{"id":270073,"date":"2025-12-30T20:14:00","date_gmt":"2025-12-30T12:14:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=270073"},"modified":"2025-12-30T21:31:00","modified_gmt":"2025-12-30T13:31:00","slug":"%e6%b8%a9%e5%b7%9e%e5%a4%a7%e5%ad%a6angew%ef%bc%9a%e5%8e%9f%e4%bd%8d%e8%a7%a3%e6%9e%90%e7%86%b5%e5%a2%9e%e7%a8%b3%e5%ae%9a%e5%90%88%e9%87%91%e7%bc%ba%e9%99%b7%e7%bb%93%e6%9e%84%e7%9a%84%e5%86%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=270073","title":{"rendered":"\u6e29\u5dde\u5927\u5b66Angew\uff1a\u539f\u4f4d\u89e3\u6790\u71b5\u589e\u7a33\u5b9a\u5408\u91d1\u7f3a\u9677\u7ed3\u6784\u7684\u5185\u5728\u673a\u5236"},"content":{"rendered":"\n

doi.org\/10.1002\/anie.202520550<\/p>\n\n\n\n

Highly Stable Twin Defects Enabled by High Entropy Configuration<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u5bfc\u8bfb<\/strong><\/strong><\/p>\n\n\n\n

\u6676\u4f53\u7f3a\u9677\u5de5\u7a0b\u88ab\u8ba4\u4e3a\u662f\u63d0\u5347\u91d1\u5c5e\u50ac\u5316\u5242\u6027\u80fd\u7684\u91cd\u8981\u7b56\u7565\uff0c\u4f46\u5728\u7eb3\u7c73\u5c3a\u5ea6\u4e0b\uff0c\u7f3a\u9677\u5f80\u5f80\u5177\u6709\u53d7\u9650\u4e14\u4e9a\u7a33\u7684\u7279\u6027\uff0c\u5c24\u5176\u662f\u5728\u591a\u5143\u7d20\u5408\u91d1\u4f53\u7cfb\u4e2d\uff0c\u5176\u5f62\u6210\u4e0e\u7a33\u5b9a\u66f4\u52a0\u96be\u4ee5\u8c03\u63a7\u3002\u672c\u7814\u7a76\u62a5\u9053\u4e86\u4e00\u79cd\u5728\u78b3\u9650\u57df FeCoNiMn \u591a\u5143\u7d20\u7eb3\u7c73\u50ac\u5316\u5242\u4e2d\u9ad8\u5ea6\u5bcc\u96c6\u4e14\u957f\u671f\u7a33\u5b9a\u5b58\u5728\u7684\u5b6a\u6676\u7f3a\u9677\u7ed3\u6784\uff08T-FeCoNiMn\/C\uff09\u3002\u901a\u8fc7\u7ed3\u5408\u6df1\u5ea6\u5b66\u4e60\u5206\u6790\u3001\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u548c\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff0c\u4ece\u539f\u5b50\u5c3a\u5ea6\u63ed\u793a\u4e86\u5b6a\u6676\u7f3a\u9677\u7684\u5e94\u53d8\u5206\u5e03\u7279\u5f81\u53ca\u5176\u591a\u6b65\u5f62\u6210\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u591a\u5143\u7d20\u5408\u91d1\u5e26\u6765\u7684\u9ad8\u6784\u578b\u71b5\u663e\u8457\u62d3\u5bbd\u4e86\u4f53\u7cfb\u7684\u80fd\u91cf\u60c5\u51b5\uff0c\u4f7f\u539f\u672c\u5904\u4e8e\u9ad8\u80fd\u6001\u3001\u6613\u5931\u7a33\u7684\u539f\u5b50\u6784\u578b\u80fd\u591f\u901a\u8fc7\u7ed3\u6784\u81ea\u9002\u5e94\u4f18\u5148\u5f1b\u8c6b\u4e3a\u7a33\u5b9a\u7684\u5b6a\u6676\u7ed3\u6784\uff0c\u800c\u975e\u53d1\u751f\u53bb\u5b6a\u6676\u5316\uff0c\u4ece\u800c\u5b9e\u73b0\u5b6a\u6676\u7f3a\u9677\u5728\u5408\u6210\u8fc7\u7a0b\u53ca\u6790\u6c27\u53cd\u5e94\u957f\u671f\u50ac\u5316\u670d\u5f79\u8fc7\u7a0b\u4e2d\u7684\u6301\u7eed\u7a33\u5b9a\u5b58\u5728\u3002\u8be5\u5de5\u4f5c\u9610\u660e\u4e86\u71b5\u9a71\u52a8\u7684\u5b6a\u6676\u7f3a\u9677\u7a33\u5b9a\u673a\u5236\uff0c\u4e3a\u91d1\u5c5e\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u7ed3\u6784\u5de5\u7a0b\u8bbe\u8ba1\u4e0e\u6027\u80fd\u4f18\u5316\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n\n\n\n

