{"id":272052,"date":"2026-05-30T09:11:00","date_gmt":"2026-05-30T01:11:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=272052"},"modified":"2026-05-30T00:20:29","modified_gmt":"2026-05-29T16:20:29","slug":"%e5%86%8d%e5%8f%91am%ef%bc%81%e5%a4%a7%e8%bf%9e%e5%b7%a5%e4%b8%9a%e8%83%a1%e9%a1%ba%e5%8f%8b%ef%bc%88%e9%9d%92%e6%8b%94%e9%9d%92%e6%89%98%ef%bc%89%e8%81%94%e5%90%88%e8%8e%86%e7%94%b0%e5%ad%a6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=272052","title":{"rendered":"\u518d\u53d1AM\uff01\u5927\u8fde\u5de5\u4e1a\u80e1\u987a\u53cb\uff08\u9752\u62d4&#038;\u9752\u6258\uff09\u8054\u5408\u8386\u7530\u5b66\u9662\u6613\u660e\u6770\u6559\u6388\uff1a\u4e00\u79cd\u79bb\u5b50\u6db2\u4f53\u4ecb\u5bfc\u4e0b\u7684\u975e\u6676\u5de5\u7a0b\u6784\u5efa\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60"},"content":{"rendered":"\n<ul class=\"wp-block-list\">\n<li>\u5bfc\u8bfb<\/li>\n<\/ul>\n\n\n\n<p>\u672c\u7814\u7a76\u9488\u5bf9\u9502\u786b\u7535\u6c60\u4e2d\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fdf\u7f13\u3001\u591a\u786b\u5316\u9502\uff08LiPSs\uff09\u7a7f\u68ad\u6548\u5e94\u4e25\u91cd\u5236\u7ea6\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u96be\u9898\uff0c\u63d0\u51fa\u4e00\u79cd\u5229\u7528\u94c1\u57fa\u79bb\u5b50\u6db2\u4f53\u8bf1\u5bfc\u975e\u6676\u5316\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u5728\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08CNFs\uff09\u4e0a\u6784\u5efa\u5177\u6709\u7535\u5076\u6781\u57df\u548c\u4e0d\u5bf9\u79f0Fe<sub>1<\/sub>-O-Bi\u7535\u5b50\u6865\uff08Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs\uff09\u7684\u5bf9\u79f0\u6027\u7834\u7f3ap\u533a\u6c27\u5316\u94cb\u3002\u975e\u6676\u76f8\u5f15\u53d1\u663e\u8457\u7535\u5b50\u79bb\u57df\uff0c\u4fc3\u8fdb\u8f68\u9053\u5927\u5e45\u91cd\u53e0\u5e76\u5f62\u6210\u7535\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u4ece\u800c\u52a0\u901f\u591a\u786b\u5316\u9502\u7684\u6c27\u5316\u8fd8\u539f\u3002\u7279\u522b\u5730\uff0c\u4e0d\u5bf9\u79f0Fe<sub>1<\/sub>-O-Bi\u7535\u5b50\u6865\u901a\u8fc73d-2p-6p\u591a\u8f68\u9053\u8026\u5408\u964d\u4f4ep\u5e26\u4e2d\u5fc3\uff0c\u4f18\u5316\u591a\u786b\u5316\u9502\u7684\u5316\u5b66\u5438\u9644\u5e76\u9632\u6b62\u6d3b\u6027\u4f4d\u70b9\u4e2d\u6bd2\u3002\u7535\u5b50\u5076\u6781\u57df\u4f5c\u4e3a\u7535\u5b50\/Li+\u201c\u6cf5\u201d\u589e\u5f3a\u7535\u8377\u8f6c\u79fb\u548cLi+\u6269\u6563\u3002\u6b64\u5916\uff0c\u7535\u5076\u6781\u57df\u8bf1\u5bfc\u5076\u6781-\u5076\u6781\u76f8\u4e92\u4f5c\u7528\uff0c\u4fc3\u8fdbLi-S\u952e\u6781\u5316\u4e0e\u65ad\u88c2\u3002\u57fa\u4e8eFe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>\u7684\u7535\u6c60\u57281.0 C\u500d\u7387\u4e0b\u5faa\u73af1000\u6b21\u540e\u4ecd\u4fdd\u6301698 mAh g\u207b\u00b9\u7684\u5bb9\u91cf\uff0c\u5355\u5708\u8870\u51cf\u7387\u4ec5\u4e3a0.026%\uff1b\u57287.4 mg cm<sup>-2<\/sup>\u786b\u8f7d\u91cf\u4e0b\u83b7\u5f976.8 mAh