{"id":272376,"date":"2026-07-03T08:41:00","date_gmt":"2026-07-03T00:41:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=272376"},"modified":"2026-07-02T19:21:12","modified_gmt":"2026-07-02T11:21:12","slug":"%e5%8d%8e%e5%8c%97%e7%94%b5%e5%8a%9b%e5%a4%a7%e5%ad%a6%e5%90%95%e7%8e%ae-%e5%be%90%e8%b6%85%e4%b8%9c%e5%8d%8e%e5%a4%a7%e5%ad%a6%e4%b9%94%e9%94%a6%e4%b8%bdccr%ef%bc%9a%e6%b0%b4%e7%b3%bb%e9%94%8c","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=272376","title":{"rendered":"\u534e\u5317\u7535\u529b\u5927\u5b66\u5415\u73ae\/\u5f90\u8d85&\u4e1c\u534e\u5927\u5b66\u4e54\u9526\u4e3dCCR\uff1a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7814\u7a76\u8fdb\u9636\u2014\u2014\u5148\u8fdb\u6750\u6599\u8bbe\u8ba1\u4e0e\u539f\u4f4d\u8868\u5f81\u7406\u8bba"},"content":{"rendered":"\n
\"\"<\/figure>\n\n\n\n

\u7814\u7a76\u80cc\u666f:<\/strong><\/strong><\/p>\n\n\n\n

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\"\"<\/figure>\n\n\n\n

Graphical Abstract<\/strong><\/strong><\/p>\n\n\n\n

\u6210\u679c\u7b80\u4ecb\uff1a<\/strong><\/strong><\/p>\n\n\n\n

\u534e\u5317\u7535\u529b\u5927\u5b66\u5415\u73ae\/\u5f90\u8d85\u8054\u5408\u4e1c\u534e\u5927\u5b66\u4e54\u9526\u4e3d<\/strong>\u5728\u56fd\u9645\u9876\u5c16\u671f\u520a Coordination Chemistry Reviews<\/em> \u53d1\u8868\u4e86\u9898\u4e3a\u201cFunctional Mechanisms of Aqueous Zinc-Ion Batteries: Advanced Materials, In-Situ<\/em> Characterizations and Theoretic Understanding\u201d\u7684\u7efc\u8ff0\u6587\u7ae0\u3002\u8be5\u7efc\u8ff0\u9996\u5148\u5168\u9762\u68b3\u7406\u4e86\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08AZIBs\uff09\u7684\u6838\u5fc3\u7ec4\u4ef6\uff08\u6b63\u6781\u3001\u8d1f\u6781\u3001\u7535\u89e3\u8d28\u53ca\u9694\u819c\uff09\u7684\u6700\u65b0\u8bbe\u8ba1\u7b56\u7565\u4e0e\u5148\u8fdb\u6750\u6599\u7814\u7a76\u8fdb\u5c55\u3002\u968f\u540e\uff0c\u6587\u7ae0\u7cfb\u7edf\u9610\u8ff0\u4e86\u591a\u79cd\u524d\u6cbf\u539f\u4f4d\u8868\u5f81\u6280\u672f\uff0c\u5982\u539f\u4f4d\u5149\u5b66\u663e\u5fae\u955c\u3001\u539f\u4f4dX\u5c04\u7ebf\u884d\u5c04(XRD)\u3001\u539f\u4f4d\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916\u5149\u8c31(FTIR)\u3001\u539f\u4f4d\u62c9\u66fc\u5149\u8c31(Raman)\u7b49\uff09\u7684\u7406\u8bba\u57fa\u7840\u3001\u6280\u672f\u4f18\u52bf\u53ca\u5176\u5728\u63ed\u793aAZIBs\u5e95\u5c42\u52a8\u6001\u53cd\u5e94\u673a\u5236\uff08\u5982\u79bb\u5b50\u63d2\u5c42\u884c\u4e3a\u3001\u679d\u6676\u751f\u957f\u548c\u754c\u9762\u6f14\u5316\uff09\u4e2d\u7684\u5173\u952e\u6838\u5fc3\u4f5c\u7528\u3002\u6700\u540e\uff0c\u6587\u7ae0\u524d\u77bb\u6027\u5730\u603b\u7ed3\u4e86\u5f53\u524dAZIBs\u6838\u5fc3\u6750\u6599\u4e0e\u539f\u4f4d\u8868\u5f81\u65b9\u6cd5\u6240\u9762\u4e34\u7684\u5171\u6027\u6311\u6218\uff0c\u5e76\u4ece\u8de8\u5b66\u79d1\u89c6\u89d2\u4e3a\u63a8\u52a8\u6750\u6599\u4f18\u5316\u3001\u673a\u5236\u89e3\u6790\u3001\u5668\u4ef6\u96c6\u6210\u548c\u672a\u6765\u7684\u5b9e\u9645\u5de5\u7a0b\u5316\u5e94\u7528\u6784\u5efa\u4e86\u6e05\u6670\u7684\u8def\u7ebf\u56fe\u3002\u672c\u7efc\u8ff0\u65e8\u5728\u52a0\u6df1\u5bf9\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u591a\u5c3a\u5ea6\u5de5\u4f5c\u673a\u5236\u7684\u7406\u8bba\u7406\u89e3\uff0c\u4e3a\u6307\u5bfc\u4e0b\u4e00\u4ee3\u9ad8\u5b89\u5168\u3001\u9ad8\u529f\u7387\u3001\u957f\u5bff\u547d\u7684\u6c34\u7cfb\u50a8\u80fd\u7cfb\u7edf\u7684\u7814\u53d1\u63d0\u4f9b\u6709\u529b\u7684\u7406\u8bba\u4e0e\u6280\u672f\u652f\u6491\u3002<\/strong><\/p>\n\n\n\n

