{"id":36260,"date":"2016-08-25T08:00:15","date_gmt":"2016-08-25T00:00:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=36260"},"modified":"2016-08-24T23:53:43","modified_gmt":"2016-08-24T15:53:43","slug":"macromolecules%ef%bc%9a%e9%95%bf%e6%98%a5%e5%ba%94%e5%8c%96%e6%89%80-%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7%e9%93%be%e7%a9%bf%e6%a2%ad%e8%81%9a%e5%90%88%ef%bc%8c%e6%96%b0%e5%9e%8b%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=36260","title":{"rendered":"Macromolecules\uff1a\u957f\u6625\u5e94\u5316\u6240-\u533a\u57df\u9009\u62e9\u6027\u94fe\u7a7f\u68ad\u805a\u5408\uff0c\u65b0\u578b\u50ac\u5316\u5242\u4f53\u7cfb\u6539\u53d8\u5f02\u620a\u4e8c\u70ef\u5355\u4f53\u5e8f\u5217"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>2006\u5e74\uff0c\u7f8e\u56fdDow\u5316\u5b66\u516c\u53f8\u7684\u51e0\u4f4d\u79d1\u5b66\u5bb6\u63d0\u51fa\u4e86\u201c\u94fe\u7a7f\u68ad\uff08chain shuttling\uff09\u805a\u5408\u201d\u7684\u6982\u5ff5\uff0c\u5c06\u94fe\u7a7f\u68ad\u805a\u5408\u5b9a\u4e49\u4e3a\u589e\u957f\u9ad8\u5206\u5b50\u94fe\u5728\u591a\u4e2a\u50ac\u5316\u5242\u6d3b\u6027\u4e2d\u5fc3\u4e4b\u95f4\u7a7f\u68ad\uff0c\u6bcf\u4e2a\u805a\u5408\u7269\u94fe\u81f3\u5c11\u5728\u4e24\u4e2a\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u4e0a\u589e\u957f\u3002\u94fe\u7a7f\u68ad\u805a\u5408\u521b\u9020\u6027\u5730\u8bbe\u8ba1\u4e86\u53cc\u50ac\u5316\u5242\u914d\u4f4d\u94fe\u7a7f\u68ad\u805a\u5408\u4f53\u7cfb\uff0c\u901a\u8fc7\u4ea4\u53c9\u914d\u4f4d\u94fe\u8f6c\u79fb\u805a\u5408\uff0c\u53ef\u4ee5\u5728\u540c\u4e00\u5927\u5206\u5b50\u94fe\u4e0a\u7ed3\u5408\u4e0d\u540c\u7c7b\u578b\u7684\u5e8f\u5217\u3002<\/p>\n<p>\u5171\u8f6d\u4e8c\u70ef\u7684\u914d\u4f4d\u805a\u5408\u5728\u9ad8\u6027\u80fd\u6a61\u80f6\u3001\u70ed\u5851\u6027\u5f39\u6027\u4f53\u4ee5\u53ca\u9ad8\u6027\u80fd\u6811\u8102\u5408\u6210\u4e2d\u5360\u636e\u91cd\u8981\u5730\u4f4d\u3002\u76ee\u524d\u4e3a\u6b62\uff0c\u5927\u90e8\u5206\u94fe\u7a7f\u68ad\u805a\u5408\u4e3b\u8981\u6210\u529f\u5e94\u7528\u4e8e\u4e59\u70ef\u548c\u03b1-\u70ef\u70c3\uff0c\u4f46\u5f88\u5c11\u6709\u63a2\u7a76\u5171\u8f6d\u4e8c\u70ef\u70c3\u7684\u94fe\u7a7f\u68ad\u805a\u5408\u7684\u62a5\u5bfc\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u671f\uff0c\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240\u5d14\u51ac\u6885\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u5206\u522b\u4f7f\u7528\u5421\u5576\u57fa-\u4e9a\u7532\u57fa\u529f\u80fd\u5316\u82b4\u57fa\u94aa\u548c\u9565\u524d\u9a71\u4f53\uff0c\u83b7\u5f97\u4e86\u5f02\u620a\u4e8c\u70ef\uff08IP\uff09\u7684\u9ad8\u65481\uff0c4-\u9009\u62e9\u6027\u548c3\uff0c4-\u9009\u62e9\u6027\u7684\u94fe\u8f6c\u79fb\u805a\u5408(