{"id":39152,"date":"2016-09-09T06:30:41","date_gmt":"2016-09-08T22:30:41","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=39152"},"modified":"2016-09-09T15:08:04","modified_gmt":"2016-09-09T07:08:04","slug":"energy-environ-sci-%e7%94%a8%e4%ba%8e%e6%b0%a7%e8%bf%98%e5%8e%9f%e5%8f%8d%e5%ba%94%e5%92%8c%e6%9e%90%e6%b0%a7%e5%8f%8d%e5%ba%94%e7%9a%84%e4%b8%80%e7%a7%8d3d%e5%8f%8c%e5%8a%9f%e8%83%bd%e5%a4%9a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=39152","title":{"rendered":"Energy Environ. Sci. \u7528\u4e8e\u6c27\u8fd8\u539f\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u7684\u4e00\u79cd3D\u53cc\u529f\u80fd\u591a\u5b54\u7684N\u63ba\u6742\u78b3\u5fae\u7ba1\u6d77\u7ef5\u72b6\u7535\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/span><\/p>\n

\u7535\u5316\u5b66\u6c27\u6c14\u8fd8\u539f\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u5bf9\u4e8e\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u80fd\u6e90\u5668\u4ef6\u800c\u8a00\u662f\u975e\u5e38\u5173\u952e\u7684\u7535\u50ac\u5316\u8fc7\u7a0b\uff0c\u5982\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u4ee5\u53ca\u88c2\u89e3\u6c34\u7b49\u3002\u7531\u4e8e\u8fc7\u7535\u52bf\u7684\u5b58\u5728\u5bfc\u81f4\u8fd9\u4e2a\u8fc7\u7a0b\u53cd\u5e94\u7f13\u6162\uff0c\u56e0\u800c\u9ad8\u6548\u7684\u3001\u6301\u4e45\u4e14\u4f4e\u6210\u672c\u7684\u6c27\u7535\u6781\u50ac\u5316\u5242\u7684\u53d1\u5c55\u5bf9\u4e8e\u8fd9\u4e9b\u7535\u5316\u5b66\u5668\u4ef6\u7684\u5b9e\u9645\u5e94\u7528\u6765\u8bf4\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u91d1\u5c5e\u7814\u7a76\u6240\u5218\u7545\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u5728NH3<\/sub>\u6c1b\u56f4\u4e0b\u901a\u8fc7\u7b80\u5355\u7684\u70ed\u5206\u89e3\u5408\u6210\u51fa\u4e86\u4e00\u79cd\u7528\u4f5c\u6c27\u6c14\u8fd8\u539f\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242\uff0c\u53733D\u67d4\u6027\u591a\u5b54\u7684N\u63ba\u6742\u78b3\u5fae\u7ba1\u6d77\u7ef5\uff0c\u8fd9\u79cd\u6750\u6599\u7684\u6d3b\u6027\u4f4d\u70b9\u5bc6\u5ea6\u9ad8\u3001\u7535\u5b50\u8f6c\u79fb\u901f\u5ea6\u5feb\uff0c\u6709\u7740\u4f18\u826f\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5728\u67d4\u6027\u80fd\u6e90\u8f6c\u6362\u548c\u80fd\u91cf\u50a8\u5b58\u4f53\u7cfb\u4e2d\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb\uff1a<\/strong><\/span><\/p>\n

\u56fe1.NCMT-1000\u7684\u5f62\u8c8c\u53ca\u5438\u9644\/\u8131\u9644\u66f2\u7ebf<\/strong><\/p>\n

\"fig1\"<\/p>\n

(a)NCMT(N-doped Carbon microtube)-1000\u7684\u5149\u5b66\u56fe\uff1b<\/p>\n

(b,c) NCMT-1000\u7684SEM\u56fe\uff1b \u00a0 \u00a0 \u00a0 \u00a0 (d,e) NCMT-1000\u7684TEM\u56fe\uff1b<\/p>\n

(f) NCMT-1000\u7684N2<\/sub>\u5438\u9644\/\u8131\u9644\u66f2\u7ebf\u3002\u63d2\u56fe\u663e\u793a\u5bf9\u5e94\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u56fe2. NCMT-1000\u7684\u5143\u7d20\u5206\u6790<\/strong><\/p>\n

