{"id":269994,"date":"2025-12-24T08:41:00","date_gmt":"2025-12-24T00:41:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=269994"},"modified":"2025-12-23T18:46:11","modified_gmt":"2025-12-23T10:46:11","slug":"%e6%b7%b1%e5%9c%b3%e5%a4%a7%e5%ad%a6%e5%bc%a0%e9%9b%b7%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%e6%9c%80%e6%96%b0advanced-functional-materials%e8%b5%8f%e6%9e%90%ef%bc%9a%e6%8f%ad%e7%a4%bani-n2o2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=269994","title":{"rendered":"\u6df1\u5733\u5927\u5b66\u5f20\u96f7\u6559\u6388\u8bfe\u9898\u7ec4\u6700\u65b0Advanced Functional Materials\u8d4f\u6790\uff1a\u63ed\u793aNi-N2O2\u5f02\u76f8\u5206\u5b50\u50ac\u5316\u5242\u5728H2O2\u7535\u5408\u6210\u7684\u9ad8\u58f3\u5c42\u914d\u4f4d\u89c4\u5f8b"},"content":{"rendered":"\n

TOC<\/strong>\u56fe<\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

<\/p>\n\n\n\n

\u56db<\/strong>\u3001\u8bba\u6587\u76f8\u5173\u4fe1\u606f<\/strong>\uff1a<\/p>\n\n\n\n

\u7b2c\u4e00\u4f5c\u8005\uff08\u6216\u8005\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff09\uff1a\u5f6d\u5efa\u948a\uff08\u526f\u7814\u7a76\u5458\uff09\uff0c\u9ea6\u666f\u884c\uff08\u7855\u58eb\u7814\u7a76\u751f\uff09 <\/p>\n\n\n\n

\u901a\u8baf\u4f5c\u8005\uff08\u6216\u8005\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\uff1a\u5f20\u96f7\u6559\u6388\uff0c\u674e\u6167\u9f50\u52a9\u7406\u6559\u6388\uff0c\u4e50\u5f26\u526f\u6559\u6388             <\/p>\n\n\n\n

\u901a\u8baf\u5355\u4f4d\uff1a\u6df1\u5733\u5927\u5b66<\/p>\n\n\n\n

Doi:       https:\/\/doi.org\/10.1002\/adfm.202527905<\/strong><\/u><\/strong><\/a>           <\/p>\n\n\n\n

