{"id":36518,"date":"2016-08-27T14:00:17","date_gmt":"2016-08-27T06:00:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=36518"},"modified":"2016-08-26T23:36:10","modified_gmt":"2016-08-26T15:36:10","slug":"jacs-%e5%a4%a7%e8%bf%9e%e5%8c%96%e7%89%a9%e6%89%80-%e5%bc%ba%e7%a2%b1%e6%9d%a1%e4%bb%b6%e4%b8%8b%e4%bb%8e%e5%8d%8a%e5%af%bc%e4%bd%93cds%e5%88%b0%e5%88%86%e5%ad%90%e5%82%ac%e5%8c%96%e5%89%82copy","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=36518","title":{"rendered":"JACS: \u5927\u8fde\u5316\u7269\u6240-\u5f3a\u78b1\u6761\u4ef6\u4e0b\u4ece\u534a\u5bfc\u4f53CdS\u5230\u5206\u5b50\u50ac\u5316\u5242CoPy\u7684\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u534a\u5bfc\u4f53\u548c\u5206\u5b50\u50ac\u5316\u5242\u7ec4\u6210\u7684\u6df7\u5408\u5149\u50ac\u5316\u7cfb\u7edf\u5df2\u88ab\u6df1\u5165\u7814\u7a76\uff0c\u8be5\u7cfb\u7edf\u53ef\u4ee5\u5229\u7528\u534a\u5bfc\u4f53\uff08\u5bbd\u7684\u5149\u5438\u6536\u4e14\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\uff09\u548c\u5206\u5b50\u50ac\u5316\u5242\uff08\u9ad8\u6d3b\u6027\u548c\u7075\u6d3b\u6027\uff09\u7684\u4f18\u70b9\u3002\u5bf9\u4e8e\u6df7\u5408\u5149\u50ac\u5316\u7cfb\u7edf\u7684\u6784\u5efa\uff0c\u534a\u5bfc\u4f53\u548c\u5206\u5b50\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u80fd\u7ea7\u5339\u914d\u662f\u91cd\u8981\u7684\u8003\u8651\u56e0\u7d20\u4e4b\u4e00\uff0c\u540c\u65f6\u4ece\u534a\u5bfc\u4f53\u5230\u5206\u5b50\u50ac\u5316\u5242\u7684\u57fa\u672c\u7535\u8377\u8f6c\u79fb\u673a\u5236\u4e5f\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u76ee\u524d\uff0c\u5927\u591a\u6570\u8d28\u5b50\u8fd8\u539f\u5206\u5b50\u50ac\u5316\u5242\u7684\u4e3b\u5bfc\u8fd8\u539f\u673a\u5236\u4e3a\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u5982\u954d\uff08II\uff09\u914d\u5408\u7269\u3001\u94b4\uff08III\uff09\u914d\u5408\u7269\u3001[FeFe]-\u6c22\u5316\u9176\u6a21\u62df\u7269\u3002\u5206\u5b50\u50ac\u5316\u5242\u7684\u7b2c\u4e8c\u8fd8\u539f\u8fc7\u7a0b\u4e2d\u4f1a\u4ea7\u751f\u6d3b\u6027\u8d28\u5b50\u8fd8\u539f\u4e2d\u95f4\u4f53\uff0c\u8be5\u8fc7\u7a0b\u901a\u5e38\u662f\u5728\u76f8\u5bf9\u8d1f\u7684\u8fd8\u539f\u7535\u4f4d\u4e0b\u8fdb\u884c\uff0c\u8fd9\u4f1a\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u9650\u5236\u534a\u5bfc\u4f53\u548c\u5206\u5b50\u50ac\u5316\u5242\u6784\u5efa\u9ad8\u6548\u6df7\u5408\u5149\u50ac\u5316\u7cfb\u7edf\u3002\u534a\u5bfc\u4f53\u5177\u6709\u4f20\u9012\u591a\u7535\u5b50\u7684\u80fd\u529b\uff0c\u5982\u679c\u5355\u6b65\u591a\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u80fd\u5e94\u7528\u4e8e\u6df7\u5408\u5149\u50ac\u5316\u7cfb\u7edf\uff0c\u5219\