{"id":27132,"date":"2016-07-19T08:00:16","date_gmt":"2016-07-19T00:00:16","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=27132"},"modified":"2016-07-18T22:14:05","modified_gmt":"2016-07-18T14:14:05","slug":"jacs%ef%bc%9a%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0li2mno3%e2%80%a2limo2%e6%ad%a3%e6%9e%81%e6%9d%90%e6%96%99%e5%ae%b9%e9%87%8f%e8%a1%b0%e5%87%8f%e7%bc%98%e7%94%b1%e7%9a%84%e6%8e%a2%e7%a9%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=27132","title":{"rendered":"JACS\uff1a\u9502\u79bb\u5b50\u7535\u6c60Li2MnO3\u2022LiMO2\u6b63\u6781\u6750\u6599\u5bb9\u91cf\u8870\u51cf\u7f18\u7531\u7684\u63a2\u7a76"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011\u7535\u52a8\u6c7d\u8f66\u7684\u53d1\u5c55\u53ef\u4ee5\u7f13\u89e3\u6211\u4eec\u5bf9\u5316\u77f3\u71c3\u6599\u7684\u4f9d\u8d56\u3002\u540c\u65f6\u5728\u5df2\u5f00\u53d1\u7684\u50a8\u80fd\u88c5\u7f6e\u4e2d\uff0c\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBS\uff09\u76f8\u6bd4\u5176\u4ed6\u7c7b\u578b\u7684\u7535\u6c60\u6709\u8f83\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u800c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u6b63\u6781\u6750\u6599\u901a\u5e38\u662f\u51b3\u5b9a\u7535\u6c60\u5bb9\u91cf\u548c\u6027\u80fd\u7684\u5173\u952e\u6240\u5728\u3002\u56e0\u6b64\u5bf9\u6b63\u6781\u6750\u6599\u5bb9\u91cf\u8870\u51cf\u7f18\u7531\u7684\u63a2\u7a76\u5c31\u53d8\u5f97\u5c24\u4e3a\u91cd\u8981\u3002\u8fd1\u65e5\uff0c\u56fd\u7acb\u53f0\u6e7e\u5927\u5b66\u7684Ru-Shi Liu<\/strong>\u6559\u6388\u548cChih-Jung Chen<\/strong>\u4e0e\u6fb3\u5927\u5229\u4e9a\u5367\u9f99\u5c97\u5927\u5b66\u7684Wei Kong Pang<\/strong>\u7b49\u4eba\u8054\u5408\u5728JACS<\/em><\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\u201cThe Origin of Capacity Fade in the Li2<\/sub>MnO3<\/sub><\/em><\/strong>\u00b7<\/em><\/strong>LiMO2 <\/sub>(M = Li, Ni, Co, Mn) Microsphere Positive Electrode: An Operando Neutron Diffraction and Transmission X-ray Microscopy Study.<\/em><\/strong>\u201d\u3002<\/p>\n

\u6b64\u6b21\u7814\u7a76\u6210\u679c\u4e3b\u8981<\/strong><\/span>\u662f\uff1a\u8be5\u7814\u7a76\u5c0f\u7ec4\u901a\u8fc7\u7ed3\u5408\u64cd\u4f5c\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u548c\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c(TXM)\u65b9\u6cd5\u63a2\u7a76\u4e86Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub> (M <\/em>= Li, Ni, Co, Mn)\u590d\u5408\u6b63\u6781\u6750\u6599\u5728\u7535\u5316\u5b66\u5faa\u73af\u8fc7\u7a0b\u4e2d\u76f8\u3001\u6676\u4f53\u7ed3\u6784\u4ee5\u53ca\u5176\u5f62\u6001\u6f14\u53d8\uff0c\u63ed\u793a\u4e86\u8be5\u6750\u6599\u5728\u5168\u7535\u6c60\u4e2d\u7684\u8870\u51cf\u673a\u5236\u3002<\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