cm<sup>-2<\/sup>\u7684\u9ad8\u9762\u5bb9\u91cf\u3002\u8fd9\u79cd\u901a\u8fc7\u975e\u6676\u5316\u6784\u5efa\u7535\u5b50\u5076\u6781\u57df\u7684\u7b56\u7565\uff0c\u4e3a\u786b\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u9ad8\u6548\u50ac\u5316\u5242\u7684\u7406\u6027\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u6210\u679c\u63a0\u5f71<\/li>\n<\/ul>\n\n\n\n<p>\u8fd1\u65e5\uff0c<strong>\u5927\u8fde\u5de5\u4e1a\u5927\u5b66<\/strong><strong>\uff08\u9752\u62d4&amp;\u9752\u6258<\/strong><strong>\uff09<\/strong><strong>\u80e1\u987a\u53cb<\/strong><strong>\u3001\u8386<\/strong><strong>\u7530\u5b66\u9662\u7684\u6613\u660e\u6770\u6559\u6388<\/strong><strong>\u3001\u798f\u5dde\u5927\u5b66\u7684\u5de6\u94f6\u6cfd<\/strong><strong>\u8001\u5e08<\/strong><strong>\u3001\u626c\u5dde\u5927\u5b66\u7684\u5e9e\u6b22\u6559\u6388<\/strong>\uff0c\u9488\u5bf9\u9502\u786b\u7535\u6c60\u4e2d\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fdf\u7f13\u3001\u591a\u786b\u5316\u9502\uff08LiPSs\uff09\u7a7f\u68ad\u6548\u5e94\u4e25\u91cd\u5236\u7ea6\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u96be\u9898\uff0c\u63d0\u51fa\u4e00\u79cd\u5229\u7528\u94c1\u57fa\u79bb\u5b50\u6db2\u4f53\u8bf1\u5bfc\u975e\u6676\u5316\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u5728\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08CNFs\uff09\u4e0a\u6784\u5efa\u5177\u6709\u7535\u5076\u6781\u57df\u548c\u4e0d\u5bf9\u79f0Fe<sub>1<\/sub>-O-Bi\u7535\u5b50\u6865\uff08Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs\uff09\u7684\u5bf9\u79f0\u6027\u7834\u7f3ap\u533a\u6c27\u5316\u94cb\u3002\u975e\u6676\u76f8\u5f15\u53d1\u663e\u8457\u7535\u5b50\u79bb\u57df\uff0c\u4fc3\u8fdb\u8f68\u9053\u5927\u5e45\u91cd\u53e0\u5e76\u5f62\u6210\u7535\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u4ece\u800c\u52a0\u901f\u591a\u786b\u5316\u9502\u7684\u6c27\u5316\u8fd8\u539f\u3002\u7279\u522b\u5730\uff0c\u4e0d\u5bf9\u79f0Fe<sub>1<\/sub>-O-Bi\u7535\u5b50\u6865\u901a\u8fc73d-2p-6p\u591a\u8f68\u9053\u8026\u5408\u964d\u4f4ep\u5e26\u4e2d\u5fc3\uff0c\u4f18\u5316\u591a\u786b\u5316\u9502\u7684\u5316\u5b66\u5438\u9644\u5e76\u9632\u6b62\u6d3b\u6027\u4f4d\u70b9\u4e2d\u6bd2\u3002\u7535\u5b50\u5076\u6781\u57df\u4f5c\u4e3a\u7535\u5b50\/Li+\u201c\u6cf5\u201d\u589e\u5f3a\u7535\u8377\u8f6c\u79fb\u548cLi+\u6269\u6563\u3002\u6b64\u5916\uff0c\u7535\u5076\u6781\u57df\u8bf1\u5bfc\u5076\u6781-\u5076\u6781\u76f8\u4e92\u4f5c\u7528\uff0c\u4fc3\u8fdbLi-S\u952e\u6781\u5316\u4e0e\u65ad\u88c2\u3002\u57fa\u4e8eFe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>\u7684\u7535\u6c60\u57281.0 C\u500d\u7387\u4e0b\u5faa\u73af1000\u6b21\u540e\u4ecd\u4fdd\u6301698 mAh g<sup>-1<\/sup>\u7684\u5bb9\u91cf\uff0c\u5355\u5708\u8870\u51cf\u7387\u4ec5\u4e3a0.026%\uff1b\u57287.4 mg cm<sup>-2<\/sup>\u786b\u8f7d\u91cf\u4e0b\u83b7\u5f976.8 mAh cm<sup>-1<\/sup>\u7684\u9ad8\u9762\u5bb9\u91cf\u3002\u8fd9\u79cd\u901a\u8fc7\u975e\u6676\u5316\u6784\u5efa\u7535\u5b50\u5076\u6781\u57df\u7684\u7b56\u7565\uff0c\u4e3a\u786b\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u9ad8\u6548\u50ac\u5316\u5242\u7684\u7406\u6027\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n\n\n\n<h4 