\u80cc\u666f\u4ecb\u7ecd\uff1a\u8fc7\u6c27\u5316\u6c22\u662f\u4e00\u79cd\u91cd\u8981\u7684\u7eff\u8272\u6c27\u5316\u5242\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u533b\u7597\u6d88\u6bd2\u3001\u5e9f\u6c34\u5904\u7406\u3001\u7eb8\u6d46\u6f02\u767d\u548c\u6709\u673a\u5408\u6210\u7b49\u9886\u57df\u3002\u4f20\u7edf\u84bd\u918c\u5177\u6709\u9ad8\u80fd\u8017\u3001\u590d\u6742\u7684\u8fd0\u8f93\u7cfb\u7edf\u4ee5\u53ca\u5927\u91cf\u6709\u673a\u6eb6\u5242\u7684\u4f7f\u7528<\/strong>\u7684\u7f3a\u70b9<\/strong>\uff0c\u4e0d\u4ec5\u6210\u672c\u9ad8\u6602\uff0c\u8fd8\u5e26\u6765\u663e\u8457\u7684\u73af\u5883\u8d1f\u62c5\u3002\u7535\u5316\u5b66\u5408\u6210\u901a\u8fc7\u4e24\u7535\u5b50\u6c27\u8fd8\u539f\u53cd\u5e94\u5236\u5907\u8fc7\u6c27\u5316\u6c22\uff0c\u88ab\u89c6\u4e3a\u4e00\u79cd\u66f4\u6e05\u6d01\u3001\u8282\u80fd\u7684\u66ff\u4ee3\u65b9\u6848\u3002\u8fd1\u5e74\u6765\uff0c\u78b3\u57fa\u6750\u6599\u3001\u91d1\u5c5e\u5408\u91d1\u3001\u5355\u539f\u5b50\u50ac\u5316\u5242\u7b49\u591a\u79cd\u6750\u6599\u88ab\u5f00\u53d1\u7528\u4e8e\u8fc7\u6c27\u5316\u6c22\u7535\u5408\u6210\u3002\u5176\u4e2d\uff0c\u5355\u539f\u5b50\u50ac\u5316\u5242\u56e0\u5176\u8fd1100%\u7684\u539f\u5b50\u5229\u7528\u6548\u7387<\/strong>\u548c\u53ef\u901a\u8fc7\u539f\u5b50\u7ea7\u914d\u4f4d\u5de5\u7a0b\u7cbe\u786e\u8c03\u63a7\u7684\u7535\u5b50\u6784\u578b\u800c\u5907\u53d7\u5173\u6ce8\uff0c\u5728M-N-C SACs\u4e2d\uff0c\u5e73\u9762M-N<\/strong>\u2084<\/strong>\u6784\u578b\u88ab\u5e7f\u6cdb\u8ba4\u4e3a\u662fORR\u7684\u5185\u5728\u6d3b\u6027\u4f4d\u70b9<\/strong>\u3002\u8c03\u63a7\u8fd9\u4e9b\u4f4d\u70b9\u7684\u914d\u4f4d\u73af\u5883\u5df2\u6210\u4e3a\u8c03\u8282\u5176\u7535\u5b50\u7ed3\u6784\u548c\u4f18\u5316\u50ac\u5316\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002\u6b64\u5916\u6253\u7834 M-N\u2084 \u4f4d\u70b9\u7684\u9ad8\u5bf9\u79f0\u6027\u5df2\u88ab\u8bc1\u660e\u53ef\u4ee5\u6709\u6548\u91cd\u65b0\u5206\u5e03\u7535\u8377\u5bc6\u5ea6\uff0c\u79fb\u52a8d\u5e26\u4e2d\u5fc3\uff0c\u4ece\u800c\u6709\u5229\u4e8eO\u2082\u6d3b\u5316\u3001\u7535\u5b50\u8f6c\u79fb\u548c\u7a33\u5b9a\u5173\u952e\u4e2d\u95f4\u4f53\u3002\u56e0\u6b64\uff0c<\/a>\u4f4e\u5bf9\u79f0\u6027\u7684 M-N<\/strong>\u2082<\/strong>O<\/strong>\u2082<\/strong> \u6784\u578b\u5c55\u73b0\u51fa\u663e\u8457\u4f18\u52bf<\/strong>\uff1a\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3001\u5728\u4e0d\u6539\u53d8\u7b2c\u4e00\u914d\u4f4d\u5c42\u7684\u60c5\u51b5\u4e0b\u5b9e\u73b0\u7535\u5b50\u91cd\u65b0\u5206\u914d\u7684\u66f4\u5927\u7075\u6d3b\u6027\uff0c\u4ee5\u53ca\u901a\u8fc7\u914d\u4f4d\u6570\/\u5bf9\u79f0\u6027\u8c03\u63a7\u53ef\u8c03\u8282\u7684\u81ea\u65cb\u6001\/\u6c27\u5316\u6001\u3002\u5c3d\u7ba1\u5df2\u6709\u7814\u7a76\u62a5\u9053\u4e86\u5177\u6709\u9ad8\u8fc7\u6c27\u5316\u6c22\u9009\u62e9\u6027\u7684M-N\u2082O\u2082\u50ac\u5316\u5242\uff0c\u4f46\u914d\u4f4d\u8bf1\u5bfc\u7684\u7535\u5b50\u6784\u578b\u53d8\u5316\u4e0e\u50ac\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u57fa\u672c\u5173\u8054\u4ecd\u672a\u88ab\u5145\u5206\u7406\u89e3\u3002\u7279\u522b\u662f\uff0c\u81ea\u65cb\u6001\u5bf9\u8c03\u63a7<\/strong>2e<\/strong>–<\/sup><\/strong><\/sup><\/strong> ORR \u8def\u5f84\u7684\u5f71\u54cd<\/strong>\u4ecd\u662f\u4e00\u4e2a\u672a\u88ab\u6df1\u5165\u63a2\u7d22\u7684\u9886\u57df\u3002<\/p>\n\n\n\n

