{"id":269370,"date":"2025-11-10T07:49:00","date_gmt":"2025-11-09T23:49:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=269370"},"modified":"2025-11-09T21:54:00","modified_gmt":"2025-11-09T13:54:00","slug":"%e8%8e%86%e7%94%b0%e5%ad%a6%e9%99%a2%e6%98%93%e6%98%8e%e6%9d%b0%e9%bb%84%e5%bb%ba%e8%be%89-%e5%93%88%e5%b0%94%e6%bb%a8%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e5%bc%a0%e5%98%89%e6%81%92ensm-mnse-nise","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=269370","title":{"rendered":"\u8386\u7530\u5b66\u9662\u6613\u660e\u6770&#038;\u9ec4\u5efa\u8f89\/\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u5f20\u5609\u6052EnSM: MnSe\/NiSe\u2082\u5f02\u8d28\u7ed3\u6784\u4e0e\u7f3a\u9677\u5de5\u7a0b\u534f\u540c\u6784\u7b51\u9ad8\u6027\u80fd\u78b1\u6027\u6790\u6c22\u53ca\u67d4\u6027\u8d85\u7ea7\u7535\u5bb9\u5668"},"content":{"rendered":"\n<ul class=\"wp-block-list\">\n<li>\u5bfc\u8bfb<\/li>\n<\/ul>\n\n\n\n<p>\u672c\u7814\u7a76\u9488\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u5e94\u7528\u4e2d\u5b58\u5728\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0d\u8db3\u3001\u53cd\u5e94\u52a8\u529b\u5b66\u8fdf\u7f13\u53ca\u5bfc\u7535\u6027\u4e0d\u4f73\u7b49\u5173\u952e\u6311\u6218\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u591a\u7b56\u7565\u534f\u540c\u4f18\u5316\u65b9\u6cd5\u3002\u901a\u8fc7\u6574\u5408\u7f3a\u9677\u5de5\u7a0b\uff08\u7852\u7a7a\u4f4d\uff09\u3001\u5f02\u8d28\u754c\u9762\u6784\u5efa\uff08MnSe\/NiSe\u2082\uff09\u53ca\u6742\u539f\u5b50\u63ba\u6742\u7b56\u7565\uff0c\u6240\u5236\u5907\u7684 MnSe<sub>1-x<\/sub>-NiSe<sub>1-x<\/sub>\/NPC\uff08NPC\u4ee3\u8868\u6c2e\u3001\u78f7\u5171\u63ba\u6742\u78b3\uff09\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u78b1\u6027\u6790\u6c22\u6d3b\u6027\uff0810\/100 mA cm\u207b\u00b9 \u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u4f4d\u5206\u522b\u4e3a 72.5 \u548c 111.6 mV\uff09\u4e0e\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\uff08\u5728 0.799 kW kg\u207b\u00b9 \u529f\u7387\u5bc6\u5ea6\u4e0b\u80fd\u91cf\u5bc6\u5ea6\u8fbe 71.8 Wh kg\u207b\u00b9\uff09\u3002\u7ed3\u5408\u540c\u6b65\u8f90\u5c04 X \u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u3001\u539f\u4f4d\u5149\u8c31\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u83b7\u5f97\u7684\u673a\u7406\u8ba4\u77e5\uff0c\u9610\u660e\u4e86\u754c\u9762\u7535\u5b50\u8f6c\u79fb\u8def\u5f84\u3001\u6790\u6c22\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u52a8\u6001\u6c34\u5206\u89e3\u884c\u4e3a\u3001\u50a8\u80fd\u8fc7\u7a0b\u4e2d\u53ef\u9006\u76f8\u53d8\u673a\u5236\uff0c\u4ee5\u53ca\u901a\u8fc7 d \u8f68\u9053\u6742\u5316\u4f18\u5316\u6c22\u6c27\u6839\u79bb\u5b50\uff08OH\u207b\uff09\/ \u6c22\u5438\u9644\u8d28\uff08H*\uff09\u5438\u9644\u80fd\u7684\u5185\u5728\u89c4\u5f8b\u3002\u8be5\u7814\u7a76\u4e3a\u540c\u6b65\u6784\u5efa\u7852\u7a7a\u4f4d\u4e0e\u5f02\u8d28\u754c\u9762\u63d0\u4f9b\u4e86\u65b0\u9896\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u4e5f\u4e3a\u7535\u50ac\u5316\u4e0e\u50a8\u80fd\u7cfb\u7edf\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u91cd\u8981\u53c2\u8003\u3002<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u6210\u679c\u63a0\u5f71<\/li>\n<\/ul>\n\n\n\n<p>\u8fd1\u65e5\uff0c<strong>\u8386\u7530\u5b66\u9662\u7684\u6613\u660e\u6770\u6559\u6388<\/strong><strong>\/\u9ec4\u5efa\u8f89\u6559\u6388\u548c<\/strong><strong>\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u7684\u5f20\u5609\u6052\u6559\u6388<\/strong>\uff0c\u9488\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u5e94\u7528\u4e2d\u5b58\u5728\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0d\u8db3\u3001\u53cd\u5e94\u52a8\u529b\u5b66\u8fdf\u7f13\u53ca\u5bfc\u7535\u6027\u4e0d\u4f73\u7b49\u5173\u952e\u6311\u6218\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u591a\u7b56\u7565\u534f\u540c\u4f18\u5316\u65b9\u6cd5\u3002\u901a\u8fc7\u6574\u5408\u7f3a\u9677\u5de5\u7a0b\uff08\u7852\u7a7a\u4f4d\uff09\u3001\u5f02\u8d28\u754c\u9762\u6784\u5efa\uff08MnSe\/NiSe\u2082\uff09\u53ca\u6742\u539f\u5b50\u63ba\u6742\u7b56\u7565\uff0c\u6240\u5236\u5907\u7684 