{"id":270651,"date":"2026-02-06T08:33:00","date_gmt":"2026-02-06T00:33:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=270651"},"modified":"2026-02-05T22:34:32","modified_gmt":"2026-02-05T14:34:32","slug":"%e5%a4%a7%e8%bf%9e%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6%e4%ba%8e%e6%b3%bdangew-chem-%ef%bc%9a%e5%93%8c%e5%97%aa%e4%bf%ae%e9%a5%b0pcbm%e7%95%8c%e9%9d%a2%e9%80%9a%e8%bf%87%e5%8a%a8%e6%80%81%e7%a2%98","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=270651","title":{"rendered":"\u5927\u8fde\u7406\u5de5\u5927\u5b66\u4e8e\u6cfdAngew. Chem.\uff1a\u54cc\u55ea\u4fee\u9970PCBM\u754c\u9762\u901a\u8fc7\u52a8\u6001\u7898\u79bb\u5b50\u518d\u751f\u5b9e\u73b0\u53cd\u5f0f\u9499\u949b\u77ff\u5149\u4f0f\u5668\u4ef6\u6548\u7387\u4e0e\u5149\u70ed\u7a33\u5b9a\u6027\u540c\u65f6\u517c\u987e"},"content":{"rendered":"\n

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\u7814\u7a76\u4eae\u70b9\uff1a<\/strong><\/strong><\/p>\n\n\n\n

    \n
  1. \u52a8\u6001\u7898\u79bb\u5b50\u518d\u751f\u7b56\u7565<\/strong>\uff1aPCBM-PA\u5355\u4e00\u6750\u6599\u5b9e\u73b0\u4e86\u5bf9\u6325\u53d1\u6027\u7898\u5206\u5b50\u7684\u5f3a\u5438\u9644\u4e0e\u4fc3\u8fdbI\u2212I\u952e\u65ad\u88c2\u7684\u53cc\u91cd\u529f\u80fd\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u7898\u79bb\u5b50\u7684\u52a8\u6001\u518d\u751f\u548c\u5bf9\u9499\u949b\u77ff\u8584\u819c\u7684\u81ea\u4fee\u590d\uff0c\u9a71\u52a8FAPbI3<\/sub>\u4eced<\/em>\u76f8\u5230a<\/em>\u76f8\u7684\u8f6c\u53d8\u3002<\/li>\n\n\n\n
  2. \u754c\u9762\u591a\u529f\u80fd\u96c6\u6210<\/strong>\uff1a\u54cc\u55ea\u7684\u5f15\u5165\u5b9e\u73b0\u4e86\u5bf9\u4e8ePCBM\u6bcd\u4f53\u7684n\u578b\u63ba\u6742\uff0c\u63d0\u5347\u4e86\u5176\u7535\u8377\u4f20\u5bfc\u80fd\u529b\u3002\u540c\u65f6PCBM-PA\u8fd8\u53ef\u4ee5\u4f18\u5316\u9499\u949b\u77ff\/\u7535\u5b50\u4f20\u8f93\u5c42\u754c\u9762\u7684\u80fd\u7ea7\u6392\u5217\uff0c\u589e\u5f3a\u7535\u8377\u63d0\u53d6\uff0c\u949d\u5316\u8868\u9762\u7f3a\u9677\uff0c\u5b9e\u73b0\u4e86\u7535\u8377\u4f20\u8f93\u4e0e\u7f3a\u9677\u949d\u5316\u7684\u534f\u540c\u63d0\u5347<\/li>\n\n\n\n
  3. \u6548\u7387\u4e0e\u5149\u70ed\u7a33\u5b9a\u6027\u540c\u65f6\u517c\u987e<\/strong>\uff1a\u57fa\u4e8ePCBM-PA\u7684\u5012\u7f6e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5b9e\u73b0\u4e8626.26%\u7684\u51a0\u519b\u6548\u7387\uff0c\u540c\u65f6\u572865 \u00b0C\u6301\u7eed\u5149\u7167\u7684MPPT\u6d4b\u8bd5\u4e2d\uff08ISOS-L-2\uff09\uff0c1000\u5c0f\u65f6\u540e\u6548\u7387\u4fdd\u6301\u7387\u8d85\u8fc793%\uff08T<\/em>93<\/sub>\uff09<\/li>\n<\/ol>\n\n\n\n
    \"\"<\/figure>\n\n\n\n

    \u56fe1 PCBM-PA\u7684\u5408\u6210\u8def\u7ebf\u548c\u7406\u8bba\u8ba1\u7b97\u6a21\u62df<\/strong><\/strong><\/p>\n\n\n\n

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    \"\"<\/figure>\n\n\n\n

    \u56fe2 PCBM-PA\u5bf9I<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7684\u5438\u9644\u548c\u89e3\u79bb\u7684\u5b9e\u9a8c\u9a8c\u8bc1\u4ee5\u53caPCBM-PA\u5bf9<\/strong>d<\/em><\/strong><\/em><\/strong>-FAPbI<\/strong>3<\/sub><\/strong><\/sub><\/strong>\u7684\u4fee\u590d<\/strong><\/strong><\/p>\n\n\n\n