\u7814\u7a76\u51fa\u53d1\u70b9<\/strong>\uff1a\u672c\u5de5\u4f5c\u9009\u62e9\u4e86Ni-N<\/strong>\u2082<\/strong>O<\/strong>\u2082<\/strong>\u5f02\u8d28\u5206\u5b50\u50ac\u5316\u5242\u4f5c\u4e3a\u6a21\u578b\u4f53\u7cfb<\/strong>\uff0c\u901a\u8fc7\u9ad8\u58f3\u5c42\u7cbe\u51c6\u8c03\u63a7\u7684\u5f02\u76f8\u5206\u5b50Ni\u4e2d\u5fc3\u7684\u81ea\u65cb\u6001\u3002\u4ece\u201cN\u4fa7\u201d\u548c\u201cO\u4fa7\u201d\u4e24\u4e2a\u65b9\u5411\u5bf9\u914d\u4f4d\u73af\u5883\u8fdb\u884c\u5de5\u7a0b\u5316\u6539\u9020\uff0c\u5e76\u5bfb\u627e\u81ea\u65cb\u53d8\u5316\u4e0eORR\u6027\u80fd\uff0cH2<\/sub>O2<\/sub>\u9009\u62e9\u6027\u7684\u5173\u7cfb\u3002<\/p>\n\n\n\n

\u201cN \u4fa7\u201d\u5de5\u7a0b\u65e8\u5728\u901a\u8fc7<\/strong>\u66ff\u6362<\/strong>\u4e0d\u7a33\u5b9a\u7684\u4e9a\u80fa\u7ed3\u6784<\/strong>\u5e76<\/strong>\u4f7f\u7528\u521a\u6027\u7ed3\u6784<\/strong>\u6765\u63d0\u9ad8\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n\n

\u201cO \u4fa7\u201d\u5de5\u7a0b\u5219\u901a\u8fc7\u7528\u5f31\u573a\u914d\u4f53\u66ff\u6362\u5f3a\u573a\u914d\u4f53<\/strong>\uff0c\u751f\u6210\u4e86\u4e24\u4e2a\u9ad8\u81ea\u65cb\u6837\u54c1.<\/p>\n\n\n\n

\u56fe\u6587\u89e3\u6790\uff1a<\/strong><\/p>\n\n\n\n

<\/a>\u56fe1 <\/strong>\u6750\u6599\u5408\u6210\u4e0e\u7535\u955c\u8868\u5f81<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

a) \u8c03\u6574Ni-N<\/a>2<\/sub>O2<\/sub>\u914d\u5408\u7269\u7684\u914d\u4f4d\u73af\u5883
b) Ni-N2<\/sub>O2<\/sub>HMCs\u7ed3\u6784\u793a\u610f\u56fe\u3002
c) Ni-N2<\/sub>O2<\/sub>HMCs\u7684TEM\u56fe\u50cf
d) Ni-N2<\/sub>O2<\/sub>HMCs\u7684HAADF-STEM\u56fe\u50cf<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe<\/strong>2<\/strong> <\/strong>\u6750\u6599\u7684XPS\u4e0eXAS\u8868\u5f81<\/strong><\/strong><\/p>\n\n\n\n