class=\"wp-block-heading\">\u8be5\u6210\u679c\u4ee5<strong>\u5927\u8fde\u5de5\u4e1a\u5927\u5b66\u5b66\u9662\u4e3a\u7b2c\u4e00\u5355\u4f4d<\/strong>\u4ee5\u9898\u76ee\u201cLonic-Liquid-Triggered Amorphization Engineers Symmetry-Breaking p-Block Bismuth Oxides with Electric Dipole Domains for Practical Lithium-Sulfur Batteries\u201d\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520aAdvanced materials\uff08\u4e2d\u79d1\u9662\u4e00\u533a\uff09\u4e0a\u53d1\u8868\uff0c\u5f71\u54cd\u56e0\u5b50\u4e3a26.8\u3002<\/h4>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"274\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/2382c315a6ba396-32.png\" alt=\"\" class=\"wp-image-272053\"\/><\/figure>\n\n\n\n<p>\u4e09\u3001\u6838\u5fc3\u521b\u65b0\u70b9<\/p>\n\n\n\n<p>\u8be5\u7814\u7a76\u6838\u5fc3\u521b\u65b0\u70b9\u5728\u4e8e\u63d0\u51fa\u79bb\u5b50\u6db2\u4f53\u8bf1\u5bfc\u975e\u6676\u5316\uff0c\u6784\u5efa\u7535\u5076\u6781\u7574\u7684\u591a\u7b56\u7565\u534f\u540c\u4f18\u5316\u65b9\u6848\uff0c\u540c\u6b65\u89e3\u51b3\u9502\u786b\u7535\u6c60\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fdf\u7f13\u548c\u591a\u786b\u5316\u9502\u7a7f\u68ad\u6548\u5e94\u4e24\u5927\u5173\u952e\u74f6\u9888\u3002\u901a\u8fc7\u6574\u5408\u975e\u6676\u5316\u5de5\u7a0b\uff08\u6253\u7834\u6676\u4f53\u957f\u7a0b\u6709\u5e8f\uff09\u3001\u5bf9\u79f0\u6027\u7834\u7f3a\u7ed3\u6784\uff08\u6784\u5efa\u7535\u5076\u6781\u7574\uff09\u53ca\u4e0d\u5bf9\u79f0Fe\u2081-O-Bi\u7535\u5b50\u6865\u8bbe\u8ba1\uff0c\u534f\u540c\u63d0\u5347\u6750\u6599\u7535\u5b50\u79bb\u57df\u7a0b\u5ea6\u3001\u7535\u8377\u4f20\u8f93\u6548\u7387\u4e0e\u591a\u786b\u5316\u9502\u8f6c\u5316\u52a8\u529b\u5b66\u3002\u501f\u52a9\u539f\u4f4d\u8868\u5f81\u4e0eDFT\u8ba1\u7b97\uff0c\u4ece\u539f\u5b50\u5c42\u9762\u9610\u660e\u4e86\u7535\u5076\u6781\u7574\u3001\u591a\u8f68\u9053\u8026\u5408\u4e0eLi-S\u952e\u6d3b\u5316\u7684\u534f\u540c\u50ac\u5316\u673a\u5236\u3002\u6240\u8bbe\u8ba1\u50ac\u5316\u5242\u663e\u8457\u63d0\u5347\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3001\u6291\u5236\u7a7f\u68ad\u6548\u5e94\uff0c\u5b9e\u73b0\u957f\u5faa\u73af\u3001\u9ad8\u786b\u8d1f\u8f7d\u4e0e\u5b9e\u7528\u5316\u8f6f\u5305\u7535\u6c60\uff0c\u4e3a\u9ad8\u6027\u80fd\u9502\u786b\u7535\u6c60\u50ac\u5316\u5242\u8bbe\u8ba1\u63d0\u4f9b\u65b0\u9896\u8303\u5f0f\u3002<\/p>\n\n\n\n<p>\u56db\u3001\u6570\u636e\u6982\u89c8<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"590\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/ce6e2814f207c93-30.png\" alt=\"\" class=\"wp-image-272054\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;1.