{"id":272022,"date":"2026-05-28T08:42:00","date_gmt":"2026-05-28T00:42:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=272022"},"modified":"2026-05-27T22:47:47","modified_gmt":"2026-05-27T14:47:47","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e4%b8%87%e5%ae%87%e9%a9%b0-%e5%bc%a0%e4%b9%85%e4%bf%8a%e3%80%81%e6%b8%85%e5%8d%8e%e5%a4%a7%e5%ad%a6%e5%90%95%e7%91%9e%e6%b6%9badv-funct-mater-%ef%bc%9a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=272022","title":{"rendered":"\u798f\u5dde\u5927\u5b66\u4e07\u5b87\u9a70\/\u5f20\u4e45\u4fca\u3001\u6e05\u534e\u5927\u5b66\u5415\u745e\u6d9bAdv. Funct.\u00a0Mater.\uff1a\u5feb\u901f\u7126\u8033\u70ed\u548c\u5bbd\u7535\u4f4d\u7535\u5316\u5b66\u8fd8\u539f\u5b9e\u73b0\u5e9f\u785d\u9178\u76d0\u7684\u68af\u6b21\u5229\u7528"},"content":{"rendered":"\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"289\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/2382c315a6ba396-28.png\" alt=\"\" class=\"wp-image-272023\"\/><\/figure>\n\n\n\n<p>\u901a\u8baf\u4f5c\u8005\uff1a\u4e07\u5b87\u9a70\u526f\u6559\u6388\u3001\u5f20\u4e45\u4fca\u9662\u58eb\u3001\u5415\u745e\u6d9b\u6559\u6388<\/p>\n\n\n\n<p>\u901a\u8baf\u5355\u4f4d\uff1a\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u3001\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662<\/p>\n\n\n\n<p>\u8bba\u6587\u94fe\u63a5\uff1ahttp:\/\/doi.org\/10.1002\/adfm.76112<\/p>\n\n\n\n<p><strong>1. \u7814\u7a76\u80cc\u666f<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u968f\u7740\u4eba\u53e3\u6025\u5267\u589e\u957f\u548c\u5de5\u4e1a\u5316\u8fdb\u7a0b\u7684\u5feb\u901f\u63a8\u8fdb\uff0c\u5730\u4e0b\u6c34\u4e2dNO<sub>3<\/sub><sup>&#8211;<\/sup>\u6c61\u67d3\u95ee\u9898\u65e5\u76ca\u4e25\u91cd\uff0c\u5a01\u80c1\u7740\u751f\u6001\u73af\u5883\u548c\u4eba\u7c7b\u5065\u5eb7\u3002\u4f20\u7edf\u7684\u542b\u785d\u5e9f\u6c34\u5904\u7406\u65b9\u6cd5\u6210\u672c\u9ad8\u3001\u4e14\u6613\u4ea7\u751f\u4e8c\u6b21\u6c61\u67d3\u3002\u7535\u5316\u5b66\u785d\u9178\u76d0\u8fd8\u539f\u53cd\u5e94\uff08NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\uff09\u6280\u672f\u80fd\u591f\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u4ea7\u751f\u7684\u6e05\u6d01\u7535\u529b\uff0c\u65e2\u5b9e\u73b0\u5e9f\u785d\u9178\u76d0\u7684\u53ef\u6301\u7eed\u5904\u7406\uff0c\u53c8\u53ef\u751f\u4ea7\u5177\u6709\u9ad8\u9644\u52a0\u503c\u7684\u6c28\u3002\u8fd1\u5e74\u6765\uff0c\u9488\u5bf9\u5148\u8fdbNO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u7535\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u548c\u5f00\u53d1\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\uff0c\u5c3d\u7ba1NO<sub>3<\/sub><sup>&#8211;<\/sup>\u53bb\u9664\u6548\u7387\uff08&gt;95%\uff09\u548c\u6c28\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff08&gt;90%\uff09\u6709\u4e86\u663e\u8457\u63d0\u5347\uff0c\u4f46\u6700\u8fd1\u62a5\u9053\u7684\u5927\u591a\u6570\u7535\u50ac\u5316\u5242\u4ec5\u80fd\u5728\u72ed\u7a84\u7684\u7535\u4f4d\u8303\u56f4\u5185\u8868\u73b0\u51fa\u9ad8\u6027\u80fd\uff0c\u5e76