MnSe<sub>1-x<\/sub>-NiSe<sub>1-x<\/sub>\/NPC\uff08NPC \u4ee3\u8868\u6c2e\u3001\u78f7\u5171\u63ba\u6742\u78b3\uff09\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u78b1\u6027\u6790\u6c22\u6d3b\u6027\uff0810\/100 mA cm\u207b\u00b9 \u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fc7\u7535\u4f4d\u5206\u522b\u4e3a 72.5 \u548c 111.6 mV\uff09\u4e0e\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\uff08\u5728 0.799 kW kg\u207b\u00b9 \u529f\u7387\u5bc6\u5ea6\u4e0b\u80fd\u91cf\u5bc6\u5ea6\u8fbe 71.8 Wh kg\u207b\u00b9\uff09\u3002\u7ed3\u5408\u540c\u6b65\u8f90\u5c04 X \u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\uff08XANES\uff09\u3001\u539f\u4f4d\u5149\u8c31\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u83b7\u5f97\u7684\u673a\u7406\u8ba4\u77e5\uff0c\u9610\u660e\u4e86\u754c\u9762\u7535\u5b50\u8f6c\u79fb\u8def\u5f84\u3001\u6790\u6c22\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u52a8\u6001\u6c34\u5206\u89e3\u884c\u4e3a\u3001\u50a8\u80fd\u8fc7\u7a0b\u4e2d\u53ef\u9006\u76f8\u53d8\u673a\u5236\uff0c\u4ee5\u53ca\u901a\u8fc7 d \u8f68\u9053\u6742\u5316\u4f18\u5316\u6c22\u6c27\u6839\u79bb\u5b50\uff08OH\u207b\uff09\/ \u6c22\u5438\u9644\u8d28\uff08H*\uff09\u5438\u9644\u80fd\u7684\u5185\u5728\u89c4\u5f8b\u3002\u8be5\u7814\u7a76\u4e3a\u540c\u6b65\u6784\u5efa\u7852\u7a7a\u4f4d\u4e0e\u5f02\u8d28\u754c\u9762\u63d0\u4f9b\u4e86\u65b0\u9896\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u4e5f\u4e3a\u7535\u50ac\u5316\u4e0e\u50a8\u80fd\u7cfb\u7edf\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u91cd\u8981\u53c2\u8003\u3002<\/p>\n\n\n\n<h4 class=\"wp-block-heading\">\u8be5\u6210\u679c\u4ee5<strong>\u8386\u7530\u5b66\u9662\u4e3a\u7b2c\u4e00\u5355\u4f4d<\/strong>\u4ee5\u9898\u76ee\u201cSynergistic Engineering of Heterointerfaces and Defects in N, P-Codoped&nbsp;Carbon-Encapsulated MnSe\/NiSe<sub>2<\/sub>&nbsp;Heterostructure for Efficient Alkaline&nbsp;Hydrogen Evolution and High-Performance Flexible Supercapacitors\u201d\u53d1\u8868\u5728\u4e2d\u79d1\u9662\u4e00\u533atop\u671f\u520a<strong>Energy Storage Materials<\/strong>\uff0c\u5f71\u54cd\u56e0\u5b50\u4e3a<strong>20.2<\/strong>\u3002<\/h4>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"566\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/2382c315a6ba396-15.png\" alt=\"\" class=\"wp-image-269371\"\/><\/figure>\n\n\n\n<p>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n\n\n\n<p>\u8be5\u7814\u7a76\u6838\u5fc3\u521b\u65b0\u70b9\u5728\u4e8e\u63d0\u51fa\u591a\u7b56\u7565\u534f\u540c\u4f18\u5316\u65b9\u6848\uff0c\u540c\u6b65\u89e3\u51b3\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u5728\u7535\u50ac\u5316\u4e0e\u50a8\u80fd\u5e94\u7528\u4e2d\u7684\u5173\u952e\u74f6\u9888\u3002\u901a\u8fc7\u6574\u5408\u7f3a\u9677\u5de5\u7a0b\uff08\u6784\u5efa\u7852\u7a7a\u4f4d\uff09\u3001\u5f02\u8d28\u754c\u9762\u6784\u5efa\uff08\u5f62\u6210 MnSe\/NiSe\u2082\u5f02\u8d28\u7ed3\u6784\uff09\u53ca N\u3001P \u6742\u539f\u5b50\u63ba\u6742\uff0c\u7ed3\u5408\u78b3\u5c01\u88c5\u8bbe\u8ba1\uff0c\u534f\u540c\u63d0\u5347\u6750\u6599\u6d3b\u6027\u4f4d\u70b9\u6570\u91cf\u3001\u7535\u8377\u4f20\u8f93\u6548\u7387\u4e0e\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u501f\u52a9\u540c\u6b65\u8f90\u5c04 