\"2\"<\/p>\n

(a) NCMT-1000\u4e2d\u7684N\u76841s\u8f68\u9053\u7684XPS\u56fe\u8c31\u3002(b) NCMT-1000\u7684TEM\u56fe\u548c\u5bf9\u5e94\u7684C\u7684EELS\u56fe(c)\u548cN\u7684EELS\u56fe(d)\u3002<\/p>\n

\u56fe3.NCMT-1000\u53caNCMT-1000(3D)\u7684\u6027\u80fd\u00a0<\/strong><\/p>\n

\"3\"<\/p>\n

(a)1600\u8f6c\u4e0b\u5728O2<\/sub>-\u9971\u548cNaOH\u6eb6\u6db2(0.1M)\u4e2dNCMT-1000\u548cNCMT-1000(3D)\u6c27\u8fd8\u539f\u53cd\u5e94\u7684RRDE\u6781\u5316\u66f2\u7ebf\u548cH2<\/sub>O2<\/sub>\u4ea7\u91cf\u56fe\uff0c\u50ac\u5316\u5242\u8f7d\u91cf\u4e3a0.82mg cm-2<\/sup>\u3002<\/p>\n

(b)\u4f4e\u8f7d\u91cf(0.16mg cm-2<\/sup>)\u548c\u9ad8\u8f7d\u91cf(0.82mg cm-2<\/sup>)\u7684NCMT-1000\u4ee5\u53ca\u5546\u7528Pt\/C\u50ac\u5316\u5242\u6c27\u8fd8\u539f\u53cd\u5e94\u7684RRDE\u6781\u5316\u66f2\u7ebf\u548cH2<\/sub>O2<\/sub>\u4ea7\u91cf\u56fe\u3002<\/p>\n

(c)NCMT-1000\u3001NCMT-1000(3D)\u3001Ir\/C\u4ee5\u53caPt\/C\u7684\u6c27\u7535\u6781\u6027\u80fd\u3002<\/p>\n

(d)\u4ee5\u524d\u62a5\u9053\u7684\u53cc\u529f\u80fd\u7684\u78b3\u57fa\u50ac\u5316\u5242\u548cNCMT-1000\u3001NVMT-1000(3D)\u7684\u50ac\u5316\u6027\u80fd\u5bf9\u6bd4\u56fe\u3002<\/p>\n

\u56fe4.\u4e0d\u540cNCMT\u7cfb\u5217\u6837\u54c1\u7684\u6027\u80fd<\/strong><\/p>\n

\"4\"<\/p>\n

(a)\u901a\u8fc7\u8ba1\u65f6\u7535\u6d41\u53cd\u5e94\u6d4b\u8bd5\u8bc4\u4f30NCMT-1000\u548cPt\/C\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

(b) NCMT-1000\u7684\u50ac\u5316\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

(c) NCMT-800\u3001NCMT-900\u3001NCMT-1000\u3001NCMT-1100\u57281600\u8f6c\u4e0bO2<\/sub>-\u9971\u548cKOH\u6eb6\u6db2(0.1M)\u4e2d\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\u7684RRDE\u6781\u5316\u66f2\u7ebf\u548cH2<\/sub>O2<\/sub>\u4ea7\u91cf\u56fe\uff0c\u50ac\u5316\u5242\u8f7d\u91cf\u4e3a0.16mg cm-2<\/sup>\u3002<\/p>\n

(d) NCMT-800\u3001NCMT-900\u3001NCMT-1000\u3001NCMT-1100\u4e2dN\u7684\u542b\u91cf\u548c\u7c7b\u578b\u3002<\/p>\n

\u5c55\u671b:<\/strong><\/span><\/p>\n

\u7eb3\u7c73\u591a\u5b54\u7684N\u63ba\u6742\u78b3\u6750\u6599\u7531\u4e8e\u5b83\u4eec\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u72ec\u7279\u7684\u7535\u6027\u8d28\u53ca\u826f\u597d\u7684\u7a33\u5b9a\u6027\u5df2\u7ecf\u6210\u4e3a\u6c27\u7535\u6781\u50ac\u5316\u5242\u7684\u53e6\u4e00\u79cd\u9009\u62e9\uff0c\u66f4\u597d\u7684\u63a8\u8fdb\u4e863D\u67d4\u6027\u7535\u50ac\u5316\u5242\u7684\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u5218\u7545\u7814\u7a76\u5458\u7b80\u4ecb\uff1a<\/strong><\/p>\n

