{"id":269125,"date":"2025-11-25T09:29:28","date_gmt":"2025-11-25T01:29:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=269125"},"modified":"2025-11-25T09:29:29","modified_gmt":"2025-11-25T01:29:29","slug":"%e5%8d%8e%e7%a7%91%e5%a4%a7%e5%8c%97%e5%b7%a5%e5%a4%a7%e6%b7%b1%e8%81%8c%e5%a4%a7nature-energy","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=269125","title":{"rendered":"\u534e\u79d1\u5927&\u5317\u5de5\u5927&\u6df1\u804c\u5927Nature Energy"},"content":{"rendered":"\n

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\u4e8c\u3001\u3010\u521b\u65b0\u6210\u679c\u3011<\/strong><\/strong><\/p>\n\n\n\n

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\u56fe<\/strong>1<\/strong>\u9499\u949b\u77ff\u6676\u4f53\u7ed3\u6784\u4e0e\u53d6\u5411\u3002\uff08<\/strong>a<\/strong>\u3001<\/strong>b<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u63a0\u5165\u5c04\u5e7f\u89d2<\/strong>X<\/strong>\u5c04\u7ebf\u6563\u5c04\uff08<\/strong>GIWAXS<\/strong>\uff09\u56fe\u8c31\uff1b\uff08<\/strong>c<\/strong>\u3001<\/strong>d<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u622a\u9762\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u955c\uff08<\/strong>HR-TEM<\/strong>\uff09\u56fe\u50cf\uff0c\u7eff\u8272\u865a\u7ebf\u6846\u6807\u6ce8\u9499\u949b\u77ff\u8584\u819c\u7684\u6676\u754c\uff1b\uff08<\/strong>e<\/strong>\u3001<\/strong>f<\/strong>\uff09\u4ece\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u622a\u9762<\/strong>HR-TEM<\/strong>\u56fe\u50cf\u4e0d\u540c\u4f4d\u7f6e\u63d0\u53d6\u7684\u7eb3\u7c73\u675f\u884d\u5c04\uff08<\/strong>NBD<\/strong>\uff09\u56fe\u8c31\uff1b\uff08<\/strong>g<\/strong>\u3001<\/strong>i<\/strong>\uff09\u4ece\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u4e2d\u63d0\u53d6\u7684\u653e\u5927\u622a\u9762<\/strong>TEM<\/strong>\u56fe\u50cf\uff0c\uff08<\/strong>h<\/strong>\u3001<\/strong>j<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u4e2d\u7eff\u8272\u6846\u6807\u6ce8\u4e0d\u540c\u4f4d\u7f6e\u7684\u9ad8\u500d\u7387<\/strong>HR-TEM<\/strong>\u56fe\u50cf\uff1b\uff08<\/strong>k<\/strong>\u3001<\/strong>l<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u5fae\u89c2\u5e94\u53d8\u5206\u5e03\u3002<\/strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n

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\u56fe<\/strong>2<\/strong>\u9499\u949b\u77ff\u6676\u4f53\u751f\u957f\u673a\u5236\u3002\uff08<\/strong>a<\/strong>\u3001<\/strong>d<\/strong>\uff09\u4ece<\/strong>GIWAXS<\/strong>\u56fe\u8c31\u4e2d\u63d0\u53d6\u7684\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\uff08<\/strong>100<\/strong>\uff09\u6676\u9762\u6cbf\u65b9\u4f4d\u89d2\u7684\u79ef\u5206\u5f3a\u5ea6\u66f2\u7ebf\uff1b\uff08<\/strong>b<\/strong>\u3001<\/strong>e<\/strong>\uff09\u5bf9\u7167\u7ec4\uff08\u89d2\u5411\u4e0a\u751f\u957f\uff09\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\uff08\u9762\u5411\u4e0a\u751f\u957f\uff09\u9499\u949b\u77ff\u76f8\u5bf9\u4e8e\u6c27\u5316\u94df\u9521\uff08<\/strong>ITO<\/strong>\uff09\u886c\u5e95\u7684\u53d6\u5411\u793a\u610f\u56fe\uff1b\uff08<\/strong>c<\/strong>\u3001<\/strong>f<\/strong>\uff09\u5bf9\u7167\u7ec4\uff08\u65e0\u5e8f\u7ed3\u6676\uff09\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\uff08\u6709\u5e8f\u7ed3\u6676\uff09\u9499\u949b\u77ff\u6676\u4f53\u5806\u53e0\u7684\u793a\u610f\u56fe\uff1b\uff08<\/strong>g<\/strong>\uff09<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u622a\u9762<\/strong>HR-TEM<\/strong>\u56fe\u50cf\uff1b\uff08<\/strong>h<\/strong>\u3001<\/strong>i<\/strong>\uff09<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684<\/strong>SL2 L3<\/sub><\/strong>\u548c<\/strong>ClL2 L3<\/sub><\/strong>\u7535\u5b50\u80fd\u91cf\u635f\u5931\u8c31\uff08<\/strong>EELS<\/strong>\uff09\uff1b\uff08<\/strong>j<\/strong>\uff09<\/strong>2<\/strong>\u4e2a<\/strong>PHNS<\/strong>\u5206\u5b50<\/strong>+BNAC<\/strong>\u5206\u5b50<\/strong>\/<\/strong>\u9499\u949b\u77ff\u4f53\u7cfb\u7684\u4f18\u5316\u6676\u80de\u7ed3\u6784\u3002<\/strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n