CTPs)\u4ea7\u7269\u3002<\/p>\n<p>\u5176\u4e2d\uff0c\u5421\u5576\u57fa-\u4e9a\u7532\u57fa\u82b4\u57fa\u94aa\u590d\u5408\u7269\u7ed3\u5408\u6d3b\u5316\u5242[Ph<sub>3<\/sub>C][B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>4<\/sub>]\u548c\u94fe\u8f6c\u79fb\u5242Al<sup>i<\/sup>Bu<sub>3<\/sub>\uff0c\u572810\u5f53\u91cf\u7684Al<sup>i<\/sup>Bu<sub>3<\/sub>\u5b58\u5728\u65f6\uff0c\u5f02\u620a\u4e8c\u70ef\uff08IP\uff09\u7684\u94fe\u8f6c\u79fb\u805a\u5408\u8fde\u8f6c\u79fb\u6548\u7387\u9ad8\u8fbe93.8%\uff0c1\uff0c4-\u9009\u62e9\u6027\u9ad8\u8fbe83%\uff1b\u91c7\u7528\u7a00\u571f\u91d1\u5c5e\u9565\u53d6\u4ee3\u94aa\u7684\u7c7b\u4f3c\u7684\u50ac\u5316\u4f53\u7cfb\uff0c\u5f02\u620a\u4e8c\u70ef\uff08IP\uff09\u7684\u94fe\u8f6c\u79fb\u805a\u5408\u8868\u73b0\u4e3a3\uff0c4-\u533a\u57df\u9009\u62e9\u6027\uff0c\u5728Al<sup>i<\/sup>Bu<sub>3<\/sub>-\u9565\u4ece10:1 \u5230 100:1\u7684\u8f83\u5bbd\u8303\u56f4\u5185\uff0c\u5177\u670996.5-100%\u51e0\u4e4e\u5b8c\u7f8e\u7684\u94fe\u8f6c\u79fb\u6548\u7387\u3002\u800c\u4e14\uff0c\u7814\u7a76\u4e2d\u6240\u6709\u7684CTPs\u5f88\u597d\u5730\u534f\u8c03\u4e86\u9009\u62e9\u6027\u548c\u6d3b\u6027\uff0c\u5177\u6709\u76f8\u5f53\u7684\u94fe\u8f6c\u79fb\u901f\u7387\u5e38\u6570\u3002<\/p>\n<p>\u901a\u8fc7\u7814\u7a76\u589e\u957f\u53ca\u94fe\u8f6c\u79fb\u53cd\u5e94\u7684\u52a8\u529b\u5b66\uff0c\u6784\u5efa\u603b\u901f\u7387\u65b9\u7a0b\uff0c\u8ba1\u7b97\u6d3b\u6027\u79cd\u7684\u952e\u5f3a\uff0c\u4ece\u800c\u63ed\u793a\u4e86\u5f71\u54cd\u94fe\u8f6c\u79fb\u6548\u7387\u548cCSP\u7684\u7279\u6b8a\u9009\u62e9\u6027\u7684\u56e0\u7d20\u3002<\/p>\n<p>\u8fdb\u4e00\u6b65\uff0c\u56e0\u4e3a\u94aa\u50ac\u5316\u4f53\u7cfb\u548c\u9565\u50ac\u5316\u4f53\u7cfb\u7684\u9ad8\u94fe\u8f6c\u79fb\u6548\u7387\u53ca\u76f8\u5339\u914d\u7684\u94fe\u8f6c\u79fb\u901f\u7387\u5e38\u6570\uff0c\u56e0\u6b64\uff0c\u4ee5\u4e00\u5b9a\u6bd4\u4f8b\u6df7\u5408\u4e0a\u8ff0\u4e24\u79cd\u4f53\u7cfb\uff0c\u5efa\u7acb\u8d77\u4e00\u7cfb\u5217\u4ecb\u4e8e1\uff0c4-\u548c3\uff0c4-\u9009\u62e9\u6027\u94fe\u7a7f\u68ad\u805a\u5408\u7684\u9ad8\u6548\u50ac\u5316\u4f53\u7cfb\u3002\u6700\u7ec8\u5236\u5907\u51fa\u7684PIPs\u7684\u5fae\u7ed3\u6784\u4e2d\u62e5\u6709\u4e0d\u540c\u5206\u5e03\u76841\uff0c4-\u548c3\uff0c4-\u5e8f\u5217\uff0c\u4ece\u800c\u83b7\u5f97\u5177\u6709\u53ef\u63a7\u7acb\u6784\u89c4\u6574\u6027\u548c\u67b6\u6784\u7684\u65b0\u578b\u6750\u6599\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1\uff1a\u5421\u5576\u57fa-\u4e9a\u7532\u57fa\u529f\u80fd\u5316\u7684\u82b4\u57fa\u7ed3\u5408\u7684\u7a00\u571f\u91d1\u5c5e\u590d\u5408\u72691-9<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36320 