\u94dd\u8d1f\u6781\u53ef\u8fdb\u884c\u4e09\u7535\u5b50\u6c27\u5316\u8fd8\u539f\uff0c\u5176\u7406\u8bba\u8d28\u91cf\u6bd4\u5bb9\u91cf\u4e3a 2981 mAh g-1<\/sup>\uff0c\u7406\u8bba\u4f53\u79ef\u6bd4\u5bb9\u91cf\u8fbe\u5230 8056 mAh cm-3<\/sup>\u3002\u4f20\u7edf\u94dd\/\u77f3\u58a8\u4f53\u7cfb\u867d\u7136\u5faa\u73af\u5bff\u547d\u8f83\u957f\uff0c\u4f46\u4ecd\u9762\u4e34\u79bb\u5b50\u6db2\u4f53\u4ef7\u683c\u9ad8\u3001\u77f3\u58a8\u5bb9\u91cf\u504f\u4f4e\u4ee5\u53ca\u9ad8\u8f7d\u91cf\u6027\u80fd\u4e0b\u964d\u7b49\u95ee\u9898\u3002\u6709\u673a\u7535\u6781\u7684\u7ec4\u6210\u5143\u7d20\u4e30\u5bcc\u3001\u5206\u5b50\u7ed3\u6784\u5bb9\u6613\u8c03\u8282\uff0c\u7406\u8bba\u4e0a\u66f4\u6709\u5229\u4e8e\u63d0\u9ad8\u5bb9\u91cf\uff1b\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u5c0f\u5206\u5b50\u5bb9\u6613\u8fdb\u5165\u7535\u89e3\u6db2\u5e76\u7a7f\u68ad\u81f3\u8d1f\u6781\uff0c\u800c\u9884\u5148\u5408\u6210\u7684\u957f\u94fe\u805a\u5408\u7269\u53c8\u5e38\u51fa\u73b0\u56e2\u805a\u3001\u5bfc\u7535\u6027\u4e0d\u8db3\u3001\u6d3b\u5316\u7f13\u6162\u548c\u7535\u538b\u66f2\u7ebf\u503e\u659c\u3002\u5982\u4f55\u5728\u201c\u5206\u5b50\u6001\u7684\u660e\u786e\u80fd\u7ea7\u201d\u548c\u201c\u805a\u5408\u6001\u7684\u4e0d\u6eb6\u6027\u201d\u4e4b\u95f4\u53d6\u5f97\u5e73\u8861\uff0c\u662f\u672c\u5de5\u4f5c\u7684\u51fa\u53d1\u70b9\u3002<\/p>\n\n\n\n MILES-1 \u7531\u82ef\u6491\u53cc(\u5429\u567b\u55ea)\u4e2d\u5fc3\u548c\u56db\u4e2a\u672b\u7aef\u5494\u5511\u5355\u5143\u6784\u6210\u3002\u786b\u6865\u80fd\u591f\u9650\u5236\u82b3\u73af\u81ea\u7531\u65cb\u8f6c\u5e76\u5ef6\u4f38\u5171\u8f6d\uff0c\u672b\u7aef\u5494\u5511\u5219\u63d0\u4f9b\u7535\u5316\u5b66\u5076\u8054\u4f4d\u7f6e\u3002\u5206\u5b50\u4e2d N\u3001S \u6742\u539f\u5b50\u4e0e\u82b3\u73af\u7684\u6570\u91cf\u6bd4\u4e3a 4\u22365\uff1b6 \u4e2a N \u4f4d\u70b9\u4e0e 2 \u4e2a S \u4f4d\u70b9\u5747\u53ef\u53c2\u4e0e\u7535\u8377\u8865\u507f\uff0c\u5bf9\u5e94 189 mAh g-1<\/sup> \u7684\u7406\u8bba\u5bb9\u91cf\u3002\u5faa\u73af\u65f6\uff0c\u5494\u5511\u7aef\u57fa\u53d1\u751f C\u2014C \u5076\u8054\uff0c\u6d3b\u6027\u5206\u5b50\u4e0d\u518d\u4ee5\u6e38\u79bb\u5355\u4f53\u5b58\u5728\uff0c\u800c\u662f\u5728 Super-P \u5bfc\u7535\u78b3\u8868\u9762\u5f62\u6210\u8fde\u7eed\u3001\u65e0\u5b9a\u5f62\u4e14\u8d34\u5408\u7d27\u5bc6\u7684\u5be1\u805a\u5305\u8986\u5c42\u3002<\/p>\n\n\n\n \u7535\u89e3\u6db2\u91c7\u7528 AlCl\u2083\u3001\u4e09\u4e59\u80fa\u76d0\u9178\u76d0\uff08TEAC\uff09\u548c 1-\u4e59\u57fa-3-\u7532\u57fa\u54aa\u5511\u6c2f\u76d0\uff08EMIC\uff09\u7ec4\u6210\u7684\u4e09\u5143\u4f53\u7cfb\uff0c\u6469\u5c14\u6bd4\u4e3a 1.5\u22360.9\u22360.1\u3002\u52a0\u5165\u5c11\u91cf EMIC \u540e\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u7531 8.90 \u63d0\u9ad8\u81f3 9.31 mS cm-1<\/sup>\uff0c\u9ecf\u5ea6\u7531 30.4 \u964d\u81f3 28.7 mPa\u00b7s\uff1b\u540c\u65f6\u8be5\u4f53\u7cfb\u5728\u706b\u7130\u6d4b\u8bd5\u4e2d\u8868\u73b0\u4e3a\u4e0d\u53ef\u71c3\uff0c\u5728\u6210\u672c\u3001\u4f20\u8f93\u6027\u80fd\u4e0e\u5b89\u5168\u6027\u4e4b\u95f4\u5f62\u6210\u8f83\u597d\u7684\u6298\u4e2d\u3002<\/p>\n\n\n\n \u56fe 1\u3000MILES-1 \u7684\u7ed3\u6784\u8bbe\u8ba1\u3001\u5faa\u73af\u4e2d\u539f\u4f4d\u751f\u6210\u7535\u81f4\u5be1\u805a\u7269\u7684\u8fc7\u7a0b\u53caAl\/MILES-1\u7535\u6c60\u7684\u4f18\u70b9\u3002<\/p>\n\n\n\n MILES-1 \u7684\u9996\u5708\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u5305\u542b\u591a\u4e2a\u6c27\u5316\u8fd8\u539f\u5cf0\uff1b\u968f\u7740\u626b\u63cf\u7ee7\u7eed\uff0c\u5cf0\u4f4d\u9010\u6b65\u79fb\u52a8\uff0c\u5e76\u5728\u7ea6 40 \u5708\u540e\u8d8b\u4e8e\u7a33\u5b9a\uff0c\u8bf4\u660e\u7535\u6781\u5185\u90e8\u7684\u7535\u5b50\u7ed3\u6784\u7ecf\u5386\u4e86\u6301\u7eed\u91cd\u6784\u3002\u7ea2\u5916\u5149\u8c31\u4e2d\u51fa\u73b0\u65b0\u7684 804 cm-1<\/sup>\/ C\u2014C \u632f\u52a8\u4fe1\u53f7\uff0c\u62c9\u66fc\u7279\u5f81\u5cf0\u540c\u6b65\u6539\u53d8\uff0c\u8bc1\u660e\u5355\u4f53\u4e4b\u95f4\u5f62\u6210\u4e86\u65b0\u7684\u78b3\u2014\u78b3\u8fde\u63a5\u3002X \u5c04\u7ebf\u884d\u5c04\u663e\u793a\uff0c\u539f\u672c\u5bb9\u6613\u7ed3\u6676\u7684 MILES-1 \u5728\u7535\u5316\u5b66\u5904\u7406\u540e\u8f6c\u4e3a\u65e0\u5b9a\u5f62\u7ed3\u6784\uff0c\u6709\u5229\u4e8e\u7535\u89e3\u6db2\u8fdb\u5165\u7535\u6781\u5e76\u51cf\u5c11\u7d27\u5bc6\u5806\u79ef\u5bf9\u6d3b\u6027\u4f4d\u70b9\u7684\u906e\u6321\u3002<\/p>\n\n\n\n \u8d28\u8c31\u68c0\u6d4b\u5230\u6700\u591a\u4e09\u4e2a\u91cd\u590d\u5355\u5143\uff0c\u4f46\u9ad8\u5206\u5b50\u91cf\u7ec4\u5206\u7684\u79bb\u5b50\u5316\u6548\u7387\u8f83\u4f4e\uff0c\u56e0\u6b64\u7814\u7a76\u8fdb\u4e00\u6b65\u91c7\u7528\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u786e\u5b9a\u5206\u5b50\u91cf\u3002\u5faa\u73af\u540e\u6837\u54c1\u7684\u6570\u5747\u5206\u5b50\u91cf\u7ea6\u4e3a 7930\uff0c\u76f8\u5f53\u4e8e\u7ea6\u4e03\u4e2a MILES-1 \u5355\u5143\uff1b\u5316\u5b66\u6c27\u5316\u6cd5\u5236\u5f97\u7684\u5bf9\u7167\u6837\u54c1\u6570\u5747\u5206\u5b50\u91cf\u4e3a 18425\uff0c\u7ea6\u5bf9\u5e94 16 \u805a\u4f53\u3002\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u5230\uff0c\u539f\u4f4d\u4ea7\u7269\u4ee5\u7eb3\u7c73\u8936\u76b1\u7f51\u7edc\u5747\u5300\u8986\u76d6\u5bfc\u7535\u78b3\uff0c\u800c\u4e0d\u662f\u5f62\u6210\u5b64\u7acb\u7684\u5927\u9897\u7c92\u3002\u8f83\u77ed\u7684\u4e03\u805a\u4f53\u4ecd\u4fdd\u6301\u76f8\u5bf9\u79bb\u6563\u7684\u7535\u5b50\u6001\uff0c\u56e0\u6b64\u6bd4 16 \u805a\u4f53\u5bf9\u7167\u5448\u73b0\u66f4\u6e05\u6670\u7684\u7535\u538b\u5e73\u53f0\uff1b\u540e\u8005\u5bb9\u91cf\u4ec5\u4e3a 101.6 mAh g-1<\/sup>\u3001\u5e93\u4ed1\u6548\u7387\u4e3a 97.1%\u3002<\/p>\n\n\n\n \u56fe 2\u3000\u5faa\u73af\u4f0f\u5b89\u3001\u632f\u52a8\u5149\u8c31\u3001\u8d28\u8c31\u3001\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u548c\u7535\u5b50\u663e\u5fae\u8868\u5f81\u5171\u540c\u786e\u8ba4 MILES-1 \u7684\u539f\u4f4d\u5be1\u805a\u4e0e\u78b3\u8868\u9762\u5305\u8986\u3002<\/p>\n\n\n\n \u6263\u5f0f\u7535\u6c60\u4ee5\u94dd\u7b94\u4e3a\u8d1f\u6781\u3001MILES-1\/\u5bfc\u7535\u78b3\u590d\u5408\u7269\u4e3a\u6b63\u6781\u3002\u5145\u7535\u65f6\uff0c\u6b63\u6781\u5206\u5b50\u88ab\u9010\u7ea7\u6c27\u5316\uff0cAlCl\u2084\u207b \u9634\u79bb\u5b50\u8fdb\u5165\u5e76\u8865\u507f\u6b63\u7535\u8377\uff1b\u653e\u7535\u65f6 AlCl\u2084\u207b \u4ece\u6b63\u6781\u91ca\u653e\uff0c\u540c\u65f6\u8d1f\u6781\u53d1\u751f\u4e0e\u94dd\u6c89\u79ef\/\u5265\u79bb\u76f8\u5173\u7684\u6c2f\u94dd\u9178\u6839\u8f6c\u5316\u3002\u56e0\u6b64\uff0c\u8be5\u4f53\u7cfb\u672c\u8d28\u4e0a\u5c5e\u4e8e\u4ee5\u9634\u79bb\u5b50\u53c2\u4e0e\u6b63\u6781\u53cd\u5e94\u7684 p \u578b\u6709\u673a\u50a8\u80fd\uff0c\u800c\u4e0d\u662f Al\u00b3\u207a \u5728\u6709\u673a\u9aa8\u67b6\u4e2d\u7684\u7b80\u5355\u5d4c\u5165\u3002<\/p>\n\n\n\n \u5728\u6b63\u6781\u8f7d\u91cf 2.7 mg cm-2<\/sup>\u3001\u7535\u6d41\u5bc6\u5ea6 200 mA g-1<\/sup>\u6761\u4ef6\u4e0b\uff0cAl\/MILES-1 \u7535\u6c60\u7684\u53ef\u9006\u6bd4\u5bb9\u91cf\u4e3a 137 mAh g-1<\/sup>\uff0c\u5e93\u4ed1\u6548\u7387\u4e3a 99.3%\u3002\u653e\u7535\u66f2\u7ebf\u5305\u542b\u7ea6 1.8 V\uff082.04\uff5e1.60 V\uff09\u548c\u7ea6 0.9 V\uff081.10\uff5e0.74 V\uff09\u4e24\u4e2a\u5e73\u53f0\uff0c\u5176\u4e2d\u9ad8\u7535\u538b\u5e73\u53f0\u660e\u663e\u9ad8\u4e8e TCTA \u5bf9\u7167\uff1b\u8be5\u7535\u6c60\u5728 200 mA g-1<\/sup>\u4e0b\u7684\u80fd\u91cf\u6548\u7387\u4e3a 90.1%\uff0c\u8868\u660e\u5145\u653e\u7535\u6781\u5316\u8f83\u5c0f\u3002\u964d\u4f4e\u6d3b\u6027\u7269\u8d28\u8f7d\u91cf\u81f3 0.6 mg cm-2<\/sup> \u65f6\u53ef\u63a5\u8fd1\u7406\u8bba\u5bb9\u91cf\uff0c\u652f\u6301 6 \u4e2a N \u548c 2 \u4e2a S \u4f4d\u70b9\u5747\u53c2\u4e0e\u53cd\u5e94\u7684\u5224\u65ad\u3002<\/p>\n\n\n\n \u5faa\u73af\u4e0e\u500d\u7387\u6570\u636e\u8fdb\u4e00\u6b65\u4f53\u73b0\u4e86\u539f\u4f4d\u5be1\u805a\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff1a\u5728 1000 mA g-1<\/sup>\uff08\u7ea6 8.5 C\uff09\u4e0b\u8fd0\u884c 10000 \u5708\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u63a5\u8fd1 100%\uff0c\u5e93\u4ed1\u6548\u7387\u7ea6\u4e3a 100%\u3002\u5728 \u221220 \u2103\u300125 mA g\u207b<\/sup>1<\/sup>\u4e0b\uff0c\u5e73\u5747\u5bb9\u91cf\u3001\u5e93\u4ed1\u6548\u7387\u548c\u80fd\u91cf\u6548\u7387\u5206\u522b\u4e3a 115.4 mAh g-1<\/sup>\u300199.6% \u548c 85.8%\uff1b\u5728 60 \u2103\u30011000 mA g-1<\/sup>\u4e0b\uff0c\u76f8\u5e94\u6570\u503c\u4e3a 139.5 mAh g-1<\/sup>\uff0c99.0% \u548c 86.7%\u3002<\/p>\n\n\n\n \u56fe 3\u3000Al\/MILES-1 \u6263\u5f0f\u7535\u6c60\u7684\u5de5\u4f5c\u65b9\u5f0f\uff0c\u4ee5\u53ca\u5bb9\u91cf\u3001\u5faa\u73af\u3001\u500d\u7387\u3001\u81ea\u653e\u7535\u548c\u5bbd\u6e29\u6027\u80fd\u3002<\/p>\n\n\n\n \u4e3a\u76f4\u63a5\u5224\u65ad\u6d3b\u6027\u7269\u8d28\u662f\u5426\u4f1a\u8fdb\u5165\u7535\u89e3\u6db2\uff0c\u7814\u7a76\u8005\u5c06 MILES-1 \u5355\u4f53\u3001\u5316\u5b66\u6cd5\u5be1\u805a\u7269\u4ee5\u53ca\u5904\u4e8e 18%\u300140%\u3001100% \u548c 0% \u8377\u7535\u72b6\u6001\u7684\u7535\u81f4\u5be1\u805a\u7269\u7535\u6781\uff0c\u5206\u522b\u7f6e\u4e8e\u4e09\u5143\u79bb\u5b50\u6db2\u4f53\u4e2d\u6d78\u6ce1 48 h\uff0c\u6d4b\u8bd5\u6d53\u5ea6\u4e3a 1 mg