&nbsp;(a) Schematic illustration of the Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs. (b) SEM and (c, d) TEM images of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (e) HRTEM images, corresponding (f) lattice spacing profiles, (g) fast-Fourier-transform images, and (h) crystal plane&nbsp;structures of C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (i) HRTEM images, (j) corresponding fast-Fourier-transform images, and (k) geometric phase analysis&nbsp;of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (l) Spherical aberration-corrected HAADF-STEM images&nbsp;and (m) corresponding 3D topographic atom images of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. AFM images and corresponding height profiles of (n) Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>&nbsp;and (o) C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (p) Elemental distribution of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"561\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/7f88dbbcaa77a1d-29.png\" alt=\"\" class=\"wp-image-272055\"\/><\/figure>\n\n\n\n<p>Fig. 2.\u00a0(a) Diagram of Synchrotron Radiation. (b) Bi L<sub>3<\/sub>-edge XANES spectra. (c) Linear relationship between L<sub>3<\/sub>-edge absorption energy and oxidation state. WT contour plots of C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs (d, e) and Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs (f, g). FT-EXAFS spectra (h) and the corresponding fitting result for C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs (i) and Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs (j). (k) The total DOS diagrams of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs and C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs. (l, m, n) The calculated charge density differences of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs. (o) Calculated electrostatic potentials of C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs and Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs. (p) The diagram of electric dipole domains within Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"586\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/4e9a0ba2491dfde-27.png\" alt=\"\" class=\"wp-image-272056\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;3.&nbsp;Contour maps of in situ UV-vis spectra of the cells with (a) Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs and (b) C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs. (c) Schematic diagram of the in situ XRD setup and corresponding (d) contour maps. (e) Schematic diagram of the in situ Raman setup and corresponding (f) contour maps. (g) UV absorbance spectra of the Li<sub>2<\/sub>S<sub>6<\/sub>&nbsp;solutions. (h, i) ELF of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (j) The difference charge density of Li<sub>2<\/sub>S<sub>6<\/sub>&nbsp;adsorbed on Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>&nbsp;and C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (k) The PDOS of Bi-6<em>p<\/em>&nbsp;orbitals. (l) Schematic illustrations of the electronic interactions among orbitals. (m) Scheme for energy level splitting of Bi-6<em>p<\/em>&nbsp;orbitals and S-3<em>p<\/em>&nbsp;orbitals. (n) COHP for Bi-S coupling between LiPSs and Bi-based catalysts. (o) Adsorption energy between LiPSs and catalysts.