{"id":269513,"date":"2025-11-19T07:49:00","date_gmt":"2025-11-18T23:49:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=269513"},"modified":"2025-11-18T20:54:28","modified_gmt":"2025-11-18T12:54:28","slug":"%e5%8d%8e%e4%b8%ad%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e9%bb%84%e4%ba%91%e8%be%89-%e8%a3%b4%e9%9d%9e%e5%9b%a2%e9%98%9fjacs%ef%bc%9a%e6%96%b0%e5%9e%8b%e9%92%9b%e6%b0%a7%e5%9b%a2%e7%b0%87%e6%b7%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=269513","title":{"rendered":"\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u9ec4\u4e91\u8f89\/\u88f4\u975e\u56e2\u961fJACS\uff1a\u65b0\u578b\u949b\u6c27\u56e2\u7c07\u6dfb\u52a0\u5242\u8c03\u63a7\u9ad8\u6bd4\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u754c\u9762\u5316\u5b66"},"content":{"rendered":"\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"181\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/2382c315a6ba396-24.png\" alt=\"\" class=\"wp-image-269514\"\/><\/figure>\n\n\n\n<p><strong>\u7b2c\u4e00\u4f5c\u8005\uff1a\u6797\u6587\u6770<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u901a\u8baf\u4f5c\u8005\uff1a\u88f4\u975e*\uff0c\u9ec4\u4e91\u8f89*<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u5355\u4f4d\uff1a\u534e\u4e2d\u79d1\u6280\u5927\u5b66 \u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662<\/strong><strong>&nbsp;&nbsp;\u6750\u6599\u6210\u5f62\u4e0e\u6a21\u5177\u6280\u672f\u5168\u56fd\u91cd\u70b9\u5b9e\u9a8c\u5ba4<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u9502\u91d1\u5c5e\u8d1f\u6781\u51ed\u501f\u6700\u4f4e\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff08\u76f8\u5bf9\u4e8e\u6807\u51c6\u6c22\u7535\u6781\u7684\u7535\u4f4d\u4e3a\u22123.04 V\uff09\u548c\u8d85\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff083860 mAh g<sup>\u22121<\/sup>\uff09\uff0c\u5f53\u4e0e\u9ad8\u954d\u4e09\u5143\u6b63\u6781\uff08\u4f8b\u5982 LiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>\uff0c\u5373 NCM811\uff09\u642d\u914d\u65f6\uff0c\u88ab\u89c6\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u9ad8\u7535\u538b\u9502\u91d1\u5c5e\u7535\u6c60\uff08HVLMBs\uff09\u7684\u7406\u60f3\u5019\u9009\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u9502\u91d1\u5c5e\u4e0e\u4f20\u7edf\u78b3\u9178\u916f\u7c7b\u7535\u89e3\u6db2\u7684\u9ad8\u53cd\u5e94\u6d3b\u6027\uff0c\u4ee5\u53ca\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7535\u6781\u4ea7\u751f\u7684\u673a\u68b0\u5e94\u529b\uff0c\u4f1a\u5bfc\u81f4\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u548c\u9634\u6781\u7535\u89e3\u8d28\u754c\u9762\uff08CEI\uff09\u6301\u7eed\u53d1\u751f\u7834\u88c2\u4e0e\u91cd\u6784\u3002\u540c\u65f6\uff0c\u5546\u7528\u78b3\u