{"id":32377,"date":"2016-08-10T14:00:12","date_gmt":"2016-08-10T06:00:12","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=32377"},"modified":"2016-08-10T10:14:48","modified_gmt":"2016-08-10T02:14:48","slug":"adv-funct-mater-%e4%b8%8a%e6%b5%b7%e5%a4%a7%e5%ad%a6%e7%a0%94%e5%8f%91%e4%bb%8b%e5%ad%94%e7%ba%b3%e7%b1%b3%e6%a3%92%e4%b8%89%e5%85%83%e9%87%91%e5%b1%9e%e7%a1%ab%e7%a2%b3%e5%a4%8d%e5%90%88%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=32377","title":{"rendered":"Adv. Funct. Mater. \u4e0a\u6d77\u5927\u5b66\u7814\u53d1\u4ecb\u5b54\u7eb3\u7c73\u68d2\u4e09\u5143\u91d1\u5c5e\u786b\/\u78b3\u590d\u5408\u7535\u6781\u6750\u6599"},"content":{"rendered":"<p><strong>\u5f15\u8bed<\/strong><br \/>\n\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u9010\u6b65\u5e94\u7528\u5728\u5927\u578b\u7535\u52a8\u8bbe\u5907\u4e0a\uff0c\u5f00\u53d1\u9ad8\u5bb9\u91cf\u3001\u957f\u5bff\u547d\u548c\u500d\u7387\u6027\u80fd\u4f18\u5f02\u7684\u7535\u6c60\u6750\u6599\u662f\u9502\u7535\u6c60\u7814\u7a76\u6700\u4e3a\u91cd\u8981\u7684\u5173\u952e\u3002\u4e0a\u6d77\u5927\u5b66\u73af\u5883\u4e0e\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u738b\u52c7\u6559\u6388\u8bfe\u9898\u7ec4\u7ec4\u6700\u8fd1\u5728\u8be5\u9886\u57df\u53d6\u5f97\u4e0b\u5217\u7814\u7a76\u6210\u679c\uff1a\u4ee5\u53cc\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e3a\u524d\u9a71\u4f53\u8bbe\u8ba1\u5f97\u5230\u4e86\u4e00\u79cd\u591a\u5b54\u78b3\u7eb3\u7c73\u7ba1\u590d\u5408\u6750\u6599\uff0c\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u8868\u73b0\u51fa\u5f88\u9ad8\u7684\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u5faa\u73af\u53ca\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p><strong>\u6210\u679c\u7b80\u4ecb<\/strong><br \/>\n\u8be5\u7814\u7a76\u56e2\u961f\u901a\u8fc7\u8bbe\u8ba1\u51fa\u5728\u591a\u5b54\u5341\u4e8c\u9762\u4f53\u4e2d\u751f\u957f\u5177\u6709N-S\u5171\u63ba\u6742\u78b3\u5c42\u7684\u78b3\u7eb3\u7c73\u7ba1\u590d\u5408\u6750\u6599\u3002\u8be5\u6750\u6599\u662f\u4ee5\u53cc\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08BMOF\uff09\u4e3a\u524d\u8eaf\u4f53\uff0c\u7ecf\u8fc7\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u548c\u786b\u5316\u8fc7\u7a0b\u4e24\u6b65\u53cd\u5e94\u5f97\u5230\u3002<\/p>\n<p>\u56e0\u8be5\u590d\u5408\u6750\u6599\u4e2d\u4e24\u79cd\u91d1\u5c5e\u786b\u5316\u7269\u7684\u534f\u540c\u4f5c\u7528\u3001\u5341\u4e8c\u9762\u4f53\u7684\u591a\u5b54\u7ed3\u6784\u3001N-S\u5171\u63ba\u6742\u78b3\u5c42\u7684\u5f62\u6210\u548c\u6839\u6df1\u8482\u56fa\u7684\u78b3\u7eb3\u7c73\u7ba1\u7f51\u72b6\u7ed3\u6784\uff0c\u4f7f\u5f97\u8be5\u6750\u6599\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u5c55\u73b0\u51fa\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u5faa\u73af\u6027\u80fd\u4f18\u5f02\uff1a\u5728100 mA g\u22121\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0c\u5faa\u73af250\u5708\u540e\uff0c\u4ecd\u4fdd\u6301\u5bb9\u91cf941 mAh g\u22121 \u6bd4\u5bb9\u91cf\uff08\u8d85\u8fc7\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\uff09\u3002\u57281\uff0c2\uff0c5 Ag-1 \u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af500\u5708\u540e\u4ecd\u5206\u522b\u5177\u6709734\u3001591\u3001505 mAh g\u22121\u6bd4\u5bb9\u91cf\uff0c\u8bf4\u660e\u5176\u5177\u6709\u8f83\u597d\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p><strong>\u56fe\u6587\u7b80\u4ecb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32380 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-14.png\" alt=\"1\" width=\"700\" height=\"353\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-14.