{"id":33589,"date":"2016-08-15T10:00:04","date_gmt":"2016-08-15T02:00:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=33589"},"modified":"2016-08-22T17:18:45","modified_gmt":"2016-08-22T09:18:45","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%ef%bd%9caemacie%e7%ad%89%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e8%bf%91%e6%9c%9f%e5%ad%a6%e6%9c%af%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=33589","title":{"rendered":"\u9876\u520a\u52a8\u6001\uff5cNature\u5b50\u520a\/AM\/Angew\u7b49\u9502\u79bb\u5b50\u7535\u6c60\u8fd1\u671f\u5b66\u672f\u8fdb\u5c55\u6c47\u603b\u3010\u65b0\u80fd\u6e90\u5468\u62a5\u7b2c16\u671f\u3011"},"content":{"rendered":"

\u9502\u79bb\u5b50\u7535\u6c60\u4f5c\u4e3a\u6700\u5148\u8fdb\u7684\u50a8\u80fd\u8bbe\u5907\u4ecd\u7136\u6709\u80fd\u91cf\u5bc6\u5ea6\u3001\u5faa\u73af\u5bff\u547d\u3001\u5b89\u5168\u6027\u4ee5\u53ca\u6210\u672c\u7b49\u8bf8\u591a\u65b9\u9762\u7684\u63d0\u5347\u7a7a\u95f4\u3002\u5176\u4e2d\u5728\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u4e00\u76f4\u662f\u91cd\u70b9\u7814\u7a76\u5bf9\u8c61\uff0c\u672c\u7bc7\u603b\u7ed3\u4e86\u8fd1\u671f\u4e00\u4e9b\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u65b9\u9762\u7684\u7814\u7a76\uff0c\u4f8b\u5982\uff1a\u8f74\u5bf9\u79f0\u7ed3\u6784\u7684\u8fc7\u5145\u6846\u67b6\u4fdd\u62a4\u3001\u751f\u7269\u884d\u751f\u7269\u6b63\u6781\u6750\u6599\u3001\u4e09\u660e\u6cbb\u7ed3\u6784\u7684\u77f3\u58a8\u70ef\u7535\u6781\u6750\u6599\u7b49\u3002\u4e0b\u9762\u8ba9\u6211\u4eec\u4e00\u8d77\u770b\u770b\u8fd1\u671f\u5404\u7c7b\u9876\u520a\u5728\u9502\u79bb\u5b50\u7535\u6c60\u7b49\u65b9\u9762\u7684\u7814\u7a76\u8fdb\u5c55\u5427\u3002<\/p>\n

1\u3001Nat. Energy <\/strong>\u7528\u4e8e\u9ad8\u500d\u7387\u9502\u79bb\u5b50\u7535\u6c60\u7684\u78c1\u5bf9\u9f50\u77f3\u58a8\u7535\u6781<\/strong><\/span><\/p>\n

\"\u65e0\u6807\u98987\"<\/p>\n

\u00a0\u77f3\u58a8\u8584\u7247\u548c\u7535\u6781\u5236\u9020\u7684\u529f\u80fd\u5316<\/p>\n

\u7531\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u7528\u9014\u65e0\u5904\u4e0d\u5728\uff0c\u80fd\u6e90\u5b58\u50a8\u5e02\u573a\u6b63\u5728\u52aa\u529b\u5bfb\u627e\u5177\u6709\u66f4\u597d\u6027\u80fd\uff0c\u66f4\u957f\u5bff\u547d\u548c\u66f4\u9ad8\u5b89\u5168\u6027\u7684\u50a8\u80fd\u8bbe\u5907\u6765\u6ee1\u8db3\u9700\u6c42\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0c\u4eba\u4eec\u5f80\u5f80\u662f\u4e13\u6ce8\u4e8e\u5bfb\u627e\u65b0\u7684\u6750\u6599\u800c\u8f83\u5c11\u5c06\u7cbe\u529b\u6295\u5165\u5728\u7535\u6781\u5de5\u7a0b\u3002\u4e3a\u4e86\u63d0\u9ad8\u529f\u7387\u5bc6\u5ea6\u800c\u589e\u52a0\u6d3b\u6027\u6750\u6599\u7684\u6570\u91cf\u4ecd\u7136\u662f\u4e0d\u5207\u5b9e\u9645\u7684\uff0c\u56e0\u4e3a\u5b83\u5f71\u54cd\u4e86\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u901a\u8fc7\u7535\u6781\u65f6\u7684\u8f93\u8fd0\u8fc7\u7a0b\u3002<\/p>\n