a) Ni-N2<\/sub>O2 <\/sub>HMCs\u7684Ni 2p\u56fe\u50cf\uff0c\u53ef\u4ee5\u89c1\u5230\u9ad8\u81ea\u65cb\u6837\u54c1\u51fa\u73b0\u4e86\u660e\u663e\u7684\u536b\u661f\u5cf0\uff0c\u5e76\u4e14\u6c27\u5316\u6001\u66f4\u9ad8
b) Ni-N2<\/sub>O2<\/sub>\u7684Ni 2p\uff0c\u53ef\u4ee5\u5421\u5576\u6c2e\u914d\u4f4d\u6837\u54c1\u7684XPS\u7ed3\u5408\u80fd\u9ad8\u4e8e\u4e9a\u80fa\u7ed3\u6784\u6837\u54c1
c) XANES \u8c31\u56fe\u663e\u793a\uff0c\u6240\u6709 Ni-N\u2082O\u2082\u00a0HMCs \u7684\u8fb9\u7f18\u80fd\u91cf\u63a5\u8fd1 NiO\uff0c\u8868\u660e\u954d\u7684\u4ef7\u6001\u4e3a Ni\u00b2\u207a\u3002
d) EXAFS \u5206\u6790\u663e\u793a\uff0c\u6240\u6709 Ni-N\u2082O\u2082\u00a0HMCs \u4e2d\u5747\u672a\u89c2\u5bdf\u5230 Ni-Ni \u6216 Ni-O-Ni \u6563\u5c04\u5cf0\uff0c\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u954d\u4f4d\u70b9\u662f\u539f\u5b50\u7ea7\u5206\u6563\u3002<\/p>\n\n\n\n

(e)\u901a\u8fc7\u62df\u5408\u540c\u6b65\u8f90\u5c04\u8bc1\u660eNi-N2O2 HMCs\u7684\u914d\u4f4d\u60c5\u51b5<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe<\/strong>3 RRDE\u6d4b\u8bd5<\/strong><\/strong><\/p>\n\n\n\n

a) LSV\u6d4b\u8bd5\uff1a\u9ad8\u81ea\u65cb\u6837\u54c1\u5728RRDE\u6d4b\u8bd5\u4e2d\u8d77\u59cb\u7535\u4f4d\u660e\u663e\u9ad8\u4e8e\u4f4e\u81ea\u65cb\u6837\u54c1<\/p>\n\n\n\n

b) RRDE\u9009\u62e9\u6027\uff1a\u53ef\u4ee5\u770b\u51faNi-DPP HMCs \u5728\u5bbd\u7535\u4f4d\u4e0b\uff080.2-0.7 V vs. RHE\uff09\u7684\u9009\u62e9\u6027\u5747\u9ad8\u4e8e90%
c) \u57280.4V\u30010.5V\u548c0.6V\u65f6\uff0cNi-N2<\/sub>O2<\/sub> <\/sub>HMCs\u7684H2O2\u9009\u62e9\u6027\u4e0e\u8d77\u59cb\u7535\u4f4d\uff08E0<\/sub>\uff09\u4e4b\u95f4\u7684\u76f8\u5173\u6027\u3002
d) N2<\/sub>\u6c1b\u56f4\u4e0b\u7684H2<\/sub>O2<\/sub>RR\u6d4b\u8bd5\uff0c\u53ef\u4ee5\u770b\u51faNi-DPP HMCs\u5bf9H2<\/sup>O2<\/sup>\u7684\u5206\u89e3\u80fd\u529b\u6700\u5f31\uff0c\u8fdb\u4e00\u6b65\u5370\u8bc1\u5176\u9009\u62e9\u6027\u9ad8\u7684\u539f\u56e0<\/p>\n\n\n\n

(e)KSCN\u6bd2\u5316\u5b9e\u9a8c\uff1a\u4f4e\u81ea\u65cb\u6837\u5728KSCN\u6bd2\u5316\u5b9e\u9a8c\u4e2d\u7535\u6d41\u51cf\u5f31\u7a0b\u5ea6\u660e\u663e\u4f4e\u4e8e\u9ad8\u81ea\u65cb\u6837\u54c1\uff0c\u8fd9\u5f88\u53ef\u80fd\u5f52\u529f\u4e8e\u90bb\u8fd1Ni-N2<\/sub>O2<\/sub>\u57fa\u5e8f\u7684\u03b1\u78b3\uff0c\u8be5\u57fa\u5e8f\u4fc3\u8fdbO2<\/sub>\u6d3b\u5316\uff0c\u5e76\u4e0eSCN–<\/sup>\u7ade\u4e89\u5438\u9644\u3002<\/p>\n\n\n\n

