{"id":270730,"date":"2026-02-14T07:58:00","date_gmt":"2026-02-13T23:58:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=270730"},"modified":"2026-02-13T22:02:26","modified_gmt":"2026-02-13T14:02:26","slug":"%e5%8d%97%e5%bc%80%e5%a4%a7%e5%ad%a6%e9%be%99%e5%ae%98%e5%a5%8e%e5%9b%a2%e9%98%9fccs-chemistry%ef%bc%9a%e5%85%b7%e6%9c%89%e5%bc%ba%e7%a3%81%e5%85%89%e6%b4%bb%e6%80%a7%e5%92%8c%e8%bf%91%e7%ba%a2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=270730","title":{"rendered":"\u5357\u5f00\u5927\u5b66\u9f99\u5b98\u594e\u56e2\u961fCCS Chemistry\uff1a\u5177\u6709\u5f3a\u78c1\u5149\u6d3b\u6027\u548c\u8fd1\u7ea2\u5916\u533a\u5706\u504f\u632f\u53d1\u5149\u7684\u955d\u57fa\u624b\u6027\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff"},"content":{"rendered":"\n

\u5706\u504f\u632f\u53d1\u5149\u6750\u6599\u56e0\u5176\u5728\u81ea\u65cb\u7535\u5b50\u5b66\u3001\u5706\u504f\u632f\u5149\u6e90\u3001\u4fe1\u606f\u5b58\u50a8\u4e0e\u9632\u4f2a\u9886\u57df\u5177\u5907\u5e94\u7528\u524d\u666f\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u51ed\u501f\u7ed3\u6784\u53ef\u8c03\u3001\u6eb6\u6db2\u52a0\u5de5\u6027\u826f\u597d\u4ee5\u53ca\u624b\u6027\u5149\u5b66\u6d3b\u6027\u4f18\u5f02\u7b49\u7279\u70b9\uff0c\u6210\u4e3a\u8be5\u9886\u57df\u6700\u5177\u53d1\u5c55\u6f5c\u529b\u7684\u6750\u6599\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u76ee\u524d\u5173\u4e8e\u8fd9\u7c7b\u6750\u6599\u7684\u62a5\u9053\u591a\u96c6\u4e2d\u4e8e\u7d2b\u5916\u81f3\u53ef\u89c1\u5149\u533a\uff0c\u8fd1\u7ea2\u5916\u533a\uff08near-infrared\uff0cNIR\uff09\u7684\u5706\u504f\u632f\u53d1\u5149\u4ecd\u9c9c\u6709\u62a5\u9053\u3002\u4e0e\u53ef\u89c1\u5149\u533a\u5706\u504f\u632f\u53d1\u5149\u76f8\u6bd4\uff0c\u8fd1\u7ea2\u5916\u5706\u504f\u632f\u53d1\u5149\u5177\u5907\u7a7f\u900f\u6df1\u5ea6\u5927\u3001\u4f20\u8f93\u635f\u8017\u4f4e\u3001\u9690\u853d\u6027\u7b49\u7279\u5f81\uff0c\u5728\u751f\u7269\u6210\u50cf\u3001\u5149\u5b66\u9632\u4f2a\u4e0e\u4fe1\u606f\u52a0\u5bc6\u9886\u57df\u5c55\u73b0\u51fa\u65e0\u53ef\u6bd4\u62df\u7684\u4f18\u52bf\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u5728\u8fd1\u7ea2\u5916\u533a\u5177\u6709\u9ad8\u6548\u5706\u504f\u632f\u53d1\u5149\u6027\u80fd\u7684\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u662f\u4e00\u9879\u517c\u5177\u6311\u6218\u4e0e\u91cd\u5927\u7814\u7a76\u4ef7\u503c\u7684\u5de5\u4f5c\u3002\u5728\u7a00\u571f\u5bb6\u65cf\u4e2d\uff0c\u4e09\u4ef7\u955d\u79bb\u5b50\uff08Dy3+<\/sup>\uff09\u7531\u4e8e\u5176\u5177\u6709\u4e30\u5bcc\u76844f<\/em>-4f<\/em>\u8dc3\u8fc1\u80fd\u7ea7\u7ed3\u6784\uff0c\u4e0d\u4ec5\u5728NIR\u533a\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u53d1\u5149\u6027\u80fd\uff0c\u5176\u78c1\u6027\u7279\u6027\u4e5f\u5907\u53d7\u5173\u6ce8\u3002<\/p>\n\n\n\n