\u6210\u679c\u7b80\u4ecb\uff1a<\/strong><\/span><\/p>\n

Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub> (M <\/em>= Li, Ni, Co, Mn)\u7cfb\u7edf\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6781\u6709\u524d\u666f\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u5176\u5bb9\u91cf\u7ea6\u4e3a250~300 mA h g-1<\/sup>\u3002\u8fd9\u79cd\u7535\u6781\u6700\u521d\u8868\u73b0\u4e3a73(1) wt % \u7684LiM<\/em>O2<\/sub>\uff08R3\u0305m\u70b9\u7fa4\uff09\u548c27\uff081\uff09% Li2<\/sub>MnO3<\/sub>\uff08C2 \/ m\u70b9\u7fa4\uff09\u7684\u5171\u751f\u4f53\u3002\u5f53\u5145\u7535\u52304.55V\uff08vs Li\/Li+<\/sup>\uff09\u65f6\uff0cLiM<\/em>O2<\/sub>\u76f8\u7684\u56fa\u6eb6\u53cd\u5e94\u4f1a\u5f15\u53d1Li2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7c92\u5b50\u7684\u88c2\u89e3\u3002\u5f53\u5145\u7535\u52304.7 V \uff08vs Li\/Li+<\/sup>\uff09\u88c2\u89e3\u52a0\u5267\uff0c\u540c\u65f6LiMO2<\/sub>\u76f8\u53d1\u751f\u4e24\u76f8\u53cd\u5e94\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5728\u968f\u540e\u7684\u653e\u7535\u8fc7\u7a0b\u4e2dLi2<\/sub>MnO3<\/sub>\u00b7LiM<\/em>O2<\/sub>\u7535\u6781\u7c92\u5b50\u663e\u8457\u6108\u5408\uff0c\u8fd9\u4e00\u4fee\u590d\u8fc7\u7a0b\u4e5f\u4e3b\u8981\u548cLiM<\/em>O2<\/sub>\u76f8\u7684\u56fa\u6eb6\u53cd\u5e94\u6709\u5173\u3002\u8be5\u7814\u7a76\u5c0f\u7ec4\u53d1\u73b0\u5728\u5145\u7535\u8fc7\u7a0b\u4e2d\u6676\u683c\u5c3a\u5bf8\u7684\u51cf\u5c11\u5bfc\u81f4\u4e86Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7535\u6781\u7c92\u5b50\u7684\u5f00\u88c2\uff0c\u4e14\u5f00\u88c2\u7684\u7a0b\u5ea6\u4e0e\u6676\u683c\u5c3a\u5bf8\u53d8\u5316\u7684\u7a0b\u5ea6\u76f8\u5173\uff0c\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u88c2\u7eb9\u7684\u6108\u5408\u53ef\u80fd\u662f\u7531\u4e8e\u53d1\u751f\u4e86\u53cd\u5411\u56fa\u6eb6\u53cd\u5e94\u3002\u91cd\u8981\u7684\u662f\uff0cLiMO2<\/sub>\u76f8\u5728\u4e24\u76f8\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u76f8\u5206\u79bb\u4f1a\u963b\u6b62\u7535\u6781\u9897\u7c92\u7684\u5b8c\u5168\u6108\u5408\uff0c\u5bfc\u81f4\u6750\u6599\u5728\u591a\u6b21\u5faa\u73af\u540e\u53d1\u751f\u7c89\u5316\u3002\u8fd9\u9879\u7814\u7a76\u7ed3\u679c\u8868\u660e\u5c06\u76f8\u5206\u79bb\u7684\u884c\u4e3a\u6700\u5c0f\u5316\u662f\u9632\u6b62\u7535\u6781\u5bb9\u91cf\u8870\u51cf\u4e00\u4e2a\u5173\u952e\u7684\u7b56\u7565\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb\uff1a<\/strong><\/span><\/p>\n

\u56fe1\uff1aRietveld\u7cbe\u4fee\u56fe<\/strong><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

\uff08a\uff09X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09 \u7684Rietveld\u7cbe\u4fee\u56fe\uff08\u6ce2\u957f\u4e3a1.54178 \u00c5\uff09\u3002<\/p>\n

\uff08b\uff09\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u7684Rietveld\u7cbe\u4fee\u56fe\uff08\u6ce2\u957f\u4e3a1.6215(1) \u00c5\uff09\u3002<\/p>\n

\uff08c\uff09\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u7684Rietveld\u7cbe\u4fee\u56fe\uff08\u6ce2\u957f\u4e3a2.4393(2) \u00c5\uff09\u3002<\/p>\n

\u4ee5\u4e0a\u4e09\u56fe\u76f8\u5e94\u7684\u52a0\u6743\u5206\u5e03R\u56e0\u5b50\uff08RWP<\/sub>\uff09\u5206\u522b\u4e3a2.73%\u30014.43%\u548c3.86%\u3002<\/p>\n

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\"\u65e0\u6807\u98981\"<\/p>\n

(a) Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub> \u7684SEM \u56fe\u3002(b) Li4<\/sub>Ti5<\/sub>O12<\/sub>\uff08LTO\uff09\u7684SEM \u56fe\u3002<\/p>\n

\u56fe3\uff1a\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

\uff08a\uff09Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7684\u7ebd\u6263\u7535\u6c60\u5728\u7b2c1\u6b21\u30012\u6b21\u300110\u6b21\u7684\u653e\u7535\u66f2\u7ebf\u56fe\u3002<\/p>\n

\uff08b\uff09\u7535\u6d41\u5bc6\u5ea6\u4e3a10 mA g-1<\/sup>\u65f6\uff0c\u7ebd\u6263\u7535\u6c60\u76f8\u5e94\u7684\u5faa\u73af\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\u3002<\/p>\n

\u56fe4\uff1a\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u6570\u636e\u7b49\u503c\u7ebf\u56fe<\/strong><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub> || LTO\u7535\u6c60\u7684\u4e2d\u5b50\u7c89\u672b\u884d\u5c04(NPD)\u6570\u636e\u7b49\u503c\u7ebf\u56fe\uff0c\u7528\u53f3\u8fb9\u7684\u989c\u8272\u8868\u793a\u5f3a\u5ea6(arb.)\uff0c\u7535\u538b\u8868\u793a\u4e3a\u767d\u7ebf\u3002<\/p>\n