\u56fe\u6587\u89e3\u8bfb\uff1a<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1. <\/strong>\u539f\u4f4d\u6280\u672f\u5728AZIBs\u4e2d\u7684\u6838\u5fc3\u4f5c\u7528\u793a\u610f\u56fe\u3002<\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe2. <\/strong>(a) <\/strong>\u6240\u5236\u5907\u7684\u9634\u6781\u5fae\u89c2\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/strong>(b)<\/strong> Zn-\u5d4c\u5165 C@\u03b4-MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>-OV \u7684 MnO<\/strong>6<\/sub><\/strong><\/sub><\/strong> \u516b\u9762\u4f53\u7684\u8ba1\u7b97 Mn<\/strong>–<\/strong>O \u952e\u5408\u8ddd\u79bb\uff08\u5355\u4f4d\uff1a\u00c5\uff09\u3002<\/strong>(c) <\/strong>MN-0.5\u3001MN-1\u3001MN-2\u3001MN-3 \u548c MN-4 \u7684 4000 \u6b21\u5faa\u73af\u7a33\u5b9a\u6027<\/strong>\u3002(<\/strong>d<\/strong>)<\/strong> MnO<\/strong>x<\/sub><\/em><\/strong><\/sub><\/em><\/strong>\/Co<\/strong>3<\/sub><\/strong><\/sub><\/strong>O<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/strong>(e) <\/strong>M<\/strong>g<\/strong>x<\/sub><\/em><\/strong><\/sub><\/em><\/strong>MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7684HRTEM\u56fe\u50cf\u548c\u6676\u4f53\u7ed3\u6784\u6a21\u578b\u3002<\/strong>(<\/strong>f<\/strong>)<\/strong> p-CD<\/strong>s<\/strong>\u7684\u793a\u610f\u7ed3\u6784\u3002<\/strong>(<\/strong>g<\/strong>)<\/strong> 40\u2103<\/strong>\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/strong>\u3002<\/strong>(h) <\/strong>\u57280.1\u548c1 A g<\/strong>\u22121<\/sup><\/strong><\/sup><\/strong>\u4e0b<\/strong>\u7684\u957f\u5faa\u73af<\/strong>\u6027\u80fd\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe3. (a)<\/strong> Zn@CuCK \u7684\u7ed3\u6784\u53ca\u5176\u653e\u5927\u793a\u610f\u56fe\u3002<\/strong>(b) <\/strong>IDAN \u7684\u7535\u6fc0\u53d1\u548c\u6c34\u89e3\u793a\u610f\u56fe\u3002<\/strong>(c) <\/strong>\u4e0d\u540c\u8d1f\u6781\u5bf9\u79f0\u7535\u6c60\u5728 0.25 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u548c 0.25 mAh cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u4e0b\u7684\u957f\u671f\u6052\u7535\u6d41\u5faa\u73af\u6027\u80fd\u3002<\/strong>(d) <\/strong>\u88f8Cu||Zn\u975e\u5bf9\u79f0\u7535\u6c60\u548c BZC\/ZCZH\/SA@Cu||Zn \u975e\u5bf9\u79f0\u7535\u6c60\u7684\u6052\u7535\u6d41\u5145\u653e\u7535 (GCD) \u66f2\u7ebf\u3002<\/strong>(e) <\/strong>ZWO@Zn \u8d1f\u6781\u4e0a\u950c\u6c89\u79ef\u7684\u793a\u610f\u56fe\u3002<\/strong>(f) <\/strong>TEOS\/\u805a\u4e8c\u7532\u57fa\u7845\u6c27\u70f7 Zn (PDMS@Zn) \u8d1f\u6781\u7684\u5236\u5907\u548c\u529f\u80fd\u5316\u793a\u610f\u56fe\u3002<\/strong>(g) <\/strong>Zn||Zn \u5bf9\u79f0\u7535\u6c60\u5728 1 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u548c 1 mAh cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/strong>(h) <\/strong>\u5177\u6709\u5404\u79cd\u754c\u9762\u7684 Zn \u8d1f\u6781\u7684\u5bf9\u79f0\u7535\u6c60\u6027\u80fd\u3002\u4e09\u79cd\u6d3b\u6027\u57fa\u5e95\u7684 Zn||Zn \u5bf9\u79f0\u7535\u6c60\u5728 2 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u548c 1 mAh cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u4e0b\u7684\u6052\u7535\u6d41\u5faa\u73af\u66f2\u7ebf\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe4. <\/strong>(a) <\/strong>\u950c\u7535\u6781\u5728\u7535\u6c60\u9759\u7f6e\u671f\u95f4\u5f71\u54cd\u5176\u7a33\u5b9a\u6027\u7684\u95ee\u9898\u793a\u610f\u56fe\u3002<\/strong>(b) <\/strong>\u539f\u4f4d GPE\/Zn \u8d1f\u6781\u754c\u9762\u4e0a\u5f62\u6210\u7684\u68af\u5ea6 SEI \u5c42<\/strong>\u7684<\/strong>\u793a\u610f\u56fe<\/strong>\u3002(c) <\/strong>\u950c\u7535\u9540\/\u5265\u79bb\u7684 CE\u3002<\/strong>(d) <\/strong>\u950c||\u950c\u5bf9\u79f0\u7535\u6c60\u5728 1 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> <\/strong>\u548c 1 mAh cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> <\/strong>\u4e0b\u7684\u957f\u671f\u6052\u7535\u6d41\u5faa\u73af\u6027\u80fd\u3002<\/strong>(e) <\/strong>\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\uff0c\u950c\u91d1\u5c5e\u8fd1\u8868\u9762\u5728 ZS-H \u548c Val-H \u4e2d\u7684\u5316\u5b66\u7ec4\u5206\u5206\u5e03\u7684\u4fa7\u89c6\u56fe\u548c\u524d\u89c6\u56fe\u3002<\/strong>(f) <\/strong>\u6d77\u85fb\u7cd6\u6539\u6027 PAM \u6c34\u51dd\u80f6\u7535\u89e3\u8d28\u5728\u67d4\u6027 AZIBs \u4e2d\u7684\u950c\u6c89\u79ef\u548c\u754c\u9762\u5316\u5b66<\/strong>\u7684<\/strong>\u793a\u610f\u56fe\u3002<\/strong>(g) <\/strong>2-\u5f02\u4e19\u9187\u590d\u5408\u7535\u89e3\u8d28\u5728 -20 \u00b0C \u4e0b\u7684<\/strong> <\/strong>Zn||V<\/strong>2<\/sub><\/strong><\/sub><\/strong>O<\/strong>5<\/sub><\/strong><\/sub><\/strong> <\/strong>\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe5. <\/strong>(a) <\/strong>\u63d0\u51fa\u7684\u7528\u4e8e\u7535\u89e3\u8d28\u4e0e PP-g-AA \u754c\u9762\u4e0a\u9009\u62e9\u6027 Zn<\/strong>2+<\/sup><\/strong><\/sup><\/strong> \u79bb\u5b50\u4f20\u8f93\u7684\u673a\u7406\u793a\u610f\u56fe\u3002<\/strong>(b) <\/strong>\u8f6f\u5305\u7535\u6c60\u793a\u610f\u56fe\u3002<\/strong>(c) <\/strong>\u8f6f\u5305 Zn||ZVO \u7535\u6c60\u5728 150 mA g<\/strong>\u22121<\/sup><\/strong><\/sup><\/strong>\u6b63\u6781\u548c 25\u00b0C \u4e0b\u7684\u957f\u671f\u5faa\u73af\u6027\u80fd\u3002<\/strong>(d) <\/strong>\u4f7f\u7528 GF \u6216 GF\/27%PTIB \u9694\u819c\u7684<\/strong> <\/strong>Zn||MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong> <\/strong>\u7535\u6c60\u5728 1 A g<\/strong>\u22121<\/sup><\/strong><\/sup><\/strong>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/strong>(e) <\/strong>\u5728\u6539\u6027\u9694\u819c\u4f5c\u7528\u4e0b\u5b9e\u73b0\u65e0\u679d\u6676\u950c\u6c89\u79ef\u7684\u673a\u7406\u793a\u610f\u56fe\u3002<\/strong>(f) <\/strong>\u4f7f\u7528 GF \u6216 GF\/27%PTIB \u4f5c\u4e3a\u9694\u819c\u65f6\uff0c\u950c\u7535\u6781\u8868\u9762\u950c\u6c89\u79ef\u884c\u4e3a\u7684\u793a\u610f\u56fe\u3002<\/strong>(g) <\/strong>\u7528\u4e8e\u7a33\u5b9a\u6b63\u6781\u548c\u950c\u8d1f\u6781\u7684\u53cc\u529f\u80fd MCM-41 \u6cb8\u77f3\u586b\u5145\u9694\u819c (MZS) \u9694\u819c<\/strong>\u7684<\/strong>\u793a\u610f\u56fe\u3002<\/strong>(h) <\/strong>\u5177\u6709 9.78 mg cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong>\u9ad8\u8d28\u91cf\u8d1f\u8f7d\u7684<\/strong> <\/strong>Zn||V<\/strong>2<\/sub><\/strong><\/sub><\/strong>O<\/strong>5<\/sub><\/strong><\/sub><\/strong> <\/strong>\u5168\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd<\/strong>\u3002(i) <\/strong>\u5728 