u5149\u50ac\u5316\u4f53\u7cfb\u5c06\u5f97\u5230\u66f4\u5927\u7684\u6269\u5c55\u3002\u76ee\u524d\uff0c\u8be5\u60f3\u6cd5\u7684\u53ef\u884c\u6027\u6709\u5f85\u7814\u7a76\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6700\u8fd1\uff0c\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u674e\u707f\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u97e9\u6d2a\u5baa\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u7814\u7a76\u4e86\u4e0d\u540cpH\u6761\u4ef6\u4e0b\uff0cCoPy\/CdS\u6df7\u5408\u5149\u50ac\u5316\u7cfb\u7edf\u4e2d\u4ece\u534a\u5bfc\u4f53CdS\u5230\u5206\u5b50\u50ac\u5316\u5242CoPy\uff08[Co(III)(dmgH)2PyCl]\uff09\u7684\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728\u9ad8pH\u503c\uff08>10.0\uff09\u4e0b\uff0cCoPy\u7684\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fd8\u539f\u5728\u70ed\u529b\u5b66\u4e0a\u662f\u4e0d\u5229\u7684\u3002\u7136\u800c\uff0c\u5f53PH\u4e3a13.5\u65f6\uff0c\u5149\u50ac\u5316\u5236\u6c22\u7684\u6d3b\u6027\u6700\u9ad8\u3002\u8fd9\u662f\u56e0\u4e3a\u4eceCdS\u5230Co(III)Py\u7684\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u6bd4\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u5728\u70ed\u529b\u5b66\u4e0a\u66f4\u4e3a\u6709\u5229\u3002\u4e0d\u540c\u7684PH \u6761\u4ef6\u4e0b\uff0cCoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u4e2d\u7535\u5b50\u8f6c\u79fb\u7684\u673a\u5236\u4e0d\u540c:\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u4e3a\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u5373Co(III) Py\u2192Co(II)Py\u2192Co(I)Py\uff1b\u968f\u7740PH\u589e\u52a0\u523010\u548c12\uff0c\u4ecd\u7136\u5b58\u5728\u7740Co(III)Py\u2192Co(II)Py\u7684\u5355\u7535\u5b50\u8fd8\u539f\uff0c\u4f46\u975e\u5e38\u4e0d\u5229\u4e8eCo(II)Py\u2192Co(I)Py\u8fd8\u539f\uff0c\u5149\u50ac\u5316\u6d3b\u6027\u53ef\u5ffd\u7565\u4e0d\u8ba1\u3002\u5f53PH\u503c\u518d\u589e\u52a0\u523013.5\u65f6\uff0c\u4f1a\u51fa\u73b0Co(III)Py\u2192Co(I)Py\u7684\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u8fd9\u4e00\u53d1\u73b0\u4e0d\u4ec5\u4e3a\u534a\u5bfc\u4f53\u548c\u5206\u5b50\u50ac\u5316\u5242\u4e4b\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u63d0\u51fa\u4e86\u65b0\u7684\u89c1\u89e3\uff0c\u800c\u4e14\u4e5f\u4e3a\u901a\u8fc7\u591a\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u7684\u534a\u5bfc\u4f53\/\u5206\u5b50\u50ac\u5316\u5242\u6df7\u5408\u7cfb\u7edf\u7684\u88c5\u914d\u548c\u4f18\u5316\u5f00\u8f9f\u4e86\u65b0\u9014\u5f84\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u4e0d\u540c<\/strong>PH<\/strong>\u6761\u4ef6\u4e0b\u5149\u50ac\u5316\u5236\u6c22\u6d3b\u6027\u7684\u7814\u7a76<\/strong><\/p>\n