mL-1<\/sup>\u3002\u5355\u4f53\u548c\u5316\u5b66\u6cd5\u5be1\u805a\u7269\u7684\u4e0a\u6e05\u6db2\u51fa\u73b0\u660e\u663e\u989c\u8272\u53ca\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\uff0c\u800c\u539f\u4f4d\u7535\u81f4\u5be1\u805a\u7269\u5728\u4e0d\u540c\u8377\u7535\u72b6\u6001\u4e0b\u7684\u4e0a\u6e05\u6db2\u5747\u53ea\u6709\u53ef\u5ffd\u7565\u7684\u5438\u6536\u4fe1\u53f7\u3002\u7531\u6b64\u53ef\u89c1\uff0c\u5faa\u73af\u4e2d\u5f62\u6210\u7684\u8d34\u5408\u5f0f\u5be1\u805a\u7f51\u7edc\u80fd\u591f\u5728\u5145\u7535\u72b6\u6001\u4e0b\u7ee7\u7eed\u56fa\u5b9a\u6d3b\u6027\u7ec4\u5206\uff0c\u5bb9\u91cf\u7a33\u5b9a\u5e76\u975e\u53ea\u6765\u81ea\u5206\u5b50\u91cf\u589e\u52a0\u3002<\/p>\n\n\n\n \u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u5206\u6790\u7ed9\u51fa 0.89\uff5e0.94 \u7684 b \u503c\uff0c\u63a5\u8fd1\u8868\u9762\u63a7\u5236\u8fc7\u7a0b\u7684\u7406\u8bba\u503c 1\uff1b\u5728 0.1\uff5e2 mV s-1<\/sup>\u8303\u56f4\u5185\uff0c\u8868\u9762\u53cd\u5e94\u5bf9\u603b\u7535\u6d41\u7684\u8d21\u732e\u7531 80% \u63d0\u9ad8\u81f3 95%\u3002\u7528\u7535\u5316\u5b66\u6bd4\u7535\u5bb9\u8861\u91cf\u53ef\u63a5\u8fd1\u754c\u9762\u7684\u53d8\u5316\uff1a\u5faa\u73af\u540e\u7535\u6781\u7531 0.032 F g-1<\/sup>\u589e\u81f3 3.413 F g-1<\/sup>\uff0c\u7ea6\u63d0\u9ad8 107 \u500d\u3002\u8fd9\u8bf4\u660e\u539f\u4f4d\u5be1\u805a\u4e0d\u4ec5\u6291\u5236\u6eb6\u89e3\uff0c\u8fd8\u6784\u7b51\u4e86\u66f4\u5927\u7684\u6709\u6548\u7535\u5316\u5b66\u754c\u9762\uff0c\u66b4\u9732\u51fa\u66f4\u591a\u53ef\u53c2\u4e0e\u9634\u79bb\u5b50\u5438\u9644\/\u89e3\u5438\u7684\u4f4d\u70b9\u3002<\/p>\n\n\n\n \u56fe 4\u3000\u6d78\u6ce1\u4e0e\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\u8bc1\u660e\u7535\u81f4\u5be1\u805a\u7269\u96be\u6eb6\uff1b\u626b\u63cf\u901f\u7387\u5206\u6790\u548c\u6bd4\u7535\u5bb9\u53d8\u5316\u53cd\u6620\u8868\u9762\u4e3b\u5bfc\u7684\u5feb\u901f\u52a8\u529b\u5b66\u3002<\/p>\n\n\n\n \u4f5c\u8005\u4f7f\u7528XPS \u5bf9\u521d\u59cb\u7535\u6781\u3001\u5145\u81f3 1.3 V\u3001\u5145\u81f3 2.1 V \u4ee5\u53ca\u653e\u7535\u540e\u7684 N 1s \u548c S 2p \u4fe1\u53f7\u8fdb\u884c\u4e86\u6bd4\u8f83\u3002\u7531\u521d\u59cb\u72b6\u6001\u5145\u81f3 1.3 V \u65f6\uff0cN \u7684\u6c27\u5316\u7ec4\u5206\u7ea6\u5360 33.5%\uff0c\u800c S \u7684\u6c27\u5316\u6bd4\u4f8b\u4ec5\u7ea6 14.2%\uff1b\u7535\u4f4d\u5347\u81f3 