{"id":35206,"date":"2016-08-23T08:00:05","date_gmt":"2016-08-23T00:00:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=35206"},"modified":"2016-09-01T21:41:07","modified_gmt":"2016-09-01T13:41:07","slug":"adv-mater-%e8%8b%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e4%bd%95%e8%80%80%e6%95%99%e6%8e%88%ef%bc%9a%e6%b0%b4%e5%88%86%e6%95%a3%e8%8d%a7%e5%85%89%e7%a1%85%e7%ba%b3%e7%b1%b3%e9%a2%97%e7%b2%92%e5%8f%8a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=35206","title":{"rendered":"Adv. Mater. \u82cf\u5dde\u5927\u5b66\u4f55\u8000\u6559\u6388\uff1a\u6c34\u5206\u6563\u8367\u5149\u7845\u7eb3\u7c73\u9897\u7c92\u53ca\u5176\u5149\u5b66\u5e94\u7528"},"content":{"rendered":"

\u3010\u80cc\u666f\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u5757\u4f53\u7684\u7845\u53ea\u80fd\u53d1\u51fa\u5f88\u5f31\u7684\u8367\u5149\uff0c\u4f46\u662f\u5f53\u5c3a\u5bf8\u8fbe\u5230\u7eb3\u7c73\u7ea7\u7684\u65f6\u5019\uff0c\u7531\u4e8e\u91cf\u5b50\u9650\u5236\u6548\u5e94\uff0c\u7845\u7eb3\u7c73\u9897\u7c92\uff08SiNPs\uff09\u4f1a\u53d1\u51fa\u5f88\u5f3a\u7684\u8367\u5149\uff0c\u81ea1990\u5e74\u53d1\u73b0\u8367\u5149\u591a\u5b54\u7845\u8d77\uff0c\u5bf9\u8367\u5149\u7845\u7eb3\u7c73\u9897\u7c92\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u8fdb\u6b65\u3002<\/p>\n

SiNPs\u6709\u51e0\u4e2a\u72ec\u7279\u7684\u4f18\u70b9\uff0c\u5305\u62ec\u8d44\u6e90\u4e30\u5bcc\u3001\u4ef7\u683c\u4fbf\u5b9c\u3001\u5bf9\u4eba\u4f53\u65e0\u6bd2\u6216\u4f4e\u6bd2\u7b49\uff0c\u4f46\u662f\u5927\u91cf\u5236\u5907\u9ad8\u8d28\u91cf\u7684SiNPs\u4ecd\u662f\u5236\u7ea6\u5176\u5149\u5b66\u5e94\u7528\u7684\u4e3b\u8981\u539f\u56e0\u3002\u65b0\u5408\u6210\u7684SiNPs\u8868\u9762\u662fSi-H\u952e\uff0cSi-H\u9047\u6c34\u4f1a\u751f\u6210Si-OH\u548cSi-O-Si\u952e\uff0c\u5728\u9ad8\u6e29\u6216\u8005\u8f90\u5c04\u4e0b\u8fd8\u6709\u53ef\u80fd\u88ab\u6c27\u5316\uff0c\u4ece\u800c\u4f7fSiNPs\u7684\u8367\u5149\u6027\u80fd\u6539\u53d8\u6216\u6076\u5316\u3002<\/p>\n

\u6700\u8fd1\uff0c\u82cf\u5dde\u5927\u5b66\u4f55\u8000\u6559\u6388\u8bfe\u9898\u7ec4\u8ba8\u8bba\u4e86\u5728\u5236\u5907SiNPs\u4e0a\u53d6\u5f97\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5c24\u5176\u662f\u5728\u6c34\u6eb6\u6db2\u4e2d\u5236\u5907\u5206\u6563SiNPs\u7684\u65b9\u6cd5\uff0c\u5e76\u4e14\u4ecb\u7ecd\u4e86\u5b83\u4eec\u5728\u751f\u7269\u6210\u50cf\u4e0e\u4f20\u611f\u65b9\u9762\u7684\u5e94\u7528<\/strong>\u3002<\/p>\n