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\u56fe<\/strong>3<\/strong>\u9499\u949b\u77ff\u8584\u819c\u7684\u5149\u7535\u6027\u80fd\u3002\uff08<\/strong>a<\/strong>\u3001<\/strong>b<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u5728<\/strong>260-660 nm<\/strong>\u6fc0\u53d1\u6ce2\u957f\u4e0b\u7684\u7a33\u6001\u5149\u81f4\u53d1\u5149\uff08<\/strong>PL<\/strong>\uff09\u5149\u8c31\uff1b\uff08<\/strong>c<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\uff08<\/strong>TRPL<\/strong>\uff09\u66f2\u7ebf\uff1b\uff08<\/strong>d<\/strong>\u3001<\/strong>e<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684<\/strong>TRPL<\/strong>\u6620\u5c04\u56fe\uff1b\uff08<\/strong>f<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u5149\u81f4\u53d1\u5149\u91cf\u5b50\u4ea7\u7387\uff08<\/strong>PLQY<\/strong>\uff09\uff1b\uff08<\/strong>g<\/strong>\u3001<\/strong>h<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u5f00\u5c14\u6587\u63a2\u9488\u529b\u663e\u5fae\u955c\uff08<\/strong>KPFM<\/strong>\uff09\u56fe\u50cf\uff1b\uff08<\/strong>i<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u8584\u819c\u7684\u80fd\u7ea7\u56fe\u3002<\/strong>\u00a9 2025 Springer Nature<\/strong><\/p>\n\n\n\n

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\u56fe<\/strong>4<\/strong>\u5668\u4ef6\u7684\u5149\u4f0f\u6027\u80fd\u3002\uff08<\/strong>a<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08<\/strong>PSCs<\/strong>\uff09\u5728\u6b63\u5411\u626b\u63cf\u548c\u53cd\u5411\u626b\u63cf\u4e0b\u7684\u7535\u6d41\u5bc6\u5ea6<\/strong>–<\/strong>\u7535\u538b\uff08<\/strong>J-V<\/strong>\uff09\u66f2\u7ebf\uff1b\uff08<\/strong>b<\/strong>\uff09\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u53cd\u5f0f<\/strong>PSCs<\/strong>\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08<\/strong>PCE<\/strong>\uff09\u7edf\u8ba1\u7ed3\u679c\uff1b\uff08<\/strong>c<\/strong>\uff09\u672c\u7814\u7a76\u4e2d<\/strong>PSCs<\/strong>\u7684\u5149\u4f0f\u6027\u80fd\u4e0e\u5176\u4ed6\u5df2\u62a5\u9053\u7684\u9499\u949b\u77ff\u7ed3\u6676\u751f\u957f\u53ca\u8d28\u91cf\u76f8\u5173\u7814\u7a76\u7684\u5bf9\u6bd4\uff1b\uff08<\/strong>d<\/strong>\uff09<\/strong>11.09 cm<\/strong>\u00b2\u7684\u6700\u4f73\u5668\u4ef6\u5728\u6b63\u5411\u626b\u63cf\u548c\u53cd\u5411\u626b\u63cf\u4e0b\u7684<\/strong>J-V<\/strong>\u66f2\u7ebf\uff1b\uff08<\/strong>e<\/strong>\uff09\u5c01\u88c5\u540e\u7684<\/strong>FA0.95<\/sub>Cs0.05<\/sub>PbI3<\/sub><\/strong> PSCs<\/strong>\uff08\u5bf9\u7167\u7ec4\u548c<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\uff09\u7ecf\u8fde\u7eed<\/strong>1<\/strong>\u500d\u592a\u9633\u7b49\u6548\u767d\u5149<\/strong>LED<\/strong>\u7167\u5c04\u5e76\u91c7\u7528\u6700\u5927\u529f\u7387\u70b9\u8ddf\u8e2a\uff08<\/strong>MPPT<\/strong>\uff09\u65f6\uff0c\u5f52\u4e00\u5316<\/strong>PCE<\/strong>\u968f\u65f6\u95f4\u7684\u53d8\u5316\u66f2\u7ebf\uff1b\uff08<\/strong>f<\/strong>\uff09\u6700\u4f73<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u5168\u9499\u949b\u77ff\u53e0\u5c42\u592a\u9633\u80fd\u7535\u6c60\u5728\u6b63\u5411\u626b\u63cf\u548c\u53cd\u5411\u626b\u63cf\u4e0b\u7684<\/strong>J-V<\/strong>\u66f2\u7ebf\uff1b\uff08<\/strong>g<\/strong>\uff09<\/strong>PHNS+BNAC<\/strong>\u4fee\u9970\u7ec4\u53e0\u5c42\u5668\u4ef6\u4e2d\u5bbd\u5e26\u9699\uff08<\/strong>WBG<\/strong>\uff09\u5b50\u7535\u6c60\u548c\u7a84\u5e26\u9699\uff08<\/strong>NBG<\/strong>\uff09\u5b50\u7535\u6c60\u7684\u5916\u91cf\u5b50\u6548\u7387\uff08<\/strong>EQE<\/strong>\uff09\u5149\u8c31\u3002<\/strong>\u00a9 2023 Springer Nature<\/strong><\/p>\n\n\n\n