2.1 V \u540e\uff0cN\u3001S \u7684\u6c27\u5316\u7ec4\u5206\u5206\u522b\u589e\u81f3\u7ea6 42.3% \u548c 47.2%\u3002\u653e\u7535\u540e\u4e24\u7c7b\u4fe1\u53f7\u5411\u4e2d\u6027\u72b6\u6001\u6062\u590d\uff0c\u8bf4\u660e N \u4e0e S \u90fd\u662f\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u4e2d\u5fc3\uff0c\u540c\u65f6\u4e5f\u8868\u660e\u4f4e\u7535\u4f4d\u9636\u6bb5\u4e3b\u8981\u7531 N \u4f4d\u70b9\u627f\u62c5\u7535\u8377\uff0c\u9ad8\u7535\u4f4d\u9636\u6bb5 S \u4f4d\u70b9\u7684\u53c2\u4e0e\u660e\u663e\u589e\u5f3a\u3002<\/p>\n\n\n\n DFT\u8ba1\u7b97\u5f97\u5230\u7684\u7535\u8377\u5206\u5e03\u7ed9\u51fa\u4e00\u4e2a\u516b\u7535\u5b50\u3001\u4e09\u9636\u6bb5\u7684\u6c27\u5316\u8def\u5f84\uff1a\u9996\u5148\u79fb\u53bb 2 \u4e2a\u7535\u5b50\uff0c\u6b63\u7535\u8377\u4e3b\u8981\u96c6\u4e2d\u5728\u5429\u567b\u55ea\u5355\u5143\u7684 N \u9644\u8fd1\uff1b\u968f\u540e\u518d\u79fb\u53bb 4 \u4e2a\u7535\u5b50\uff0c\u5494\u5511 N \u6210\u4e3a\u4e3b\u8981\u53cd\u5e94\u4f4d\u7f6e\uff1b\u6700\u540e\u79fb\u53bb 2 \u4e2a\u7535\u5b50\uff0c\u6b63\u7535\u8377\u96c6\u4e2d\u5230\u5429\u567b\u55ea S \u5468\u56f4\u3002\u76f8\u5e94\u7684\u8ba1\u7b97\u7535\u4f4d\u4e3a 0.69\u30011.31 \u548c 2.23 V\uff08\u76f8\u5bf9\u4e8e Ag\/Ag+<\/sup>\uff09\uff0c\u4e0e\u5b9e\u9a8c\u5faa\u73af\u4f0f\u5b89\u4e2d\u7684\u591a\u7ea7\u53cd\u5e94\u8d8b\u52bf\u4e00\u81f4\u3002\u6bcf\u4e00\u7ea7\u6c27\u5316\u90fd\u4f34\u968f AlCl4<\/sub>–<\/sup>\u4e0e\u5e26\u6b63\u7535\u4f4d\u70b9\u7ed3\u5408\uff0c\u653e\u7535\u65f6\u8fc7\u7a0b\u53cd\u5411\u8fdb\u884c\u3002\u56e0\u6b64\uff0cMILES-1 \u7684\u50a8\u80fd\u53ef\u6982\u62ec\u4e3a N\u3001S \u4f4d\u70b9\u4f9d\u6b21\u6c27\u5316\u5e76\u7531\u6c2f\u94dd\u9178\u6839\u9634\u79bb\u5b50\u8865\u507f\u7535\u8377\uff0c\u5176\u4e2d N \u5148\u4e8e S \u53c2\u4e0e\u53cd\u5e94\u3002<\/p>\n\n\n\n \u56fe 5\u3000DFT \u6a21\u62df\u7684\u4e09\u7ea7\u6c27\u5316\u4e0e AlCl4<\/sub>–<\/sup>\u7535\u8377\u8865\u507f\u8fc7\u7a0b\uff0c\u8bf4\u660e N \u4f4d\u70b9\u5148\u54cd\u5e94\u3001S \u4f4d\u70b9\u5728\u9ad8\u7535\u4f4d\u7ee7\u7eed\u8d21\u732e\u5bb9\u91cf\u3002<\/p>\n\n\n\n \u5728\u4e24\u5c42\u8f6f\u5305\u7535\u6c60\u4e2d\uff0cMILES-1 \u8f7d\u91cf\u8fbe\u5230 15.6 mg cm\u207b\u00b2\uff0c\u7535\u6781\u9762\u79ef\u4e3a 16 cm\u00b2\uff1b\u4ee5 50 