\u56fe5\uff1aLi2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub> || LTO\u7535\u6c60\u7684\u4e2d\u5b50\u7c89\u672b\u884d\u5c04\uff08NPD\uff09\u6570\u636e\u5206\u6790\u7ed3\u679c<\/strong><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

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\"\u65e0\u6807\u98981\"<\/p>\n

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\u56fe7\uff1a\u4e0d\u540c\u7535\u538b\u503c\u4e0bLi2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7c92\u5b50\u7684\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c(TXM)\u56fe\u50cf\u5bf9\u6bd4<\/strong><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

\u4e0d\u540c\u7535\u538b\u503c\u4e0bLi2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7c92\u5b50\u7684\u900f\u5c04X\u5c04\u7ebf\u663e\u5fae\u955c(TXM)\u56fe\u50cf\u5bf9\u6bd4<\/p>\n

(a) 4.5 V \u4e0e\u5f00\u8def\u7535\u538b\uff1b(b) 4.7 \u4e0e4.5 V\uff1b(c) 3.6\u4e0e4.7 V\uff1b(d) 2.0\u4e0e3.6 V\uff1b (e) 4.7 V \u4e0e\u5f00\u8def\u7535\u538b\uff1b(f) 2.0 V \u4e0e\u5f00\u8def\u7535\u538b.\uff08vs. Li+\/Li\uff09<\/p>\n

\u56fe8\uff1a\u7814\u7a76\u603b\u7ed3<\/strong>
\n\"\u65e0\u6807\u98981\"<\/p>\n

\u5728\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u00b7Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7535\u6781\u7ed3\u6784\u3001\u7535\u5316\u5b66\u3001\u6676\u4f53\u5b66\u7684\u603b\u7ed3\u3002<\/p>\n

\u7531\u4e0a\u56fe\u8868\u53ef\u4ee5\u770b\u51fa\uff1a\u5728\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u4e0d\u540c\u9636\u6bb5Li2<\/sub>MnO3<\/sub>\u00b7LiMO2<\/sub>\u7535\u6781\u5fae\u7403\u7684\u53cd\u5e94\u7c7b\u578b\uff08Reaction type\uff09<\/span><\/strong>\u548c\u8be5\u9636\u6bb5\u5bf9\u5e94\u7684\u6676\u683c\u7ed3\u6784\u7684\u53d8\u5316\u60c5\u51b5\uff0c\u540c\u65f6\u8fd8\u6709\u5fae\u7403\u53d8\u5316\u60c5\u51b5\uff08\u5f00\u88c2\u548c\u6108\u5408\uff09\u5bf9\u5176\u5927\u5c0f\u7684\u5f71\u54cd\u3002\u53ef\u4ee5\u770b\u51fa\u5728\u6574\u4e2a\u9636\u6bb5\u4e2d\uff0cLiMO2<\/sub>\u76f8\u7684\u56fa\u6eb6\u53cd\u5e94<\/span><\/strong>\u5bf9\u4e8e\u7535\u6781\u5fae\u7403\u7684\u6676\u683c\u7ed3\u6784\u53ca\u5176\u5f00\u88c2\u548c\u6108\u5408\u7684\u5f71\u54cd\u6700\u5927\u3002\u800c\u5728\u5145\u653e\u7535\u9636\u6bb5\u4e2d\uff0c\u7535\u538b\u8f83\u9ad8\u65f6\u51fa\u73b0\u7684\u6790\u6c27\u53cd\u5e94<\/span><\/strong>\u548c\u8131\u5d4c\u9502\u53cd\u5e94<\/span><\/strong>\u5bf9\u4e8e\u6574\u4f53\u7ed3\u6784\u53d8\u5316\u5f71\u54cd\u76f8\u5bf9\u8f83\u5c0f\uff0c\u4f46\u4f1a\u5bfc\u81f4\u5fae\u7403\u7684\u5f00\u88c2\u7a0b\u5ea6\u52a0\u5267\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011\u603b\u7684\u8bf4\u6765\uff0c\u5728\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\uff0c\u6b63\u6781\u6750\u6599\u901a\u5e38\u662f\u51b3\u5b9a\u7535\u6c60\u5bb9\u91cf\u548c\u6027\u80fd\u7684\u5173\u952e\u6240\u5728\u3002\u8fd9\u4e00\u7814\u7a76\u7ed3\u679c\u5bf9\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7814\u7a76\u548c\u53d1\u5c55\u6765\u8bf4\u6781\u5177\u5efa\u8bbe\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aThe Origin of Capacity Fade in the Li2MnO3\u00b7LiMO2 (M = Li,\u00a0Ni, Co, Mn) Microsphere Positive Electrode: An Operando\u00a0Neutron Diffraction and Transmission X-ray Microscopy Study.\uff08JACS,2016\uff0cDOI: <\/strong>10.1021\/jacs.6b03932\uff09<\/a><\/p>\n

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