1. \u9ad8\u5bc6\u5ea6\u5b6a\u6676\u591a\u7ec4\u5206\u7eb3\u7c73\u7c92\u5b50\u7684\u5408\u6210\u4e0e\u8868\u5f81<\/p>\n\n\n\n

\u901a\u8fc7\u914d\u4f53\u9650\u57df\u7684\u78b3\u70ed\u51b2\u51fb\u5408\u6210\uff08CHTS\uff09\u7b56\u7565\u4e0e\u9ad8\u71b5\u591a\u5143\u7d20\u6548\u5e94\u7684\u534f\u540c\u4f5c\u7528\uff0c\u53ef\u5728\u78b3\u5305\u8986\u7684 FeCoNiMn \u5408\u91d1\u7eb3\u7c73\u9897\u7c92\u4e2d\u5b9e\u73b0\u9ad8\u5bc6\u5ea6\u3001\u5f3a\u5e94\u53d8\u4e14\u7a33\u5b9a\u7684\u5b6a\u6676\u7f3a\u9677\uff0c\u5176\u5f62\u6210\u663e\u8457\u4f9d\u8d56\u4e8e\u914d\u4f4d\u9650\u57df\u4e0e\u9ad8\u71b5\u8bf1\u5bfc\u7684\u6676\u683c\u7578\u53d8\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

2. \u5b6a\u751fFeCoNiMn\/C\u5408\u91d1\u7eb3\u7c73\u7c92\u5b50\u7684\u5f62\u6838\u4e0e\u751f\u957f\u673a\u5236<\/p>\n\n\n\n

\u901a\u8fc7\u539f\u4f4d\u52a0\u70ed TEM \u7cfb\u7edf\u63ed\u793a\u4e86 CHTS \u8fc7\u7a0b\u4e2d\u5b6a\u6676\u7f3a\u9677\u7684\u5f62\u6210\u4e0e\u6f14\u5316\u673a\u5236\uff1a\u5728\u8d85\u5feb\u5347\u6e29\u4e0e\u51b7\u5374\u6761\u4ef6\u4e0b\uff0c\u91d1\u5c5e\u2013\u914d\u4f53\u524d\u9a71\u4f53\u7ecf\u5386\u201c\u77ac\u65f6\u6210\u6838\u2014\u5b9a\u5411\u805a\u96c6\u2014\u5b6a\u6676\u5f62\u6210\u4e0e\u8fc1\u79fb\u2014\u77f3\u58a8\u5c42\u9650\u57df\u751f\u957f\u201d\u7684\u591a\u9636\u6bb5\u8fc7\u7a0b\uff0c\u5176\u4e2d\u914d\u4f53\u8bf1\u5bfc\u7684\u975e\u5747\u5300\u914d\u4f4d\u5e94\u529b\u4e0e\u77f3\u58a8\u9650\u57df\u5171\u540c\u6291\u5236\u6676\u4f53\u5145\u5206\u5f1b\u8c6b\uff0c\u4ece\u800c\u5728\u5feb\u901f\u6dec\u51b7\u540e\u7a33\u5b9a\u4fdd\u7559\u9ad8\u5bc6\u5ea6\u5b6a\u6676\u7f3a\u9677\uff0c\u800c\u5bf9\u6bd4\u5b9e\u9a8c\u8868\u660e\u7f3a\u5931\u914d\u4f53\u6216\u91c7\u7528\u6162\u901f\u5347\u6e29\u5747\u4f1a\u663e\u8457\u524a\u5f31\u5b6a\u6676\u5f62\u6210\u5e76\u5f15\u53d1\u5143\u7d20\u504f\u6790\uff0c\u51f8\u663e CHTS \u5728\u6784\u7b51\u9ad8\u5bc6\u5ea6\u5b6a\u6676\u5408\u91d1\u7eb3\u7c73\u9897\u7c92\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