\u4e14\u5176\u50ac\u5316\u6d3b\u6027\u968f\u7535\u4f4d\u53d8\u5316\u5448\u73b0\u51fa\u201c\u706b\u5c71\u578b\u201d\u8d8b\u52bf\u3002\u5728\u5bbd\u7535\u4f4d\u8303\u56f4\u5185NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u6027\u80fd\u7684\u5de8\u5927\u5dee\u5f02\u96be\u4ee5\u5339\u914d\u53ef\u518d\u751f\u80fd\u6e90\u7684\u95f4\u6b47\u6027\u7279\u6027\uff0c\u4ece\u800c\u589e\u52a0\u4e86\u5728\u7535\u5316\u5b66\u785d\u9178\u76d0\u5904\u7406\u4e2d\u5229\u7528\u53ef\u518d\u751f\u80fd\u6e90\u7684\u96be\u5ea6\u3002\u56e0\u6b64\uff0c\u63d0\u5347\u5728\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u6027\u80fd\uff0c\u5e76\u901a\u8fc7\u5e9f\u5f03\u7269\u8d44\u6e90\u7684\u68af\u6b21\u5229\u7528\u964d\u4f4e\u50ac\u5316\u5242\u6210\u672c\uff0c\u5e94\u8be5\u6210\u4e3a\u7535\u5316\u5b66\u785d\u9178\u76d0\u8fd8\u539f\u7684\u7814\u7a76\u91cd\u70b9\u3002<\/p>\n\n\n\n<p><strong>2. <\/strong><strong>\u6587\u7ae0\u7b80\u4ecb<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u4e07\u5b87\u9a70\u526f\u6559\u6388\/\u5f20\u4e45\u4fca\u9662\u58eb\u3001\u6e05\u534e\u5927\u5b66\u5415\u745e\u6d9b\u6559\u6388\u7b49\u5728<em>Adv. Funct<\/em><em>. <\/em><em>Mater.<\/em>\u53d1\u8868\u7814\u7a76\u6587\u7ae0\u201cStepwise upgrading of waste nitrate by fast Joule-heating and electrochemical reduction at wide potentials\u201d\u3002\u8be5\u5de5\u4f5c\u63d0\u51fa\u4e86\u4e00\u79cd\u542b\u785d\u5e9f\u6c34\u7684\u68af\u6b21\u5229\u7528\u8def\u7ebf\uff08\u56fe1\uff09\uff0c\u9996\u5148\u901a\u8fc7\u5feb\u901f\u7126\u8033\u70ed\u65b9\u6cd5\u5c06\u5e9f\u6c34\u4e2d\u7684\u91d1\u5c5e\u79bb\u5b50\u8f6c\u5316\u4e3a\u53cc\u91d1\u5c5eCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\uff0c\u7136\u540e\u8fdb\u4e00\u6b65\u901a\u8fc7\u7535\u5316\u5b66NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u5c06\u785d\u9178\u76d0\u8f6c\u5316\u4e3a\u6c28\u3002Co<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728-0.2 V ~ -0.5 V vs. RHE\u7684\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u8868\u73b0\u51fa\u4f18\u5f02\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u6027\u80fd\uff0c\u5176\u4ea7\u6c28\u6cd5\u62c9\u7b2c\u6548\u7387\u63a5\u8fd1100%\u3002\u6b64\u5916\uff0c\u5728\u819c\u7535\u6781\uff08MEA\uff09\u7535\u89e3\u69fd\u4e2d\uff0cCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728\u5de5\u4e1a\u7ea7\u7535\u6d41\u5bc6\u5ea6200\u202fmA\u202fcm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0b\uff0c\u53ef\u5b9e\u73b0\u8d85\u8fc7300\u5c0f\u65f6\u7684\u957f\u671fNO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u7a33\u5b9a\u6027\u3002\u6b64\u5916\uff0c\u53ef\u4ee5\u5c06NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u4e0e\u80bc\u6c27\u5316\u53cd\u5e94\uff08HzOR\uff09\u8fdb\u884c\u8026\u5408\uff0c\u53ef\u964d\u4f4e\u69fd\u538b\uff0c\u5e76\u5b9e\u73b0\u785d\u9178\u76d0\u4e0e\u80bc\u6c61\u67d3\u7269\u7684\u534f\u540c\u5904\u7406\u3002TEA\u7ecf\u6d4e\u6027\u5206\u6790\u8868\u660e\uff0c\u7535\u5316\u5b66NO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\/\/ HzOR\u8026\u5408\u4f53\u7cfb\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"\" alt=\"\"\/><\/figure>\n\n\n\n<p>\u56fe1 \u5bcc\u785d\u9178\u76d0\u5e9f\u6c34\u5904\u7406\u6280\u672f\u8def\u7ebf\u56fe<\/p>\n\n\n\n<p><strong>3. <\/strong><strong>\u56fe\u6587\u89e3\u6790<\/strong><strong><\/strong><\/p>\n\n\n\n<p><strong>3.1 <\/strong><strong>\u6750\u6599\u5236\u5907\u4e0e\u8868\u5f81<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8be5\u5de5\u4f5c\u4ee5\u542b\u6709\u91d1\u5c5e\u79bb\u5b50\u7684\u785d\u9178\u76d0\u5e9f\u6c34\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u901a\u8fc7\u7126\u8033\u52a0\u70ed\u6cd5\u5408\u6210\u4e86\u53cc\u91d1\u5c5eCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u3002TEM\u663e\u793a\u51fa\u53cc\u91d1\u5c5e\u8d85\u7ec6\u7eb3\u7c73\u9897\u7c92\u5747\u5300\u8d1f\u8f7d\u4e8e\u78b3\u5e03\u4e0a\uff0c\u5e73\u5747\u7c92\u5f84\u4e3a21.25 nm\u3002HRTEM\u8868\u660e\u91d1\u5c5eCo\u66b4\u9732(111)\u6676\u9762\uff0c\u8bc1\u660e\u4e86\u91d1\u5c5e\u94b4\u7684\u5b58\u5728\uff0c\u5176\u6676\u683c\u95f4\u8ddd\u4e3a0.208 nm\uff0c\u4e14\u76f8\u8f83\u4e8e\u7eaf\u94b4\u50ac\u5316\u5242\u660e\u663e\u589e\u5927\uff0c\u8bf4\u660e\u539f\u5b50\u534a\u5f84\u8f83\u5927\u7684Cu\u63ba\u6742\u8fdb\u5165Co\u57fa\u4f53\u5f15\u8d77\u6676\u683c\u81a8\u80c0\u3002\u901a\u8fc7XANES\u548cEXAFS\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u50ac\u5316\u5242\u4e2dCo\u7684\u4ef7\u6001\u4ee5\u53ca\u914d\u4f4d\u7ed3\u6784\uff0c\u5e76\u4e14\u8bc1\u5b9e\u4e86Cu\u7684\u6210\u529f\u63ba\u6742\uff08\u56fe2\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"508\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/7f88dbbcaa77a1d-26.png\" alt=\"\" class=\"wp-image-272024\"\/><\/figure>\n\n\n\n<p>\u56fe2&nbsp;Co<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u7684\u5408\u6210\u4e0e\u8868\u5f81<\/p>\n\n\n\n<p><strong>3.2 <\/strong><strong>\u7535\u50ac\u5316<\/strong><strong>NO<\/strong><strong><sub>3<\/sub><\/strong><strong><sup>&#8211;<\/sup><\/strong><strong>RR<\/strong><strong>\u6027\u80fd\u6d4b\u8bd5<\/strong><strong><\/strong><\/p>\n\n\n\n<p>Co<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728-0.2 V ~ -0.5 V vs. RHE\u4e0b\u7684\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u8868\u73b0\u51fa\u63a5\u8fd1100%\u7684\u9ad8\u4ea7\u6c28\u6cd5\u62c9\u7b2c\u6548\u7387\u3002\u6b64\u5916\uff0c\u5728\u6574\u4e2a\u6d4b\u8bd5\u7535\u4f4d\u8303\u56f4\u5185\uff0cCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u7684\u4ea7\u6c28\u901f\u7387\u5747\u9ad8\u4e8e\u5355\u4e00\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u5728MEA\u4e2d\uff0cCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728200\u202fmA\u202fcm<sup>&#8211;<\/sup><sup>2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ef\u4ee5\u5b9e\u73b0\u8d85\u8fc7300\u5c0f\u65f6\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002\u5176\u7535\u50ac\u5316NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u7efc\u5408\u6027\u80fd\u8d85\u8fc7\u591a\u6570\u540c\u671f\u62a5\u9053\u7684\u50ac\u5316\u5242\uff08\u56fe3\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"\" alt=\"\"\/><\/figure>\n\n\n\n<p>\u56fe3&nbsp;\u7535\u50ac\u5316\u785d\u9178\u6839\u8fd8\u539f\u4ea7\u6c28\u6027\u80fd\u6d4b\u8bd5<\/p>\n\n\n\n<p><strong>3.3 <\/strong><strong>\u53cd\u5e94\u673a\u5236\u89e3\u6790<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u539f\u4f4dEIS\u5206\u6790\u8868\u660e\uff0c\u7535\u89e3\u6db2\u4e2d\u52a0\u5165\u785d\u9178\u76d0\u4e4b\u540e\uff0cCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u7684\u76f8\u89d2\u964d\u4f4e\u4e14\u5411\u9ad8\u9891\u65b9\u5411\u79fb\u52a8\uff0c\u8bf4\u660e\u7535\u5316\u5b66\u785d\u9178\u76d0\u6c22\u5316\u8fc7\u7a0b\u589e\u52a0\u4e86<sup>*<\/sup>H\u7684\u6d88\u8017\uff0c\u4fc3\u8fdb\u4e86\u6c34\u89e3\u79bb\u8fc7\u7a0b\u3002\u539f\u4f4dXRD\u7ed3\u679c\u8868\u660e\uff0cCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728\u6574\u4e2a\u6d4b\u8bd5\u7535\u4f4d\u8303\u56f4\u5185\u5747\u572844.2<sup>\u00b0<\/sup>\u548c51.5<sup>\u00b0<\/sup>\u5904\u5448\u73b0\u4e24\u4e2a\u7279\u5f81\u884d\u5c04\u5cf0\uff0c\u8868\u660e\u91d1\u5c5e\u94b4\u7269\u76f8\u5728\u7535\u5316\u5b66\u785d\u9178\u76d0\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u7a33\u5b9a\u3002\u539f\u4f4d\u62c9\u66fc\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0c\u5f53\u65bd\u52a0\u7535\u4f4d\u4ece0 V&nbsp;vs. RHE\u8d1f\u79fb\u81f3-0.1 V&nbsp;vs. RHE\u65f6\uff0c<sup>*<\/sup>NO<sub>3<\/sub>\u548c\u754c\u9762H<sub>2<\/sub>O\u7684\u62c9\u66fc\u4fe1\u53f7\u5f3a\u5ea6\u663e\u8457\u4e0b\u964d\uff0c\u8bf4\u660e<sup>*<\/sup>NO<sub>3<\/sub>\u548c\u754c\u9762H<sub>2<\/sub>O\u88ab\u5927\u91cf\u6d88\u8017\uff0c\u8868\u660eCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5177\u6709\u8f83\u5feb\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u539f\u4f4dATR-FTIR\u548c\u539f\u4f4dDEMS\u68c0\u6d4bNO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u4e2d\u95f4\u4ea7\u7269\uff0c\u63a8\u6d4b\u53cd\u5e94\u8def\u5f84\u4e3a\uff1a<sup>*<\/sup>NO<sub>3<\/sub>\u2192 <sup>*<\/sup>NO<sub>2<\/sub>\u2192<sup>&nbsp;*<\/sup>NO\u2192 <sup>*<\/sup>NOH\u2192 <sup>*<\/sup>NH\u2192 <sup>*<\/sup>NH<sub>2<\/sub>\u2192 <sup>*<\/sup>NH<sub>3<\/sub>\uff08\u56fe4\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"451\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/b14210e1ee30421-23.png\" alt=\"\" class=\"wp-image-272025\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/b14210e1ee30421-23.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/b14210e1ee30421-23-200x150.png 200w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/figure>\n\n\n\n<p>\u56fe4&nbsp;\u53cd\u5e94\u673a\u7406\u7814\u7a76<\/p>\n\n\n\n<p><strong>3.4 <\/strong><strong>\u7406\u8bba\u8ba1\u7b97\u4e0e\u5206\u6790<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u90e8\u5206\u6295\u5f71\u6001\u5bc6\u5ea6\uff08PDOS\uff09\u5206\u6790\u8868\u660e\uff0cCo<sub>9<\/sub>Cu\u50ac\u5316\u5242\u7684Cu 3d\u8f68\u9053\u548cCo 