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-14-300x151.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u65b9\u6848\u8bbe\u8ba1\uff1a\u793a\u610f\u56fe\u8bf4\u660e\u7531\u53cc\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(Co\/Zn-ZIF- 67)\u5728\u7ecf\u5316\u5b66\u6c14\u76f8\u6c89\u6dc0\u8fc7\u7a0b\u5f97\u5230\u4e2d\u95f4\u4f53Co\/Co3Zn@N-C-CNT\uff0c\u8fdb\u800c\u7ecf\u786b\u5316\u8fc7\u7a0b\u5408\u6210\u6700\u7ec8\u4ea7\u7269Co-Zn-S@N-S-C-CNT\u590d\u5408\u6750\u6599\u3002\u540c\u65f6\u7531\u4e8eCo\u5143\u7d20\u7684\u50ac\u5316\u4f5c\u7528,\u5c0f\u7684\u78b3\u7eb3\u7c73\u7ba1\u5f62\u6210\u5e76\u6df1\u6df1\u624e\u6839\u5728\u5341\u4e8c\u9762\u4f53\u4ea7\u7269\u4e2d\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32381 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-14.png\" alt=\"6-8\" width=\"600\" height=\"475\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-14-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\u56fe1 \u672c\u6750\u6599\u7684\u7279\u70b9\u4e3a\u53cc\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08Co\/Zn-ZIF-67)\uff0c\u6240\u4ee5\u91c7\u53d6\u5355\u539f\u5b50\u91d1\u5c5e\u9aa8\u67b6\uff08Co-ZIF-67\uff09\u4e3a\u57fa\u51c6\uff0c\u7814\u7a76\u5176\u6027\u80fd\u3002<br \/>\na)Co\/Zn-ZIF-67\u548cCo-ZIF-67\u7684X\u5c04\u7ebf\u884d\u5c04\u8c31\u56fe;<br \/>\nb)Co\/Co3ZnC@N-C-CNT \u548cCo@N-C-CNT\u7684X\u5c04\u7ebf\u884d\u5c04\u8c31\u56fe;<br \/>\nc)Co-Zn-S@N-S-C-CNT\u548cCoS2@N-S-C-CNT\u7684X\u5c04\u7ebf\u884d\u5c04\u8c31\u56fe;<br \/>\nd)Co-Zn-S@N-S-C-CNT\u548c CoS2@N-S-C-CNT\u62c9\u66fc\u5149\u8c31\u56fe.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32382 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-15.png\" alt=\"3\" width=\"520\" height=\"595\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-15.png 520w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-15-262x300.png 262w\" sizes=\"(max-width: 520px) 100vw, 520px\" \/><\/p>\n<p>\u56fe2 \u4e2d\u95f4\u4ea7\u7269Co\/Co3ZnC@N-C-CNT\u7684\u5f62\u8c8c\u8868\u5f81\u3002<br \/>\na,b) SEM\u56fe, c) EDS \u8c31\u56fe, d\u2013f) TEM\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32383 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-14.png\" alt=\"4\" width=\"600\" height=\"535\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-14.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-14-300x268.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n\u56fe3 \u7ec8\u4ea7\u7269Co-Zn-S@N-S-C-CNT\u7684\u5f62\u8c8c\u8868\u5f81a,b) SEM \u56fe,c\u2013f) TEM \u56fe, g,h) HRTEM \u56fe\uff0c\u53ef\u6e05\u6670\u770b\u5230\u591a\u9762\u4f53\u4e2d\u751f\u957f\u7684\u78b3\u7eb3\u7c73\u7ba1, i) \u9009\u533a\u7535\u5b50\u884d\u5c04\u56fe,\u5c55\u73b0\u826f\u597d\u7684\u591a\u6676\u7ed3\u6784, j)\u5143\u7d20\u5206\u6790\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32386 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-13.png\" alt=\"5\" width=\"600\" height=\"572\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-13-300x286.