\u5218\u7545\uff0c\u4e2d\u79d1\u9662\u535a\u58eb\uff0c\u82ac\u5170Aalto\u5927\u5b66\u9ad8\u7ea7\u8bbf\u95ee\u5b66\u8005\uff0c\u73b0\u4efb\u4e2d\u56fd\u79d1\u5b66\u9662\u91d1\u5c5e\u7814\u7a76\u6240\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u3002\u4e3b\u8981\u4ece\u4e8b\u78b3\u7eb3\u7c73\u7ba1\u7684\u5236\u5907\u3001\u6027\u80fd\u4e0e\u5e94\u7528\u63a2\u7d22\u7814\u7a76\u3002\u7387\u5148\u63d0\u51fa\u4e86\u5b8f\u91cf\u5236\u5907\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7684\u6c22\u7535\u5f27\u65b9\u6cd5\uff0c\u5229\u7528\u6c22\u5728\u9ad8\u6e29\u4e0b\u5bf9\u65e0\u5b9a\u5f62\u70ad\u7b49\u6742\u8d28\u7684\u523b\u8680\u4f5c\u7528\uff0c\u83b7\u5f97\u7eaf\u5ea6\u9ad8\u3001\u7ed3\u6784\u5b8c\u6574\u6027\u597d\u7684\u5355\u58c1\u3001\u53cc\u58c1\u78b3\u7eb3\u7c73\u7ba1\u53ca\u5176\u5b8f\u89c2\u7ef3\u72b6\u7ed3\u6784\uff08Adv Mater 2000; Carbon 1999, 2005\uff09\uff1b\u5229\u7528\u91d1\u5c5e\u6027\u548c\u534a\u5bfc\u4f53\u6027\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u5728\u5316\u5b66\u7a33\u5b9a\u6027\u4e0a\u7684\u5dee\u5f02\uff0c\u63d0\u51fa\u4e86\u6c27\u8f85\u52a9\u6d6e\u52a8\u50ac\u5316\u5242\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\u751f\u957f\u534a\u5bfc\u4f53\u6027\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\uff0c\u76f4\u63a5\u5236\u5907\u5f97\u5230\u534a\u5bfc\u4f53\u6027\u78b3\u7eb3\u7c73\u7ba1\u542b\u91cf\u8fbe\u523090%\u7684\u5b8f\u91cf\u6837\u54c1\uff08JACS 2011; Carbon 2010\uff09\uff1b\u5efa\u7acb\u4e86\u4e00\u79cd\u78b3\u7eb3\u7c73\u7ba1\u751f\u957f\u673a\u5236\u7684\u900f\u5c04\u7535\u955c\u539f\u4f4d\u7814\u7a76\u65b9\u6cd5\uff0c\u5bf9\u6bd4\u7814\u7a76\u4e86\u91d1\u5c5e\u548c\u975e\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u50ac\u5316\u751f\u957f\u78b3\u7eb3\u7c73\u7ba1\u7684\u8fc7\u7a0b\u548c\u673a\u5236\uff0c\u5e76\u7387\u5148\u63d0\u51fa\u975e\u91d1\u5c5e\u50ac\u5316\u751f\u957f\u78b3\u7eb3\u7c73\u7ba1\u7684\u6c14-\u56fa-\u56fa\u673a\u7406\uff08Carbon 2009; JACS 2009 & 2011\uff09\uff1b\u7814\u7a76\u53d1\u73b0\u5b9a\u5411\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1\u7ef3\u5177\u6709\u4f18\u5f02\u7684\u573a\u53d1\u5c04\u6027\u80fd\uff0c\u8fdb\u800c\u63d0\u51fa\u5176\u4e8c\u7ea7\u589e\u5f3a\u573a\u53d1\u5c04\u673a\u5236\uff08APL 2005; JAP 2005\uff09\uff1b\u9996\u6b21\u8bbe\u8ba1\u5236\u5907\u51fa\u78b3\u7eb3\u7c73\u7ba1\u5939\u6301\u91d1\u5c5e\u539f\u5b50\u94fe\uff0c\u7406\u8bba\u548c\u5b9e\u9a8c\u7814\u7a76\u53d1\u73b0\u5176\u5177\u6709\u91cf\u5b50\u5316\u7535\u5bfc\uff0c\u4e3a\u91d1\u5c5e\u539f\u5b50\u94fe\u7684\u8fde\u63a5\u4e0e\u96c6\u6210\u63d0\u4f9b\u4e86\u65b0\u9014\u5f84\uff08PNAS, 2010\uff09\uff1b\u7814\u5236\u51fa\u5177\u6709\u4f18\u5f02\u500d\u7387\u6027\u80fd\u548c\u826f\u597d\u5faa\u73af\u7a33\u5b9a\u6027\u7684\u78b3\u7eb3\u7c73\u7ba1\u590d\u5408\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\uff08Adv Energy Mater 2011; Adv Mater 2010; Chem Comm 2010\uff09\uff0c\u5e76\u83b7\u5f97\u4e86\u5b9e\u9645\u5e94\u7528\uff08\u8f6c\u8ba9\u4e13\u5229\uff1aZL200410021395.X\uff09\u3002\u5df2\u5728Proc National Acad Sci USA, Nano Letters, J Am Chem Soc, Adv Mater, ACS Nano, Chem Comm\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868SCI\u6536\u5f55\u8bba\u6587100\u4f59\u7bc7\uff0c\u5176\u4e2d\u5f71\u54cd\u56e0\u5b50\u5927\u4e8e4.0\u768445\u7bc7\uff0c\u88ab\u5f15\u75284000\u4f59\u6b21\u3002\u83b7\u5f97\u4e13\u5229\u6388\u674328\u9879\uff0c\u5176\u4e2d\u5305\u62ec\u7f8e\u56fd\u548c\u6b27\u76df\u4e13\u5229\u54041\u9879\uff1b\u5df2\u67091\u9879\u4e2d\u56fd\u4e13\u5229\u8f6c\u8ba9\u5b9e\u65bd\u3002\u5206\u522b\u5728\u56fd\u9645\u3001\u56fd\u5185\u5b66\u672f\u4f1a\u8bae\u4e0a\u4f5c\u9080\u8bf7\u62a5\u544a9\u6b21\u548c4\u6b21\u3002(\u901a\u8baf\u4f5c\u8005\u4fe1\u606f\u6765\u6e90\u4e8e\u4e2d\u56fd\u79d1\u5b66\u9662\u91d1\u5c5e\u7814\u7a76\u6240\u5b98\u7f51)<\/p>\n