9178\u916f\u57fa\u7535\u89e3\u8d28\u4e2d\u5fae\u91cf\u7684\u6c34\u5206\u4f1a\u751f\u6210\u6c1f\u5316\u6c22\uff08HF\uff09\uff0c\u4e25\u91cd\u7834\u574f\u4e86\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7684\u7a33\u5b9a\u6027\uff0c\u52a0\u5267\u4e86\u7535\u89e3\u8d28\u7684\u5206\u89e3\uff0c\u5bfc\u81f4\u9ad8\u538b\u9502\u91d1\u5c5e\u7535\u6c60\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\u4e0e\u7535\u6c60\u5931\u6548\u3002<\/p>\n\n\n\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8fd1\u65e5\uff0c\u5728<strong>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u9ec4\u4e91\u8f89\u6559\u6388<\/strong><strong>\u548c<\/strong><strong>\u88f4\u975e\u526f\u7814\u7a76\u5458<\/strong>\u5e26\u9886\u7814\u7a76\u56e2\u961f\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a<a href=\"https:\/\/letpub.com.cn\/index.php?page=journalapp&amp;view=detail&amp;journalid=5235\"><strong>Journal of the American Chemical Society<\/strong><\/a>\u4e0a\u53d1\u8868\u9898\u4e3a\u201c<a><\/a><strong>Tuning interphasial chemistry with titanium<a><\/a><\/strong><strong>\u2013<\/strong><strong>oxo clusters for high-energy-density lithium metal batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c<strong>\u6797\u6587\u6770\u535a\u58eb<\/strong>\u4e3a\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u3002\u8be5\u5de5\u4f5c\u63d0\u51fa\u5c06<strong>\u805a\u5df1\u5185\u916f\u4e8c\u9187\u4fee\u9970\u7684\u949b\u6c27\u7c07\uff08TOC-PCL\uff09<\/strong>\u7528\u4f5c\u591a\u529f\u80fd\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\uff0c\u4ee5<strong>\u8c03\u63a7\u9ad8\u954d\u6b63\u6781\u4e0e\u9502\u8d1f\u6781\u7684\u754c\u9762\u5316\u5b66<\/strong>\u3002\u7535\u89e3\u6db2\u4e2d\u7684\u5fae\u91cfH<sub>2<\/sub>O \u548cHF\u901a\u8fc7TOC-PCL\u7684\u6c34\u89e3\u4f5c\u7528\u88ab\u6709\u6548\u6e05\u9664\uff0c\u968f\u540e\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u6784\u5efa\u51fa\u5bcc\u542b\u65e0\u673a\u6210\u5206\uff08TiO<sub>2<\/sub>\u3001Li<sub>2<\/sub>TiF<sub>6<\/sub>\u548cLiF\uff09\u7684\u7a33\u5b9a\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\uff0c\u5927\u5e45\u6291\u5236\u4e86\u754c\u9762\u5316\u5b66\u4fb5\u8680\u3002\u7ed3\u679c\u8868\u660e\uff0c\u6dfb\u52a0TOC-PCL\u7684LiNi<sub>0.8<\/sub>Co<sub>0.1<\/sub>Mn<sub>0.1<\/sub>O<sub>2<\/sub>||Li\u7535\u6c60\u57281C\u500d\u7387\u4e0b\u5faa\u73af1000\u6b21\u4ee5\u4e0a\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u8fbe80.4%\uff1b\u5373\u4fbf\u5728\u8d85\u9ad8\u6b63\u6781\u8f7d\u91cf\uff0841 mg&nbsp;cm<sup>\u2212<\/sup><sup>2<\/sup>\uff09\u4e0e\u9ad8\u954d\u542b\u91cf\uff0896 