{"id":272962,"date":"2026-08-29T08:28:00","date_gmt":"2026-08-29T00:28:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=272962"},"modified":"2026-08-28T22:34:04","modified_gmt":"2026-08-28T14:34:04","slug":"%e5%85%89%e7%83%ad%e5%82%ac%e5%8c%96%e4%b8%ad%ef%bc%8c%e4%bb%80%e4%b9%88%e6%b8%a9%e5%ba%a6%e7%9c%9f%e6%ad%a3%e5%86%b3%e5%ae%9a%e5%82%ac%e5%8c%96%e6%80%a7%e8%83%bd%ef%bc%9f-%e6%b4%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=272962","title":{"rendered":"\u5149\u70ed\u50ac\u5316\u4e2d\uff0c\u4ec0\u4e48\u6e29\u5ea6\u771f\u6b63\u51b3\u5b9a\u50ac\u5316\u6027\u80fd\uff1f\u2014\u2014\u6d3b\u6027\u4f4d\u70b9\u5149\u70ed\u80fd\u91cf\u5229\u7528\u7684\u65b0\u8ba4\u8bc6"},"content":{"rendered":"\n<p><strong>\u8bba\u6587\u4fe1\u606f<\/strong><strong><\/strong><\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"344\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/08\/2382c315a6ba396-18.png\" alt=\"\" class=\"wp-image-272963\"\/><\/figure>\n\n\n\n<p><strong>\u7814\u7a76\u80cc\u666f<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u5149\u70ed\u50ac\u5316\u901a\u8fc7\u5149\u70ed\u8f6c\u6362\u76f4\u63a5\u4e3a\u5316\u5b66\u53cd\u5e94\u63d0\u4f9b\u70ed\u80fd\uff0c\u5728\u964d\u4f4e\u4f20\u7edf\u70ed\u50ac\u5316\u80fd\u8017\u3001\u63a8\u52a8\u53ef\u6301\u7eed\u5316\u5b66\u8f6c\u5316\u65b9\u9762\u5c55\u73b0\u51fa\u91cd\u8981\u6f5c\u529b\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u8005\u9010\u6e10\u8ba4\u8bc6\u5230\u5c40\u90e8\u52a0\u70ed\u6548\u5e94\u7684\u91cd\u8981\u6027\uff0c\u5e76\u5f00\u59cb\u5173\u6ce8\u6574\u4f53\u6e29\u5ea6\u4e4b\u5916\u7684\u5c40\u57df\u70ed\u884c\u4e3a\u3002\u7136\u800c\uff0c\u4e00\u4e2a\u66f4\u4e3a\u6839\u672c\u7684\u95ee\u9898\u4ecd\u672a\u5f97\u5230\u5145\u5206\u56de\u7b54\uff1a\u5728\u7a7a\u95f4\u975e\u5747\u4e00\u7684\u5149\u70ed\u50ac\u5316\u4f53\u7cfb\u4e2d\uff0c\u54ea\u4e2a\u5c3a\u5ea6\u7684\u6e29\u5ea6\u771f\u6b63\u51b3\u5b9a\u50ac\u5316\u884c\u4e3a\uff1f \u5316\u5b66\u53cd\u5e94\u6700\u7ec8\u53d1\u751f\u4e8e\u6d3b\u6027\u4f4d\u70b9\uff0c\u56e0\u6b64\uff0c\u76f8\u8fd1\u7684\u5b8f\u89c2\u6e29\u5ea6\u5e76\u4e0d\u610f\u5473\u7740\u6d3b\u6027\u4f4d\u70b9\u5177\u6709\u76f8\u540c\u7684\u80fd\u91cf\u72b6\u6001\u3002\u5398\u6e05\u5149\u70ed\u8f6c\u5316\u3001\u80fd\u91cf\u4f20\u9012\u3001\u6d3b\u6027\u4f4d\u70b9\u6709\u6548\u6e29\u5ea6\u4e0e\u50ac\u5316\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