5 A g<\/strong>\u22121<\/sup><\/strong><\/sup><\/strong> <\/sup><\/strong><\/sup><\/strong>\u4e0b\uff0c\u5177\u6709\u8f7b\u5ea6\u65e0\u5e8f\u518d\u751f\u7ea4\u7ef4\u7d20\u9694\u819c (LDCS) \u548c\u9ad8\u5ea6\u65e0\u5e8f\u7ea4\u7ef4\u7d20\u9694\u819c (HDCS) \u7684<\/strong> <\/strong>Zn||I<\/strong>2<\/sub><\/strong><\/sub><\/strong> <\/strong>\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/strong>\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe6. <\/strong>\u8bf4\u660e AZIBs \u4e2d\u539f\u4f4d\u8868\u5f81\u57fa\u672c\u539f\u7406\u7684\u793a\u610f\u56fe\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe7. <\/strong>(a) <\/strong>\u900f\u660e\u7535\u5316\u5b66\u7535\u6c60\uff0c\u7528\u4e8e\u4ece\u6a2a\u622a\u9762\u89c6\u56fe\u8fdb\u884c\u539f\u4f4d\u5149\u5b66\u6210\u50cf\u3002<\/strong>(b) <\/strong>\u7528\u4e8e\u4ece\u4fef\u89c6\u89d2\u5ea6\u8fdb\u884c\u539f\u4f4d\u5149\u5b66\u6210\u50cf\u7684\u5149\u5b66\u53cd\u5c04\u6d4b\u91cf\u88c5\u7f6e\u3002<\/strong>(c) <\/strong>\u5728\u88f8\u9732\u7684 Zn \u548c COP@Zn \u7535\u6781\u4e0a\uff0c\u4ee5 5 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u7684\u7535\u6d41\u5bc6\u5ea6\u8fdb\u884c Zn \u6c89\u79ef\u7684\u539f\u4f4d OM \u89c2\u5bdf\u3002<\/strong>(d) <\/strong>\u7528\u4e8e\u539f\u4f4d Zn \u679d\u6676\u89c2\u5bdf\u7684\u5149\u5b66 Cu||Zn \u7535\u6c60\u88c5\u7f6e\uff1a\u4f7f\u7528\u542b\u6709 Cu \u9634\u6781\u548c Zn \u9633\u6781\u7684\u53cc\u7535\u6781\u7cfb\u7edf\uff0c\u5e76\u5e26\u6709\u7528\u4e8e Zn \u6c89\u79ef\/\u5265\u79bb\u89c2\u5bdf\u7684\u73bb\u7483\u7a97\u3002<\/strong>(e) <\/strong>Zn \u5728 ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong> \u548c MPS05 \u7535\u89e3\u6db2\u4e2d\u7684\u6c89\u79ef\u8fc7\u7a0b\u3002<\/strong>(f) <\/strong>\u5728 3 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5728\u4e0d\u540c\u65f6\u95f4\u8bb0\u5f55\u7684 Zn \u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u7684\u539f\u4f4d\u5149\u5b66\u53ef\u89c6\u5316\u89c2\u5bdf\u3002<\/strong>(g) <\/strong>\u539f\u4f4d\u7535\u5316\u5b66 OM \u88c5\u7f6e\u7684\u7ed3\u6784\u3002<\/strong>(h) <\/strong>\u5728\u5265\u79bb 2\u30015 \u548c 10 mAh cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u540e\uff0cPCu@Zn \u7535\u6781\u5728 3.0 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6a2a\u622a\u9762\u539f\u4f4d OM \u7167\u7247<\/strong>\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe8. <\/strong>(a) \u5206\u6790\u950c\u7535\u9540\/\u5265\u79bb\u8fc7\u7a0b\u4e2d\u7684\u52a8\u529b\u5b66\u8fc7\u7a0b\u5e76\u5e94\u5bf9<\/strong> Zn<\/strong>||<\/strong>Zn <\/strong>\u7535\u6c60\u7684\u5173\u952e\u6311\u6218\u3002<\/strong>(b) <\/strong>DP-0 \u548c DP-0.1 \u7535\u89e3\u8d28\u5728\u524d 20 \u4e2a\u5faa\u73af\u4e2d\u950c||\u950c\u5bf9\u79f0\u7535\u6c60\u7684\u539f\u4f4d DRT \u56fe\u3002<\/strong>(c) <\/strong>DP \u6dfb\u52a0\u5242\u5bf9\u672c\u4f53\u7535\u89e3\u8d28\u548c\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u7684\u5f71\u54cd\u673a\u7406\u3002<\/strong>(d) <\/strong>1 mA cm<\/strong>\u22122<\/sup><\/strong><\/sup><\/strong> \u4e0b<\/strong> Zn<\/strong>||<\/strong>Zn <\/strong>\u5bf9\u79f0\u7535\u6c60\u7684\u539f\u4f4d EIS \u793a\u610f\u56fe<\/strong>\u3002(e) <\/strong>\u4f7f\u7528 0.3 NE \u7535\u89e3\u8d28\u548c\u7eaf<\/strong> <\/strong>ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u8d28\u5728\u4e0d\u540c\u7535\u9540\/\u5265\u79bb\u5faa\u73af\u671f\u95f4\u7684<\/strong>Zn<\/strong>||<\/strong>Zn<\/strong>\u5bf9\u79f0\u7535\u6c60\u7684\u539f\u4f4d EIS\u3002<\/strong>(f) <\/strong>Rct<\/strong> <\/strong>\u503c\u4e0e\u7b2c 1 \u4e2a\u548c\u7b2c 5000 \u4e2a\u5faa\u73af\u4e2dV<\/strong>2<\/sub><\/strong><\/sub><\/strong>O<\/strong>5<\/sub><\/strong><\/sub><\/strong>\u00b70.48H<\/strong>2<\/sub><\/strong><\/sub><\/strong>O<\/strong> <\/strong>\u548c VNACOF \u7684\u76f8\u5e94\u539f\u4f4d DRT \u7684\u6bd4\u8f83\u3002<\/strong>(g) <\/strong>\u539f\u4f4d\u77ff\u5316\u7b56\u7565\u7684\u673a\u7406\u56fe\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe9. <\/strong>(a) <\/strong>\u9633\u79bb\u5b50-\u9634\u79bb\u5b50\u534f\u540c\u63ba\u6742\u793a\u610f\u56fe\u3002<\/strong>(b) <\/strong>\u7535\u6c60\u539f\u4f4dXRD\u7684\u53cd\u5c04\u6a21\u5f0f\u548c\u900f\u5c04\u6a21\u5f0f\u5178\u578b\u88c5\u7f6e\u3002<\/strong>(c) <\/strong>CNF\u4ecb\u5bfc\u7684\u6df7\u5408\u8584\u819c\u7a33\u5b9aAZIBs\u7684\u673a\u7406\u3002<\/strong>(d) <\/strong>3D HAVO-MMo6<\/strong>\u7684\u5408\u6210\u3002(e) <\/strong>Zn-Mg<\/strong>x<\/sub><\/em><\/strong><\/sub><\/em><\/strong>MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684\u7535\u8377\u5b58\u50a8\u673a\u7406\u793a\u610f\u56fe\u3002<\/strong>(f) <\/strong>HAVO-FeMo<\/strong>6<\/sub><\/strong><\/sub><\/strong>-50\u7684\u539f\u4f4dXRD\u8868\u5f81<\/strong>\u3002(g) <\/strong>Zn\u6d78\u6ce124\u5c0f\u65f6\u7684\u539f\u4f4dXRD\u6d4b\u8bd5\u3002<\/strong>(h) <\/strong>TS(001)\u548cTS(011)\u7684\u521d\u59cb\u653e\/\u5145\u7535GCD\u66f2\u7ebf\u548c\u539f\u4f4dXRD\u56fe\u8c31\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe10. <\/strong>(a) H<\/strong>+<\/sup><\/strong><\/sup><\/strong>\u901a\u8fc7<\/strong>Grotthuss \u673a\u5236\u77ed\u6682\u6269\u6563\u5e76\u5438\u9644\u5728 Zn \u7535\u6781\u4e0a\uff0c\u5bfc\u81f4\u4e0d\u53ef\u63a7\u7684 HER\uff08\u5de6\uff09\u3002\u754c\u9762\u7a7a\u95f4\u7535\u8377\u5c42\u548c\u9634\u79bb\u5b50\u8017\u5c3d\u5bfc\u81f4 Zn \u679d\u6676\u751f\u957f\uff08\u53f3\uff09\u3002<\/strong>(b) <\/strong>\u7528\u4e8e\u539f\u4f4d FTIR \u6d4b\u91cf\u548c\u901a\u8fc7\u6052\u7535\u4f4d\u6cd5\u6d4b\u8bd5\u7684\u76f8\u5e94\u79bb\u5b50\u6d53\u5ea6\u5206\u5e03\u7684\u7535\u5316\u5b66\u7535\u6c60\u3002<\/strong>(c) <\/strong>\u6709\u673a\u6b63\u6781\u5728\u4e00\u4e2a\u653e\u7535\/\u5145\u7535\u5faa\u73af\u4e2d\u7684\u539f\u4f4d ATR-FTIR \u5206\u6790\u548c\u539f\u4f4d ATR-FTIR \u5149\u8c31\u3002(\u7ebf\u989c\u8272\u4ece\u84dd\u8272\u53d8\u4e3a\u7ea2\u8272\u8868\u793a\u6709\u673a\u6b63\u6781\u4ece\u653e\u7535\u72b6\u6001\u5230\u5145\u7535\u72b6\u6001\u7684\u8f6c\u53d8)<\/strong>\u3002(d) <\/strong>MPS00 \u7535\u89e3\u6db2\u4e2d\u4e0d\u540c\u6c89\u79ef\u9636\u6bb5 Zn \u7b94\u8868\u9762\u7684\u539f\u4f4d FTIR \u5149\u8c31\u3002<\/strong>(e) <\/strong>\u5728\u57fa\u4e8e\u88f8 Zn \u548c COP@Zn \u7535\u6781\u7684 Zn||Zn \u5bf9\u79f0\u7535\u6c60\u4e2d\u8fdb\u884c Zn \u7535\u9540\u671f\u95f4\u6536\u96c6\u7684 FTIR \u5149\u8c31\u3002<\/strong>(f) <\/strong>NE \u7535\u89e3\u6db2\u4e2d Zn<\/strong>2+<\/sup><\/strong><\/sup><\/strong> \u79bb\u5b50\u6eb6\u5242\u5316\u7ed3\u6784\u548c Zn \u6c89\u79ef\u884c\u4e3a\u7684\u793a\u610f\u56fe\u3002<\/strong>(g) <\/strong>Zn \u7535\u6781\u5728\u7535\u89e3\u6db2\u4e2d\u6d78\u6ce1 12 \u5c0f\u65f6\u540e\u7684\u539f\u4f4d FTIR<\/strong> \u70ed\u6210\u50cf<\/strong>\u56fe\u50cf\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe11. <\/strong>(a) <\/strong>DMeNQ\u7535\u6781\u5728\u4e0d\u540c\u7535\u5316\u5b66\u72b6\u6001\u4e0b\u7684\u539f\u4f4d\u62c9\u66fc\u6d4b\u8bd5\u793a\u610f\u56fe\u53ca\u76f8\u5e94\u7684\u5149\u8c31\u3002<\/strong>(b) <\/strong>\u4f7f\u75283 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong> <\/strong>\u548c3-7 CNF\u7535\u89e3\u6db2\u7684<\/strong> <\/strong>Zn||SS<\/strong> <\/strong>\u4e0d\u5bf9\u79f0\u7535\u6c60\u7684\u539f\u4f4d\u62c9\u66fc\u56fe\u8c31\u3002<\/strong>(c) <\/strong>\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u7684\u88c5\u7f6e\u793a\u610f\u56fe\u3002<\/strong>(d) <\/strong>\u57285 mA cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong> <\/strong>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u57fa\u4e8e1 M Zn(OTf)<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u53ca\u6dfb\u52a01 wt% PS\u7684\u7535\u89e3\u6db2\u4e2d\u950c\u6c89\u79ef\u8fc7\u7a0b\u6301\u7eed60\u5206\u949f\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/strong>(e) <\/strong>MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>@CNT\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u81a8\u80c0\u3002<\/strong>(f) <\/strong>Mg<\/strong>x<\/sub><\/em><\/strong><\/sub><\/em><\/strong>MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7eb3\u7c73\u7ebf\u7684\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong>2<\/strong>. (a)<\/strong> <\/strong>\u542b\u73af\u70ef\u7684ZS\u7535\u89e3\u6db2\u4e2dZn\u7535\u6781\u7684\u673a\u7406\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u5728\u542b\u73af\u70ef\u7684ZS\u7535\u89e3\u6db2\u4e2d\u950c\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u7684\u539f\u4f4dpH\u66f2\u7ebf\u3002<\/strong>(b) <\/strong>\u4e09\u7f9f\u7532\u57fa\u7518\u6c28\u9178\u4ecb\u5bfc\u7684AZIBs\u754c\u9762\u950c\u6c89\u79ef\u8fc7\u7a0b\uff0c\u4ee5\u53caTEOS\/PDMS@Zn\u5bf9\u79f0\u7535\u6c60\u57285 mA cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u30011.25 mAh cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u6761\u4ef6\u4e0b\u5faa\u73af\u65f6\u7684\u539f\u4f4dpH\u76d1\u6d4b\u3002<\/strong>(c) <\/strong>2.5% Sr-MnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7535\u6781\u5728\u5145\u653e\u7535\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u539f\u4f4dpH\u76d1\u6d4b\u53capH\u53d8\u5316\u3002<\/strong>(d) <\/strong>\u4eb2\u950c\u758f\u6c34\u4fdd\u62a4\u5c42\u5728\u6291\u5236\u6790\u6c22\u53cd\u5e94\u548c\u526f\u53cd\u5e94\u4e2d\u7684\u4f5c\u7528\uff0c\u4ee5\u53caTEOS\/PDMS@Zn\u5bf9\u79f0\u7535\u6c60\u57285 mA cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u30011.25 mAh cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u6761\u4ef6\u4e0b\u5faa\u73af\u65f6\u7684\u539f\u4f4dpH\u76d1\u6d4b\u3002<\/strong>(e) <\/strong>\u57282 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u548c2 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong> + 0.05 M SG\u7535\u89e3\u6db2\u4e2d\uff0cZn||Zn\u7535\u6c60\u5185\u5bf9\u7535\u6781\u4e0a\u7684\u539f\u4f4dpH\u6d4b\u8bd5\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong>3<\/strong>. <\/strong>(a) <\/strong>PS\u5206\u5b50\u5bf91 