wt%\uff09\u7684\u6761\u4ef6\u4e0b\uff0c\u8be5\u7535\u6c60\u4e5f\u80fd\u7a33\u5b9a\u5de5\u4f5c\u30021.6Ah&nbsp;NCM811\u8f6f\u5305\u7535\u6c60\uff0c\u5728\u5faa\u73af150\u6b21\u540e\u4ecd\u5c55\u73b0\u51fa401.6 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\u80fd\u6709\u6548\u6e05\u9664\u5546\u7528\u7535\u89e3\u6db2\u4e2d\u7684\u5fae\u91cf H\u2082O\/HF \u6742\u8d28\uff0c\u7f13\u89e3 HF \u5f15\u53d1\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\/\u6b63\u6781\u7535\u89e3\u8d28\u754c\u9762\uff08CEI\uff09\u7ec4\u5206\u8150\u8680\u4e0e\u9ad8\u6d3b\u6027\u7535\u6781\u8150\u8680\u3002\u5373\u4fbf\u5728\u82db\u523b\u73af\u5883\uff081000 ppm H<sub>2<\/sub>O\u621660&nbsp;\u2103\uff09\u4e0b\uff0cTOC-PCL \u4ecd\u80fd\u663e\u8457\u6291\u5236HF\u751f\u6210\uff0c\u540c\u65f6\u4f7f\u7535\u6c60\u5faa\u73af\u7a33\u5b9a\u6027\u4fdd\u6301\u826f\u597d\u3002<\/p>\n\n\n\n<p><strong>\u8981\u70b9\u4e8c\uff1a\u6784\u5efa\u5bcc\u542b\u65e0\u673a\u7ec4\u5206\u7684\u754c\u9762\u5c42<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0cTOC-PCL\u901a\u8fc7\u6c34\u89e3\u4e0e\u9010\u6b65\u6c27\u5316\u5206\u89e3\uff0c\u539f\u4f4d\u6784\u5efa\u51fa\u575a\u56fa\u7684\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\/CEI\uff09\uff0c\u8be5\u754c\u9762\u5bcc\u542bTiO<sub>2<\/sub>\u3001Li<sub>2<\/sub>TiF<sub>6<\/sub>\u548cLiF\u65e0\u673a\u6210\u5206\u3002\u5176\u4e2d\uff0cTiO<sub>2<\/sub>\u4f18\u5f02\u7684\u5316\u5b66\u60f0\u6027\u4e0e\u521a\u6027\u7ed3\u6784\uff0c\u4ee5\u53caLi<sub>2<\/sub>TiF<sub>6<\/sub>\/LiF\u51fa\u8272\u7684\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u5bf9\u7a33\u5b9a\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u754c\u9762\u5316\u5b66\u8d77\u5230\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n\n\n\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"400\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/ce6e2814f207c93-25.png\" alt=\"\" class=\"wp-image-269515\"\/><\/figure>\n\n\n\n<p><strong>\u56fe1. <\/strong>TOC-PC \u6dfb\u52a0\u5242\u6539\u5584 NCM811||Li \u7535\u6c60\u4e2d\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7a33\u5b9a\u6027\u7684\u4f5c\u7528\u673a\u5236\u3002<\/p>\n\n\n\n<p>\u5c06\u805a\u5df1\u5185\u916f\u4e8c\u9187\u4fee\u9970\u7684\u949b\u6c27\u7c07\uff08TOC-PCL\uff09\u7528\u4f5c\u591a\u529f\u80fd\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\uff0c\u4ee5\u8c03\u63a7\u9ad8\u954d\u6b63\u6781\u4e0e\u9502\u8d1f\u6781\u7684\u754c\u9762\u5316\u5b66\uff08\u56fea\uff09\u3002\u7535\u89e3\u6db2\u4e2d\u7684\u5fae\u91cfH<sub>2<\/sub>O\u548cHF\u901a\u8fc7TOC-PCL\u7684\u6c34\u89e3\u4f5c\u7528\u88ab\u6709\u6548\u6e05\u9664\uff0c\u968f\u540e\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u6784\u5efa\u51fa\u5bcc\u542b\u65e0\u673a\u6210\u5206\uff08TiO<sub>2<\/sub>\u3001Li<sub>