\u5bf9\u6bd4\u5bf9\u7167\u7ec4\u4e0ePHNS+BNAC\u4fee\u9970\u7ec4\uff0c\u4fee\u9970\u7ec4PL\u5f3a\u5ea6\u6700\u9ad8\uff0cPLQY\u4ece\u5bf9\u7167\u7ec40.69%\u63d0\u5347\u81f37.78%\uff0cTRPL\u5bff\u547d\u6700\u957f\uff0c\u8bc1\u660e\u975e\u8f90\u5c04\u590d\u5408\u51cf\u5c11\u3001\u7f3a\u9677\u949d\u5316\u66f4\u4f18\uff1b\u5171\u805a\u7126PL\/TRPL\u6620\u5c04\u56fe\u8c31\u663e\u793a\u4fee\u9970\u7ec4\u53d1\u5149\u5747\u5300\u3001\u8f7d\u6d41\u5b50\u5bff\u547d\u5206\u5e03\u5747\u4e00\uff1bKPFM\u8868\u660e\u4fee\u9970\u7ec4\u8868\u9762\u7535\u52bf\u66f4\u5e73\u6574\uff0c\u8d39\u7c73\u80fd\u7ea7\u5411\u5bfc\u5e26\u504f\u79fb0.34 eV\uff0c\u4f18\u5316\u80fd\u7ea7\u5339\u914d\u4ee5\u4fc3\u8fdb\u7535\u5b50\u63d0\u53d6\uff0c\u4e14\u7f3a\u9677\u5bc6\u5ea6\u7ecf\u8868\u5f81\u4e3a\u6700\u4f4e\u3002\u5668\u4ef6\u5149\u4f0f\u6027\u80fd\u663e\u793a\uff0c\u5355\u7ed3\u53cd\u5f0fPSCs\u4fee\u9970\u7ec4PCE\u8fbe27.02%\uff08\u8ba4\u8bc126.88%\uff09\uff0cJ-V\u66f2\u7ebf\u663e\u793a\u6548\u7387\u3001Jsc<\/sub>\u3001Voc<\/sub>\u3001FF\u5747\u63d0\u5347\uff0cEQE\u79ef\u5206Jsc<\/sub>\u4e0eJ-V\u7ed3\u679c\u4e00\u81f4\uff1b11.09 cm2<\/sup>\u5668\u4ef6\u8ba4\u8bc1\u7a33\u6001\u6548\u738723.18%\uff1b\u5168\u9499\u949b\u77ff\u53e0\u5c42\u7535\u6c60\u8ba4\u8bc1\u7684PCE\u4e3a29.07%\u3002\u7a33\u5b9a\u6027\u4e0a\uff0c\u4fee\u9970\u7ec4\u5c01\u88c5\u5668\u4ef62000\u5c0f\u65f6MPPT\u6548\u7387\u4fdd\u755998.2%\uff0c85\u2103\/85%RH\u4e0b600\u5c0f\u65f6\u4fdd\u755995.9%\uff0c\u663e\u8457\u4f18\u4e8e\u5bf9\u7167\u7ec4\u3002<\/p>\n\n\n\n