\u6700\u8fd1\uff0c\u745e\u58eb\u4fdd\u7f57\u8c22\u5c14\u7814\u7a76\u6240\u7684Claire Villevieille\u548c\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662\u7684Andr\u00e9 R Studart\uff08\u5171\u540c\u901a\u8baf\uff09\u7b49\u4eba\u5bf9\u77f3\u58a8\u7535\u6781\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u8be5\u7814\u7a76\u5c0f\u7ec4\u901a\u8fc7\u4e00\u79cd\u4f4e\u5916\u90e8\u78c1\u573a\u5236\u5907\u4e86\u5177\u6709\u5e73\u9762\u5bf9\u51c6\u7ed3\u6784\u7684\u8584\uff08\u539a\u5ea6\u7ea6\u4e3a200 \u03bcm\uff09\u4e14\u5177\u6709\u9ad8\u8f7d\u91cf\uff08\u5927\u7ea610 mg\u00b7cm-2<\/sup>\uff09\u7684\u77f3\u58a8\u8d1f\u6781\u6750\u6599\uff0c\u8be5\u65b9\u6cd5\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u7531\u4e8e\u8fd9\u6837\u4e00\u79cd\u7b80\u5355\u7684\u3001\u53ef\u6269\u5c55\u7684\u78c1\u53d6\u5411\u65b9\u6cd5\u9020\u6210\u7684\u4f4e\u5ea6\u626d\u66f2\u53ef\u4ee5\u5c06\u7535\u6781\u7684\u6bd4\u5bb9\u91cf\u57281 C\u500d\u7387\u4e0b\u63d0\u5347\u81f3\u65e0\u7ed3\u6784\u7535\u6781\u7684\u4e09\u500d\u4ee5\u4e0a\u3002\u8fd9\u9879\u7814\u5de5\u4f5c\u901a\u8fc7\u5bf9\u78c1\u6027\u5bf9\u9f50\u77f3\u58a8\u7535\u6781\u7684\u7814\u7a76\u63d0\u51fa\u4e86\u63d0\u5347\u7535\u6c60\u6027\u80fd\u7684\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Magnetically aligned graphite electrodes for high-rate performance Li-ion batteries<\/a> (Nat. Energy\uff0c2016\uff0cDOI: 10.1038\/nenergy.2016.97)<\/p>\n

2\u3001Adv. Mater.<\/strong>\u00a0<\/strong>\u77f3\u58a8\u70ef\u5939\u5728\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u7684\u4ecb\u5b54\u7ed3\u6784\u4e2d<\/strong><\/span><\/p>\n

\"fig2\"<\/p>\n

\u00a0 \u4e09\u7ef4V2<\/sub>O5<\/sub>@graphene@V2<\/sub>O5<\/sub>\u6b63\u6781\u4e09\u660e\u6cbb\u7ed3\u6784\u5236\u4f5c\u7684\u793a\u610f\u56fe<\/p>\n

\u968f\u7740\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u4e0e\u8f66\u8f86\u7535\u6c14\u5316\u7684\u53d1\u5c55\uff0c\u5bf9\u80fd\u91cf\u5b58\u50a8\u8bbe\u5907\u7684\u6539\u8fdb\u7684\u8981\u6c42\u4e0d\u65ad\u589e\u52a0\u3002\u4e3a\u4e86\u8fbe\u5230\u66f4\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u7535\u6781\u4e2d\u6d3b\u6027\u7269\u8d28\u7684\u4f53\u79ef\u5e94\u6700\u5927\u5316\uff0c\u76f8\u5e94\u5730\u7535\u5b50\u3001\u79bb\u5b50\u8fd0\u8f93\u901a\u9053\u6240\u5360\u7684\u4f53\u79ef\u5e94\u6700\u5c0f\u5316\u3002\u4f46\u662f\u8fd9\u6837\u4f1a\u5bfc\u81f4\u500d\u7387\u7b49\u6027\u80fd\u53d7\u5230\u5f71\u54cd\u3002<\/p>\n

\u6700\u8fd1\uff0c\u7f8e\u56fd\u4f0a\u5229\u8bfa\u4f0a\u5927\u5b66\u5384\u672c\u90a3-\u9999\u69df\u5206\u6821\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u7684Paul V. Braun\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5229\u7528\u7535\u6c89\u79ef\u6cd5\u3001\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\u7b49\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u4e0eV2<\/sub>O5<\/sub>\u6d3b\u6027\u6750\u6599\u7684\u4e09\u7ef4V2<\/sub>O5<\/sub>@graphene@V2<\/sub>O5<\/sub>\u7ed3\u6784\u3002\u5d4c\u5165\u9634\u6781\u7684\u4e09\u7ef4\u77f3\u58a8\u70ef\u7ed3\u6784\u63d0\u4f9b\u4e86\u826f\u597d\u7684\u5bfc\u7535\u6027\uff0c\u540c\u65f6\u77f3\u58a8\u70ef\u5728\u7535\u6781\u4e2d\u7684\u4f4e\u8d28\u91cf\u548c\u4f4e\u4f53\u79ef\u5206\u6570\u4f7f\u5f97\u6d3b\u6027\u6750\u6599V2<\/sub>O5<\/sub>\u7684\u4f53\u79ef\u4e0e\u8d28\u91cf\u5206\u6570\u8fbe\u5230\u4e86\u6700\u5927\u5316\u3002\u8fd9\u6837\u7684\u7ed3\u6784\u4f7f\u5f97\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff08442 mAh\u00b7g-1<\/sup>\uff09\u4ee5\u53ca\u8d85\u957f\u7684\u5faa\u73af\u5bff\u547d\uff08\u6b63\u6781\u5faa\u73af2000\u6b21\u4ee5\u4e0a\uff09\uff0c\u4ece\u800c\u8868\u660e\u7535\u6781\u7ed3\u6784\u4e2d\u5bfc\u7535\u6750\u6599\u4e0e\u6d3b\u6027\u6750\u6599\u9700\u8981\u6709\u5408\u7406\u7684\u6bd4\u4f8b\u3002<\/p>\n