2<\/sub>TiF<sub>6<\/sub>\u548cLiF\uff09\u7684\u7a33\u5b9a\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\uff0c\u5927\u5e45\u6291\u5236\u4e86\u754c\u9762\u5316\u5b66\u4fb5\u8680\uff08\u56feb\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"362\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/7f88dbbcaa77a1d-22.png\" alt=\"\" class=\"wp-image-269516\"\/><\/figure>\n\n\n\n<p><strong>\u56fe2.<\/strong>&nbsp;TOC-PCL\u7684\u7269\u7406\u5316\u5b66\u548c\u7535\u5316\u5b66\u6027\u8d28<\/p>\n\n\n\n<p>\u7ecf\u914d\u4f53\u4ea4\u6362\u540e\u5f97\u5230\u7684TOC-PCL\uff0c\u4f9d\u76f8\u4f3c\u76f8\u6eb6\u539f\u7406\u53ef\u6eb6\u4e8e\u78b3\u9178\u76d0\u57fa\u7535\u89e3\u6db2\uff08\u56fea\uff09\u3002FTIR\u5149\u8c31\u4e2d\u916f\u57fa\u57281721 cm<sup>\u2212<\/sup><sup>1<\/sup>\uff08C=O\u952e\uff09\u548c 1220 cm<sup>\u2212<\/sup><sup>1<\/sup>\uff08C\u2013O\u2013C \u952e\uff09\u6709\u7279\u5f81\u3002\u7531<sup>19<\/sup>F&nbsp;NMR\u5149\u8c31\u8bc1\u660eTOC-PCL\u53ef\u6e05\u9664\u7535\u89e3\u6db2\u4e2d H<sub>2<\/sub>O\u548cHF\uff08\u56feb\u3001c\uff09\u3002TOC-PCL\u8fd8\u80fd\u5c06 H<sub>2<\/sub>O\u3001HF 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V\u6709\u5206\u89e3\u5cf0\uff08\u56fei\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"383\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/4e9a0ba2491dfde-22.png\" alt=\"\" class=\"wp-image-269517\"\/><\/figure>\n\n\n\n<p><strong>\u56fe3. <\/strong>TOC-PCL\u5bf9\u9502\u91d1\u5c5e\u8d1f\u6781\u754c\u9762\u7684\u7a33\u5b9a\u4f5c\u7528<\/p>\n\n\n\n<p>\u57281.0 mA&nbsp;cm<sup>\u2212<\/sup><sup>2<\/sup>\u30011.0 mAh&nbsp;cm<sup>\u2212<\/sup><sup>2<\/sup>\u6761\u4ef6\u4e0b\uff0cLi|TOC-PCL|Li \u5faa\u73af1700\u5c0f\u65f6\uff08\u56fea\uff09\u3002\u57280.2\u20136.0 mA&nbsp;cm<sup>\u2212<\/sup><sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6d4b\u8bd5\u500d\u7387\u6027\u80fd\uff0cLi|TOC-PCL|Li\u6781\u5316\u7535\u538b\u66f4\u7a33\u5b9a\uff08\u56feb\uff09\u3002SEM\u548cXRF\u5747\u68c0\u6d4b\u5230\u5faa\u73af\u540e\u9502\u91d1\u5c5e\u8868\u9762\u7684\u5bcc\u949b\u65e0\u673a\u5c42\uff08\u56fec\u3001d\uff09\uff1bTOC-PCL\u8c03\u63a7\u7684SEI\u5448\u5206\u5c42\u7ed3\u6784\uff08\u5916\u5c42\u6709\u673a\u67d4\u6027\u5c42\u3001\u5185\u5c42\u65e0\u673a\u521a\u6027\u5c42\uff09\uff0c\u53ef\u6291\u5236\u526f\u53cd\u5e94\u548c\u9502\u679d\u6676\uff08\u56fee\uff09\u3002XPS \u6df1\u5ea6\u5256\u6790\u663e\u793a\uff0cTOC-PCL\u7535\u89e3\u6db2\u4e2dSEI\u66f4\u8584\uff0c\u4e14\u4e0d\u540c\u6df1\u5ea6\u6709\u5747\u5300Ti\u4fe1\u53f7\uff08\u5bf9\u5e94 TiO<sub>2<\/sub>\u3001Li<sub>2<\/sub>TiF<sub>6<\/sub>\u7b49\uff09\uff08\u56fef\uff09\uff1b\u57fa\u51c6\u7535\u89e3\u6db2SEI 