(f)Ni-DPP HMCs\u7684H2<\/sub>O2<\/sub>\u9009\u62e9\u6027\uff0c\u8d77\u59cb\u7535\u4f4d\uff08E0<\/sub>\uff09\u4e0e\u5df2\u62a5\u9053\u6587\u732e\u8fdb\u884c\u5bf9\u6bd4<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe<\/strong>4<\/strong>\u00a0<\/strong>\u5de5\u4e1a\u7ea7\u7535\u6d41\u4e0b\u9ad8\u6548\u751f\u4ea7H<\/strong>2<\/sub><\/strong><\/sub><\/strong>O<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u4e0e\u6709\u673a\u5408\u6210\u5e94\u7528<\/strong><\/p>\n\n\n\n

(a) 0.1M KOH\u6d41\u52a8\u6c60\u4e0b\u7684LSV<\/p>\n\n\n\n

(b) 1M KOH\u4e0b\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u7684FE\u4e0eH2<\/sub>O2<\/sub>\u4ea7\u7387<\/p>\n\n\n\n

(c) \u6d41\u52a8\u6c60\u6027\u80fd\u5bf9\u6bd4\uff1aNi-DPP HMCs\u80fd\u5728\u6d41\u52a8\u7535\u89e3\u6c60\u4e2d\u4e8e800 mA cm\u207b\u00b2\u7684\u5de5\u4e1a\u7ea7\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5b9e\u73b0\u4e8652.13 mol gcat<\/sub>\u207b\u00b9 h\u207b\u00b9\u7684\u9ad8\u4ea7\u7387\uff0c\u9886\u5148\u4e8e\u5df2\u62a5\u9053\u6587\u732e\u3002<\/p>\n\n\n\n

(d) \u6d41\u52a8\u6c60\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5<\/p>\n\n\n\n

(e) Ni-DPP HMCs\u5728\u6d41\u52a8\u6c60\u9634\u6781\u5bf9\u82ef\u7532\u8148\u539f\u4f4d\u6c34\u89e3\u7684\u793a\u610f\u56fe<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe5 \u673a\u7406\u89e3\u91ca<\/strong><\/strong><\/p>\n\n\n\n

<\/a>(a) Ni-DPP HMCs\u539f\u4f4d\u7ea2\u5916\u6d4b\u8bd5\uff0c\u53ef\u4ee5\u89c1\u5230 OOH*\u5cf0\u6bd4\u5176\u4ed6\u6837\u54c1\u5f3a\u5ea6\u66f4\u9ad8\uff0c\u4f53\u73b0\u4e86\u5176\u826f\u597d\u7684OOH*\u5438\u9644\u80fd\u529b\uff0c\u89e3\u91ca\u5176\u9009\u62e9\u6027\u826f\u597d\u7684\u539f\u56e0<\/p>\n\n\n\n

(b) \u539f\u4f4d\u62c9\u66fc\u6d4b\u8bd5\uff1aNi-DPP HMC\u5728755 cm\u207b\u00b9\u5904\u8868\u73b0\u51fa\u5178\u578b\u7684Ni-OOH\u5cf0\uff0c\u968f\u7740\u8fc7\u7535\u4f4d\u5347\u9ad8\uff080.5V-0.3V\uff09\u800c\u589e\u5f3a\uff0c\u8fd9\u4e0e\u539f\u4f4dATR-SEIRAS\u4e2d\u89c2\u5bdf\u5230\u7684*OOH\u8d8b\u52bf\u4e00\u81f4\u3002<\/p>\n\n\n\n

(c-d) EPR\u6d4b\u8bd5\u4e0e\u78c1\u5316\u7387\u6d4b\u8bd5\uff1a\u89e3\u91caNi-N2<\/sub>O2<\/sub> HMCs\u81ea\u65cb\u6001<\/p>\n\n\n\n

(e) \u4e0d\u540c\u81ea\u65cb\u6001Ni\u91d1\u5c5e\u4e2d\u5fc3\u7535\u5b50\u5206\u5e03\u793a\u610f\u56fe<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe6 DFT\u8ba1\u7b97<\/strong><\/strong><\/p>\n\n\n\n

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