\"\u56fe\u72472\"<\/p>\n

a.<\/strong> CoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u5149\u50ac\u5316\u5236\u6c22\u53cd\u5e94\u7684\u793a\u610f\u56fe\u3002<\/p>\n

b-d.<\/strong> \u5149\u50ac\u5316\u5236\u6c22\u7684\u6d3b\u6027\uff1ab) CoPy\/CdS\u6df7\u5408\u7cfb\u7edf\uff1bc) \u4ec5\u6709\u534a\u5bfc\u4f53CdS\u7cfb\u7edf\uff1bPt\/CdS\u6df7\u5408\u7cfb\u7edf\u3002\u53cd\u5e94\u6761\u4ef6: 100 mgCdS \u6216 Pt\/CdS\uff080.1 wt % Pt\uff09\uff1b100ml\u7532\u9187\u6c34\u6eb6\u6db2\uff08\u4f53\u79ef\u6bd420%\uff09\uff1b300WXe\u706f\uff08\u03bb\u2265420nm\uff09\uff1b0.25 mM CoPy\u3002<\/p>\n

\u56fe<\/strong>2\u00a0 CoPy\/CdS<\/strong>\u6df7\u5408\u7cfb\u7edf\u4e2d\u7535\u8377\u8f6c\u79fb\u52a8\u529b\u5b66\u7684\u7814\u7a76<\/strong><\/p>\n

\"\u56fe\u72473\"<\/p>\n

a.<\/strong> CoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u4e2d\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u7684\u80fd\u91cf\u56fe\u8c31\uff1a\u9ed1\u8272\u65b9\u683c\u2014Cds\u7684\u5e73\u5e26\u7535\u4f4d\u4e0ePH\u5173\u7cfb\uff1b\u7ea2\u8272\u5706\u2014Co(II)Py\/Co(I)Py\u7684\u8fd8\u539f\u7535\u52bf\u4e0ePH\u5173\u7cfb\uff1b\u84dd\u8272\u4e09\u89d2\u5f62\u2014 H+<\/sup>\/H2<\/sub>\u8fd8\u539f\u7535\u52bf\u4e0ePH\u5173\u7cfb\uff1b<\/p>\n

b.<\/strong> \u5f53PH\u4e3a13.5\u65f6\uff0c\u4eceCds\u5230CoPy\u7684\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\uff0c\u63d2\u56fe\u662f\u5143\u7d20\u7535\u52bf\u56fe\u3002<\/p>\n

\u56fe<\/strong>3\u00a0 <\/strong>\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u7684\u8bc1\u660e<\/strong><\/p>\n

\"\u56fe\u72474\"<\/p>\n

a.<\/strong> \u4e0d\u540cPH\u6761\u4ef6\u4e0b\uff0cCoPy\/CdS \u6df7\u5408\u7cfb\u7edf\u5149\u7167\u5c04\uff08\u03bb\u2265 420 nm\uff0990min\u540e\u7684EPR\u5149\u8c31\u3002<\/p>\n

b.<\/strong> \u4e0d\u540cpH\u6761\u4ef6\u4e0b\uff0c\u4e00\u5b9a\u65f6\u95f4\u7684\u5149\u50ac\u5316\u53cd\u5e94\u524d\u540e\u7684CoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u4e0a\u6e05\u6eb6\u6db2\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002\u5bf9\u4e8e\u5149\u50ac\u5316\u53cd\u5e94\u540e\u7684\u6d4b\u91cf\uff0c\u901a\u8fc7\u5728\u8bd5\u7ba1\u4e2d\u4f7f\u75280.2\u03bcM\u6ce8\u5c04\u5668\u5f0f\u6ee4\u5668\u5f97\u5230\uff0c\u7136\u540e\u5728\u624b\u5957\u7bb1\u4e2d\u4f7f\u7528PARA\u819c\u5bc6\u5c01\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u9879\u5de5\u4f5c\u7814\u7a76\u4e86\u5728\u5f3a\u78b1\u6027\u6761\u4ef6\u4e0b\uff08pH\u4e3a13.5\uff09\uff0cCoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u4e2d\u4ece\u534a\u5bfc\u4f53\u5230\u5206\u5b50\u50ac\u5316\u5242\u7684\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u3002\u7ed3\u679c\u8868\u660e\u5728\u5f3a\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u5355\u6b65\u53cc\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u6bd4\u4e24\u6b65\u8fde\u7eed\u5355\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u66f4\u6709\u5229\uff0c\u8fd9\u662fCoPy\/CdS\u6df7\u5408\u7cfb\u7edf\u4e2d\u5149\u50ac\u5316\u5236\u6c22\u7684\u5173\u952e\u8fc7\u7a0b\u3002\u8fd9\u4e00\u53d1\u73b0\u53ef\u80fd\u4e3a\u591a\u7535\u5b50\u8f6c\u79fb\u5236\u5907\u592a\u9633\u80fd\u71c3\u6599\u7684\u6df7\u5408\u7cfb\u7edf\u7684\u88c5\u914d\u548c\u4f18\u5316\u5f00\u8f9f\u4e00\u4e2a\u65b0\u9014\u5f84\u3002<\/p>\n