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"571\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/b14210e1ee30421-26.png\" alt=\"\" class=\"wp-image-272057\"\/><\/figure>\n\n\n\n<p>Fig. 4. Contour plots of&nbsp;(a) peak A and (c)&nbsp;peak C from the CV curves of Li||S batteries. The linear relationships between <em>I<\/em><sub>p<\/sub>&nbsp;and the square root of scan rates for (b)&nbsp;peak A and&nbsp;(d) peak C.&nbsp;The energy barrier&nbsp;for the diffusion process of Li<sup>+<\/sup>&nbsp;within (e) C-Bi<sub>2<\/sub>O<sub>3<\/sub>&nbsp;and (f) Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (g) LSV curves and corresponding (h) Tafel plots. Contour plots of CV patterns for (i) Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs, (j) C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs, and (k) CNFs at different temperatures. (l) The linear relationship between ln&nbsp;(<em>I<\/em><sub>p<\/sub>) and 1\/<em>T<\/em>. (m) Tafel plots, (n) EIS plots, and (o) chronoamperometric curves for the symmetric cells. (p) DRT curves of the Li||S battery. EIS plots and corresponding DRT contour plots at different temperatures for (q) Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs, (r) C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs, and (s) CNFs-based cells. (t) The linear relationship between the ln(1\/<em>R<\/em>) and the 1\/<em>T<\/em>.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"582\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/de5bcf7d8eaea98-20.png\" alt=\"\" class=\"wp-image-272058\"\/><\/figure>\n\n\n\n<p>Fig. 5. (a, b) In situ EIS and the corresponding DRT contour of&nbsp;Li||S cells during the discharging process. (c) Kinetic assessment using PITT measurement. (d, f) Dimensionless current-time transient profile during the deposition of Li<sub>2<\/sub>S. (e) Rate performance of the Li||S batteries. (g) Galvanostatic discharge profiles of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based cell. (h) Diagram of lithium metal corrosion caused by the shuttle effect of LiPSs. (i, j) AFM images of lithium anode after cycling. (k) GITT curves of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based cells. (l, m, n) COHP of Li-S coupling in Li<sub>2<\/sub>S. (o, p) Energy barrier&nbsp;of Li<sub>2<\/sub>S decomposition.<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"550\" height=\"523\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/05\/aa3023e0288002c-14.png\" alt=\"\" class=\"wp-image-272059\"\/><\/figure>\n\n\n\n<p>Fig.&nbsp;6.&nbsp;(a) Discharge profiles and (b) cycling performance of Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based cells with high sulfur loadings. (c) Performance comparisons of Li||S batteries with recent references. (d) Fabrication process of the Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based pouch cell. (e) Cycling performance of Li||S pouch cell. (f)&nbsp;Performance comparison of the Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based pouch cell with recent literature. (g) Practical utilization of the Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>@CNFs-based pouch cell. (h) Schematic illustration of the enhanced SRR kinetics mediated by the Fe<sub>1<\/sub>\u2282A\/C-Bi<sub>2<\/sub>O<sub>3<\/sub>. (i\u2212k) Gibbs free energy for SRR.