u8f6c\u6362\u6548\u7387\uff08IPCE\uff09\u79ef\u5206\u77ed\u8def\u7535\u6d41\u5bc6\u5ea6\u6700\u9ad8\uff0c\u7535\u5316\u5b66\u963b\u6297\u8c31\uff08EIS\uff09\u663e\u793a\u5176\u754c\u9762\u7535\u963b\u6700\u4f18\uff1b\u7a33\u5b9a\u6027\u4e0a\uff0c\u5c01\u88c5\u5668\u4ef6\u73af\u5883\u50a8\u5b581344 h\u4fdd\u755995%\u4ee5\u4e0a\u521d\u59cbPCE\uff0c1-sun\u5149\u71671550 h\u4fdd\u755994%\u4ee5\u4e0a\uff0c\u4e14\u9996\u6b21\u5b9e\u73b0NiO\u2093\u57faHTL\u6027\u80fd\u8d85\u8d8a\u4f20\u7edfPEDOT:PSS\u3002<\/p>\n\n\n\n

\u8be5\u7814\u7a76\u5b9e\u73b0\u4e86\u4e00\u79cd\u9ad8\u6027\u80fd\u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08TPSCs\uff09\uff0c\u4ee5\u201cTin-based perovskite solar cells with a homogeneous buried interface<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature<\/strong>\u4e0a\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u70ed\u8bae\u3002<\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n\n\n\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5b9e\u73b0\u4e86\u4e00\u79cd\u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08TPSCs\uff09\uff0c\u901a\u8fc7\u8bbe\u8ba1\u5408\u6210MBC\u548cMBP\u4e24\u79cd\u65b0\u578b\u5206\u5b50\uff0c\u4fee\u9970\u6c27\u5316\u954d\uff08NiO\u2093\uff09\u7a7a\u7a74\u4f20\u8f93\u5c42\uff08HTL\uff09\u4ee5\u4f18\u5316\u57cb\u5e95\u754c\u9762\u3002\u8be5\u7535\u6c60\u53ef\u5f62\u6210\u5747\u5300 interfacial\u5c42\u3001\u5b9e\u73b0\u80fd\u7ea7\u7cbe\u51c6\u5339\u914d\u5e76\u6784\u5efa\u8d85\u6d78\u6da6\u5e95\u5c42\uff0c\u51cf\u5c11\u7f3a\u9677\u4e0e\u975e\u8f90\u5c04\u590d\u5408\uff0c\u5c0f\u9762\u79ef\u5668\u4ef6\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u8fbe17.89%\uff08\u53cd\u5411\u626b\u63cf\u8ba4\u8bc117.71%\uff09\uff0c1 cm\u00b2\u5927\u9762\u79ef\u5668\u4ef6PCE\u8fbe14.40%\uff1b\u5c01\u88c5\u540e\u5728\u73af\u5883\u50a8\u5b581344 h\u4fdd\u755995%\u4ee5\u4e0a\u521d\u59cbPCE\uff0c1-sun\u5149\u7167\u4e0b\u8fde\u7eed\u5de5\u4f5c1550 h\u4fdd\u755994%\u4ee5\u4e0a\u521d\u59cbPCE\uff0c\u8fd8\u9996\u6b21\u5b9e\u73b0NiO\u2093\u57faHTL\u6027\u80fd\u8d85\u8d8a\u4f20\u7edfPEDOT:PSS\uff0c\u4e3aTPSCs\u5b9e\u7528\u5316\u5960\u5b9a\u57fa\u7840\u3002<\/p>\n\n\n\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aLi, T., Luo, X., Wang, P. et al. Tin-based perovskite solar cells with a homogeneous buried interface. Nature (2025). https:\/\/doi.org\/10.1038\/s41586-025-09724-2<\/p>\n\n\n\n

\u672c\u6587\u7531\u666f\u884c\u64b0\u7a3f<\/strong><\/strong><\/p>\n\n\n\n

<\/p>\n\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

\u666f\u884c \u4e00\u3001\u3010\u79d1\u5b66\u80cc\u666f\u3011   \u9521\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08TPSCs\uff09\u4f5c\u4e3a\u65e0\u94c5\u4e14\u73af\u5883\u53cb\u597d\u7684\u5668\u4ef6\uff0c\u5df2\u6210\u4e3a\u94c5\u57fa\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6f5c\u5728\u66ff\u4ee3\u65b9\u6848\uff0c\u5176\u5012\u7f6e\u7ed3\u6784\u7684\u8ba4\u8bc1\u529f\u7387…<\/p>\n","protected":false},"author":36004,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-268885","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268885"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/36004"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=268885"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268885\/revisions"}],"predecessor-version":[{"id":268891,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/268885\/revisions\/268891"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=268885"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=268885"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=268885"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}