{"id":36628,"date":"2016-08-28T14:00:20","date_gmt":"2016-08-28T06:00:20","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=36628"},"modified":"2017-03-04T10:35:42","modified_gmt":"2017-03-04T02:35:42","slug":"adv-fun-mater-%e9%92%92%e9%85%b8%e9%92%a0%e6%b0%a7%e5%8c%96%e7%89%a9%e7%ba%b3%e7%b1%b3%e6%a3%92%e7%94%b5%e6%9e%81%e5%8e%9f%e4%bd%8d%e6%8d%95%e6%8d%89%e7%a6%bb%e5%ad%90%e5%8c%96%e6%b0%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=36628","title":{"rendered":"Adv. Funct. Mater. \u9492\u9178\u94a0\u6c27\u5316\u7269\u7eb3\u7c73\u68d2\u7535\u6781\u539f\u4f4d\u6355\u6349\u79bb\u5b50\u5316\u6c27"},"content":{"rendered":"<p><span style=\"color: #ff0000;\"><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\u5f15\u8d77\u4e86\u901a\u8baf\u548c\u8fd0\u8f93\u7684\u50a8\u80fd\u65b9\u5f0f\u7684\u5de8\u5927\u53d8\u9769\uff0c\u63a8\u52a8\u4e86\u79fb\u52a8\u624b\u673a\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u5b9e\u7528\u5316\u53d1\u5c55\uff0c\u5df2\u7ecf\u6269\u5c55\u81f3\u5927\u89c4\u6a21\u50a8\u80fd\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u73b0\u6709\u5546\u4e1a\u5316\u6b63\u6781\u6709\u9650\u7684\u50a8\u80fd\u5bb9\u91cf\u548c\u9ad8\u6210\u672c\u963b\u788d\u4e86\u9502\u7535\u6750\u6599\u5546\u4e1a\u5316\u5e94\u7528\u7684\u53d1\u5c55\u3002\u63a2\u7d22\u9ad8\u5bb9\u91cf\u6bd4\u7535\u5bb9\u548c\u4f4e\u6210\u672c\u7684\u6b63\u6781\u662f\u4e00\u4e2a\u5177\u6709\u6311\u6218\u6027\u7684\u4efb\u52a1\u3002\u9492\u6c27\u5316\u7269\u56e0\u5176\u4e30\u5bcc\u7684\u8d44\u6e90\u548c\u4f4e\u6210\u672c\u4f5c\u4e3a\u9502\u7535\u6c60\u7535\u6781\u6750\u6599\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u901a\u5e38\u53d7\u5230\u5173\u6ce8\u7684\u5757\u4f53\u9492\u6c27\u5316\u7269\u7684\u4f4e\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570\uff0c\u8f83\u5dee\u7684\u5bfc\u7535\u6027\u4ee5\u53ca\u957f\u65f6\u95f4\u5faa\u73af\u7684\u4e0d\u7a33\u5b9a\u6027\u6210\u4e3a\u9650\u5236\u5176\u5e94\u7528\u7684\u91cd\u8981\u539f\u56e0\u3002<\/p>\n<p style=\"text-align: left;\"><span style=\"color: #ff0000;\"><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n<p>\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u7684\u9ea6\u7acb\u5f3a\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\u5229\u7528\u539f\u4f4dXRD\uff0cXPS\uff0c\u62c9\u66fc\uff0cTEM\u6280\u672f\u5bf9\u5408\u6210\u7684Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u8fdb\u884c\u8868\u5f81\uff0c\u7814\u7a76\u4e86\u53cd\u5e94\u7535\u538b\u7a97\u53e3\u548c\u7535\u5316\u5b66\u6027\u80fd\u7684\u5173\u7cfb\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\u9502\u79bb\u5b50\u7684\u6df1\u5ea6\u5d4c\u5165\\\u8131\u51fa\u80fd\u591f\u5e26\u6765\u66f4\u660e\u663e\u7684\u7535\u538b\u964d\uff0c\u7535\u5316\u5b66\u6781\u5316\u4ee5\u53ca\u6d3b\u6027\u949d\u5316\u3002\u5bf9\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u76f8\u5173\u7535\u538b\u7a97\u53e3\u7684\u7814\u7a76\u5bf9\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5b9e\u7528\u5316\u5e94\u7528\u53ca\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u4f18\u5316\u5177\u6709\u91cd\u8981\u7684\u6307\u5bfc\u4f5c\u7528\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36798 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0001.png\" width=\"650\" height=\"619\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0001.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0001-300x286.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><strong>\u56fe1.