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-\u56fe1-1.png\" width=\"400\" height=\"358\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-\u56fe1-1.png 400w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/1-\u56fe1-1-300x269.png 300w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/><\/p>\n<p><strong>\u88681\uff1a\u4f7f\u7528\u590d\u5408\u72691-9\/[Ph<sub>3<\/sub>C]\/[B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>4<\/sub>]\/Al<sup>i<\/sup>Bu<sub>3<\/sub>\u50ac\u5316\u805a\u5408IP\u7684\u6570\u636e<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36262\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-\u88681.png\" alt=\"2-\u88681\" width=\"660\" height=\"588\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-\u88681.png 660w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/2-\u88681-300x267.png 300w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/><\/p>\n<p>\u88681\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u94aa\uff08Sc\uff09\u5177\u6709\u663e\u8457\u76841\uff0c4-\u9009\u62e9\u6027\uff0c\u800c\u5176\u4ed6\u7a00\u571f\u91d1\u5c5e\u5143\u7d20\u5747\u8868\u73b0\u51fa3\uff0c4-\u9009\u62e9\u6027\uff0c\u5c24\u5176\u6ce8\u610f\u5230\u9565\uff08Lu\uff09\u7684\u94fe\u8f6c\u79fb\u6548\u7387\u8fbe\u5230100%\u3002\uff08PDI\u4e3a\u591a\u5206\u6563\u6307\u6570\uff09<\/p>\n<p><strong>\u88682\uff1a\u5728\u4e0d\u540c\u7684Al<sup>i<\/sup>Bu<sub>3<\/sub>-Ln\u6bd4\u7387\u4e0b\uff0c\u7531\u590d\u5408\u72691\u548c3\u50ac\u5316\u5f02\u620a\u4e8c\u70ef\u805a\u5408\u00a0<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36263\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-\u88682.png\" alt=\"3-\u88682\" width=\"660\" height=\"351\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-\u88682.png 660w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/3-\u88682-300x160.png 300w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/><\/p>\n<p>\u7531\u88681\u4e2d\u7684\u6570\u636e\uff0c\u7b5b\u9009\u51fa\u7684\u94aa\uff08Sc\uff09-1\u53f7\uff0c\u9565\uff08Lu\uff09-3\u53f7\uff0c\u4f5c\u4e3a\u50ac\u5316\u5242\u4e2d\u7684\u7a00\u571f\u91d1\u5c5e\u5143\u7d20\uff0c\u5728\u4e0d\u540c\u7684\u94fe\u8f6c\u79fb\u5242Al<sup>i<\/sup>Bu<sup>3<\/sup>-\u91d1\u5c5e\u6bd4\u7387\u4e0b\u8fdb\u884c\u5f02\u620a\u4e8c\u70ef\u7684\u805a\u5408\u53cd\u5e94\u3002<\/p>\n<p>\u5728\u6240\u6709\u4f53\u7cfb\uff0c\u5355\u4f53\u51e0\u4e4e\u5b8c\u5168\u8f6c\u5316(\u5927\u4e8e99%)\uff0c\u4f46\u662f\u94fe\u8f6c\u79fb\u901f\u7387\u4f9d\u8d56\u94fe\u8f6c\u79fb\u5242Al<sup>i<\/sup>Bu<sup>3<\/sup>\u7684\u7528\u91cf\u3002\u5728Al<sup>i<\/sup>Bu<sup>3<\/sup>-\u91d1\u5c5e\u6bd4\u7387\u8fbe\u523010\uff1a1\uff0c\u94fe\u8f6c\u79fb\u6548\u7387\u8fbe\u523093.8%\uff