3d\u8f68\u9053\u4e4b\u95f4\u5b58\u5728\u663e\u8457\u7684\u91cd\u53e0\uff0c\u4e14\u76f8\u6bd4\u8f83\u5355\u91d1\u5c5e\u66f4\u63a5\u8fd1\u8d39\u7c73\u80fd\u7ea7\u3002\u6b64\u5916\uff0cCu 3d\u8f68\u9053\u4e0eCo 3d\u8f68\u9053\u4e4b\u95f4\u5b58\u5728d-d\u6742\u5316\u6548\u5e94\uff0c\u63d0\u5347\u4e86Co\u7684d\u5e26\u4e2d\u5fc3\uff0c\u5bfc\u81f4\u53cd\u952e\u8f68\u9053\u4e2d\u7684\u7535\u5b50\u5206\u5e03\u51cf\u5c11\uff0c\u4ece\u800c\u589e\u5f3a\u4e86Co\u4f4d\u70b9\u4e0e\u5438\u9644\u7269\u4e4b\u95f4\u7684\u7ed3\u5408\u5f3a\u5ea6\u3002\u901a\u8fc7pCOHP\u7814\u7a76\u4e86NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u8fc7\u7a0b\u7684\u5173\u952e\u4e2d\u95f4\u4f53<sup>*<\/sup>NOH\u4e0e\u91d1\u5c5e\u8868\u9762\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u4e0e\u7eafCo\u548cCu\u50ac\u5316\u5242\u76f8\u6bd4\uff0cCo<sub>9<\/sub>Cu\u50ac\u5316\u5242\u663e\u793a\u51fa\u66f4\u8d1f\u7684ICOHP\u503c\uff0c\u8868\u660e<sup>*<\/sup>NOH\u5728Co<sub>9<\/sub>Cu\u50ac\u5316\u5242\u4e0a\u7684\u5438\u9644\u589e\u5f3a\u3002\u53cd\u5e94\u8def\u5f84\u81ea\u7531\u80fd\u8ba1\u7b97\u8868\u660e\uff0c\u53cc\u91d1\u5c5eCo<sub>9<\/sub>Cu\u50ac\u5316\u5242\u7684\u6574\u4e2a\u53cd\u5e94\u8def\u5f84\u4e3a\u653e\u70ed\u8fc7\u7a0b\uff0c\u4e14\u76f8\u8f83\u4e8e\u7eafCo\u548cCu\u50ac\u5316\u5242\uff0cCo<sub>9<\/sub>Cu\u50ac\u5316\u5242\u5bf9<sup>*<\/sup>NOH\u7684\u5438\u9644\u81ea\u7531\u80fd\u6700\u4f4e\uff0cH<sub>2<\/sub>O\u89e3\u79bb\u52a8\u529b\u5b66\u80fd\u5792\u6700\u4f4e\uff08\u56fe5\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"482\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/de5bcf7d8eaea98-18.png\" alt=\"\" class=\"wp-image-272026\"\/><\/figure>\n\n\n\n<p>\u56fe5&nbsp;\u7406\u8bba\u8ba1\u7b97\u4e0e\u5206\u6790<\/p>\n\n\n\n<p><strong>3.5 <\/strong><strong>\u6269\u5c55\u5e94\u7528\u7814\u7a76<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8be5\u5de5\u4f5c\u5c06\u81ea\u652f\u6491\u53cc\u91d1\u5c5eCo<sub>9<\/sub>Cu@CC\u4f5c\u4e3a\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff0c\u540c\u65f6\u7528\u4e8e\u9634\u6781NO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\u548c\u9633\u6781HzOR\uff0c\u5728\u819c\u7535\u6781\u7ec4\u4ef6\u4e2d\uff08MEA\uff09\uff0c\u7ec4\u6210\u4e86NO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\/\/ HzOR\u7535\u5316\u5b66\u7cfb\u7edf\u3002\u6781\u5316\u66f2\u7ebf\u663e\u793a\uff0cNO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\/\/ HzOR\u7684\u7535\u6d41\u5bc6\u5ea6\u8fdc\u9ad8\u4e8eNO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\/\/ OER\u4ee5\u53caHER \/\/ OER\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u5728200\u202fmA\u202fcm<sup>&#8211;<\/sup><sup>2<\/sup>\u7684\u5927\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fde\u7eed\u8fd0\u884c\u8d85\u8fc7300\u5c0f\u65f6\uff0c\u80fd\u591f\u7ef4\u6301\u76f8\u5bf9\u7a33\u5b9a\u7684\u7535\u6c60\u7535\u538b\u548cNH<sub>3<\/sub>\u4ea7\u7387\u3002\u6280\u672f\u7ecf\u6d4e\u5206\u6790\uff08TEA\uff09\u8fdb\u4e00\u6b65\u8bc1\u660e\u4e86\u7535\u5316\u5b66NO<sub>3<\/sub><sup>&#8211;<\/sup>RR&nbsp;\/\/ HzOR\u7cfb\u7edf\u7684\u5e94\u7528\u4ef7\u503c\uff08\u56fe6\uff09\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"557\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/aa3023e0288002c-13.png\" alt=\"\" class=\"wp-image-272027\"\/><\/figure>\n\n\n\n<p>\u56fe6&nbsp;NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u4e0e\u80bc\u6c27\u5316\u7684\u7535\u5316\u5b66\u5076\u8054<\/p>\n\n\n\n<p><strong>4<\/strong><strong>.<\/strong><strong>&nbsp;<\/strong><strong>\u603b\u7ed3<\/strong><strong>\u5c55\u671b<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u672c\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u7528\u4e8e\u5904\u7406\u5e9f\u785d\u9178\u76d0\u7684\u68af\u6b21\u5229\u7528\u8def\u7ebf\u3002\u901a\u8fc7\u785d\u9178\u76d0\u53c2\u4e0e\u7684\u7126\u8033\u52a0\u70ed\u6cd5\u5408\u6210\u4e86\u53cc\u91d1\u5c5eCo<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u3002\u8be5\u785d\u9178\u76d0\u884d\u751f\u7684Co<sub>9<\/sub>Cu@CC\u50ac\u5316\u5242\u5728-0.2 V ~ -0.5 V vs. RHE\u4e0b\u7684\u5bbd\u7535\u4f4d\u8303\u56f4\u5185\u8868\u73b0\u51fa\u4f18\u5f02\u7684NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u6027\u80fd\uff0cNH<sub>3<\/sub>\u6cd5\u62c9\u7b2c\u6548\u7387\u63a5\u8fd1100%\u3002\u6b64\u5916\uff0c\u5728MEA\u7535\u89e3\u6c60\u4e2d\uff0c\u5728\u5de5\u4e1a\u7ea7\u7535\u6d41\u5bc6\u5ea6200\u202fmA\u202fcm<sup>&#8211;<\/sup><sup>2<\/sup>\u4e0b\uff0c\u53ef\u5b9e\u73b0\u8d85\u8fc7300\u5c0f\u65f6\u7684\u957f\u671fNO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u7a33\u5b9a\u6027\u3002\u539f\u4f4dEIS\u63ed\u793a\u4e86\u7535\u5316\u5b66\u785d\u9178\u76d0\u52a0\u6c22\u8fc7\u7a0b\u5bf9<sup>*<\/sup>H\u7684\u6d88\u8017\u3002\u539f\u4f4dXRD\u6d4b\u8bd5\u8bc1\u5b9e\u4e86\u7535\u5316\u5b66NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u8fc7\u7a0b\u4e2d\u91d1\u5c5eCo\u76f8\u7684\u7a33\u5b9a\u6027\u3002\u539f\u4f4dRaman\u3001\u539f\u4f4dATR-FTIR\u5149\u8c31\u7ed3\u5408\u539f\u4f4dDEMS\u68c0\u6d4b\u4e86\u53cd\u5e94\u4e2d\u95f4\u4f53\uff0c\u5e76\u786e\u5b9a\u4e86NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u8def\u5f84\u3002DFT\u8ba1\u7b97\u8868\u660e\uff0cCu\u4e0eCo\u4e4b\u95f4\u7684\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\u53ef\u589e\u5f3a\u4e2d\u95f4\u4f53<sup>*<\/sup>NOH\u7684\u7ed3\u5408\u5f3a\u5ea6\uff0c\u4ece\u800c\u964d\u4f4eNO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u51b3\u901f\u6b65\u9aa4\u7684\u80fd\u5792\u3002\u5728\u785d\u9178\u76d0\u5347\u7ea7\u7684\u6269\u5c55\u5e94\u7528\u65b9\u9762\uff0c\u5c06NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\u4e0e\u80bc\u6c27\u5316\u53cd\u5e94\u8fdb\u884c\u7535\u5316\u5b66\u8026\u5408\u53ef\u964d\u4f4e\u69fd\u538b\uff0c\u5e76\u5b9e\u73b0\u785d\u9178\u76d0\u4e0e\u80bc\u6c61\u67d3\u7269\u7684\u534f\u540c\u5904\u7406\u3002TEA\u7ed3\u679c\u663e\u793a\uff0c\u7535\u5316\u5b66NO<sub>3<\/sub><sup>&#8211;<\/sup>RR\/\/ HzOR\u4f53\u7cfb\u5177\u6709\u4e00\u5b9a\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n\n\n\n<p><strong>5. <\/strong><strong>\u8bba\u6587\u4fe1\u606f<\/strong><strong><\/strong><\/p>\n\n\n\n<p>Yuchi Wan<sup>*<\/sup>, Yu Chen, Yixiang Tang, Wei Yan, Jiujun Zhang<sup>*<\/sup>, Ruitao Lv<sup>*<\/sup>, \u201cStepwise Upgrading of Waste Nitrate by Fast Joule-Heating and Electrochemical Reduction at Wide Potentials.