3. \u5b6a\u6676\u7f3a\u9677\u7a33\u5b9a\u6027\u7684\u8bc4\u4f30<\/p>\n\n\n\n

\u6211\u4eec\u901a\u8fc7\u539f\u4f4d\u52a0\u70ed TEM \u4e0e\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u76f8\u7ed3\u5408\uff0c\u4ece\u539f\u5b50\u5c3a\u5ea6\u7cfb\u7edf\u63ed\u793a\u4e86 FeCoNiMn \u9ad8\u71b5\u5408\u91d1\u4e2d\u5b6a\u6676\u7f3a\u9677\u7684\u5f62\u6210\u52a8\u529b\u5b66\u4e0e\u7a33\u5b9a\u673a\u5236\uff1a\u5728\u56fa\u6001\u56e2\u7c07\u5e76\u5408\u8fc7\u7a0b\u4e2d\uff0c\u9ad8\u80fd\u65e0\u5e8f\u6676\u754c\u7684\u5f62\u6210\u3001\u6676\u683c\u65cb\u8f6c\u4e0e\u91cd\u6784\u4fc3\u4f7f\u5b6a\u6676\u5728\u754c\u9762\u6210\u6838\u3001\u8fc1\u79fb\u5e76\u5411\u4f4e\u80fd\u6784\u578b\u6f14\u5316\uff0c\u800c\u9ad8\u71b5\u6548\u5e94\u663e\u8457\u62d3\u5bbd\u4e86\u5b6a\u6676\u754c\u9762\u80fd\u7684\u5206\u5e03\u8303\u56f4\uff0c\u4f7f\u9ad8\u80fd\u5b6a\u6676\u53ef\u81ea\u53d1\u8f6c\u5316\u4e3a\u4f4e\u80fd\u7a33\u5b9a\u5b6a\u6676\u800c\u975e\u53bb\u5b6a\u6676\u5316\uff1b\u8fdb\u4e00\u6b65\u7684\u539f\u4f4d\u9ad8\u6e29\u5bf9\u6bd4\u5b9e\u9a8c\u8868\u660e\uff0c\u968f\u7740\u6784\u578b\u71b5\u4ece\u5355\u91d1\u5c5e\u5230\u591a\u7ec4\u5143\u5408\u91d1\u9010\u6b65\u589e\u52a0\uff0c\u5b6a\u6676\u7ed3\u6784\u7684\u70ed\u7a33\u5b9a\u6027\u663e\u8457\u63d0\u5347\uff0c\u6700\u7ec8\u4f7f\u9ad8\u71b5 FeCoNiMn\/C \u7eb3\u7c73\u9897\u7c92\u5728\u9ad8\u6e29\u4e0b\u4ecd\u80fd\u4fdd\u6301\u9ad8\u5bc6\u5ea6\u3001\u7a33\u5b9a\u7684\u5b6a\u6676\u7f3a\u9677\uff0c\u4e3a\u5176\u957f\u671f\u50ac\u5316\u670d\u5f79\u63d0\u4f9b\u4e86\u7ed3\u6784\u57fa\u7840\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n
\"\"<\/figure>\n\n\n\n