\u00a0<\/strong>\u539f\u6587\u94fe\u63a5\uff1a<\/strong>A 3D bi-functional porous N-doped carbonmicrotube sponge electrocatalyst for oxygen reduction and oxygen evolution reactions<\/a>(Energy Environ.Sci.,2016,DOI:10.1039\/c6ee02169g)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4YenHo\u4f9b\u7a3f\uff0c\u70b9\u8fd9\u91cc\u52a0\u5165\u6750\u6599\u4eba\u7684\u5927\u5bb6\u5ead<\/a>\u3002\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d,\u6b22\u8fce\u5173\u6ce8\u5fae\u4fe1\u516c\u4f17\u53f7\uff0c\u5fae\u4fe1\u641c\u7d22\u201c\u65b0\u80fd\u6e90\u524d\u7ebf\u201d\u6216\u626b\u7801\u5173\u6ce8\u3002\"\u65b0\u80fd\u6e90\u524d\u7ebf\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u6c27\u6c14\u8fd8\u539f\u53cd\u5e94\u548c\u6790\u6c27\u53cd\u5e94\u5bf9\u4e8e\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u80fd\u6e90\u5668\u4ef6\u800c\u8a00\u662f\u975e\u5e38\u5173\u952e\u7684\u7535\u50ac\u5316\u8fc7\u7a0b\uff0c\u5982\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u4ee5\u53ca\u88c2\u89e3\u6c34\u7b49\u3002\u7531\u4e8e\u8fc7\u7535\u52bf\u7684\u5b58\u5728\u5bfc\u81f4\u8fd9\u4e2a\u8fc7\u7a0b\u53cd…<\/p>\n","protected":false},"author":1405,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[116,76],"class_list":["post-39152","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-catalyst","tag-carbon"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/39152"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1405"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=39152"}],"version-history":[{"count":12,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/39152\/revisions"}],"predecessor-version":[{"id":39677,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/39152\/revisions\/39677"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=39152"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=39152"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=39152"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}