\u8fd9\u9879\u7814\u7a76\u901a\u8fc7\u6d3b\u6027\u6750\u6599\u7684\u4e09\u7ef4\u5939\u5c42\u7ed3\u6784\u7684\u5236\u5907\u4f7f\u7535\u6c60\u6b63\u6781\u5177\u6709\u4e86\u826f\u597d\u7684\u6027\u80fd\uff0c\u4e3a\u6d3b\u6027\u7269\u8d28\u4e0e\u5bfc\u7535\u7ed3\u6784\u4e4b\u95f4\u7684\u51b2\u7a81\u63d0\u4f9b\u4e86\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Graphene Sandwiched Mesostructured Li-Ion Battery Electrodes<\/a>\uff08Adv. Mater., 2016, DOI:\u00a010.1002 \/adma.201600829\uff09<\/p>\n

3\u3001Angew. Chem. Int. Ed.<\/strong> \u6c27\u5316\u9530\u7eb3\u7c73\u7247\u5c42\u4e2d\u7684\u9633\u79bb\u5b50\u63d2\u5c42<\/strong>:<\/strong>\u5bf9\u9502\u548c\u94a0\u50a8\u80fd\u6027\u80fd\u7684\u5f71\u54cd<\/strong><\/span><\/p>\n

\"\u65e0\u6807\u98983\"<\/p>\n

\u4e09\u7ef4\u5c42\u72b6\u6c27\u5316\u9530\u6846\u67b6\u7684\u5236\u5907<\/p>\n

\u50a8\u80fd\u8bbe\u5907\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u9700\u8981\u663e\u8457\u6539\u8fdb\u7535\u6781\u7684\u6027\u80fd\u4ee5\u53ca\u8be6\u7ec6\u4e86\u89e3\u57fa\u672c\u7684\u80fd\u91cf\u5b58\u50a8\u8fc7\u7a0b\uff0c\u6240\u4ee5\u6b63\u6781\u6750\u6599\u7684\u5236\u5907\u6210\u4e3a\u4e86\u5173\u952e\u3002<\/p>\n

\u6700\u8fd1\uff0c\u5c71\u4e1c\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5b66\u5de5\u7a0b\u5b66\u9662\u7684\u9a6c\u539a\u4e49\u6559\u6388\u548c\u5f20\u8fdb\u6d9b\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u8bfe\u9898\u7ec4\u901a\u8fc7\u4e00\u79cd\u5e38\u89c4\u6709\u6548\u7684\u65b9\u6cd5\u5c06\u4e8c\u7ef4\u6c27\u5316\u9530\u7eb3\u7c73\u7247\u548c\u5404\u79cd\u91d1\u5c5e\u9633\u79bb\u5b50\u8fdb\u884c\u81ea\u7ec4\u88c5\uff0c\u4ece\u800c\u5f62\u6210\u5c42\u95f4\u8ddd\u53ef\u8c03\u7684\u4e09\u660e\u6cbb\u7ed3\u6784Mx<\/sub>MnO2<\/sub>\uff08M=Li\uff0cNa\uff0cK\uff0cCo\uff0cMg\uff09\u6b63\u6781\u6750\u6599\u3002\u6b64\u5916\uff0c\u8be5\u7814\u7a76\u5c0f\u7ec4\u8fd8\u8fdb\u884c\u4e86Li+<\/sup>\u3001Na+<\/sup>\u5728\u8be5\u7535\u6781\u4e2d\u50a8\u80fd\u6027\u80fd\u7814\u7a76\u3002\u5bf9\u4e8eLi+<\/sup>\u3001Na+<\/sup>\u7684\u50a8\u80fd\uff0c\u8fd9\u4e9b\u7535\u6781\u6750\u6599\u8868\u73b0\u51fa\u4e0d\u540c\u7684\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u5b58\u50a8\u8fc7\u7a0b\u7684\u6548\u7387\u4e0d\u4ec5\u53d7\u5c42\u95f4\u8ddd\u7684\u5f71\u54cd\uff0c\u4e5f\u53d7\u5185\u90e8\u9633\u79bb\u5b50\u548c\u7a7f\u68ad\u79bb\u5b50\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u7684\u5f71\u54cd\uff0c\u4ece\u800c\u8bc1\u5b9e\u4e86\u5176\u4e2d\u9633\u79bb\u5b50\u7684\u5173\u952e\u4f5c\u7528\u3002\u8fd9\u4e9b\u7ed3\u679c\u4e3a\u9502\u548c\u94a0\u50a8\u5b58\u7684\u5148\u8fdb\u7535\u6781\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u6709\u524d\u9014\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Cation Intercalation in Manganese Oxide Nanosheets: Effects on Lithium and Sodium Storage<\/a>\uff08Angew. Chem. Int. Ed., 2016, DOI:\u00a010.1002\/anie.201605102\uff09<\/p>\n