XANES\u3001\u539f\u4f4d\u5149\u8c31\u53ca DFT \u8ba1\u7b97\uff0c\u4ece\u539f\u5b50\u5c42\u9762\u63ed\u793a\u754c\u9762\u7535\u5b50\u8f6c\u79fb\u3001\u6c34\u5206\u89e3\u673a\u5236\u53ca\u5438\u9644\u80fd\u4f18\u5316\u89c4\u5f8b\uff0c\u9610\u660e\u591a\u7b56\u7565\u534f\u540c\u4f5c\u7528\u672c\u8d28\u3002\u6240\u5236\u5907\u7684 MnSe<sub>1-X<\/sub>-NiSe<sub>2-X<\/sub>\/NPC&nbsp;\u6750\u6599\u540c\u65f6\u5b9e\u73b0\u4f18\u5f02\u78b1\u6027\u6790\u6c22\u6d3b\u6027\u4e0e\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u50a8\u80fd\u6027\u80fd\uff0c\u4e3a\u540c\u6b65\u6784\u5efa\u7f3a\u9677\u4e0e\u5f02\u8d28\u754c\u9762\u7684\u591a\u529f\u80fd\u6750\u6599\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u9896\u8303\u5f0f\u3002<\/p>\n\n\n\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"818\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/ce6e2814f207c93-15.png\" alt=\"\" class=\"wp-image-269372\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;1.&nbsp;(a) Illustration of the preparation process of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(b, c)&nbsp;SEM images and&nbsp;(d) TEM image&nbsp;of&nbsp;NiMn-ILs-MOF.&nbsp;(e, f) SEM images&nbsp;and&nbsp;(g) TEM image&nbsp;of&nbsp;MnNi\/NPC.&nbsp;(h) SEM image and&nbsp;(i) TEM image&nbsp;of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(j) High-resolution TEM image&nbsp;(Inset: GPA analysis of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC),&nbsp;(k, l)&nbsp;inverse FFT lattice image and (m, n)&nbsp;lattice spacing of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC. (o)&nbsp;Heterostructure model of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>, (p) Mapping of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(q-s) Water contact angles of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC, NiSe<sub>2-x<\/sub>\/NPC and MnSe<sub>1-x<\/sub>\/NPC.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"648\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/7f88dbbcaa77a1d-14.png\" alt=\"\" class=\"wp-image-269373\"\/><\/figure>\n\n\n\n<p>Fig. 2.&nbsp;(a) XRD&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(b) BET&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(c) Electron Paramagnetic Resonance spectrum&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC, NiSe<sub>2-x<\/sub>\/NPC,&nbsp;and MnSe<sub>1-x<\/sub>\/NPC.&nbsp;(d)&nbsp;Electron density difference images of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC,&nbsp;XPS of (e)&nbsp;Mn&nbsp;2<em>p<\/em><em>, <\/em>(f) Ni&nbsp;2<em>p<\/em><em>,<\/em>&nbsp;(g) Se<em>&nbsp;<\/em>3<em>d<\/em>&nbsp;in<em>&nbsp;<\/em>MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC, NiSe<sub>2-x<\/sub>\/NPC, MnSe<sub>1-x<\/sub>\/NPC and (h) C 1s&nbsp;in MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;Total density of states (TDOS) for&nbsp;(i) MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>, (j) MnSe<sub>1-x<\/sub>, and (k) NiSe<sub>2-x<\/sub>.&nbsp;XANES spectra&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its comparative materials&nbsp;at (l)&nbsp;Ni K-edge&nbsp;and (m)&nbsp;Mn K-edge. The corresponding&nbsp;FT-EXAFS curves of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its comparative materials&nbsp;at (n)&nbsp;Ni K-edge&nbsp;and (o)&nbsp;Mn K-edge. WT-EXAFS plots of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its comparative materials&nbsp;at (p)&nbsp;Ni K-edge&nbsp;and (q)&nbsp;Mn K-edge.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"578\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/4e9a0ba2491dfde-13.png\" alt=\"\" class=\"wp-image-269374\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;3.