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g<sup>\u2212<\/sup><sup>1<\/sup>\u3001\u4fdd\u6301\u7387 80.4%\uff0c\u5176\u500d\u7387\u6027\u80fd\u4f18\u5f02\uff080.2\u20135 C\u5bb9\u91cf 127\u2013194 mAh g<sup>\u2212<\/sup><sup>1<\/sup>\uff09\uff08\u56fea\u2212d\uff09\u3002\u9ad8\u6e29\u4e0e\u9ad8\u622a\u6b62\u7535\u538b\u4e0b\u6027NCM811|TOC-PCL|Li\u53ef\u5b9e\u73b0\u7a33\u5b9a\u957f\u5faa\u73af\uff08\u56fee\u3001f\uff09\u3002\u9ad8\u8f7d\u91cf\u3001\u9ad8\u954d\u542b\u91cf\u4e0b\uff0cNCM|TOC-PCL|Li\u7535\u6c60\u4e5f\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u6c60\u6027\u80fd\uff08\u56feg\u2212i\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"398\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/de5bcf7d8eaea98-15.png\" alt=\"\" class=\"wp-image-269519\"\/><\/figure>\n\n\n\n<p><strong>\u56fe5. <\/strong>TOC-PCL\u5bf9\u9ad8\u954d\u6b63\u6781\u754c\u9762\u7684\u7a33\u5b9a\u4f5c\u7528\u3002<\/p>\n\n\n\n<p>\u7528TOF\u2013SIMS\u63a2\u7a76TOC-PCL\u8c03\u63a7\u7684\u6b63\u6781CEI\u7ec4\u5206\uff1aTiO<sub>2<\/sub>\u207b\u7b49\u65e0\u673a\u6210\u5206\u5206\u5e03\u5747\u5300\uff0cCEI\u4e2dLiF\u8fdc\u591a\u4e8eC\u2013F\uff08\u6c1f\u4ee5\u65e0\u673a\u5f62\u5f0f\u4e3a\u4e3b\uff09\uff08\u56fea\uff09\uff1bXPS\u7ed3\u679c\u8bf4\u660e\u57fa\u51c6\u7535\u89e3\u6db2\u4e2d\u78b3\u9178\u76d0\u5206\u89e3\u4ea7\u751f\u5f3a\u6709\u673a\u4fe1\u53f7\uff0cTOC-PCL\u8c03\u63a7\u5f62\u6210\u7684\u5bccTi\u2013F\/Ti\u2013O\u7684CEI\u53ef\u6291\u5236\u7535\u89e3\u6db2\u5206\u89e3\uff0c\u51cf\u5c11\u6709\u673a\u526f\u4ea7\u7269\u3001\u589e\u52a0 LiF\uff08\u56feb\u2212d\uff09\u3002\u539f\u4f4d XRD \u663e\u793a\uff0cTOC-PCL\u7535\u89e3\u6db2\u4e2d NCM811\uff08003\uff09\u5cf0\u504f\u79fb 0.49\u00b0\uff08\u5c0f\u4e8e\u57fa\u51c6\u7535\u89e3\u6db2\u7684 0.62\u00b0\uff09\uff0cc\u8f74\u53d8\u5f62\u5c0f\u3001\u53ef\u9006\u6027\u4f18\uff08\u56fee\u3001f\uff09\u3002\u57fa\u51c6\u7535\u89e3\u6db2\u5faa\u73af\u540eNCM811\u9897\u7c92\u8868\u9762\u6709\u660e\u663e\u88c2\u7eb9\uff0cTOC-PCL\u8c03\u63a7\u7684\u9897\u7c92\u8868\u9762\u5b8c\u6574\uff0c\u5bccTi \u754c\u9762\u5206\u5e03\u5747\u5300\uff0c\u4e14\u5f62\u6210\u8584\u800c\u5747\u5300\u7684CEI\uff089\u201310 nm\uff09\uff0c\u57fa\u51c6\u7535\u89e3\u6db2CEI\u539a\u4e14\u4e0d\u5747\uff0818\u201324 nm\uff09\uff08\u56feg\u2212j\uff09\u3002HAADF\u2013STEM\u663e\u793a\u57fa\u51c6\u7535\u89e3\u6db2\u4e2dNCM811\u9010\u6b65\u53d8\u4e3a\u5ca9\u76d0\u76f8\uff0cTOC-PCL\u53ef\u6291\u5236\u9633\u79bb\u5b50\u65e0\u5e8f\uff0c\u7ef4\u6301\u5c42\u72b6\u7ed3\u6784\u4e0eLi\u207a\u6269\u6563\u901a\u9053\uff08\u56fek\u3001l\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"395\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2025\/11\/aa3023e0288002c-11.png\" alt=\"\" class=\"wp-image-269520\"\/><\/figure>\n\n\n\n<p><strong>\u56fe6. <a><\/a><\/strong>\u8f6f\u5305\u7535\u6c60\u7684\u7535\u5316\u5b66\u53ca\u8d85\u58f0\u6210\u50cf\u5206\u6790\u3002<\/p>\n\n\n\n<p><a><\/a>1.6 