4. \u5b6a\u6676\u7f3a\u9677\u5bf9OER\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd<\/p>\n\n\n\n

\u672c\u8282\u7cfb\u7edf\u9610\u660e\u4e86\u5b6a\u6676\u7f3a\u9677\u5bf9\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u6027\u80fd\u7684\u5173\u952e\u4fc3\u8fdb\u4f5c\u7528\uff1a\u5b6a\u6676\u5f15\u5165\u7684\u5f3a\u975e\u5747\u5300\u5e94\u53d8\u4e0e\u9ad8\u71b5\u6548\u5e94\u534f\u540c\u8c03\u63a7\u5c40\u57df\u7535\u5b50\u7ed3\u6784\uff0c\u6784\u5efa\u5f3a\/\u5f31\u5438\u9644\u4f4d\u70b9\u5171\u5b58\u7684\u6700\u4f18\u53cd\u5e94\u754c\u9762\uff0c\u4f7f T-FeCoNiMn\/C \u5728\u4f4e\u8fc7\u7535\u4f4d\u3001\u9ad8\u7535\u6d41\u5bc6\u5ea6\u548c\u8d85\u957f\u65f6\u95f4\u8fd0\u884c\u6761\u4ef6\u4e0b\u5747\u8868\u73b0\u51fa\u663e\u8457\u4f18\u4e8e\u5355\u91d1\u5c5e\u53ca\u4f4e\u71b5\u5408\u91d1\u7684\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\uff1b\u540c\u65f6\uff0c\u8be5 CHTS \u7b56\u7565\u53ef\u666e\u9002\u62d3\u5c55\u81f3 FeCoNiMnX \u9ad8\u71b5\u5408\u91d1\u4f53\u7cfb\uff0c\u5176\u4e2d X = V\u3001Nb\u3001Y\u3001Cr\u3001Zr\u3001Ce\u3001W\u3001La \u548c Ti\uff0c\u5e76\u53ef\u901a\u8fc7\u6210\u5206\u6bd4\u4f8b\u8c03\u63a7\u8fdb\u4e00\u6b65\u63d0\u5347\u50ac\u5316\u672c\u5f81\u6d3b\u6027\uff0c\u9a8c\u8bc1\u4e86\u5bcc\u5b6a\u6676\u9ad8\u71b5\u5408\u91d1\u5728\u9ad8\u6548\u3001\u7a33\u5b9a OER \u50ac\u5316\u4e2d\u7684\u5e7f\u9614\u5e94\u7528\u524d\u666f\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