&nbsp;(a) The illustration of the reaction process of HER. (b) HER polarization curve. (c)&nbsp;Tafel plots&nbsp;and (d)&nbsp;the calculated electrochemical parameters&nbsp;of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC,&nbsp;Pt\/C,&nbsp;NiSe<sub>2-x<\/sub>\/NPC&nbsp;and MnSe<sub>1-x<\/sub>\/NPC&nbsp;in 1.0&nbsp;M KOH.&nbsp;(e) Comparison of the HER overpotential of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;with reference electrocatalysts.&nbsp;(f) The estimated amounts of gas produced over MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(g)&nbsp;CV graphs of the MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;electrode at different scan rates. (h) C<sub>dl<\/sub>&nbsp;and relative electrochemically active surface area of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and other references in 1.0&nbsp;M KOH.&nbsp;(i)&nbsp;Normalized with ECSA in 1.0&nbsp;M KOH.&nbsp;(j) Cycling stability of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;at 10 mA cm<sup>&#8211;<\/sup><sup>2<\/sup>&nbsp;for 100&nbsp;h in 1.0&nbsp;M KOH.&nbsp;(k)&nbsp;HER polarization curve for 1st&nbsp;and 1000th&nbsp;in 1.0&nbsp;M KOH.&nbsp;(l) XRD results after HER in 1.0&nbsp;M KOH. (m)&nbsp;SEM images of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"620\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/b14210e1ee30421-12.png\" alt=\"\" class=\"wp-image-269375\"\/><\/figure>\n\n\n\n<p>Fig. 4. (a) Schematic of in situ Raman. (b) Operando 2D Raman contour plot. (c) Deconvolution of O-H stretching modes. (d) In situ spectra of interfacial water. (e) Potential-dependent normalized v<sub>O-H<\/sub>&nbsp;intensity&nbsp;at MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC. (f) Stark tuning rate of v<sub>O-H<\/sub>&nbsp;vibration. (g) Proposed HER mechanism in alkaline electrolyte and (h) corresponding free energy profile.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"698\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/de5bcf7d8eaea98-10.png\" alt=\"\" class=\"wp-image-269376\"\/><\/figure>\n\n\n\n<p>Fig. 5. (a) Schematic of the supercapacitor reaction process. (b) CV curves of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;at different scan rates. (c) Comparative CV curves&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its reference materials. (d) GCD curves of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;at different current densities. (e) Comparative GCD curves&nbsp;abd (f) Rate capability&nbsp;of the MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its reference materials. (g) Specific capacity comparison with reported samples. (h) EIS and (i) Cycling performance&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its reference materials.&nbsp;(j) Determination of b-values. (k)&nbsp;CV curves measured at 100&nbsp;mV&nbsp;s<sup>-1 <\/sup>of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC. (l) Capacitive versus diffusion-controlled contributions&nbsp;for for MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(m) Optimized *OH adsorption configurations. (n) HER free energy diagram&nbsp;of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;and its reference materials.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"653\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/aa3023e0288002c-7.png\" alt=\"\" class=\"wp-image-269377\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;6.