\u201d Advanced Functional Materials (2026): e76112. https:\/\/doi.org\/10.1002\/adfm.76112.<\/p>\n\n\n\n<p><strong>6<\/strong><strong>.<\/strong><strong>&nbsp;<\/strong><strong>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><strong><\/strong><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"400\" height=\"554\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/e2f457ec632c1f6-10.png\" alt=\"\" class=\"wp-image-272028\"\/><\/figure>\n\n\n\n<p><strong>\u4e07\u5b87\u9a70<\/strong>\uff0c\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u526f\u6559\u6388\uff0c\u798f\u5efa\u7701\u201c\u96cf\u9e70\u8ba1\u5212\u201d\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u30022023\u5e74\u83b7\u6e05\u534e\u5927\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u5415\u745e\u6d9b\u6559\u6388\uff1b\u540c\u5e74\u52a0\u5165\u798f\u5dde\u5927\u5b66\u5f20\u4e45\u4fca\u9662\u58eb\u56e2\u961f\u3002\u4e3b\u8981\u4ece\u4e8b\u4f4e\u7ef4\u8d1f\u8f7d\u578b\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u7535\u50ac\u5316\u6027\u80fd\u8c03\u63a7\u7814\u7a76\u5de5\u4f5c\uff0c\u4ee5\u7b2c\u4e00\u4f5c\u8005\/\u901a\u8baf\u4f5c\u8005\u5728<em>Nat. Commun.<\/em>\u3001<em>Adv. Mater.<\/em>\u3001<em>Energy Environ. Sci.<\/em>\u3001<em>Adv. Energy Mater.<\/em>\u3001<em>Adv. Funct. Mater.<\/em>\u3001<em>ACS Nano<\/em>\u3001<em>Mater. Today<\/em>\u7b49\u56fd\u9645\u671f\u520a\u4e0a\u53d1\u8868SCI\u8bba\u658710\u4f59\u7bc7\uff0c\u5176\u4e2d\u591a\u7bc7\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\u3002\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9752\u5e74\u9879\u76ee\u3001\u798f\u5efa\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u7b49\u9879\u76ee\u8d44\u52a9\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"286\" height=\"416\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/bf2e94a56e16c6a-4.png\" alt=\"\" class=\"wp-image-272029\"\/><\/figure>\n\n\n\n<p><strong>\u5f20\u4e45\u4fca<\/strong>\uff0c\u4e2d\u56fd\u5de5\u7a0b\u9662\u5916\u7c4d\u9662\u58eb\uff0c\u52a0\u62ff\u5927\u7687\u5bb6\u79d1\u5b66\u9662\u9662\u58eb\u3001\u52a0\u62ff\u5927\u5de5\u7a0b\u9662\u9662\u58eb\u3001\u52a0\u62ff\u5927\u5de5\u7a0b\u7814\u7a76\u9662\u9662\u58eb\u3001\u56fd\u9645\u7535\u5316\u5b66\u5b66\u4f1a\u4f1a\u58eb\u3001\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u5148\u8fdb\u6750\u6599\u534f\u4f1a\u4f1a\u58eb\u3001\u56fd\u9645\u7535\u5316\u5b66\u80fd\u6e90\u79d1\u5b66\u9662\uff08IAOEES\uff09\u4e3b\u5e2d\u3001\u4e2d\u56fd\u5185\u71c3\u673a\u5b66\u4f1a\u5e38\u52a1\u7406\u4e8b\u517c\u71c3\u6599\u7535\u6c60\u53d1\u52a8\u673a\u5206\u4f1a\u4e3b\u4efb\u59d4\u5458\uff0c\u73b0\u4efb\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