4\u3001Adv.\u00a0Energy Mater.:<\/strong>\u00a0\u00a0<\/strong>\u7531\u5305\u8986\u6709\u78b3\u5c42<\/strong>\/<\/strong>\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u7684\u91d1\u5c5e\u6c27\u5316\u7269\u7535\u6781\u7ec4\u6210\u7684\u9ad8\u6027\u80fd\u67d4\u6027\u56fa\u6001\u954d<\/strong>\/<\/strong>\u94c1\u7535\u6c60<\/strong><\/span><\/p>\n

\"fig4\"<\/p>\n

SEM\u56fe\u50cf\uff1aa\uff0cb\uff09\u5728\u78b3\u5c42\u4e0a\u7684\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08\u8bb0\u4e3aCC-CF\uff09c\uff0cd\uff09\u5728CC-CF\u4e0a\u751f\u957f\u7684Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u68d2\uff08\u8bb0\u4e3aCC-CF @ Fe3<\/sub>O4<\/sub>\uff09e\u2014g\uff09Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u68d2\u7684TEM\u56fe\u50cf<\/p>\n

\u7531\u4e8e\u6c34\u6027\u954d\/\u94c1\u7535\u6c60\u6210\u672c\u4f4e\u3001\u6bd2\u6027\u4f4e\u3001\u5b89\u5168\u6027\u9ad8\u3001\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u5176\u4f5c\u4e3a\u67d4\u6027\u50a8\u80fd\u88c5\u7f6e\u5177\u6709\u5f88\u5927\u7684\u6f5c\u529b\u3002\u7136\u800c\uff0c\u8f83\u5dee\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u954d\/\u94c1\u7535\u6c60\u7684\u9884\u671f\u4e2d\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5e76\u4e14\u91cd\u91d1\u5c5e\u57fa\u677f\u7684\u4f7f\u7528\u4e5f\u4e0d\u80fd\u6ee1\u8db3\u67d4\u6027\u8bbe\u5907\u7684\u57fa\u672c\u8981\u6c42\u3002<\/p>\n

\u6700\u8fd1\uff0c\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u7684Cao Guan\u535a\u58eb\u548cJohn Wang\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u8bfe\u9898\u7ec4\u5c06\u78b3\/\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u5305\u8986\u5728\u7535\u6781\u8868\u9762\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4ed6\u4eec\u5408\u7406\u5f00\u53d1\u4e86\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u529f\u7387\u5bc6\u5ea6\u7684\u67d4\u6027\u7c7b\u578b\u7684\u56fa\u6001\u954d\/\u94c1\u7535\u6c60\uff0c\u5229\u7528\u9488\u72b6Fe3<\/sub>O4<\/sub>\u548c\u7247\u72b6NiO\u4e0a\u5206\u522b\u76f4\u63a5\u751f\u957f\u5728\u78b3\u5e03\/\u78b3\u7eb3\u7c73\u7ea4\u7ef4\uff08CC\u2013CF\uff09\u57fa\u4f53\u4e0a\u4f5c\u4e3a\u8d1f\u6781\u548c\u6b63\u6781\u3002\u5206\u5c42\u7684CC\u2013CF\u57fa\u677f\u5177\u6709\u9ad8\u5bfc\u7535\u6027\u548c\u826f\u597d\u7684\u67d4\u6027\uff0c\u53ef\u4f5c\u4e3aFe3<\/sub>O4<\/sub>\u548cNiO\u7eb3\u7c73\u6676\u6d3b\u6027\u6750\u6599\u7406\u60f3\u7684\u652f\u6491\u6750\u6599\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u7f13\u51b2\u6750\u6599\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u4f53\u79ef\u53d8\u5316\u4ece\u800c\u63d0\u5347\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5229\u7528\u51dd\u80f6\u7535\u89e3\u8d28\u5c06\u5b83\u4eec\u7ec4\u88c5\u4e00\u4e2a\u6027\u80fd\u5f3a\u5927\u7ed3\u6784\u7075\u6d3b\u7684\u51c6\u56fa\u6001\u7684\u954d\/\u94c1\u7535\u6c60\u3002\u8be5\u7535\u6c60\u5c55\u793a\u51fa\u4e86\u6781\u4f73\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u4f8b\u5982\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff085.2 mWh\u00b7cm-3<\/sup>\uff0c94.5 Wh\u00b7Kg\u2212<\/sup>1<\/sup>\uff09\uff0c\u9ad8\u529f\u7387\u5bc6\u5ea6\uff080.64 W\u00b7cm\u2212<\/sup>3<\/sup>\uff0c11.8 kW\u00b7kg\u2212<\/sup>1<\/sup>\uff09\uff0c\u4ee5\u53ca\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u8fd9\u9879\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5177\u6709\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u673a\u68b0\u7075\u6d3b\u6027\u7684\u56fa\u6001\u78b1\u6027\u7535\u6c60\u7684\u4f8b\u5b50\uff0c\u4f7f\u672a\u6765\u7684\u67d4\u6027\u7535\u5b50\u8bbe\u5907\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>High-Performance Flexible Solid-State Ni\/Fe Battery Consisting of Metal Oxides Coated Carbon Cloth\/Carbon Nanofiber Electrodes<\/a> \uff08Adv.\u00a0Energy Mater., 2016,\u00a0DOI:\u00a010.1002\/aenm.201601034\uff09<\/p>\n