mA g-1\u5145\u653e\u7535\u65f6\uff0c\u6bd4\u5bb9\u91cf\u4e3a 130.8 mAh g-1\u3001\u9762\u5bb9\u91cf\u4e3a 2.0 mAh cm-2\u3001\u5e93\u4ed1\u6548\u7387\u4e3a 99.8%\uff0c\u6309\u6709\u673a\u6d3b\u6027\u7269\u8d28\u8d28\u91cf\u8ba1\u7b97\u7684\u80fd\u91cf\u5bc6\u5ea6\u7ea6\u4e3a 159.6 Wh kg-1\u3002\u8fdb\u4e00\u6b65\u653e\u5927\u5230\u4e94\u5c42\u3001\u5355\u5c42\u9762\u79ef 8 cm \u00d7 8 cm\u3001\u603b\u6d3b\u6027\u7269\u8d28 8.25 g \u7684\u5668\u4ef6\u540e\uff0c\u9762\u8f7d\u91cf\u63d0\u9ad8\u81f3 25.8 mg cm-2\uff0c\u8f6f\u5305\u7535\u6c60\u53ef\u8f93\u51fa 0.8 Ah \u53ef\u9006\u5bb9\u91cf\u548c 2.5 mAh cm-2\u9762\u5bb9\u91cf\u3002\u4f5c\u4e3a\u5bf9\u7167\uff0c19.9 mg cm-2\u8f7d\u91cf\u7684\u94dd\/\u77f3\u58a8\u8f6f\u5305\u7535\u6c60\u4ec5\u5f97\u5230 33.1 mAh g-1\u548c 0.66 mAh cm-2\uff0c\u663e\u793a\u7535\u81f4\u5be1\u805a\u6b63\u6781\u5728\u9ad8\u8f7d\u91cf\u6761\u4ef6\u4e0b\u5177\u6709\u66f4\u660e\u663e\u7684\u5bb9\u91cf\u4f18\u52bf\u3002<\/p>\n\n\n\n \u56fe 6\u3000\u9ad8\u8f7d\u91cf\u3001\u591a\u5c42\u5806\u53e0 Al\/MILES-1 \u8f6f\u5305\u7535\u6c60\u7684\u7ed3\u6784\u3001\u5145\u653e\u7535\u66f2\u7ebf\u4e0e\u957f\u671f\u5faa\u73af\u8868\u73b0\u3002<\/p>\n\n\n\n \u8fd9\u9879\u5de5\u4f5c\u7684\u5173\u952e\u5e76\u4e0d\u662f\u5355\u7eaf\u63d0\u9ad8\u5206\u5b50\u91cf\uff0c\u800c\u662f\u63a7\u5236\u5be1\u805a\u53d1\u751f\u7684\u65f6\u95f4\u548c\u4f4d\u7f6e\uff1aMILES-1 \u5148\u4ee5\u6613\u52a0\u5de5\u7684\u5c0f\u5206\u5b50\u5f62\u5f0f\u8fdb\u5165\u7535\u6781\uff0c\u968f\u540e\u5728\u5faa\u73af\u4e2d\u4e8e\u5bfc\u7535\u78b3\u754c\u9762\u751f\u6210\u7ea6\u4e03\u805a\u4f53\u7684\u65e0\u5b9a\u5f62\u6d3b\u6027\u5c42\u3002\u8fd9\u6837\u7684\u77ed\u94fe\u7ed3\u6784\u907f\u514d\u4e86\u5355\u4f53\u6eb6\u89e3\uff0c\u4e5f\u6ca1\u6709\u5b8c\u5168\u8f6c\u53d8\u4e3a\u957f\u94fe\u5171\u8f6d\u805a\u5408\u7269\u7684\u8fde\u7eed\u7535\u5b50\u6001\uff0c\u4ece\u800c\u628a\u9ad8\u7535\u538b\u5e73\u53f0\u3001\u8868\u9762\u4e3b\u5bfc\u7684\u5feb\u901f\u53cd\u5e94\u548c\u957f\u5faa\u73af\u5bff\u547d\u7ed3\u5408\u5230\u540c\u4e00\u6b63\u6781\u4e2d\u3002\u6263\u5f0f\u7535\u6c60\u4e0e\u9ad8\u8f7d\u91cf\u8f6f\u5305\u7535\u6c60\u7684\u8fde\u7eed\u9a8c\u8bc1\uff0c\u4f7f\u201c\u7535\u81f4\u5be1\u805a\u7269\u201d\u6210\u4e3a\u94dd\u6709\u673a\u7535\u6c60\u6750\u6599\u8bbe\u8ba1\u4e2d\u4e00\u4e2a\u5177\u6709\u63a8\u5e7f\u4ef7\u503c\u7684\u4e2d\u95f4\u5c3a\u5ea6\u3002<\/p>\n\n\n\n \u73b0\u9636\u6bb5\u8be5\u4f53\u7cfb\u8ddd\u79bb\u5de5\u7a0b\u5e94\u7528\u4ecd\u6709\u82e5\u5e72\u95ee\u9898\u9700\u8981\u89e3\u51b3\uff0c\u5305\u62ec\u964d\u4f4e\u7535\u89e3\u6db2\u4e0e\u6d3b\u6027\u7269\u8d28\u4e4b\u6bd4\u3001\u907f\u514d\u96c6\u6d41\u4f53\u5728\u6c2f\u94dd\u9178\u76d0\u7535\u89e3\u6db2\u4e2d\u8150\u8680\u3001\u6269\u5927\u7535\u89e3\u6db2\u7a33\u5b9a\u7535\u4f4d\u7a97\u53e3\u3001\u63d0\u9ad8\u6709\u673a\u6750\u6599\u672c\u5f81\u5bfc\u7535\u6027\u5e76\u51cf\u5c11\u5bfc\u7535\u70ad\u6bd4\u4f8b\uff0c\u4ee5\u53ca\u5728\u66f4\u5927\u9762\u79ef\u3001\u66f4\u9ad8\u9762\u8f7d\u91cf\u548c\u66f4\u957f\u5faa\u73af\u6761\u4ef6\u4e0b\u9a8c\u8bc1\u5806\u53e0\u8f6f\u5305\u7535\u6c60\u3002\u56e0\u800c\uff0c\u8bba\u6587\u7684\u4e3b\u8981\u4ef7\u503c\u5728\u4e8e\u7ed9\u51fa\u4e86\u517c\u987e\u5206\u5b50\u80fd\u7ea7\u4e0e\u56fa\u6001\u7a33\u5b9a\u6027\u7684\u65b0\u8def\u5f84\uff0c\u800c\u4e0d\u662f\u5ba3\u544a\u94dd\u6709\u673a\u7535\u6c60\u5df2\u7ecf\u8fbe\u5230\u5546\u4e1a\u5316\u6761\u4ef6\u3002<\/p>\n\n\n\n Rechargeable Aluminum-Organic Batteries with Electro-Oligomers<\/p>\n\n\n\n Xichen Zhou, Songwei Wen, Xiantao Hu, Wai-Pan Ng, Peng Liang, Shixin Wang, Fei Liu, Jiajie Zheng, Jingwen Zhou, Yan Wu, Yilin Sun, Tianyu Liu, Luyao Yang, Mingyue Wang, Zhikang Deng, Shuting Fu, Huaqing Zhang, Dechen Dong, Zuochao Wang, Yuanzhuo Li, Zigang Lu, Haoran Liu, Junzhi Liu, Jian He*, Hongjie Dai*<\/p>\n\n\n\n Journal of the American Chemical Society (2026). DOI: 10.1021\/jacs.6c09549<\/p>\n\n\n\n \u9999\u6e2f\u5927\u5b66\u535a\u58eb\u540e\u5468\u5e0c\u741b\u3001\u6587\u677e\u5a01\u3001\u80e1\u663e\u97ec\u548c\u5434\u709c\u5f6c\u4e3a\u672c\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005<\/p>\n\n\n\n \u6234\u5b8f\u6770\u9662\u58eb\uff0c1966 \u5e74\u51fa\u751f\u4e8e\u6e56\u5357\u90b5\u9633\uff0c\u73b0\u4efb\u9999\u6e2f\u5927\u5b66\u5316\u5b66\u7cfb\u8bb2\u5ea7\u6559\u6388\uff0c\u5e76\u5728\u673a\u68b0\u5de5\u7a0b\u7cfb\u548c\u533b\u5b66\u9662\u4efb\u804c\uff1b\u540c\u65f6\u4e3a\u65af\u5766\u798f\u5927\u5b66 J. G. Jackson \u4e0e C. J. 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