\u674e\u707f\u9662\u58eb\u7b80\u4ecb\uff1a<\/strong><\/p>\n

\u674e\u707f\uff0c\u7537\uff0c\u73b0\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u7814\u7a76\u5458\u3001\u6d01\u51c0\u80fd\u6e90\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\uff0c2003\u5e74\u5f53\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u3002\u8fd1\u5e74\u6765\uff0c\u4e3b\u8981\u81f4\u529b\u4e8e\u592a\u9633\u80fd\u5149\u50ac\u5316\u5236\u6c22\u4ee5\u53ca\u592a\u9633\u80fd\u5149\u4f0f\u7535\u6c60\u6750\u6599\u7814\u7a76\u3002\u5728\u56fd\u5185\u5916\u5b66\u672f\u520a\u7269\u53d1\u8868\u6b63\u5f0f\u8bba\u6587400\u4f59\u7bc7\uff0c\u5176\u4e2d300\u4f59\u7bc7\u53d1\u8868\u5728\u56fd\u9645\u5b66\u672f\u520a\u7269\u4e0a\u3002\u4efb \u201cJournal of Catalysis\u201d\uff0c\u201cJournal of Physical Chemistry C\u201d, \u201cJournal of Molecular Catalysis A\u201d\uff0c\u201cChemistry: An Asian Journal\u201d\u7b4910\u4f59\u79cd\u56fd\u9645\u520a\u7269\u7f16\u59d4\/\u987e\u95ee\u59d4\u5458\u3002<\/p>\n

\u97e9\u6d2a\u5baa\u7814\u7a76\u5458\u7b80\u4ecb<\/strong>:<\/strong><\/p>\n

2003\u5e74\u83b7\u6fb3\u5927\u5229\u4e9a\u65b0\u5357\u5a01\u5c14\u58eb\u5927\u5b66\u7269\u7406\u5316\u5b66\u4e13\u4e1a\u535a\u58eb\u5b66\u4f4d\u30022003\u5e74\u81f32008\u5e74\u5728\u7f8e\u56fd\u52b3\u4f26\u65af\u4f2f\u514b\u5229\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\u30022009\u5e74\u4ee5\u201c\u767e\u4eba\u8ba1\u5212-\u6d77\u5916\u6770\u51fa\u4eba\u624d\u201d\u5f15\u8fdb\uff0c\u8058\u4e3a\u6d01\u51c0\u80fd\u6e90\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\uff08\u7b79\uff09\u592a\u9633\u80fd\u7814\u7a76\u90e8\u7814\u7a76\u4eba\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u592a\u9633\u80fd\u5149-\u5316\u5b66\u8f6c\u5316, \u5305\u62ec\uff1a\u592a\u9633\u80fd\u5149\u50ac\u5316\u5206\u89e3\u6c34\uff0c\u592a\u9633\u80fd\u5149\u50ac\u5316\u91cd\u6574\u751f\u7269\u8d28\uff0c\u592a\u9633\u80fd\u5149\u50ac\u5316\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\uff0c\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u3002<\/p>\n

\u6ce8\uff1a\u901a\u8baf\u4f5c\u8005\u4fe1\u606f\u6765\u6e90\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5b98\u65b9\u7f51\u7ad9\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Unraveling a Single-Step Simultaneous Two-Electron Transfer Process from Semiconductor to Molecular Catalyst in a CoPy\/CdS Hybrid System for Photocatalytic H2 Evolution under Strong Alkaline Conditions<\/a>\uff08JACS, 2016,\u00a0DOI: 10.1021\/jacs.6b04080\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u5c65\u51b0\u4f9b\u7a3f\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/strong><\/p>\n

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\"1\"<\/p>\n","protected":false},"excerpt":{"rendered":"

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