5\u3001Adv.\u00a0Energy Mater.\u00a0<\/strong>\u7eb3\u7c73\u5c3a\u5ea6\u4e0b\u4f7f\u7528\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u7684<\/strong>Li2<\/sub>S\/S<\/strong>\u76f8\u5728\u56fa\u6001\u9502\u786b\u7535\u6c60\u7535\u5316\u5b66\u5d4c\u9502\u8fc7\u7a0b\u4e2d\u7684\u76f8\u5206\u79bb\u8fc7\u7a0b<\/strong><\/span><\/p>\n

\"\u65e0\u6807\u98986\"<\/p>\n

\u56fa\u6001Li-S\u7535\u6c60\u7535\u5316\u5b66\u673a\u7406\u7684\u793a\u610f\u56fe
\na\uff09\u5e26\u6709\u78b3\u6d82\u5c42\u7684\u539f\u59cb\u6837\u54c1 b\uff09S\u548cLi2<\/sub>S\u5728\u9502\u5316\u8fc7\u7a0b\u7684\u65e9\u671f\u9636\u6bb5\u7684\u76f8\u5206\u79bb
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\u867d\u7136\u5728\u5145\u7535\u7535\u6c60\u4e2d\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u5f88\u9ad8\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4f46\u662f\u5176\u6027\u80fd\u8fd8\u662f\u4e0d\u80fd\u6ee1\u8db3\u76ee\u524d\u6c7d\u8f66\u3001\u7535\u5b50\u8bbe\u5907\u7b49\u5bf9\u7535\u6c60\u80fd\u91cf\u5bc6\u5ea6\u65e5\u76ca\u589e\u957f\u7684\u9700\u6c42\u3002\u786b\u4f5c\u4e3a\u7535\u6c60\u6b63\u6781\u6750\u6599\u5176\u80fd\u91cf\u5bc6\u5ea6\u6bd4\u666e\u901a\u6750\u6599\u9ad85\u500d\uff0c\u540c\u65f6\u786b\u8fd8\u5177\u6709\u65e0\u6bd2\u3001\u4f4e\u6210\u672c\u7b49\u4f18\u70b9\u3002Li-S\u7535\u6c60\u5728\u76ee\u524d\u5df2\u63a5\u8fd1\u5b83\u4eec\u7684\u7406\u8bba\u5bb9\u91cf\uff0c\u4f46\u662f\u4f7f\u7528\u786b\u7684\u7535\u6781\u6709\u5bfc\u7535\u6027\u4f4e\u3001\u786b\u6613\u53d1\u751f\u81a8\u80c0\u7b49\u7f3a\u70b9\u3002\u6240\u4ee5\u7814\u7a76Li-S\u7535\u6c60\u7535\u6781\u7684\u5fae\u89c2\u7ed3\u6784\u4e0e\u5145\u653e\u7535\u6027\u80fd\u6210\u4e86\u5173\u952e\u3002<\/p>\n

\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u7684\u8c37\u6797\u6559\u6388\u548c\u80e1\u52c7\u80dc\u6559\u6388\u8bfe\u9898\u7ec4\u4ee5\u53ca\u6c99\u7279\u963f\u62c9\u4f2f\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\u7269\u7406\u79d1\u5b66\u4e0e\u5de5\u7a0b\u90e8\u7684Xixiang Zhang\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u8bfe\u9898\u7ec4\u901a\u8fc7\u539f\u4f4d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u7b2c\u4e00\u6b21\u5728\u56fa\u6001Li-S\u7535\u6c60\u4e2d\u89c2\u5bdf\u5230\u7eb3\u7c73\u5c3a\u5ea6\u7684S\/Li2<\/sub>S\u76f8\u5206\u79bb\u8fc7\u7a0b\u3002\u8fd9\u4e2a\u7eb3\u7c73\u76f8\u5206\u79bb\u8fc7\u7a0b\u4e0d\u4ec5\u964d\u4f4e\u4e86\u79bb\u5b50\u7684\u6269\u6563\u8ddd\u79bb\uff0c\u540c\u65f6\u4e5f\u4e3aS \/ Li2<\/sub>S\u63d0\u4f9b\u4e86\u754c\u9762\u7f51\u7edc\uff0c\u8fd9\u6709\u5229\u4e8e\u9502\u5316\u8fc7\u7a0b\u4e2d\u7535\u5b50\u548c\u9502\u79bb\u5b50\u7684\u8fc1\u79fb\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\u4e86\u56fa\u6001\u9502\u786b\u7535\u6c60\u7684\u76f8\u5206\u79bb\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u5728\u4ecb\u8d28\u4e2d\u7684\u8fc1\u79fb\u7387\u63d0\u9ad8\uff0c\u6709\u5229\u4e8e\u7535\u6c60\u6027\u80fd\u7684\u63d0\u9ad8\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Phase Separation of Li2S\/S at Nanoscale during Electrochemical Lithiation of the Solid-State Lithium\u2013Sulfur Battery Using In Situ TEM<\/a> (Adv.\u00a0Energy Mater.,\u00a02016,\u00a0DOI:\u00a010.1002\/aenm.201600806)<\/p>\n