u9662\u957f\u3001\u65b0\u80fd\u6e90\u6750\u6599\u4e0e\u5de5\u7a0b\u7814\u7a76\u9662\u9662\u957f\u3002\u957f\u671f\u4ece\u4e8b\u7535\u5316\u5b66\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u6362\u53ca\u5176\u6750\u6599\u7684\u7814\u7a76\u548c\u4ea7\u4e1a\u5316\u5e94\u7528\u5f00\u53d1\uff0c\u5305\u62ec\u71c3\u6599\u7535\u6c60\u3001\u9ad8\u6bd4\u80fd\u4e8c\u6b21\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001CO<sub>2<\/sub>\u7535\u5316\u5b66\u8fd8\u539f\u548c\u7535\u89e3\u6c34\u7b49\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"616\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/bafe803af52db04-2.png\" alt=\"\" class=\"wp-image-272030\"\/><\/figure>\n\n\n\n<p><strong>\u5415\u745e\u6d9b<\/strong>\uff0c\u6e05\u534e\u5927\u5b66\u957f\u8058\u6559\u6388\uff0c\u6750\u6599\u5b66\u9662\u526f\u9662\u957f\u30022009\u5e74\u83b7\u6e05\u534e\u5927\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c2009\u5e74-2013\u5e74\u5148\u540e\u5728\u6e05\u534e\u5927\u5b66\u548c\u7f8e\u56fd\u5bbe\u5915\u6cd5\u5c3c\u4e9a\u5dde\u7acb\u5927\u5b66\u7269\u7406\u7cfb\u505a\u535a\u58eb\u540e\u7814\u7a76\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u4f4e\u7ef4\u6750\u6599\u7f3a\u9677\u8c03\u63a7\u4e0e\u529f\u80fd\u521b\u5236\u3002\u5728<em>Science<\/em>\u3001<em>Nat. Commun.<\/em>\u3001<em>Adv. Mater.<\/em>\u7b49\u671f\u520a\u53d1\u8868\u8bba\u6587200\u4f59\u7bc7\uff0c\u88ab\u5f1520,400\u4f59\u6b21\uff0cH\u56e0\u5b5068\u30022017\u5e74\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4-\u4f18\u79c0\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u8d44\u52a9\uff0c2022\u5e74\u83b7\u4e2d\u56fd\u6750\u6599\u7814\u7a76\u5b66\u4f1a\u79d1\u5b66\u6280\u672f\u5956\uff08\u57fa\u7840\u7814\u7a76\uff09\u4e00\u7b49\u5956\uff0c2025\u5e74\u83b7\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4-\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\uff08A\u7c7b\uff09\uff08\u539f\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff09\u8d44\u52a9\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u901a\u8baf\u4f5c\u8005\uff1a\u4e07\u5b87\u9a70\u526f\u6559\u6388\u3001\u5f20\u4e45\u4fca\u9662\u58eb\u3001\u5415\u745e\u6d9b\u6559\u6388 \u901a\u8baf\u5355\u4f4d\uff1a\u798f\u5dde\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u3001\u6e05\u534e\u5927\u5b66\u6750\u6599\u5b66\u9662 \u8bba\u6587\u94fe\u63a5\uff1ahttp:\/\/doi.org\/10.1002\/&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-272022","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272022"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=272022"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272022\/revisions"}],"predecessor-version":[{"id":272031,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272022\/revisions\/272031"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=272022"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=272022"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=272022"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}