Ah\u7ea7NCM811||Li\u8f6f\u5305\u7535\u6c600.3 C\u500d\u7387\u4e0b\u5faa\u73af150\u6b21\uff0c\u5bb9\u91cf\u4fdd\u6301\u738789.5%\uff08\u56fea\u3001b\uff09\u3002\u901a\u8fc7\u539f\u4f4d\u8d85\u58f0\u76d1\u6d4b\u6280\u672f\uff08\u4fe1\u53f7\u7279\u5f81\u4e3a\u7ea2\u5f3a\u84dd\u5f31\uff0c\u53cd\u6620\u7535\u6c60\u7ed3\u6784\u4e0e\u754c\u9762\u72b6\u6001\u7684\u53d8\u5316\uff09\u53d1\u73b0\uff0c\u6dfb\u52a0TOC-PCL\u8c03\u63a7\u7684\u7535\u6c60\u8868\u73b0\u51fa\u4fe1\u53f7\u5f3a\u5ea6\u9ad8\u4e14\u5206\u5e03\u5747\u5300\u7684\u7279\u70b9\uff0c\u8868\u660e\u5176\u754c\u9762\u66f4\u4e3a\u7a33\u5b9a\uff08\u56fec\u2212f\uff09\u30023 Ah NCM811|TOC-PCL|Si\/C\u8f6f\u5305\u7535\u6c60\u57280.5 C\u4e0b\u5faa\u73af500\u6b21\u4fdd\u6301\u7387 80.2%\uff0c\u539a\u5ea6\u81a8\u80c0\u7387\u4ec516.6%\uff08\u56feg\u3001h\uff09\u3002<\/p>\n\n\n\n<p><strong>\u3010\u7ed3\u8bba\u3011<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u672c\u7814\u7a76\u5408\u6210\u7684\u949b\u6c27\u56e2\u7c07\uff08TOC-PCL\uff09\u4f5c\u4e3a\u591a\u529f\u80fd\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\uff0c\u53ef\u901a\u8fc7\u6e05\u9664H<sub>2<\/sub>O\/HF\u6742\u8d28\u3001\u539f\u4f4d\u6784\u5efa\u5bcc\u542bTiO<sub>2<\/sub>\u7b49\u65e0\u673a\u6210\u5206\u7684\u7a33\u5b9aSEI\/CEI\u754c\u9762\uff0c\u6709\u6548\u63d0\u5347\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u9502\u91d1\u5c5e\u7535\u6c60\u754c\u9762\u7a33\u5b9a\u6027\uff0c\u4f7fNCM811||Li\u7535\u6c601&nbsp;C\u5faa\u73af1000\u6b21\u5bb9\u91cf\u4fdd\u6301\u7387\u8fbe80.4%\uff0c\u4e14\u5728\u8d85\u9ad8\u8f7d\u91cf\u3001\u9ad8\u954d\u542b\u91cf\u7535\u6c60\u53caAh\u7ea7\u8f6f\u5305\u7535\u6c60\u4e2d\u5747\u5c55\u73b0\u4f18\u5f02\u7a33\u5b9a\u6027\u4e0e\u53ef\u6269\u5c55\u6027\u3002\u8fd9\u79cd\u7ed3\u6784\u521b\u65b0\u7684\u91d1\u5c5e-\u6c27\u56e2\u7c07\u7535\u89e3\u8d28\u6dfb\u52a0\u5242\u4e3a\u6784\u5efa\u5177\u6709\u957f\u5faa\u73af\u5bff\u547d\u548c\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u7a33\u5b9a\u9502\u91d1\u5c5e\u7535\u6c60\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7b56\u7565\u3002<\/p>\n\n\n\n<p><strong>\u6587\u7ae0\u94fe\u63a5<\/strong><strong><\/strong><\/p>\n\n\n\n<p>Wenjie Lin, Qiang Gao, Yi Zhang, Fenghua Zhang, Zhenyu Huang, Qi Kang, Yaqi Liao, Lin Wu, Shuaipeng Hao, Yang Ren, Fei Pei*, Yunhui Huang*, Tuning interphasial chemistry with titanium\u2013oxo clusters for high-energy-density lithium metal batteries. <strong><em>J. Am. Chem. Soc. <\/em><\/strong>2025, 