<\/p>\n\n\n\n<p>\u4e94\u3001\u6210\u679c\u542f\u793a<\/p>\n\n\n\n<p>\u8be5\u7814\u7a76\u7684\u6210\u679c\u542f\u793a\u4e3b\u8981\u4f53\u73b0\u5728\u56db\u65b9\u9762\u3002\u5176\u4e00\uff0c\u975e\u6676\u5316\u4e0e\u6676\u6001\/\u975e\u6676\u5f02\u8d28\u754c\u9762\u8026\u5408\u53ef\u6784\u5efa\u5f3a\u5185\u5efa\u7535\u573a\u548c\u7535\u5076\u6781\u7574\uff0c\u4e3a\u6539\u5584\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u3001\u6291\u5236\u591a\u786b\u5316\u9502\u7a7f\u68ad\u6548\u5e94\u63d0\u4f9b\u4e86\u901a\u7528\u65b0\u7b56\u7565\u3002\u5176\u4e8c\uff0c\u4e0d\u5bf9\u79f0Fe\u2081-O-Bi\u7535\u5b50\u6865\u4e0e\u591a\u8f68\u9053\u8026\u5408\u53ef\u7cbe\u51c6\u8c03\u63a7p\u5e26\u4e2d\u5fc3\uff0c\u5b9e\u73b0\u591a\u786b\u5316\u9502\u6e29\u548c\u5438\u9644\u4e0e\u9ad8\u6548\u8f6c\u5316\uff0c\u4e3ap\u533a\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7535\u5b50\u7ed3\u6784\u8c03\u63a7\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002\u5176\u4e09\uff0c\u539f\u4f4d\u8868\u5f81\u4e0e\u7406\u8bba\u8ba1\u7b97\u7ed3\u5408\uff0c\u53ef\u4ece\u539f\u5b50\u5c42\u9762\u63ed\u793a\u50ac\u5316\u673a\u5236\uff0c\u4e3a\u786b\u6b63\u6781\u50ac\u5316\u5242\u7684\u673a\u7406\u7814\u7a76\u4e0e\u7ed3\u6784\u8bbe\u8ba1\u5efa\u7acb\u4e86\u89c4\u8303\u65b9\u6cd5\u3002\u5176\u56db\uff0c\u672c\u5de5\u4f5c\u5b9e\u73b0\u9ad8\u786b\u8d1f\u8f7d\u3001\u957f\u5faa\u73af\u7a33\u5b9a\u4e0e\u5b9e\u7528\u5316\u8f6f\u5305\u7535\u6c60\uff0c\u8bc1\u660e\u975e\u6676\u5316\u4e0e\u7535\u5076\u6781\u7574\u8bbe\u8ba1\u53ef\u6709\u6548\u63a8\u52a8\u9502\u786b\u7535\u6c60\u5b9e\u7528\u5316\uff0c\u4e3a\u9ad8\u6bd4\u80fd\u50a8\u80fd\u5668\u4ef6\u53d1\u5c55\u5f00\u8f9f\u4e86\u65b0\u8def\u5f84\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u672c\u7814\u7a76\u9488\u5bf9\u9502\u786b\u7535\u6c60\u4e2d\u786b\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fdf\u7f13\u3001\u591a\u786b\u5316\u9502\uff08LiPSs\uff09\u7a7f\u68ad\u6548\u5e94\u4e25\u91cd\u5236\u7ea6\u5b9e\u9645\u5e94\u7528\u7684\u5173\u952e\u96be\u9898\uff0c\u63d0\u51fa\u4e00\u79cd\u5229\u7528\u94c1\u57fa\u79bb\u5b50\u6db2\u4f53\u8bf1\u5bfc\u975e\u6676\u5316\u7684\u7b56\u7565\uff0c\u901a\u8fc7\u5728\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08&#8230;<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-272052","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272052"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=272052"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272052\/revisions"}],"predecessor-version":[{"id":272060,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272052\/revisions\/272060"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=272052"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=272052"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=272052"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}