    \u5b9e\u9a8c\u9a8c\u8bc1<\/strong>\uff1a\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u663e\u793a\uff0cPCBM-PA\u4e0eI2<\/sub>\u5f62\u6210\u7535\u8377\u8f6c\u79fb\u590d\u5408\u7269\uff1b\u70ed\u91cd\u5206\u6790\u5b9e\u9a8c\u8868\u660ePCBM-PA\u4f7fI2<\/sub>\u7684\u6325\u53d1\u6e29\u5ea6\u4ece70 \u00b0C\u63d0\u5347\u81f3130 \u00b0C\uff1b\u62c9\u66fc\u5149\u8c31\u68c0\u6d4b\u5230I3<\/sub>\u2012<\/sup>\u548cI5<\/sub>\u2012<\/sup>\u7279\u5f81\u5cf0\uff0c\u76f4\u63a5\u8bc1\u660eI\u2212I\u952e\u65ad\u88c2\uff1bX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u5206\u6790\u8868\u660e\uff0cPCBM-PA\u4fee\u9970\u7684FAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u5728\u7898\u84b8\u6c14\u5904\u7406\u540e\u53d1\u751f\u03b4<\/em>\u76f8\u5230\u03b1<\/em>\u76f8\u7684\u8f6c\u53d8\uff0c\u8bc1\u5b9e\u518d\u751f\u7898\u79bb\u5b50\u53ef\u586b\u8865\u7a7a\u4f4d\u7f3a\u9677\uff0c\u5b9e\u73b0\u9499\u949b\u77ff\u8584\u819c\u7684\u52a8\u6001\u4fee\u590d\u3002<\/p>\n\n\n\n

    \"\"<\/figure>\n\n\n\n

    \u56fe3 PCBM-PA\u7684\u591a\u529f\u80fd\u5c55\u793a\uff1a\u5bfc\u7535\u6027\u80fd\u8868\u5f81\u4ee5\u53ca\u4fee\u9970\u540e\u9499\u949b\u77ff\u8584\u819c\u7684\u80fd\u7ea7\u8868\u5f81<\/strong><\/strong><\/p>\n\n\n\n

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    \"\"<\/figure>\n\n\n\n

    \u56fe4 PCBM-PA\u4fee\u9970\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u7684\u5149\u7535\u6027\u80fd\u8868\u5f81\u4ee5\u53ca\u7a33\u5b9a\u6027\u63d0\u5347\u7684\u7814\u7a76<\/strong><\/p>\n\n\n\n

    \u5668\u4ef6\u5149\u4f0f\u6027\u80fd<\/strong>\uff1a\u57fa\u4e8ePCBM-PA\u7684\u5012\u7f6e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u83b7\u5f97\u4e8626.26%\u7684\u51a0\u519b\u6548\u7387\uff08V<\/em>oc<\/sub> = 1.18 V\uff0cJ<\/em>sc<\/sub> = 26.23 mA cm\u207b\u00b2\uff0cFF = 85.08%\uff09\uff0c\u8f83\u5bf9\u7167\u7ec4\uff0824.53%\uff09\u663e\u8457\u63d0\u5347\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u672a\u5c01\u88c5\u5668\u4ef6\u572865 \u00b0C\u8fde\u7eedMPPT\u6d4b\u8bd51000\u5c0f\u65f6\u540e\u4ecd\u4fdd\u630193.2%\u7684\u521d\u59cb\u6548\u7387\uff08\u5bf9\u7167\u7ec4\u4ec577.5%\uff09\u3002XRD\u548cEDS\u5206\u6790\u8868\u660ePCBM-PA\u6709\u6548\u6291\u5236\u4e86d<\/em>\u76f8\u751f\u6210\u548cAg\u7535\u6781\u8150\u8680\uff08I\/Ag\u539f\u5b50\u6bd4\u4ec5\u4ece0.25\u589e\u81f30.37\uff0c\u5bf9\u7167\u7ec4\u4ece0.27\u98d9\u5347\u81f33.11\uff09\uff0c\u4ece\u800c\u8d77\u5230\u7a33\u5b9a\u9499\u949b\u77ff\u548c\u4fdd\u62a4\u94f6\u7535\u6781\u7684\u53cc\u91cd\u4f5c\u7528\u3002<\/p>\n\n\n\n

    \u6210\u679c\u542f\u793a\uff1a<\/strong><\/strong><\/p>\n\n\n\n

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    \u539f\u6587\u8be6\u60c5\uff1a<\/strong><\/strong><\/p>\n\n\n\n

    Dynamic Iodide Regeneration Enabled by Piperazine-Tailored PCBM Interfaces for Photothermally Stable and Efficient Inverted Perovskite Photovoltaics<\/p>\n\n\n\n

    Yulong Chen, Zijin Wu, Liangyu Zhao, Huaiman Cao, Xufan Zheng, Runze Liu, Prof. Geert Brocks, Prof. Shuxia Tao, Prof. Ze Yu<\/p>\n\n\n\n

    \u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u9648\u96e8\u9f99\u548c\u57c3\u56e0\u970d\u6e29\u7406\u5de5\u5927\u5b66\u535a\u58eb\u7814\u7a76\u751f\u5434\u5b50\u887f\u3002\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u4e3a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u4e8e\u6cfd\u6559\u6388\u548c\u57c3\u56e0\u970d\u6e29\u7406\u5de5\u5927\u5b66\u9676\u4e66\u971e\u6559\u6388\u3002<\/p>\n\n\n\n

    Angewandte Chemie International Edition<\/em><\/em><\/p>\n\n\n\n

    DOI: 10.1002\/anie.6909224<\/p>\n","protected":false},"excerpt":{"rendered":"

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