\u3010SiNPs\u7684\u5236\u5907\u65b9\u6cd5\u3011
\n<\/strong>
\n\u5236\u5907SiNPs\u7684\u5e38\u7528\u65b9\u6cd5\u5305\u62ec\u6db2\u76f8\u8fd8\u539f\u3001\u5fae\u4e73\u6db2\u3001\u6fc0\u5149\u5206\u89e3\u3001\u7535\u5316\u5b66\/\u5316\u5b66\u8150\u8680\u7b49\uff0c\u4f46\u662f\u8fd9\u4e9b\u65b9\u6cd5\u5236\u5907\u7684SiNPs\u4e0d\u7a33\u5b9a\uff0c\u5e76\u4e14\u5728\u5e38\u7528\u7684\u6eb6\u5242\u4e2d\u4e0d\u6613\u5206\u6563\u3002\u4e3a\u4e86\u589e\u5f3aSiNPs\u7684\u7a33\u5b9a\u6027\u53ca\u5206\u6563\u6027\uff0c\u901a\u5e38\u8981\u5bf9\u5176\u8fdb\u884c\u8868\u9762\u6539\u6027\uff0c\u5982\u7528\u805a\u4e19\u70ef\u9178\u3001\u4e19\u70ef\u9178\u3001\u4e19\u70ef\u80fa\u7b49\u6765\u4fee\u9970\u3002\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u5305\u62ec\u4e24\u6b65\uff1a\u5373\u5148\u5408\u6210SiNPs\uff0c\u518d\u8fdb\u884c\u8868\u9762\u6539\u6027\uff0c\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u8fd1\u51e0\u5e74\u5174\u8d77\u4e86\u5728\u6db2\u76f8\u4e2d\u76f4\u63a5\u5408\u6210\u7a33\u5b9aSiNPs\u7684\u7814\u7a76\u3002<\/p>\n

\u5728\u6db2\u76f8\u4e2d\u76f4\u63a5\u5408\u6210SiNPs\u662f\u6307\u5c06\u542bSi\u7684\u6709\u673a\u524d\u9a71\u4f53\u6eb6\u89e3\u5728\u6eb6\u6db2\u4e2d\uff0c\u5728\u5fae\u6ce2\u7684\u8f90\u5c04\u4e0b\u76f4\u63a5\u751f\u6210\u7a33\u5b9a\u7684\u3001\u5206\u6563\u7684SiNPs\u30022015\u5e74\uff0c\u5229\u7528\u7845\u85fb\u5355\u7ec6\u80de\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u5728\u5fae\u6ce2\u7684\u8f90\u5c04\u4e0b\uff0c\u79d1\u5b66\u5bb6\u5f97\u5230\u4e86\u53d1\u7ea2\u5149\u7684SiNPs\uff08\u56fe1A\uff09\uff0c\u8fd9\u79cdSiNPs\u5177\u6709\u826f\u597d\u7684\u7ed3\u6676\u6027\u548c\u5206\u6563\u6027\uff0c\u5e76\u4e14\u53d1\u5c04\u5cf0\u7684\u534a\u9ad8\u5bbd\u53ea\u670930nm\uff0c\u662f\u6240\u6709\u62a5\u5bfc\u7684SiNPs\u4e2d\u6700\u4f4e\u7684\u3002\u6700\u8fd1\uff0cZhong\u7b49\u4eba\u8fd8\u62a5\u5bfc\u4e86\u4e00\u79cd\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u5236\u5907\u53d1\u4e0d\u540c\u8367\u5149\u7684SiNPs\u7684\u65b9\u6cd5\uff0c\u53ea\u9700\u5c06Si\u524d\u9a71\u4f53APTMS\u548c\u8fd8\u539f\u5242\u6df7\u5408\u518d\u7528\u7d2b\u5916\u7ebf\u8f90\u5c04\u4e0d\u540c\u7684\u65f6\u95f4\uff0c\u5c31\u80fd\u5f97\u5230\u53d1\u84dd\u5149\u3001\u7eff\u5149\u6216\u8005\u6d45\u7eff\u5149\u7684SiNPs\uff08\u56fe1B\uff09\u3002<\/p>\n