\u8be5\u7814\u7a76\u5b9e\u73b0\u4e86\u4e00\u79cd\u9ad8\u6027\u80fd\u53cd\u5f0f\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff0c\u4ee5\u201cAromatic interaction-driven out-of-plane orientation for inverted perovskite solar cells with improved efficiency<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aNature Energy<\/strong>\u4e0a\uff0c\u5f15\u8d77\u4e86\u76f8\u5173\u9886\u57df\u7814\u7a76\u4eba\u5458\u70ed\u8bae\u3002<\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u4e09\u3001\u3010\u79d1\u5b66\u542f\u8fea\u3011<\/strong><\/p>\n\n\n\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u901a\u8fc7PHNS\u4e0eBNAC\u53cc\u5206\u5b50\u82b3\u9999\u76f8\u4e92\u4f5c\u7528\uff0c\u7cbe\u51c6\u8c03\u63a7FA0.95<\/sub>Cs0.05<\/sub>PbI3<\/sub>\u9499\u949b\u77ff\u7ed3\u6676\uff0c\u5b9e\u73b0\uff08100\uff09\u9762\u5916\u53d6\u5411\u751f\u957f\uff0c\u540c\u65f6\u5f3a\u5316\u7f3a\u9677\u949d\u5316\uff0c\u4f7f\u53cd\u5f0fPSCs\u5355\u7ed3\u8ba4\u8bc1\u6548\u7387\u8fbe26.88%\uff0c\u5c01\u88c5\u5668\u4ef62000\u5c0f\u65f6MPPT\u6548\u7387\u4fdd\u755998.2%\uff1b11.09 cm2<\/sup>\u5168\u9499\u949b\u77ff\u53e0\u5c42\u7535\u6c60\u8ba4\u8bc1\u6548\u7387\u5206\u522b\u4e3a23.18%\u300129.07%\uff0c\u7a81\u7834\u4f20\u7edf\u5355\u6dfb\u52a0\u5242\u5c40\u9650\uff0c\u517c\u987e\u6548\u7387\u4e0e\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n\n

\u672a\u6765\uff0c\u53ef\u5c06\u53cc\u5206\u5b50\u7b56\u7565\u62d3\u5c55\u81f3\u65e0\u94c5\u9499\u949b\u77ff\u7b49\u4f53\u7cfb\uff0c\u8fdb\u4e00\u6b65\u4f18\u5316\u5206\u5b50\u7ed3\u6784\u4ee5\u9002\u914d\u66f4\u591a\u9499\u949b\u77ff\u7ec4\u6210\uff1b\u9488\u5bf9\u89c4\u6a21\u5316\u5e94\u7528\uff0c\u9700\u6539\u8fdb\u72ed\u7f1d\u6d82\u5e03\u7b49\u5de5\u827a\uff0c\u89e3\u51b3\u5927\u9762\u79ef\u8584\u819c\u5747\u5300\u6027\u95ee\u9898\uff1b\u8fd8\u53ef\u6df1\u5316\u82b3\u9999\u76f8\u4e92\u4f5c\u7528\u4e0e\u6676\u4f53\u751f\u957f\u7684\u5b9a\u91cf\u5173\u7cfb\u7814\u7a76\uff0c\u5e76\u7ed3\u5408\u66f4\u7a33\u5b9a\u7535\u8377\u4f20\u8f93\u5c42\uff0c\u6301\u7eed\u63d0\u5347\u5668\u4ef6\u5bff\u547d\uff0c\u52a9\u529b\u53cd\u5f0fPSCs\u5546\u4e1a\u5316\u8fdb\u7a0b\u3002<\/p>\n\n\n\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aZhou, Q., Huang, G., Wang, J. et al. Aromatic interaction-driven out-of-plane orientation for inverted perovskite solar cells with improved efficiency. Nat Energy (2025). https:\/\/doi.org\/10.1038\/s41560-025-01882-x<\/p>\n\n\n\n

\u672c\u6587\u7531\u666f\u884c\u64b0\u7a3f<\/strong><\/strong><\/p>\n\n\n\n

<\/p>\n\n\n\n

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