\u5357\u5f00\u5927\u5b66\u9f99\u5b98\u594e<\/strong>\u7814\u7a76\u5458\u3001\u9648\u6c38\u80dc\u9662\u58eb\u548c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u5218\u65b0\u98ce\u7814\u7a76\u5458\u56e2\u961f<\/strong>\uff0c\u9996\u6b21\u5408\u6210\u4e86Dy\u57fa\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\uff0c(R<\/em>\/S<\/em>-MBA)3<\/sub>DyCl6<\/sub>(MBA = methylbenzylammonium, R<\/em><\/strong><\/em><\/strong>\/S<\/em><\/strong><\/em><\/strong>–Dy<\/strong>)\u3002\u4e0e\u5df2\u62a5\u9053\u7684\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u76f8\u6bd4\uff0cR<\/em><\/strong><\/em><\/strong>\/S<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5b9e\u73b0\u4e86\u5706\u504f\u632f\u53d1\u5149\u54cd\u5e94\u4ece\u53ef\u89c1\u5149\u533a\u5411NIR\u533a\u7684\u5ef6\u4f38\uff0c\u5176\u53d1\u5149\u4e0d\u5bf9\u79f0\u56e0\u5b50\uff08|g<\/em>\u2097\u1d64\u2098|\uff09\u5728579 nm\u5904\u4e3a10.64\u00d710-2<\/sup>\uff0c\u57281015 nm\u5904\u4e3a8.58\u00d710-2<\/sup>\u3002\u6b64\u5916\uff0cR<\/em><\/strong><\/em><\/strong>\/S<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u8fd1\u7ea2\u5916\u4e8c\u533a\uff08NIR-II region\uff0c1000-1700 nm\uff09\u4e5f\u5c55\u73b0\u51fa\u4e86\u8d85\u5f3a\u7684\u78c1\u5149\u6d3b\u6027\u3002\u672c\u7814\u7a76\u4e3a\u8bbe\u8ba1\u5177\u6709NIR\u533a\u5706\u504f\u632f\u53d1\u5149\u6027\u80fd\u7684\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u63d0\u4f9b\u4e86\u65b0\u7b56\u7565\uff0c\u4e5f\u4e3a\u63a8\u52a8\u7a00\u571f\u57fa\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u5728\u78c1\u5149\u9886\u57df\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u7814\u7a76\u57fa\u7840\uff0c\u76f8\u5173\u7ed3\u679c\u53d1\u8868\u5728CCS Chemistry<\/em>\u4e0a\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong> a, b. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684\u6676\u4f53\u7ed3\u6784\u3002c, d. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684\u7c89\u672bXRD\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe2<\/strong> a, b. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u7684\u5438\u6536\u5149\u8c31\u3002c. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684\u5706\u4e8c\u8272\u6027\u5438\u6536\u5149\u8c31\u3002d. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684\u80fd\u5e26\u7ed3\u6784\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe3<\/strong> a, b. \u5916\u52a0\u78c1\u573a\u4e0bR<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u7684\u8868\u89c2\u5706\u4e8c\u8272\u6027\u5438\u6536\u5149\u8c31\u3002c, d. \u5916\u52a0\u78c1\u573a\u4e0bS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u7684\u8868\u89c2\u5706\u4e8c\u8272\u6027\u5438\u6536\u5149\u8c31\u3002e, f. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u7d2b\u5916-\u53ef\u89c1-\u8fd1\u7ea2\u5916\u7684\u78c1\u5706\u4e8c\u8272\u6027\u5149\u8c31\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe4<\/strong> a, b. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u53ef\u89c1\u5149\u533a\u548cNIR\u533a\u7684\u5706\u504f\u632f\u53d1\u5149\u5149\u8c31\u3002c, d. R<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u548cS<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u5728\u53ef\u89c1\u5149\u533a\u548cNIR\u533a\u7684\u5706\u504f\u632f\u53d1\u5149\u5f3a\u5ea6\u3002<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe5<\/strong> \u5df2\u62a5\u9053\u7684\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u4e0e\u672c\u7814\u7a76\u4e2dR<\/em><\/strong><\/em><\/strong>–Dy<\/strong>\u7684g<\/em>lum<\/sub>\u6bd4\u8f83\u3002<\/p>\n\n\n\n

\u8bba\u6587\u4fe1\u606f\uff1a<\/p>\n\n\n\n

Chiral Dysprosium Halides with Strong Magneto-Optical Activity and Circularly Polarized Luminescence in the NIR region<\/strong><\/p>\n\n\n\n

Tianyin Shao, Xinyi Niu, Xin Zeng, Wenkai Zhao, Haolin Lu, Hebin Wang, Zhaoyu Wang, Tianjiao Qiao, Wenting Liu, Yunxin Zhang, Bing Sun, Hao-Li Zhang, Xinfeng Liu*, Yongsheng Chen*, Guankui Long*<\/p>\n\n\n\n

CCS Chemistry<\/em><\/p>\n\n\n\n

DOI: 10.31635\/ccschem.026.202507067<\/p>\n\n\n\n

\u539f\u6587\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.31635\/ccschem.026.202507067<\/p>\n","protected":false},"excerpt":{"rendered":"

\u5706\u504f\u632f\u53d1\u5149\u6750\u6599\u56e0\u5176\u5728\u81ea\u65cb\u7535\u5b50\u5b66\u3001\u5706\u504f\u632f\u5149\u6e90\u3001\u4fe1\u606f\u5b58\u50a8\u4e0e\u9632\u4f2a\u9886\u57df\u5177\u5907\u5e94\u7528\u524d\u666f\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5176\u4e2d\uff0c\u624b\u6027\u6709\u673a-\u65e0\u673a\u6742\u5316\u91d1\u5c5e\u5364\u5316\u7269\u9499\u949b\u77ff\u51ed\u501f\u7ed3\u6784\u53ef\u8c03\u3001\u6eb6\u6db2\u52a0\u5de5\u6027\u826f\u597d\u4ee5…<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-270730","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270730"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=270730"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270730\/revisions"}],"predecessor-version":[{"id":270736,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/270730\/revisions\/270736"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=270730"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=270730"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=270730"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}