\"\u56fe\u72471\"<\/p>\n

\u56fe1 <\/strong>\uff08A\uff09\u7528\u7845\u85fb\u5355\u7ec6\u80de\u524d\u9a71\u4f53\u5236\u5907SiNPs\u7684\u793a\u610f\u56fe\uff08\u4e0a\uff09\uff1b\u7845\u85fb\u524d\u9a71\u4f53\u6eb6\u6db2\uff08\u5de6\uff09\u548cSiNPs\u6eb6\u6db2\uff08\u53f3\uff09\u7684\u5149\u5b66\u548cTEM\u7167\u7247\uff08\u4e2d\uff09\uff1bSiNPs\u548c\u4ece\u7845\u85fb\u4e2d\u63d0\u53d6\u7684\u53f6\u7eff\u7d20\u7684\u4eb2\u6c34\u6027\uff08\u5de6\uff09\uff0c\u7528\u4e0d\u540c\u65b9\u6cd5\u5236\u5907\u7684SiNPs\u4ee5\u53ca\u7845\u85fb\u7684\u8367\u5149\u5149\u8c31\uff08\u53f3\uff09\uff08\u4e0b\uff09\uff1b\uff08B\uff09\u5408\u6210SiNPs\u7684\u793a\u610f\u56fe\uff08\u4e0a\uff09\uff1bSiNPs\u7684TEM\u548cHRTEM\u56fe\u7247\uff08\u4e2d\uff09\uff1b10g\u7eff\u5149SiNPs\u6eb6\u89e3\u57281L\u6eb6\u6db2\u4e2d\u5e76\u7528365nm\u6fc0\u5149\u7167\u5c04\u7684\u56fe\u7247\uff08\u5de6\uff09\u4ee5\u53caSiNPs\u7684UV-PL\u5149\u8c31\uff08\u53f3\uff09\uff08\u4e0b\uff09\u3002<\/p>\n

\u3010SiNPs\u7684\u5149\u5b66\u5e94\u7528\u3011
\n<\/strong>
\n1\u3001\u751f\u7269\u6210\u50cf
\n<\/strong>
\n\u7531\u4e8e\u5176\u65e0\u6bd2\u6216\u8005\u4f4e\u6bd2\u6027\uff0cSiNPs\u975e\u5e38\u9002\u5408\u7528\u6765\u8fdb\u884c\u751f\u7269\u6210\u50cf\uff0c\u5c24\u5176\u662f\u957f\u671f\u548c\u5b9e\u65f6\u751f\u7269\u6210\u50cf\u3002\u5bf9SiNPs\u6210\u50cf\u7684\u7814\u7a76\u53ef\u4ee5\u5206\u4e3a\u51e0\u4e2a\u9636\u6bb5\uff0c2004-2010\u662f\u521d\u59cb\u9636\u6bb5\uff0c\u8fd9\u4e2a\u9636\u6bb5\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u8bc1\u660eSiNPs\u80fd\u7528\u4e8e\u751f\u7269\u6210\u50cf\uff1b2011-2013\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u63d0\u9ad8SiNPs\u7684\u8d28\u91cf\uff1b\u6700\u8fd1\u5229\u7528SiNPs\u8fdb\u884c\u591a\u989c\u8272\u6210\u50cf\u53d6\u5f97\u8fdb\u5c55\uff0c Wu\u7b49\u4eba\u8bc1\u660e\u53ef\u4ee5\u5229\u7528\u84dd\u5149\u548c\u7ea2\u5149SiNPs\u8fdb\u884c\u53cc\u989c\u8272\u6210\u50cf\uff08\u56fe2A\uff09\u3002<\/p>\n