M Zn(OTf<\/strong>)<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u53ca\u542b1 wt% PS\u7684\u7535\u89e3\u6db2\u4e2d\u7535\u89e3\u8d28\u4e0e\u754c\u9762\u5316\u5b66\u7684\u5f71\u54cd\uff0c\u4ee5\u53ca\u572810 mV <\/strong>s<\/strong>-1<\/sup><\/strong><\/sup><\/strong>\u626b\u63cf\u901f\u7387\u4e0b\u57fa\u4e8eEQCM\u5728\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u6d4b\u5f97\u7684\u8ba1\u65f6\u5e93\u4ed1\u66f2\u7ebf\u548c\u8d28\u91cf\u53d8\u5316\u3002<\/strong>(b) <\/strong>TS(001)\u548cTS(011)\u5728\u653e\u7535\uff08\u79bb\u5b50\u5d4c\u5165\uff09\u8fc7\u7a0b\u4e2d\u7535\u6781\u8d28\u91cf\u53d8\u5316\u4e0e\u7535\u8377\u7684\u5173\u7cfb\u3002<\/strong>(c) <\/strong>TiS<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u8d1f\u6781TS(011)\u7684\u6676\u9762\u4f9d\u8d56\u6027\u7535\u8377\u5b58\u50a8\u673a\u5236\u3002<\/strong>(d) <\/strong>NMI\u6dfb\u52a0\u5242\u63d0\u9ad8Zn\u7535\u6781\u53ef\u9006\u6027\u7684\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u57280.2 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u4e2d\u8fdb\u884c\u7684\u76f8\u5e94EQCM\u6d4b\u8bd5\u3002<\/strong>(e) <\/strong>\u901a\u8fc7\u542b\u73af\u70ef\u6dfb\u52a0\u5242\u539f\u4f4d\u76d1\u6d4b\u754c\u9762\u950c\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u3002\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u4ea4\u66ff\u7535\u4f4d\u4e0b\u7684EQCM\u54cd\u5e94\uff08fp\uff09\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong>4<\/strong>. <\/strong>(a) <\/strong>\u901a\u8fc7\u4f4eAPI\u542b\u91cf\u7684Zn(HBS)<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u6291\u5236\u8150\u8680\u4ee5\u5b9e\u73b0\u7a33\u5b9a\u5feb\u901f\u7684\u950c\u91d1\u5c5e\u7535\u6781\uff0c\u4ee5\u53ca\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u6db2\u65f6\u950c\u6c89\u79ef\/\u5265\u79bb\u8fc7\u7a0b\u4e2d\u6c22\u6c14\u91ca\u653e\u7684\u539f\u4f4dDEMS\u6d4b\u8bd5\u3002<\/strong>(b) <\/strong>\u539f\u4f4dDEMS\u6d4b\u91cf\u793a\u610f\u56fe\u53ca\u6d4b\u91cf\u8fc7\u7a0b\u4e2d\u7684\u6c22\u6c14\u91ca\u653e\uff0c\u4ee5\u53ca\u57283 mA cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u4e0b\u7684\u76f8\u5e94\u7535\u538b\u66f2\u7ebf\u3002<\/strong>(c) <\/strong>\u4f7f\u7528GF\u9694\u819c\u548cPP-g-AA\u9694\u819c\u7684Zn||Zn\u7535\u6c60\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u950c\u5265\u79bb\/\u6c89\u79ef\u66f2\u7ebf\u53ca\u76f8\u5e94\u7684\u539f\u4f4dDEMS\u66f2\u7ebf\uff0c\u7528\u4e8e\u8bc4\u4f30\u6c22\u6c14\u91ca\u653e\uff0c\u5e76\u5c55\u793a\u5faa\u73af\u8fc7\u7a0b\u4e2d\u91ca\u653e\u7684\u6c22\u6c14\u91cf\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong>5<\/strong>. (a)<\/strong> <\/strong>\u539f\u4f4d\u7535\u5316\u5b66\u539f\u5b50\u529b\u663e\u5fae\u955c\u88c5\u7f6e\u793a\u610f\u56fe\u3002<\/strong>(b) <\/strong>\u626b\u63cf\u7535\u5316\u5b66\u663e\u5fae\u955c\u8d1f\u53cd\u9988\u4e0e\u6b63\u53cd\u9988\u6a21\u5f0f\u793a\u610f\u56fe\uff0c\u4ee5\u53ca\u5c55\u793aFre-Zn\u7247\u6c34\u5e73\u4e0e\u5782\u76f4\u751f\u957f\u7684\u76f8\u5e94\u626b\u63cf\u7535\u955c\u56fe\u50cf\u3002<\/strong>(c) <\/strong>\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u57281 M