1b\u800c3\u53f7\uff0c\u968f\u7740Al<sup>i<\/sup>Bu<sup>3<\/sup>-\u91d1\u5c5e\u6bd4\u7387\u7684\u589e\u52a0\uff0c\u94fe\u8f6c\u79fb\u6548\u7387\u9010\u6e10\u589e\u81f3100%\u3002\u5206\u5b50\u91cf\u7684\u53d8\u5316\u4e0e\u8ba1\u7b97\u503c\u57fa\u672c\u543b\u5408\uff0c\u6240\u6709\u4f53\u7cfb\u5bf91\uff0c4-\u548c3\uff0c4-\u9009\u62e9\u6027\u51e0\u4e4e\u6ca1\u6709\u5f71\u54cd\u3002<\/p>\n<p><strong>\u88683\uff1a\u8054\u5408[Ph<sub>3<\/sub>C][B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>4<\/sub>]\u548c\u94fe\u8f6c\u79fb\u5242Al<sup>i<\/sup>Bu<sub>3<\/sub>\uff0c\u4f7f\u75281-3\u7684\u4e0d\u540c\u914d\u6bd4\u8fdb\u884cIP\u805a\u5408<\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36264\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-\u88683.png\" alt=\"4-\u88683\" width=\"660\" height=\"528\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-\u88683.png 660w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/4-\u88683-300x240.png 300w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/>\u88683\u4e2d\uff0c\u5bf91-3\u8fdb\u884c\u590d\u914d\u65f6\uff0centry1\u5168\u90e8\u91c7\u7528\u590d\u5408\u72691,\u8868\u73b0\u51fa83%\u76841\uff0c4-\u9009\u62e9\u6027\uff0c\u4f46\u662fentry2\u53ea\u52a0\u5165\u5c11\u91cf3\uff0c1\uff0c4-\u9009\u62e9\u6027\u4e0b\u964d\u523053%\u3002\u968f\u7740\u50ac\u5316\u4f53\u7cfb3\u7684\u52a0\u5165\uff0c3\uff0c4\u9009\u62e9\u6027\u9010\u6e10\u589e\u5f3a\u3002\u7acb\u6784\u89c4\u6574\u7684\u9009\u62e9\u6027\u5f3a\u70c8\u4f9d\u8d56\u50ac\u5316\u4f53\u7cfb\u7684\u6bd4\u4f8b\uff0c\u4e5f\u6b63\u8bf4\u660e\u4e86\u5d14\u51ac\u6885\u7814\u7a76\u56e2\u961f\u6210\u529f\u5efa\u7acb\u4e86\u7528\u4e8e\u533a\u57df\u9009\u62e9\u94fe\u7a7f\u68ad\u805a\u5408\u7684\u50ac\u5316\u524d\u9a71\u4f53\u3002<\/p>\n<p><strong>\u56fe2\uff1a\u4e0d\u540c\u76841-3\u6bd4\u7387\u4e0b\uff0c\u901a\u8fc7\u533a\u57df\u94fe\u7a7f\u68ad\u805a\u5408\u83b7\u5f97\u5177\u6709\u76f8\u4f3c3\uff0c4-\u5355\u5143PIP\u7684 <sup>13<\/sup>C NMR\u8c31 (from top to bottom, 1:3 = 0:10 (line 1), 1:3 = 1:9 (line 2), 1:3 = 3:7(line 3), and 1:3 = 5:5 (line 4)).<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-36265\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-\u56fe2.png\" alt=\"5-\u56fe2\" width=\"660\" height=\"558\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-\u56fe2.png 660w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/5-\u56fe2-300x254.png 300w\" sizes=\"(max-width: 660px) 100vw, 660px\" \/><\/p>\n<p>\u5728\u88683\u4e2d\uff0centry6-9\u8fd9\u56db\u79cd\u4f53\u7cfb\uff0c\u5177\u6709\u51e0\u4e4e\u76f8\u540c\u76843\uff0c4-\u5355\u5143\u542b\u91cf\uff0c\u4f46\u662fTg\u5b58\u5728\u8f83\u5927\u5dee\u522b\uff0c \u4e3b\u8981\u539f\u56e0\u5728\u4e8e3\uff0c4-\u548c1\uff0c4-PIP\u5e8f\u5217\u5728PIP\u5927\u5206\u5b50\u94fe\u4e0a\u7684\u4e0d\u540c\u5206\u5e03\u9020\u6210\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u901a\u8fc7\u7b5b\u9009\u51fa\u5177\u6709\u9ad8\u94fe\u8f6c\u79fb\u6548\u7387\u7684\u94aa\u548c\u9565\u7a00\u571f\u91d1\u5c5e\u94fe\u7a7f\u68ad\u805a\u5408\u50ac\u5316\u4f53\u7cfb\uff0c\u5206\u522b\u5b9e\u73b0\u4e86\u5f02\u620a\u4e8c\u70ef\u76841\uff0c4-\u548c3\uff0c4-\u9009\u62e9\u6027\u805a\u5408\uff0c\u5bf9\u4e8e\u63a7\u5236\u5171\u8f6d\u4e8c\u70ef\u7684\u5e8f\u5217\u987a\u5e8f\u8fdb\u800c\u5408\u6210\u51fa\u5177\u6709\u7279\u6b8a\u5fae\u7ed3\u6784\u53ca\u6027\u80fd\u7684\u65b0\u6750\u6599\u8d77\u5230\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p><strong>\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u5d14\u51ac\u6885\uff0c1963\u5e74\u751f\uff0c\u73b0\u4e3a\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u5316\u6240\u9ad8\u5206\u5b50\u7269\u7406\u4e0e\u5316\u5b66\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30021985\u5e747\u6708\u6bd5\u4e1a\u4e8e\u5927\u8fde\u7406\u5de5\u5927\u5b66\uff0c\u83b7\u5de5\u5b66\u5b66\u4f4d\uff1b1988\u5e74\u5728\u5927\u8fde\u7406\u5de5\u5927\u5b66\u83b7\u5de5\u5b66\u7855\u58eb\u5b66\u4f4d\uff1b2001\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\u30021988\u5e74\u81f31992\u5e74\u5728\u6c88\u9633\u836f\u79d1\u5927\u5b66\u62c5\u4efb\u8bb2\u5e08\uff1b1992\u5e74\u81f32002\u5e74\u671f\u95f4\u5728\u957f\u6625\u5de5\u4e1a\u5927\u5b66\u4efb\u8bb2\u5e08\u3001\u526f\u6559\u6388\u3001\u6559\u6388\uff1b1996\u5e74\u81f31997\u5e74\u5728\u82f1\u56fd\u62c9\u592b\u5821\u5927\u5b66\u505a\u8bbf\u95ee\u5b66\u8005\uff0c2002\u81f32004\u5e74\u5728\u65e5\u672c\u7406\u5316\u5b66\u7814\u7a76\u6240\u505aJSPS\u7279\u522b\u535a\u58eb\u540e\uff0c2003\u83b7\u65e5\u672c\u79d1\u5b66\u632f\u5174\u4f1a\uff08JSPS \uff09\u8d44\u52a9\u5728\u65e5\u672c\u7406\u5316\u6240\u4ece\u4e8b\u7a00\u571f\u50ac\u5316\u7814\u7a76\uff1b2005\u5165\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\uff0c\u5e76\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u9ad8\u5206\u5b50\u7269\u7406\u4e0e\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5de5\u4f5c\u81f3\u4eca\u3002<\/p>\n<p>\u7814\u7a76\u9886\u57df\uff1a\u7a00\u571f\u914d\u5408\u7269\u7684\u8bbe\u8ba1\u4e0e\u50ac\u5316\u6027\u80fd\u7684\u7814\u7a76\u3002\u65e8\u5728\u89e3\u51b3\u201c\u5408\u6210\u5929\u7136\u6a61\u80f6\u201d\u5de5\u4e1a\u5316\u8fc7\u7a0b\u4e2d\u7684\u5173\u952e\u79d1\u5b66\u95ee\u9898\uff0c\u4ee5\u53ca\u5236\u5907\u9ad8\u6027\u80fd\u53ef\u751f\u7269\u964d\u89e3\u6750\u6599\uff0c\u66ff\u4ee3\u201c\u767d\u8272