\u9664\u4e86\u86cb\u767d\u8d28\uff0c\u8fd8\u53ef\u4ee5\u7528\u5c0f\u5206\u5b50\uff08\u5982\u6c28\u57fa\u9178\u3001\u80bd\u3001\u5355\u7cd6\uff09\u6765\u4fee\u9970SiNPs\uff0c\u4f7f\u5176\u5177\u6709\u9776\u5411\u529f\u80fd\uff0c\u4ece\u800c\u5bf9\u7ec6\u80de\u8fdb\u884c\u9009\u62e9\u6027\u6210\u50cf\u3002\u53e6\u5916\uff0c\u6700\u8fd1\u51e0\u5e74\uff0c\u5355\u5206\u5b50\u6210\u50cf\u548c\u53cc\u5149\u5b50\u6fc0\u53d1\u8367\u5149\u6210\u50cf\u4e5f\u51fa\u73b0\u5728\u62a5\u5bfc\u4e0a\u3002<\/p>\n

\"\u56fe\u72472\"<\/p>\n

\u56fe2 <\/strong>\uff08A\uff09\u7528SiNPs\u8fdb\u884c\u53cc\u989c\u8272\u6210\u50cf\u3002\u7ec6\u80de\u6838\u548c\u5fae\u7ba1\u5206\u522b\u88ab\u84dd\u5149\u548c\u7ea2\u5149SiNPs\u6807\u8bb0\uff08\u4e0a\uff0c\u4e2d\uff09\uff1b\u80a0\u9053\u4e2d\u7684\u4e0d\u540c\u90e8\u5206\u88ab\u67d3\u6210\u4e0d\u540c\u7684\u989c\u8272\uff08\u4e0b\uff09\uff1b\uff08B\uff09U87MG\u7ec6\u80de\u7528\u4e0d\u540cSiNPs\u57f9\u517b\u7684\u8367\u5149\u56fe\uff08\u4e0a\uff09\uff0c\u7528SiNPs-RGD\u57f9\u517b\u4e0d\u540c\u65f6\u95f4\u7684\u8367\u5149\u56fe\uff08\u4e0b\uff09\uff1b\uff08C\uff09\u8bc1\u660eSiNPs\u80fd\u88ab\u9009\u62e9\u6027\u5438\u6536<\/p>\n

2\u3001\u4f20\u611f
\n<\/strong>
\nSiNPs\u80fd\u7528\u505a\u4f20\u611f\u5668\u4e3b\u8981\u662f\u7531\u4e8eSiNPs\u9047\u5230\u67d0\u4e9b\u5206\u5b50\u4f1a\u4ea7\u751f\u8367\u5149\u731d\u706d\uff0c\u4f7f\u5f97SiNPs\u7684\u8367\u5149\u5f3a\u5ea6\u51cf\u5f31\u3002\u6bd4\u5982\u8bf4H2O2\u80fd\u6355\u83b7SiNPs\u4ea7\u751f\u7684\u5149\u6fc0\u7535\u5b50\uff0c\u4f7f\u5176\u4e0d\u80fd\u4e0e\u7a7a\u7a74\u590d\u5408\u800c\u53d1\u5149\uff0c\u5229\u7528\u8fd9\u4e2a\u539f\u7406\u53ef\u4ee5\u68c0\u6d4b\u8461\u8404\u7cd6\uff08\u88ab\u9176\u6c27\u5316\u751f\u6210H2O2\uff09\u6216\u8005\u679c\u852c\u4e2d\u6b8b\u7559\u519c\u836f\u7684\u6d53\u5ea6\uff08\u519c\u836f\u53ef\u4ee5\u6291\u5236H2O2\u7684\u4ea7\u751f\uff09\uff1b\u4ea7\u751f\u8367\u5149\u731d\u706d\u7684\u53e6\u4e00\u6761\u9014\u5f84\u662f\u5728SINPs\u8868\u9762\u8986\u76d6\u4e00\u5c42\u590d\u5408\u7269\uff0c\u590d\u5408\u7269\u7684\u5438\u6536\u5149\u8c31\u4e0eSiNPs\u7684\u53d1\u5c04\u5149\u8c31\u76f8\u4e92\u91cd\u53e0\uff0c\u4ece\u800c\u964d\u4f4e\u8367\u5149\u5f3a\u5ea6\uff0c\u5229\u7528\u8fd9\u4e00\u539f\u7406\u53ef\u4ee5\u68c0\u6d4bTNT\u3002<\/p>\n