6\u3001Adv.\u00a0Energy Mater. \u5177\u6709\u8f74\u5bf9\u79f0\u67b6\u6784\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8fc7\u5145\u4fdd\u62a4\u6c27\u5316\u8fd8\u539f\u68ad<\/strong><\/span><\/p>\n

\"\u65e0\u6807\u98981\"<\/p>\n

\u00a0 TDTN\u548cTTBN\u7684\u5408\u6210\u65b9\u6cd5<\/p>\n

1,4-\u4e8c\u7532\u6c27\u57fa\u82ef\u884d\u751f\u7269\u662f\u8fc4\u4eca\u4e3a\u6b62\u6700\u597d\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8fc7\u5145\u4fdd\u62a4\u7684\u6c27\u5316\u8fd8\u539f\u68ad\u6dfb\u52a0\u5242\u3002\u8fd9\u79cd\u884d\u751f\u7269\u6700\u8010\u7528\u7684\u5206\u5b50\u4e00\u822c\u5177\u6709\u4e24\u4e2a\u7532\u6c27\u57fa\u5e73\u9762\uff0c\u5b83\u4eec\u7531\u4e8e\u53cd\u6f14\u5bf9\u79f0\u6027\u800c\u7b49\u6548\u3002\u7136\u800c\uff0c\u8fd9\u6837\u7684\u51e0\u4f55\u5f62\u72b6\u5bfc\u81f4\u4e00\u4e2a\u5e73\u5747\u5076\u6781\u77e9\u6d88\u5931\uff0c\u4ece\u800c\u4f7f\u8fd9\u4e9b\u5206\u5b50\u5728\u78b3\u9178\u916f\u57fa\u7535\u89e3\u8d28\u4e2d\u7684\u6eb6\u89e3\u5ea6\u4f4e\u3002\u5728\u8fd9\u9879\u7814\u7a76\u4e2d\uff0c\u4ecb\u7ecd\u4e86\u4e00\u79cd\u65b0\u7684\u6c27\u5316\u8fd8\u539f\u5242\uff0c\u5176\u514b\u670d\u4e86\u6eb6\u89e3\u5ea6\u4f4e\u7684\u7f3a\u70b9\u3002<\/p>\n

\u6700\u8fd1\uff0c\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u7684Zhengcheng Zhang\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u5408\u6210\u4e86\u65b0\u7684\u6c27\u5316\u8fd8\u539f\u6dfb\u52a0\u52421,2,3,4 – tetrahydro – 6,7 – dimethoxy – 1,1,4,4 – tetramethyl-naphthalene\uff08TDTN\uff09\u3002\u5b83\u5df2\u88ab\u8bc1\u660e\u80fd\u57284.05 V\u7535\u538b\uff08vs. Li+\/Li\uff09\u4e0b\u8fdb\u884c\u53ef\u9006\u6c27\u5316\uff0c\u4e14\u5177\u6709\u9ad8\u6781\u6027\u3001\u9ad8\u6eb6\u89e3\u5ea6\uff08\u7ea60.4 M\uff09\u4ee5\u53ca\u826f\u597d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u5728C\/2\u500d\u7387\u3001100%\u8fc7\u5145\u7684\u60c5\u51b5\u4e0b\u53ef\u8fdb\u884c150\u6b21\u8fc7\u5145\u5faa\u73af\uff09\u7684\u7279\u70b9\u90fd\u53ef\u4ee5\u901a\u8fc7\u7531\u7535\u6c60\u4e2dTDTN\u7684\u7535\u5316\u5b66\u6c27\u5316\u4ea7\u751f\u9633\u79bb\u5b50\u81ea\u7531\u57fa\u7684\u8f74\u5bf9\u79f0\u7ed3\u6784\u800c\u5b9e\u73b0\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u5229\u7528\u78c1\u5171\u632f\u5149\u8c31\u548c\u7535\u5b50\u7ed3\u6784\u5efa\u6a21\u6765\u7814\u7a76\u9633\u79bb\u5b50\u81ea\u7531\u57fa\u7684\u5bf9\u79f0\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u4e4b\u95f4\u590d\u6742\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u8fd9\u9879\u5de5\u4f5c\u63d0\u9ad8\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u8fc7\u5145\u4fdd\u62a4\u6c27\u5316\u8fd8\u539f\u5242\u7684\u6eb6\u89e3\u5ea6\uff0c\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Redox Shuttles with Axisymmetric Scaffold for Overcharge Protection of Lithium- Ion Batteries<\/a> \uff08Adv.\u00a0Energy Mater., 2016,\u00a0<\/strong>DOI:\u00a010.1002\/aenm.201600795\uff09<\/p>\n