<\/strong>a\uff09\u626b\u63cf\u7535\u955c\u7167\u7247\uff0cb\uff09\u900f\u5c04\u7535\u955c\u7167\u7247\uff0cc\uff09\u7c89\u672bXRD\u884d\u5c04\u8c31\u56fe\u548cXRD\u7cbe\u4fee\u62df\u5408\u56fe\u8c31\uff0cd\uff09EDS\u56fe\uff0ce,f\uff09Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u9ad8\u500d\u900f\u5c04\u7535\u955c\u7167\u7247\u3002\uff08f\uff09\u4e2d\u7684\u63d2\u5165\u4e3a\u5bf9\u5e94\u7684\u5feb\u901f\u5085\u91cc\u53f6\u53d8\u6362\u6a21\u5f0f\u3002g\uff09Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u5f62\u6210\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36799 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0002.png\" width=\"600\" height=\"445\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0002.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0002-300x223.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n<strong>\u56fe2.<\/strong> Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u6750\u6599a\uff09\u7535\u538b\u57281.5-4.0 V\u548cb\uff092.0-4.0 V\u4e0b\u626b\u63cf\u901f\u5ea6\u4e3a0.1 mV s<sup>-1<\/sup>,\u7535\u6d41\u5bc6\u5ea6\u4e3ac\uff090.1 A g<sup>\u22121<\/sup>\u548cd\uff09\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36800 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0003.png\" width=\"600\" height=\"730\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0003.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0003-247x300.png 247w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u56fe3.<\/strong> Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u534a\u7535\u6c60\u5728a\uff092.0-4.0 V\u548cb\uff091.5-4.0 V\u7535\u538b\u4e0b\u8fdb\u884c\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u7684\u6052\u6d41\u5145\u653e\u7535\u65f6\u7684\u539f\u4f4dXRD\u6570\u636e\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36801 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0004.png\" width=\"650\" height=\"351\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0004.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0004-300x162.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><strong>\u56fe4.<\/strong>a\uff09Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u57281.5 V-4.0 V\u7535\u538b\u8303\u56f4\u91cc: b\uff09 4.0 V\uff0c c\uff09 3.3 V\uff0c d\uff09 2.8 V\uff0ce\uff09 2.5 V\uff0cf\uff09 1.7 V\u8fdb\u884c\u6052\u6d41\u5145\u653e\u7535\u7684\u539f\u4f4dXRD\u6570\u636e\u3002\u6240\u6709\u7684\u6837\u54c1\u6570\u636e\u5747\u7ecf\u8fc7XRD\u7cbe\u4fee\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-36802 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0005.png\" width=\"650\" height=\"329\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0005.png 650w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/adfm201602134-fig-0005-300x152.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p><strong>\u56fe5.<\/strong>a\uff09Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u539f\u72b6\u6001\u4e0b\u7684XPS\u6570\u636e\uff0cb\uff09\u4ece2.0 V\u81f34.0 V\uff0cc\uff09\u4ece1.5 V\u5145\u81f34.0 V\u3002d\uff09Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7535\u6781\u7684\u7535\u538b\u964d\u3002\u7535\u6c60\u9996\u5148\u5145\u7535\u81f34.0 V\u6216\u653e\u7535\u81f31.5 V\u62162.0 V\u3002\u7136\u540e\u7535\u6c60\u9648\u531630 s\u3002e\uff09\u7535\u6c60\u57281.5 -4.0 V\u548c2.0 -4.0 \u5faa\u73af\u5145\u653e\u7535\u65f6\uff0c\u57282.5 