\u6b64\u5916\u8fd8\u6709\u4eba\u5c06SiNPs\u6d78\u6d82\u5728\u7eb8\u4e0a\u505a\u6210\u4f20\u611f\u5668\uff0c\u5f53\u8fd9\u79cd\u4f20\u611f\u5668\u9047\u5230\u542b\u785d\u57fa\u5316\u5408\u7269\uff08\u9ad8\u80fd\u6750\u6599\uff0c\u70b8\u836f\u7684\u539f\u6599\uff09\u7684\u6eb6\u6db2\u65f6\uff0cSiNPs\u4e5f\u4f1a\u4ea7\u751f\u8367\u5149\u731d\u706d\uff08\u56fe3B\uff09\uff0c\u8fd9\u662f\u7531\u4e8eSiNPs\u5bfc\u5e26\u4e2d\u7684\u7535\u5b50\u8f6c\u79fb\u5230\u785d\u57fa\u5316\u5408\u7269\u7684\u53cd\u03c0\u8f68\u9053\u4e2d\u3002<\/p>\n

\"\u56fe\u72473\"<\/p>\n

\u56fe3 <\/strong>\uff08A\uff09SiNPs\u4f20\u611f\u5668\u68c0\u6d4b\u519c\u836f\u7684\u793a\u610f\u56fe\uff1b\uff08B\uff09SiNPs\u57fa\u7eb8\u4f20\u611f\u5668\u7684\u5236\u5907\u53ca\u5176\u5728\u785d\u57fa\u5316\u5408\u7269\u4f5c\u7528\u4e0b\u7684\u8367\u5149\u56fe\u3002<\/p>\n

\u3010\u603b\u7ed3\u4e0e\u5c55\u671b\u3011<\/strong><\/p>\n

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\u3010\u4f55\u8000\u6559\u6388\u4ecb\u7ecd\u3011<\/strong><\/p>\n

2003\u5e74\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u83b7\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c\u4fdd\u9001\u76f4\u7814\u81f3\u590d\u65e6\u5927\u5b66\u5148\u8fdb\u6750\u6599\u7814\u7a76\u9662\uff0c\u4e8e2007\u5e74\u535a\u58eb\u6bd5\u4e1a\uff1b\u540c\u5e74\u4e8e\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u7269\u7406\u4e0e\u6750\u6599\u79d1\u5b66\u7cfb\u53ca\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u5e94\u7528\u7269\u7406\u7814\u7a76\u6240\u751f\u7269\u7269\u7406\u5b9e\u9a8c\u5ba4\u5f00\u5c55\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff1b2009\u5e741\u6708\u52a0\u5165\u82cf\u5dde\u5927\u5b66\u529f\u80fd\u7eb3\u7c73\u4e0e\u8f6f\u7269\u8d28\u7814\u7a76\u9662\uff0c\u7279\u8058\u526f\u6559\u6388\uff0c\u7855\u58eb\u751f\u5bfc\u5e08\uff1b2011\u5e744\u6708\uff0c\u664b\u5347\u4e3a\u7279\u8058\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\uff08\u4fe1\u606f\u6765\u81ea\uff1a\u4f55\u8000\u6559\u6388\u8bfe\u9898\u7ec4<\/a>\uff09<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Water-Dispersible Fluorescent Silicon Nanoparticles and their Optical Applications<\/a>\uff08Adv. Mater., 2016, DOI\uff1a10.1002\/adma.201601173\uff09<\/p>\n

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