\u201d\u6c61\u67d3\u578b\u3001\u77f3\u6cb9\u8d44\u6e90\u4f9d\u8d56\u578b\u805a\u70ef\u70c3\u6750\u6599\u3002\u76ee\u524d\u91c7\u7528\u5f00\u53d1\u7684\u65b0\u578b\u7a00\u571f\u9633\u79bb\u5b50\u4f53\u7cfb\u5236\u5907\u7684\u805a\u5f02\u620a\u4e8c\u70ef\u6a61\u80f6\u5df2\u8fbe\u5230\u4e86\u5929\u7136\u6a61\u80f6\u7684\u7406\u60f3\u7ed3\u6784\uff0c\u5e76\u5728\u7814\u7a76\u50ac\u5316\u5242\u5206\u5b50\u7ed3\u6784-\u50ac\u5316\u6027\u80fd-\u9ad8\u5206\u5b50\u6750\u6599\u6027\u80fd\u4e4b\u95f4\u7684\u89c4\u5f8b\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u8981\u6210\u679c\uff0c\u4e3a\u50ac\u5316\u5242\u8bbe\u8ba1\u5960\u5b9a\u4e86\u7406\u8bba\u57fa\u7840\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.macromol.6b00904\" target=\"_blank\">Regioselective Chain Shuttling Polymerization of Isoprene: An Approach To Access New Materials from Single Monomer<\/a>\uff08Macromolecules, 2016, DOI :10.1021\/acs.macromol.6b00904\uff09<\/p>\n<p>\u611f\u8c22\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u7ec4Fang_WenX\u63d0\u4f9b\u7d20\u6750\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08 298064863\uff09\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u672c\u79d1\u751f\u3001\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u3002<\/p>\n<p><\/a>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\"><br \/>\n<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 2006\u5e74\uff0c\u7f8e\u56fdDow\u5316\u5b66\u516c\u53f8\u7684\u51e0\u4f4d\u79d1\u5b66\u5bb6\u63d0\u51fa\u4e86\u201c\u94fe\u7a7f\u68ad\uff08chain shuttling\uff09\u805a\u5408\u201d\u7684\u6982\u5ff5\uff0c\u5c06\u94fe\u7a7f\u68ad\u805a\u5408\u5b9a\u4e49\u4e3a\u589e\u957f\u9ad8\u5206\u5b50\u94fe\u5728\u591a\u4e2a\u50ac\u5316\u5242\u6d3b\u6027&#8230;<\/p>\n","protected":false},"author":393,"featured_media":36261,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,42],"class_list":["post-36260","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst","tag-gaofenzi"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36260"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/393"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=36260"}],"version-history":[{"count":8,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36260\/revisions"}],"predecessor-version":[{"id":36346,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36260\/revisions\/36346"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/36261"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=36260"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=36260"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=36260"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}