&nbsp;(a)&nbsp;The illustration of the as-assembled MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC\/AC&nbsp;flexibilible device. (b) CV curves of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>&nbsp;and AC at 20 mV s<sup>&#8211;<\/sup><sup>1<\/sup>. CV curves of&nbsp;MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;in at (c)&nbsp;various potential&nbsp;and (d)&nbsp;various different scan rates. (e) GCD curves&nbsp;and (f) specific capacitance at different current densities. (g) Ragone plots of the present device as compared with previously reported ones. (h)&nbsp;GCD&nbsp;and (i) CV curves of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;at under 4&nbsp;A g<sup>&#8211;<\/sup><sup>1<\/sup>&nbsp;and 20&nbsp;mV s<sup>&#8211;<\/sup><sup>1<\/sup><sup>&nbsp;<\/sup>of bending. (j) Schematic of the&nbsp;in situ XRD. (k) XRD patterns and (l) operando Raman patterns of the 2D color-filled contour plot of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC.&nbsp;(m)&nbsp;Cycling performance and (n)&nbsp;Coulombic efficiency of MnSe<sub>1-x<\/sub>-NiSe<sub>2-x<\/sub>\/NPC&nbsp;at 4 A g<sup>&#8211;<\/sup><sup>1<\/sup>&nbsp;current density.&nbsp;(o) A fan powered by the flexible asymmetric supercapacitor device.<\/p>\n\n\n\n<p>\u4e94\u3001\u6210\u679c\u542f\u793a<\/p>\n\n\n\n<p>\u8be5\u7814\u7a76\u7684\u6210\u679c\u542f\u793a\u4e3b\u8981\u4f53\u73b0\u5728\u4e09\u65b9\u9762\u3002\u5176\u4e00\uff0c\u591a\u7b56\u7565\u534f\u540c\u8bbe\u8ba1\u662f\u7a81\u7834\u5355\u4e00\u6539\u6027\u5c40\u9650\u7684\u5173\u952e\uff0c\u7f3a\u9677\u5de5\u7a0b\u3001\u5f02\u8d28\u754c\u9762\u6784\u5efa\u4e0e\u6742\u539f\u5b50\u63ba\u6742\u7684\u7ec4\u5408\uff0c\u4e3a\u540c\u6b65\u4f18\u5316\u6750\u6599\u6d3b\u6027\u3001\u5bfc\u7535\u6027\u53ca\u7a33\u5b9a\u6027\u63d0\u4f9b\u4e86\u53ef\u590d\u5236\u601d\u8def\u3002\u5176\u4e8c\uff0c\u8de8\u8868\u5f81\u6280\u672f\u8054\u7528\uff08\u540c\u6b65\u8f90\u5c04 XANES + \u539f\u4f4d\u5149\u8c31 + DFT \u8ba1\u7b97\uff09\u4e3a\u89e3\u6790\u591a\u7ec4\u5206\u534f\u540c\u4f5c\u7528\u673a\u5236\u63d0\u4f9b\u4e86\u9ad8\u6548\u8303\u5f0f\uff0c\u52a9\u529b\u4ece\u539f\u5b50\u5c42\u9762\u6307\u5bfc\u6750\u6599\u7cbe\u51c6\u8bbe\u8ba1\u3002\u5176\u4e09\uff0c\u591a\u529f\u80fd\u4e00\u4f53\u5316\u6750\u6599\u8bbe\u8ba1\u53ef\u5b9e\u73b0\u7535\u50ac\u5316\u4e0e\u50a8\u80fd\u6027\u80fd\u7684\u517c\u987e\uff0c\u4e3a\u5f00\u53d1\u9002\u914d\u67d4\u6027\u7535\u5b50\u3001\u6c22\u80fd\u5236\u5907\u7b49\u573a\u666f\u7684\u590d\u5408\u578b\u5668\u4ef6\u5960\u5b9a\u57fa\u7840\uff0c\u4e5f\u4e3a\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u5728\u80fd\u6e90\u9886\u57df\u7684\u9ad8\u6027\u80fd\u5e94\u7528\u5f00\u8f9f\u4e86\u65b0\u8def\u5f84\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u672c\u7814\u7a76\u9488\u5bf9\u8fc7\u6e21\u91d1\u5c5e\u7852\u5316\u7269\u5728\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u5e94\u7528\u4e2d\u5b58\u5728\u7684\u6d3b\u6027\u4f4d\u70b9\u4e0d\u8db3\u3001\u53cd\u5e94\u52a8\u529b\u5b66\u8fdf\u7f13\u53ca\u5bfc\u7535\u6027\u4e0d\u4f73\u7b49\u5173\u952e\u6311\u6218\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u591a\u7b56\u7565\u534f\u540c\u4f18\u5316\u65b9\u6cd5\u3002\u901a\u8fc7\u6574\u5408\u7f3a&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-269370","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269370"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=269370"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269370\/revisions"}],"predecessor-version":[{"id":269378,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269370\/revisions\/269378"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=269370"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=269370"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=269370"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}