10.1021\/jacs.5c13474. <a href=\"https:\/\/doi.org\/10.1021\/jacs.5c13474\"><u>https:\/\/doi.org\/10.1021\/jacs.5c13474<\/u><\/a><\/p>\n\n\n\n<p><strong>\u9ec4\u4e91\u8f89\u6559\u6388\u8bfe\u9898\u7ec4\u62db\u8058\u805a\u5408\u7269\u56fa\u6001\u9502\u7535\u6c60\u65b9\u5411\u535a\u58eb\u540e\uff0c\u8be6\u60c5\u8054\u7cfb\uff1apeifei@hust.edu.cn<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u4f5c\u8005\u7b80\u4ecb<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>\u88f4\u975e\u526f\u7814\u7a76\u5458<\/strong>\uff0c\u695a\u5929\u82f1\u624d\u8ba1\u5212\u9752\u5e74\u62d4\u5c16\u4eba\u624d\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u7279\u522b\u8d44\u52a9\u535a\u58eb\u540e(\u5bfc\u5e08\u9ec4\u4e91\u8f89\u6559\u6388)\u3002\u53a6\u95e8\u5927\u5b66\u535a\u58eb(\u5bfc\u5e08\u90d1\u5357\u5cf0\u9662\u58eb)\u3002\u957f\u671f\u4ece\u4e8b\u9ad8\u6bd4\u80fd\u9502\u91d1\u5c5e\u7535\u6c60\u3001\u56fa\u6001\u805a\u5408\u7269\u7535\u89e3\u8d28\u7b49\u65b9\u9762\u7684\u7814\u7a76\u3002\u4e3b\u6301\u56fd\u81ea\u7136\u9762\u4e0a\u9879\u76ee\u3001\u56fd\u81ea\u7136\u9752\u5e74\u57fa\u91d1\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u7279\u522b\u8d44\u52a9\u3001\u4e2d\u56fd\u535a\u58eb\u540e\u9762\u4e0a\u8d44\u52a9\u4ee5\u53ca\u6e56\u5317\u7701\u535a\u58eb\u540e\u521b\u65b0\u5c97\u4f4d\u8d44\u52a9\u7b49\uff0c\u72ec\u7acb\u627f\u62c5\u5e94\u6025\u7ba1\u7406\u90e8\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5f00\u653e\u8bfe\u9898\u3001\u6d59\u6c5f\u7701\u6c7d\u8f66\u7535\u5b50\u667a\u80fd\u5316\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5f00\u653e\u8bfe\u9898\uff0c\u6838\u5fc3\u53c2\u4e0e\u56fd\u81ea\u7136\u91cd\u5927\u7814\u7a76\u8ba1\u5212\u3001\u5de5\u4fe1\u90e8\u56fa\u6001\u7535\u6c60\u91cd\u5927\u9879\u76ee\u4ee5\u53ca\u79d1\u6280\u90e8\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3002\u4ee5\u7b2c\u4e00\/\u901a\u8baf\u4f5c\u8005\u53d1\u8868\u5305\u542bNature\u3001Nat. Commun.(2\u7bc7)\u3001Adv. Mater.(2\u7bc7)\u3001JACS\u3001Natl. Sci. Rev\u3001Joule\u3001Energy Environ. Sci. (2\u7bc7)\u3001Adv. Energy Mater.(3\u7bc7)\u3001Adv. Funct. Mater.\u3001ACS Nano\u5728\u5185\u7684\u671f\u520a24\u7bc7\uff0c\u8c37\u6b4c\u5b66\u672f\u5f15\u75285400\u4f59\u6b21\uff0c\u6388\u6743\/\u516c\u5f00\u53d1\u660e\u4e13\u522920\u9879\u3002\u62c5\u4efb\u56fd\u9645\u671f\u520aeScience\u3001Renewables\u548cCarbon Neutralization\u9752\u5e74\u7f16\u59d4\u3002<\/p>\n\n\n\n<p><strong>\u9ec4\u4e91\u8f89\u6559\u6388<\/strong>\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u6559\u6388\/\u535a\u5bfc\uff0c\u6821\u5b66\u672f\u59d4\u5458\u4f1a\u526f\u4e3b\u4efb\uff0c\u6559\u80b2\u90e8\u201c\u957f\u6c5f\u5b66\u8005\u201d\u7279\u8058\u6559\u6388\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff0c\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u5e38\u52a1\u7406\u4e8b\uff0cElectrochem. Energy Rev.