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4 \u5bf9\u6bd4\u6837\u4e2d\u95f4\u4ea7\u7269Co@N-C-CNT\u7684\u5f62\u8c8c\u8868\u5f81\uff1aa,b) SEM \u56fe\uff1bc,d) TEM\u56fe\uff1b<br \/>\n\u5bf9\u6bd4\u6837\u7ec8\u4ea7\u7269CoS2@N-S-C-CNT\u7684\u5f62\u8c8c\u8868\u5f81\uff1ae,f) SEM\u56fe\uff0cg,h) TEM\u56fe, i) HRTEM\u56fe, j)\u5143\u7d20\u5206\u6790\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-32385 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/6-13.png\" alt=\"6\" width=\"600\" height=\"625\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/6-13.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/6-13-288x300.png 288w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>\u56fe5 \u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5<br \/>\na)Co-Zn-S@N-S-C-CNT\u7684CV\u56fe\uff0c\u63d2\u56fe\u653e\u5927\u533a\u57df\u5bf9\u5e94\u7684\u662f\u8be5\u7535\u4f4d\u4e0bLi-Zn\u5408\u91d1\u7684\u8131\u5408\u91d1\u5316\u8fc7\u7a0b\uff1b<br \/>\nb) Co-Zn-S@N-S-C-CNT\u57280.1, 1, 2,\u548c5 C (1 C = 1000 mA g\u22121) \u4e0b\u7684\u9996\u5708\u5145\u653e\u7535\u66f2\u7ebf;<br \/>\nc) Co-Zn-S@N-S-C-CNT \u548cCoS2@N-S-C-CNT\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a100 mA g\u22121 (0.1 C)\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u5bf9\u6bd4\uff1b<br \/>\nd) Co-Zn-S@N-S-C-CNT\u7684\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p>\u8fd9\u6837\u4e00\u4e2a\u7cbe\u5fc3\u8bbe\u8ba1\u7684\u5177\u6709\u7279\u6b8a\u7ed3\u6784\u7684\u4e09\u5143\u91d1\u5c5e\u786b\/\u78b3\u590d\u5408\u6750\u6599\u6709\u671b\u6210\u4e3a\u672a\u6765\u50a8\u80fd\u5bb6\u65cf\u4e2d\u7684\u65b0\u5019\u9009\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.201601631\/full\">Carbon Nanotubes Rooted in Porous Ternary Metal Sulfide@N\/S-Doped Carbon Dodecahedron: Bimetal-Organic-Frameworks Derivation and Electrochemical Application for High-Capacity and Long-Life Lithium-Ion Batteries.<\/a>\uff08Adv. Funct. Mater., 2016, DOI\uff1a10.1002\/adfm.201601631\uff09<\/p>\n<p>\u4fdd\u6301\u5b66\u4e60\u7684\u4e60\u60ef\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8bed \u9502\u79bb\u5b50\u7535\u6c60\u6b63\u9010\u6b65\u5e94\u7528\u5728\u5927\u578b\u7535\u52a8\u8bbe\u5907\u4e0a\uff0c\u5f00\u53d1\u9ad8\u5bb9\u91cf\u3001\u957f\u5bff\u547d\u548c\u500d\u7387\u6027\u80fd\u4f18\u5f02\u7684\u7535\u6c60\u6750\u6599\u662f\u9502\u7535\u6c60\u7814\u7a76\u6700\u4e3a\u91cd\u8981\u7684\u5173\u952e\u3002\u4e0a\u6d77\u5927\u5b66\u73af\u5883\u4e0e\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u738b\u52c7\u6559\u6388\u8bfe\u9898\u7ec4\u7ec4\u6700\u8fd1&#8230;<\/p>\n","protected":false},"author":1164,"featured_media":32380,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[18,54,129],"class_list":["post-32377","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-xinnengyuan","tag-making","tag-battery"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/32377"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1164"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=32377"}],"version-history":[{"count":11,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/32377\/revisions"}],"predecessor-version":[{"id":32445,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/32377\/revisions\/32445"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/32380"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=32377"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=32377"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=32377"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}