5. \u7ed3\u8bed<\/p>\n\n\n\n

\u603b\u7684\u6765\u8bf4\uff0c\u6211\u4eec\u901a\u8fc7\u4e00\u79cd\u534f\u540c\u9ad8\u6e29\u70ed\u51b2\u51fb\u7b56\u7565\uff0c\u6210\u529f\u6784\u7b51\u4e86\u5177\u6709\u9ad8\u5bc6\u5ea6\u3001\u9ad8\u6d3b\u6027\u4e14\u9ad8\u7a33\u5b9a\u6027\u5b6a\u6676\u7f3a\u9677\u7684 FeCoNiMn \u57fa\u5408\u91d1\u50ac\u5316\u5242\u3002\u8be5\u65b9\u6cd5\u5c06\u9ad8\u71b5\u7eb3\u7c73\u6750\u6599\u7406\u5ff5\u4e0e\u5b9a\u5411\u805a\u96c6\u548c\u9650\u57df\u751f\u957f\u8bf1\u5bfc\u7f3a\u9677\u7684\u7ed3\u6784\u8c03\u63a7\u7b56\u7565\u6709\u673a\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86\u5b6a\u6676\u7f3a\u9677\u5728\u5408\u91d1\u7eb3\u7c73\u9897\u7c92\u4e2d\u7684\u5747\u5300\u5206\u5e03\u4e0e\u957f\u671f\u7a33\u5b9a\u5b58\u5728\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u591a\u5143\u7d20\u9ad8\u71b5\u7279\u6027\u4e3a\u5b6a\u6676\u7f3a\u9677\u63d0\u4f9b\u4e86\u9ad8\u5ea6\u7075\u6d3b\u7684\u539f\u5b50\u6784\u578b\u548c\u5bbd\u5e7f\u7684\u80fd\u91cf\u7a7a\u95f4\uff0c\u4f7f\u539f\u672c\u5904\u4e8e\u9ad8\u80fd\u6001\u7684\u4e0d\u7a33\u5b9a\u7ed3\u6784\u80fd\u591f\u81ea\u53d1\u6f14\u5316\u4e3a\u66f4\u7a33\u5b9a\u7684\u5b6a\u6676\uff0c\u800c\u975e\u6d88\u5931\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347\u4e86\u7f3a\u9677\u5728\u9ad8\u6e29\u548c\u53cd\u5e94\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u3002\u8fd9\u4e5f\u89e3\u91ca\u4e86\u9ad8\u71b5 T-FeCoNiMn\/C \u76f8\u6bd4\u4f4e\u71b5\u7684 T-Co\/C \u548c T-Ni\/C \u5728\u7ed3\u6784\u4e0e\u6027\u80fd\u4e0a\u7684\u663e\u8457\u4f18\u52bf\u3002\u672c\u5de5\u4f5c\u4ece\u539f\u5b50\u5c3a\u5ea6\u63ed\u793a\u4e86\u71b5\u8c03\u63a7\u5728\u7a33\u5b9a\u4e9a\u7a33\u6676\u4f53\u7f3a\u9677\u4e2d\u7684\u5173\u952e\u4f5c\u7528\uff0c\u4e3a\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7f3a\u9677\u5de5\u7a0b\u63d0\u4f9b\u4e86\u65b0\u7684\u7269\u7406\u56fe\u50cf\u4e0e\u8bbe\u8ba1\u539f\u5219\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8be5\u5408\u6210\u7b56\u7565\u5177\u6709\u826f\u597d\u7684\u901a\u7528\u6027\uff0c\u53ef\u62d3\u5c55\u81f3\u591a\u79cd\u591a\u5143\u7d20\u5408\u91d1\u4f53\u7cfb\uff0c\u4e3a\u6784\u7b51\u9ad8\u53ef\u9760\u6027\u3001\u9ad8\u53ef\u6301\u7eed\u6027\u7684\u9ad8\u6548\u50ac\u5316\u6750\u6599\u5f00\u8f9f\u4e86\u4e00\u6761\u5168\u65b0\u7684\u8def\u5f84\u3002<\/p>\n\n\n\n

\u539f\u6587\u8be6\u60c5<\/strong>\uff1aY. Guo, J. Hong, Q. Dong, H. Liu, Y. Mei, J. Yan, D. Cheng, A. Nie, Q. Wang, P. Li, Y. Yao, J. Lu, Y. Yuan, Angew. Chem. Int. Ed. 2025, e20550. https:\/\/doi.org\/10.1002\/anie.202520550<\/p>\n\n\n\n

\u672c\u6587\u7531\u4f5c\u8005\u56e2\u961f\u4f9b\u7a3f<\/p>\n","protected":false},"excerpt":{"rendered":"

doi.org\/10.1002\/anie.202520550 Highly Stable Twin Defects Enabled by High Entrop…<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-270073","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270073"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=270073"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270073\/revisions"}],"predecessor-version":[{"id":270082,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270073\/revisions\/270082"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=270073"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=270073"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=270073"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}