Na<\/strong>2<\/sub><\/strong><\/sub><\/strong>SO<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u4e2d\u7684\u539f\u4f4dX\u5c04\u7ebf\u8fd1\u8fb9\u5438\u6536\u8c31\u7ed3\u679c\uff1aNaCuHCF\u7684Cu K\u8fb9XANES\u8c31<\/strong>\u3002(d) <\/strong>\u7528\u4e8e\u5728\u5faa\u73af\u4f0f\u5b89\u6216\u6052\u6d41\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u63a2\u6d4bAu\u96c6\u6d41\u4f53\u4e0aMnO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u8f6c\u5316\u53cd\u5e94\u7684\u5de5\u51b5\u5149\u5b66\u53cd\u5c04\u6d4b\u91cf\u88c5\u7f6e\u793a\u610f\u56fe\u3002<\/strong>(e) <\/strong>\u7528\u4e8e\u663e\u5fae\u6210\u50cf\u7684\u539f\u4f4d\u4e09\u7ef4\u663e\u5fae\u955c\u3002<\/strong>(f) <\/strong>\u7535\u6c60\u8fd0\u884c\u8fc7\u7a0b\u4e2d\u7684\u950c\u53ef\u9006\u6027\u7814\u7a76\u3002\u5728\u542bO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u548c\u4e0d\u542bO<\/strong>2<\/sub><\/strong><\/sub><\/strong>\u76842 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong>\u7535\u89e3\u6db2\u4e2d\uff0c\u7528\u4e8e\u8bc4\u4f30\u6790\u6c22\u7684\u950c\u5265\u79bb\/\u6c89\u79ef\u66f2\u7ebf\u53ca\u76f8\u5e94\u7684\u539f\u4f4d\u6c14\u76f8\u8272\u8c31\u66f2\u7ebf\u3002<\/strong>(g) <\/strong>\u5728ID-LHCE\u7535\u89e3\u6db2\u4e2d\uff0c2 mA cm<\/strong>-2<\/sup><\/strong><\/sup><\/strong>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u4e0d\u540c\u5265\u79bb\/\u6c89\u79ef\u65f6\u95f4\u4e0bZn||Zn\u7535\u6c60\u7684\u539f\u4f4d\u7535\u5316\u5b66\u81a8\u80c0\u9ad8\u5ea6\u3002<\/strong>(h) <\/strong>\u4f7f\u75282 M ZnSO<\/strong>4<\/sub><\/strong><\/sub><\/strong>+TXE\u7535\u89e3\u6db2\u7684Zn||Cu\u7535\u6c60\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0cCu\u8868\u9762\u539f\u4f4d\u5c0f\u89d2X\u5c04\u7ebf\u6563\u5c04\u8c31\u7684\u7b49\u9ad8\u7ebf\u56fe\u3002<\/strong><\/strong><\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u56fe1<\/strong>6. <\/strong>AZIBs\u4e2d\u53d1\u5c55\u539f\u4f4d\u65b9\u6cd5\u7684\u6311\u6218\u4e0e\u524d\u666f<\/strong>\u3002<\/strong><\/strong><\/p>\n\n\n\n

\u6587\u732e\u94fe\u63a5\uff1ahttps:\/\/doi.org\/10.1016\/j.ccr.2026.218262<\/p>\n","protected":false},"excerpt":{"rendered":"

\u7814\u7a76\u80cc\u666f: \u968f\u7740\u5168\u7403\u5411\u53ef\u6301\u7eed\u6e05\u6d01\u80fd\u6e90\u8f6c\u578b\uff0c\u7535\u7f51\u7ea7\u50a8\u80fd\u6280\u672f\u7684\u9700\u6c42\u65e5\u76ca\u589e\u957f\u3002\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08AZIBs\uff09\u51ed\u501f\u5176\u672c\u5f81\u9ad8\u5b89\u5168\u6027\u3001\u6210\u672c\u4f4e\u5ec9\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7b49\u663e\u8457\u4f18\u52bf\uff0c\u88ab\u8ba4\u4e3a\u662f…<\/p>\n","protected":false},"author":31345,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-272376","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272376"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/31345"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=272376"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272376\/revisions"}],"predecessor-version":[{"id":272415,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/272376\/revisions\/272415"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=272376"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=272376"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=272376"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}