\uff0c\u662f\u7406\u89e3\u5149\u70ed\u50ac\u5316\u8fc7\u7a0b\u7684\u5173\u952e\u79d1\u5b66\u95ee\u9898\u3002<\/p>\n\n\n\n<p><strong>\u6587\u7ae0\u6982\u8ff0<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u56f4\u7ed5\u8fd9\u4e00\u95ee\u9898\uff0c\u4f5c\u8005\u6784\u5efa\u4e86Pd\u2013CNG\u548cPdPOM\u2013CNG\u4e24\u79cd\u5355\u539f\u5b50\u5149\u70ed\u50ac\u5316\u4f53\u7cfb\u3002\u901a\u8fc7\u63a7\u5236Pd\u542b\u91cf\u3001\u7535\u5b50\u6027\u8d28\u3001\u5b54\u7ed3\u6784\u53ca\u5b8f\u89c2\u5149\u70ed\u54cd\u5e94\u7b49\u5173\u952e\u53c2\u6570\uff0c\u5c06\u4e3b\u8981\u53d8\u91cf\u805a\u7126\u4e8ePd\u6d3b\u6027\u4f4d\u70b9\u4e0e\u5149\u70ed\u57fa\u5e95\u7684\u7a7a\u95f4\u8026\u5408\u65b9\u5f0f\uff1a\u524d\u8005\u76f4\u63a5\u8026\u5408\uff0c\u540e\u8005\u901a\u8fc7POM\u5f15\u5165\u989d\u5916\u7684\u80fd\u91cf\u4f20\u9012\u754c\u9762\uff0c\u4ece\u800c\u5efa\u7acb\u5177\u6709\u4e0d\u540c\u80fd\u91cf\u4f20\u9012\u8def\u5f84\u7684\u6a21\u578b\u4f53\u7cfb\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"376\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/08\/ce6e2814f207c93-17.png\" alt=\"\" class=\"wp-image-272964\"\/><\/figure>\n\n\n\n<p><strong>\u56fe 1. <\/strong><strong>\u6a21\u578b\u4f53\u7cfb\u8bbe\u8ba1\uff1a<\/strong><strong>Pd\u2013CNG \u548c PdPOM\u2013CNG \u7684\u7ed3\u6784\u6a21\u578b\u3002T \u548c PT \u5206\u522b\u4ee3\u8868\u70ed\u50ac\u5316\u548c\u5149\u70ed\u50ac\u5316\u6761\u4ef6\u3002<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u8fd9\u4e00\u6a21\u578b\u4f53\u7cfb\u5448\u73b0\u51fa\u53cd\u5e38\u7684\u50ac\u5316\u6d3b\u6027\u53cd\u8f6c\uff1a155 \u00b0C\u6697\u70ed\u6761\u4ef6\u4e0b\uff0cPdPOM\u2013CNG\u7684PET\u8f6c\u5316\u7387\uff0822.5%\uff09\u9ad8\u4e8ePd\u2013CNG\uff0815.3%\uff09\u3002\u6309\u7167\u4f20\u7edf\u8ba4\u8bc6\uff0c\u82e5\u5149\u70ed\u4f5c\u7528\u4e3b\u8981\u901a\u8fc7\u5347\u6e29\u9a71\u52a8\u53cd\u5e94\uff0cPdPOM\u2013CNG\u7406\u5e94\u7ee7\u7eed\u4fdd\u6301\u4f18\u52bf\u3002\u7136\u800c\uff0c\u5149\u70ed\u6761\u4ef6\u4e0bPd\u2013CNG\u7684\u8f6c\u5316\u7387\u8dc3\u5347\u81f387.5%\uff0c\u663e\u8457\u8d85\u8fc7PdPOM\u2013CNG\u768448.4%\uff0c\u800c\u4e24\u8005\u5b8f\u89c2\u6e29\u5dee\u4e0d\u8db33 \u00b0C\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"486\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/08\/7f88dbbcaa77a1d-17.png\" alt=\"\" class=\"wp-image-272965\"\/><\/figure>\n\n\n\n<p><strong>\u56fe<\/strong><strong>2<\/strong><strong>. PET\u7684\u5149\u70ed\u548c\u70ed\u50ac\u5316\u89e3\u805a\u3002a) \u5728\u70ed\uff08155<\/strong><strong>\u2103<\/strong><strong>\uff0c\u9ed1\u6697\uff09\u548c\u5149\u70ed\uff08155<\/strong><strong>\u2103<\/strong><strong>\uff0c0.35 W\u00b7cm<\/strong><strong>\u207b<\/strong><strong>\u00b2<\/strong><strong>\u5149\u7167\uff09\u6761\u4ef6\u4e0b4\u5c0f\u65f6\u540e\u7684PET\u8f6c\u5316\u7387\u3002b) \u5728\u76f8\u540c\u7684\u70ed\u548c\u5149\u70ed\u6761\u4ef6\u4e0b\uff0cPET\u8f6c\u5316\u7387\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff082\u81f36\u5c0f\u65f6\uff09\u3002c) PET\u5728\u4e0d\u540c\u6e29\u5ea6\u548c\u5149\u7167\u5f3a\u5ea6\u4e0b\u7684\u8f6c\u5316\u7387\u3002d) \u5728\u672c\u4f53\u6e29\u5ea6175<\/strong><strong>\u2103<\/strong><strong>\u548c0.45 W\u00b7cm<\/strong><strong>\u207b<\/strong><strong>\u00b2<\/strong><strong>\u5149\u7167\u6761\u4ef6\u4e0b\u7684BHET\u4ea7\u7387\u548c\u9009\u62e9\u6027\u3002<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4e3a\u7406\u89e3\u8fd9\u4e00\u53cd\u8f6c\uff0c\u52a8\u529b\u5b66\u5206\u6790\u8868\u660ePdPOM\u2013CNG\u5177\u6709\u66f4\u4f4e\u7684\u8868\u89c2\u6d3b\u5316\u80fd\uff0899.8 vs 105.2 kJ mol\u207b\u00b9\uff09\uff0cDFT\u8ba1\u7b97\u5f97\u5230\u7684\u53cd\u5e94\u80fd\u5792\u8d8b\u52bf\u4e5f\u4e0e\u6697\u70ed\u5b9e\u9a8c\u4e00\u81f4\u3002\u8fd9\u8bf4\u660e\u4f20\u7edf\u7ed3\u6784\u2013\u6d3b\u6027\u5173\u7cfb\u80fd\u591f\u89e3\u91ca\u5176\u70ed\u50ac\u5316\u4f18\u52bf\uff0c\u5374\u65e0\u6cd5\u89e3\u91ca\u5149\u70ed\u6761\u4ef6\u4e0b\u5b8c\u5168\u76f8\u53cd\u7684\u6d3b\u6027\u6392\u5e8f\uff1a\u65e2\u7136\u672c\u5f81\u6d3b\u6027\u66f4\u9ad8\u3001\u5b8f\u89c2\u6e29\u5ea6\u53c8\u8fd1\u4e4e\u76f8\u540c\uff0c\u4e3a\u4ec0\u4e48PdPOM\u2013CNG\u53cd\u800c\u5931\u53bb\u4e86\u4f18\u52bf\uff1f<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"486\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/08\/4e9a0ba2491dfde-17.png\" alt=\"\" class=\"wp-image-272966\"\/><\/figure>\n\n\n\n<p><strong>\u56fe <\/strong><strong>3<\/strong><strong>. a) Pd\u2013CNG \u548c PdPOM\u2013CNG \u7684\u89e3\u805a\u901f\u7387\u5e38\u6570\u7684\u963f\u4f26\u5c3c\u4e4c\u65af\u56fe\u3002b) \u52a0\u70ed\u9636\u6bb5\u548c c) \u53cd\u5e94\u9636\u6bb5 Pd\u2013CNG \u4e0a PET \u89e3\u805a\u7684\u539f\u4f4d\u6f2b\u53cd\u5c04\u7ea2\u5916\u5085\u91cc\u53f6\u53d8\u6362\u5149\u8c31 (DRIFTS)\u3002d) \u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba (DFT) \u8ba1\u7b97\u7684\u53cd\u5e94\u8def\u5f84\uff0c\u4ee5\u53ca e) \u8fc7\u6e21\u6001 1 (TS 1) \u548c f) \u8fc7\u6e21\u6001 2 (TS 2) \u7684 DFT \u4f18\u5316\u7ed3\u6784\u3002\u989c\u8272\u4ee3\u7801\uff1a\u6a59\u8272\uff0cPd\uff1b\u767d\u8272\uff0cH\uff1b\u9ec4\u8272\uff0cN\uff1b\u7eff\u8272\uff0cO\uff1b\u6df1\u7070\u8272\uff0cC\uff1b\u7070\u8272\uff0cW\uff1b\u7c89\u8272\uff0cP\u3002g) Pd\u2013CNG \u548c PdPOM\u2013CNG \u7684\u7a7a\u95f4\u53ef\u53ca\u6027\u3002<\/strong><strong><\/strong><\/p>\n\n\n\n<p>\u4ece\u6697\u70ed\u8f6c\u5411\u5149\u70ed\uff0c\u771f\u6b63\u6539\u53d8\u7684\u662f\u80fd\u91cf\u8f93\u5165\u65b9\u5f0f\u3002NEMD\u6a21\u62df\u8fdb\u4e00\u6b65\u8868\u660e\uff0cPd\u2013CNG\u7684\u76f4\u63a5\u8026\u5408\u6709\u5229\u4e8e\u5149\u70ed\u80fd\u91cf\u5411Pd\u4f4d\u70b9\u4f20\u9012\uff0c\u800cPdPOM\u2013CNG\u4e2d\u7684\u989d\u5916\u754c\u9762\u589e\u52a0\u4e86\u80fd\u91cf\u4f20\u9012\u963b\u529b\u3002\u7ed3\u5408\u5149\u70ed\u4e0e\u6697\u70ed\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u4f5c\u8005\u8fdb\u4e00\u6b65\u91cf\u5316\u4e86\u201c\u6d3b\u6027\u4f4d\u70b9\u6709\u6548\u6e29\u5ea6\u201d\uff1aPd\u2013CNG\u7684\u6709\u6548\u6e29\u5347\u8fbe\u523050.3 \u00b0C\uff0c\u800cPdPOM\u2013CNG\u4ec5\u4e3a31.4 \u00b0C\u3002\u7531\u6b64\u63ed\u793a\uff0c\u5b8f\u89c2\u6e29\u5ea6\u76f8\u8fd1\u5e76\u4e0d\u610f\u5473\u7740\u6d3b\u6027\u4f4d\u70b9\u5904\u4e8e\u76f8\u540c\u7684\u70ed\u72b6\u6001\uff0c\u771f\u6b63\u5f71\u54cd\u5149\u70ed\u50ac\u5316\u884c\u4e3a\u7684\u662f\u80fd\u91cf\u80fd\u5426\u6709\u6548\u5230\u8fbe\u6d3b\u6027\u4f4d\u70b9\u5e76\u88ab\u5229\u7528\u3002\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"700\" height=\"441\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2026\/08\/b14210e1ee30421-14.png\" alt=\"\" class=\"wp-image-272967\"\/><\/figure>\n\n\n\n<p><strong>\u56fe <\/strong><strong>4<\/strong><strong>. a) \u4ece\u4fef\u89c6\u56fe\u548c\u4fa7\u89c6\u56fe\u89c2\u5bdf\u7684 Pd\u2013CNG \u548c PdPOM\u2013CNG \u7684\u7ed3\u6784\u6a21\u578b\u3002b) Pd\u2013CNG \u548c PdPOM\u2013CNG \u7684\u4e09\u7ef4\u6e29\u5ea6\u5206\u5e03\u3002c) \u6cbf Z \u8f74\u7684\u6e29\u5ea6\u5206\u5e03\u3002d) Pd\u2013CNG \u548c e) 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