V\u7535\u538b\u5e73\u53f0\u9644\u8fd1\u5145\u7535\u7684\u53d8\u5316\u3002f\uff09\u4e0d\u540c\u7535\u5316\u5b66\u72b6\u6001\u4e0b\u7684Na<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u62c9\u66fc\u5149\u8c31\u3002<\/p>\n<p><span style=\"color: #ff0000;\"><strong>\u5c0f\u7ed3<\/strong><\/span><\/p>\n<p>\u901a\u8fc7\u4f18\u5316\u7535\u538b\u7a97\u53e3\u4ece1.5-4.0 V\u548c2.0-4.0 V\uff0cNa<sub>0.76<\/sub>V<sub>6<\/sub>O<sub>15<\/sub>\u7eb3\u7c73\u68d2\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u5316\u6c27\u7684\u6269\u6563\u548c\u6676\u4f53\u65e0\u5b9a\u578b\u5316\u7684\u7a0b\u5ea6\u80fd\u591f\u88ab\u6291\u5236\uff0c\u7535\u6c60\u5bb9\u91cf\u4fdd\u7559\u7a0b\u5ea6\u4ece26%\u63d0\u9ad8\u523080%\u3002\u9274\u4e8e\u6b64\uff0c\u53ef\u4ee5\u770b\u51fa\uff0c\u5bf9\u4e0e\u7535\u5316\u5b66\u53cd\u5e94\u9014\u5f84\u5bc6\u5207\u76f8\u5173\u7684\u7535\u538b\u7a97\u53e3\u7684\u7814\u7a76\u5bf9\u4e0e\u9502\u79bb\u5b50\u7684\u5b9e\u7528\u5316\u63a8\u5e7f\u548c\u8fdb\u4e00\u6b65\u4f18\u5316\u7535\u6c60\u6750\u6599\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u5177\u6709\u6781\u5927\u7684\u501f\u9274\u610f\u4e49\u3002<\/p>\n<p><strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.201602134\/full\" target=\"_blank\">The Capturing of Ionized Oxygen in Sodium Vanadium Oxide Nanorods Cathodes under Operando Conditions <\/a>\uff08Adv. Fun. Mater., 2016, DOI: 10.1002\/adfm.201602134\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4 \u4e1c\u6d77\u6728\u5b50\u674e \u4f9b\u7a3f\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002<img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-36286 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/%E6%96%B0%E8%83%BD%E6%BA%90%E5%89%8D%E7%BA%BF-3-300x300.jpg\" sizes=\"(max-width: 300px) 100vw, 300px\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/\u65b0\u80fd\u6e90\u524d\u7ebf-3-300x300.jpg 300w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/\u65b0\u80fd\u6e90\u524d\u7ebf-3-150x150.jpg 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/08\/\u65b0\u80fd\u6e90\u524d\u7ebf-3.jpg 340w\" alt=\"\u65b0\u80fd\u6e90\u524d\u7ebf\" width=\"300\" height=\"300\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u9502\u79bb\u5b50\u7535\u6c60\u5f15\u8d77\u4e86\u901a\u8baf\u548c\u8fd0\u8f93\u7684\u50a8\u80fd\u65b9\u5f0f\u7684\u5de8\u5927\u53d8\u9769\uff0c\u63a8\u52a8\u4e86\u79fb\u52a8\u624b\u673a\u548c\u7535\u52a8\u6c7d\u8f66\u7684\u5b9e\u7528\u5316\u53d1\u5c55\uff0c\u5df2\u7ecf\u6269\u5c55\u81f3\u5927\u89c4\u6a21\u50a8\u80fd\u4f53\u7cfb\u3002\u7136\u800c\uff0c\u73b0\u6709\u5546\u4e1a\u5316\u6b63\u6781\u6709\u9650\u7684\u50a8\u80fd\u5bb9\u91cf\u548c\u9ad8&#8230;<\/p>\n","protected":false},"author":1225,"featured_media":36798,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1295],"class_list":["post-36628","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-mailiqiang"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36628"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1225"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=36628"}],"version-history":[{"count":10,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36628\/revisions"}],"predecessor-version":[{"id":38271,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/36628\/revisions\/38271"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/36798"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=36628"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=36628"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=36628"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}