7\u3001Adv.\u00a0Funct.\u00a0Mater.<\/strong>\u00a0\u7528\u4e8e\u73af\u4fdd\u7684\u9502\u79bb\u5b50\u7535\u6c60\u7684\u751f\u7269\u884d\u751f\u805a\u5408\u7269<\/strong><\/span><\/p>\n

\"\u65e0\u6807\u98982\"<\/p>\n

\u5f00\u73af\u6613\u4f4d\u805a\u5408\u6210P3\u7684\u793a\u610f\u56fe<\/p>\n

\u968f\u7740\u5bf9\u4fbf\u643a\u5f0f\u7535\u5b50\u8bbe\u5907\u548c\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\u7684\u9700\u6c42\u6301\u7eed\u589e\u957f\uff0c\u6211\u4eec\u5fc5\u987b\u5f00\u53d1\u51fa\u91cd\u91cf\u8f7b\uff0c\u5177\u6709\u6210\u672c\u6548\u76ca\uff0c\u5e76\u53ef\u4ee5\u7531\u73af\u5883\u53cb\u597d\u6750\u6599\u5236\u9020\u7684\u80fd\u91cf\u5b58\u50a8\u6280\u672f\u3002\u591a\u6570\u56fd\u5bb6\u6700\u5148\u8fdb\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u4f7f\u7528\u7684\u662f\u8fc7\u6e21\u91d1\u5c5e\u6750\u6599\uff0c\u8fd9\u5c31\u9700\u8981\u80fd\u6e90\u5bc6\u96c6\u578b\u7684\u52a0\u5de5\u4ee5\u53ca\u5bf9\u73af\u5883\u6709\u5bb3\u7684\u63d0\u53d6\u65b9\u6cd5\u3002\u6b64\u5916\uff0c\u9502\u7535\u6c60\u5927\u7ea630%\u7684\u6210\u672c\u5f52\u56e0\u4e8e\u6b63\u6781\u6750\u6599\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u51fa\u53ef\u6301\u7eed\u53d1\u5c55\u4e14\u6ce8\u91cd\u6210\u672c\u6548\u76ca\u7684\u80fd\u6e90\u5b58\u50a8\u8bbe\u5907\u5341\u5206\u5173\u952e\u3002<\/p>\n

\u6700\u8fd1\uff0c\u591a\u4f26\u591a\u5927\u5b66\u5316\u5b66\u7cfb\u7684Dwight S. Seferos\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4\u7814\u7a76\u4e86\u751f\u7269\u884d\u751f\u7684\u6709\u673a\u5206\u5b50\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u4e00\u79cd\u534a\u5408\u6210\u7684\u65b9\u6cd5\u5408\u6210\u4e86\u6709\u673a\u805a\u5408\u7269P3\u7136\u540e\u4e0e\u70ad\u9ed1\uff08CB\uff09\u4e00\u8d77\u5747\u5300\u6d82\u8986\u5728\u7535\u6781\u8868\u9762\u3002\u6b64\u5916\uff0c\u4ed6\u4eec\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86\u6d82\u8986\u6709\u805a\u5408\u7269\u7684\u7535\u6781\u7684\u5bb9\u91cf\u3001\u5faa\u73af\u7279\u6027\u7b49\uff0c\u53d1\u73b0\u8be5\u805a\u5408\u7269\u4e0e\u70ad\u9ed1\u901a\u8fc7\u5f62\u6210\u5206\u5c42\u7ed3\u6784\u4f7f\u7535\u8377\u4f20\u8f93\u5927\u5927\u63d0\u9ad8\uff0c\u5bf9\u80fd\u5e94\u7528\u4e8e\u4e00\u822c\u805a\u5408\u7269\u7535\u6781\u7684\u964d\u89e3\u673a\u5236\u6709\u4e86\u66f4\u6df1\u5165\u7684\u8ba4\u8bc6\u3002\u88c5\u6709\u8fd9\u79cd\u805a\u5408\u7269\u7535\u6781\u7684\u7535\u6c60\u5de5\u4f5c\u7535\u4f4d\u7ea6\u4e3a5 V\uff0c\u5176\u5bb9\u91cf\u8fbe\u5230\u4e86125 mAh\u00b7g-1<\/sup>\uff0c\u4ece\u800c\u8868\u660e\u751f\u7269\u884d\u751f\u805a\u5408\u7269\u5728\u7535\u6781\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u751f\u7269\u884d\u751f\u805a\u5408\u7269\u5728\u53ef\u6301\u7eed\u3001\u9ad8\u6027\u80fd\u7684\u9502\u79bb\u5b50\u7535\u6c60\u4e0a\u4f7f\u7528\u63d0\u4f9b\u4e86\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Bio-Derived Polymers for Sustainable Lithium-Ion Batteries<\/a>\uff08Adv. Funct. Mater,\u00a02016,\u00a0DOI:\u00a010.1002\/adfm.201602114\uff09<\/p>\n