\u526f\u4e3b\u7f16\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u9502\u79bb\u5b50\u52a8\u529b\u4e0e\u50a8\u80fd\u7535\u6c60\u3001\u4e0b\u4e00\u4ee3\u9ad8\u6bd4\u80fd\u548c\u9ad8\u5b89\u5168\u7535\u6c60\u3001\u7535\u6c60\u5148\u8fdb\u76d1\u6d4b\u6280\u672f\u7b49\u3002\u6240\u7814\u53d1\u7684\u78f7\u9178\u94c1\u9502\u590d\u5408\u6b63\u6781\u6750\u6599\u3001\u7535\u6c60\u8d85\u7ea7\u5feb\u5145\u5173\u952e\u6280\u672f\u3001\u7535\u6c60\u5065\u5eb7\u72b6\u6001\u8d85\u58f0\u68c0\u6d4b\u6280\u672f\u53ca\u8bbe\u5907\u7b49\u4e00\u6279\u6210\u679c\u5df2\u5e94\u7528\u4e8e\u534e\u4e3a\u3001\u5b81\u5fb7\u65f6\u4ee3\u3001\u5b81\u5fb7\u65b0\u80fd\u6e90\u3001\u6bd4\u4e9a\u8fea\u5357\u65b9\u7535\u7f51\u3001\u901a\u7528\u6c7d\u8f66\u3001\u7279\u65af\u62c9\u7b49\u4f01\u4e1a\u3002\u5728Science\u3001Nature\u3001Nat. Mater.\u3001Nat. Sustain.\u3001Nat. Commun.\u3001J. Am. Chem. Soc.\u3001Chem. Soc. Rev\u3001Energy Environ. Sci.\u3001Adv. Mater.\u3001Joule\u7b49\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u6587700\u4f59\u7bc7\uff0c\u8bba\u6587\u5f15\u75288.3\u4e07\u4f59\u6b21\uff0cH-\u56e0\u5b50150\uff0c\u83b7\u6559\u80b2\u90e8\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u4e8c\u7b49\u5956\u3001\u6e56\u5317\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3002<\/p>\n\n\n\n<p><a href=\"http:\/\/sysdoing.mat.hust.edu.cn\/info\/1058\/2273.htm\"><u>http:\/\/sysdoing.mat.hust.edu.cn\/info\/1058\/2273.htm<\/u><\/a>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7b2c\u4e00\u4f5c\u8005\uff1a\u6797\u6587\u6770 \u901a\u8baf\u4f5c\u8005\uff1a\u88f4\u975e*\uff0c\u9ec4\u4e91\u8f89* \u5355\u4f4d\uff1a\u534e\u4e2d\u79d1\u6280\u5927\u5b66 \u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662&nbsp;&nbsp;\u6750\u6599\u6210\u5f62\u4e0e\u6a21\u5177\u6280\u672f\u5168\u56fd\u91cd\u70b9\u5b9e\u9a8c\u5ba4 \u3010\u7814\u7a76\u80cc\u666f\u3011 \u9502\u91d1&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-269513","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269513"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=269513"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269513\/revisions"}],"predecessor-version":[{"id":269521,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/269513\/revisions\/269521"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=269513"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=269513"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=269513"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}