8\u3001\u00a0Adv. Funct. Mater. \u7845\u7eb3\u7c73\u9897\u7c92\u5728\u5355\u5c42\u77f3\u58a8\u6ce1\u6cab\u4e2d\u5206\u5c42\u6392\u5e03\uff0c\u50a8\u7535\u6027\u80fd\u5f97\u5230\u63d0\u9ad8<\/strong><\/span><\/p>\n

\"adfm201602324-fig-0006\"\u4f7fSi NPs\u5728GF\u4e2d\u5206\u5c42\u6392\u5e03\u7684\u5408\u6210\u8fc7\u7a0b<\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u5177\u6709\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u6210\u672c\u4f4e\u3001\u6301\u4e45\u6027\u597d\u7b49\u4f18\u70b9\uff0c\u4f46\u7535\u6781\u6750\u6599\u635f\u574f\u548c\u7535\u63a5\u89e6\u635f\u8017\u4f1a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u91d1\u5c5e\u9633\u6781\u6027\u80fd\u52a3\u5316\u3002<\/p>\n

\u6700\u8fd1\uff0c\u4e4c\u666e\u8428\u62c9\u5927\u5b66\u3001\u897f\u5317\u5de5\u4e1a\u5927\u5b66\u7684\u9a6c\u8d8a\u3001\u4e4c\u666e\u8428\u62c9\u5927\u5b66\u7684Kristina Edstr\u00f6m\u548c\u7279\u62c9\u534e\u5927\u5b66\u7684Bingqing Wei\uff08\u5171\u540c\u901a\u8baf\uff09\u7b49\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u51b7\u51bb\u5e72\u71e5\u6cd5\uff0c\u5229\u7528Na-CMC\u805a\u5408\u7269\u7684\u6c22\u952e\u4f5c\u7528\uff0c\u5bf9\u7845\u7eb3\u7c73\u9897\u7c92\uff08Si NPs\uff09\u7684\u754c\u9762\u8fdb\u884c\u6539\u6027\uff0c\u4f7f\u7845\u7eb3\u7c73\u9897\u7c92\uff08Si NPs\uff09\u5728\u5355\u5c42\u77f3\u58a8\u6ce1\u6cab\uff08GF\uff09\u4e2d\u5206\u5c42\u6392\u5e03\u3002\u8fd9\u79cd\u6750\u6599\u4f5c\u4e3a\u65e0\u7c98\u7ed3\u5242\u7684\u9633\u6781\u4f7f\u7528\u65f6\uff0c\u8868\u73b0\u51fa\u826f\u597d\u7684\u5468\u671f\u6027\u80fd\uff0c\u50a8\u9502\u6027\u80fd\u4e5f\u5f97\u5230\u63d0\u9ad8\u3002\u53e6\u5916\uff0c\u4ed6\u4eec\u5c06\u7eb3\u7c73\u7ea4\u7ef4\u7d20\u819c\uff08NCM\uff09\u548cGF\/Si\u6574\u5408\uff0c\u5408\u6210\u53ef\u4f5c\u4e3a\u7535\u6781\u7684GF\/Si-NCM\u590d\u5408\u819c\u3002\u8fd9\u79cd\u53ef\u968f\u610f\u5f2f\u66f2\u3001\u7075\u6d3b\u3001\u8f7b\u8d28\u7684\u65e0\u91d1\u5c5e\u7535\u6781\uff0c\u5728\u67d4\u6027\u50a8\u80fd\u65b9\u9762\u6709\u7740\u6f5c\u5728\u7684\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n

\u6587\u732e\u8fde\u63a5\uff1a<\/strong>Constraining Si Particles within Graphene Foam Monolith: Interfacial Modification for High-Performance Li+Storage and Flexible Integrated Configuration<\/a>\uff08Adv. Funct. Mater.\uff0c2016\uff0cDOI:10.1002\/adfm.201602324\uff09<\/p>\n

\u8be5\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4 charles \u00a0\u4f9b\u7a3f\uff0c\u80cc\u9006\u65f6\u5149 \u5ba1\u6838\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\uff0c\u82e5\u60f3\u53c2\u4e0e\u65b0\u80fd\u6e90\u6587\u732e\u89e3\u8bfb\u548c\u6587\u732e\u6c47\u603b\u3001\u65b0\u80fd\u6e90\u77e5\u8bc6\u79d1\u666e\u548c\u6df1\u5ea6\u6316\u6398\u65b0\u80fd\u6e90\u5b66\u672f\u4ea7\u4e1a\u4fe1\u606f\uff0c\u8bf7\u52a0qq 2728811768\u3002<\/p>\n

\u6b22\u8fce\u5404\u5927\u8bfe\u9898\u7ec4\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/p>\n","protected":false},"excerpt":{"rendered":"

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