{"id":41171,"date":"2016-09-21T06:30:03","date_gmt":"2016-09-20T22:30:03","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=41171"},"modified":"2017-03-18T21:19:23","modified_gmt":"2017-03-18T13:19:23","slug":"adv-energy-mater-%e5%8f%96%e4%bb%a3%e8%b4%b5%e9%87%91%e5%b1%9e%e7%9a%84ni3fe-n%e5%8f%82%e6%9d%82%e7%9a%84%e6%96%b0%e5%9e%8b%e5%8f%8c%e5%ae%98%e8%83%bd%e5%9b%a2%e7%94%b5%e6%9e%81%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=41171","title":{"rendered":"Adv. Energy Mater. \u53d6\u4ee3\u8d35\u91d1\u5c5e\u7684Ni3Fe-N\u63ba\u6742\u7684\u65b0\u578b\u53cc\u5b98\u80fd\u56e2\u7535\u6781\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u950c-\u7a7a\u6c14\u7535\u6c60\u662f\u4ee5\u7a7a\u6c14\u4e2d\u7684\u6c27\u4e3a\u6b63\u6781\uff0c\u950c\u4e3a\u8d1f\u6781\u7684\u4e00\u79cd\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\uff0c\u7531\u4e8e\u91d1\u5c5e\u950c\u50a8\u91cf\u4e30\u5bcc\u5e76\u4e14\u53ef\u4ee5\u7535\u89e3\u56de\u6536\uff0c\u6b63\u6781\u4f7f\u7528\u6c27\u6c14\u6210\u672c\u57fa\u672c\u53ef\u4ee5\u5ffd\u7565\uff0c\u6240\u4ee5\u7535\u6c60\u9020\u4ef7\u8f83\u4f4e\u3002\u9664\u6b64\u4ee5\u5916\u8fd8\u6709\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\uff0c\u5b89\u5168\u6027\u80fd\u597d\u7b49\u7279\u70b9\uff0c\u500d\u53d7\u7814\u7a76\u8005\u5173\u6ce8\u3002<\/p>\n

\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u9634\u6781\u6240\u7528\u7684\u50ac\u5316\u5242\u8d77\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u653e\u7535\u65f6\u6c27\u6c14\u51cf\u5c11\uff0cPt\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5145\u7535\u65f6\u5219\u91c7\u7528IrO2\u6216RuO2\uff0c\u7136\u800c\u4ed6\u4eec\u4e0d\u4ec5\u4ef7\u683c\u6602\u8d35\uff0c\u800c\u4e14\u5faa\u73af\u5bff\u547d\u6709\u9650\uff0c\u6211\u4eec\u9700\u8981\u4e00\u79cd\u6d3b\u6027\u9ad8\uff0c\u6027\u80fd\u7a33\u5b9a\u800c\u4e14\u4ef7\u683c\u4f4e\u7684\u65b0\u578b\u50ac\u5316\u5242\u53d6\u4ee3\u4ed6\u4eec\u3002<\/p>\n

\u91c7\u7528\u8fc7\u6e21\u65cf\u91d1\u5c5e\uff0c\u5982Mn\u3001Co\u3001Ni\u7b49\u548c\u4ed6\u4eec\u7684\u884d\u751f\u7269\u4f5c\u4e3a\u7a7a\u6c14\u7535\u6781\u50ac\u5316\u5242\uff0c\u53d6\u5f97\u4e86\u5f88\u597d\u7684\u6548\u679c\u30021952\u5e74Edison\u548cJungner\u4e24\u4f4d\u79d1\u5b66\u5bb6\u53d1\u73b0\u672a\u7ecf\u7eaf\u5316\u7684Fe\u5728Ni\u57fa\u7684\u78b1\u6027\u7535\u6c60\u4e2d\u4f1a\u53d1\u751f\u4e2d\u6bd2\uff0c\u7ecf\u8fc7\u8be6\u7ec6\u7814\u7a76\u53d1\u73b0Ni-Fe\u5408\u91d1\u7684\u50ac\u5316\u5242\u5728ORR(O2<\/sub> + 2H2<\/sub>O + 4e\u2212<\/sup> \u2192 4OH\u2013<\/sup>)\u53cd\u5e94\u4e2d\u5177\u6709\u5f88\u597d\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u53cd\u4e4b\u4e0d\u7136\u3002\u5728OER\uff084OH– <\/sup>\u2192O2<\/sub> + 2H2<\/sub>O + 4e\u2212<\/sup> \uff09\u65b9\u9762,\u78b3\u53c2\u6742N\u3001P\u6216S\u7b49\u5143\u7d20\u7ec4\u6210\u7684\u50ac\u5316\u5242\u5177\u6709\u9ad8\u6548\u7387\u3001\u4f4e\u6210\u672c\u7b49\u7279\u70b9\u3002\u7406\u8bba\u4e0a\u8fd9\u4e24\u79cd\u50ac\u5316\u5242\u7ec4\u6210\u53cc\u5b98\u80fd\u56e2\u7684\u50ac\u5316\u5242\uff0c\u53d6\u4ee3Pt\u548cRu\u7b49\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u4e00\u5b9a\u4f1a\u67091+1\uff1e2\u7684\u6548\u679c\uff0c\u7ed3\u679c\u5374\u4e0d\u5c3d\u4eba\u610f\uff1a\u5408\u91d1\u9897\u7c92\u65e0\u6cd5\u56fa\u5b9a\u5728\u78b3\u57fa\u5e95\u4e0a\uff0c\u751a\u81f3\u4f1a\u6269\u6563\u5f00\u6765\u964d\u4f4e\u7535\u6c60\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u6765\u81ea\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u7684John B. Goodenough\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u548c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5510\u4e9a\u6587\u6559\u6388<\/strong>\u7684\u8bfe\u9898\u7ec4\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u7ed3\u6784\u7684\u50ac\u5316\u5242\uff0c\u8bbe\u8ba1\u601d\u8def\u662fNi3<\/sub>Fe\u7eb3\u7c73\u9897\u7c92\u5d4c\u5165\u5230N\u63ba\u6742\u76842D\u591a\u5b54\u5c42\u72b6\u77f3\u58a8\u78b3\u4e2d\uff0c\u5f62\u6210Ni3<\/sub>Fe\/N-C\u5c42\u3002\u5b9e\u9a8c\u8bc1\u660e\u5728ORR\u548cOER\u53cd\u5e94\u4e2d\uff0c\u8fd9\u79cd\u65b0\u578b\u53cc\u5b98\u80fd\u56e2\u50ac\u5316\u5242\u6d3b\u6027\u9ad8\u4e14\u7a33\u5b9a\u6027\u597d\uff0c\u56e0\u4e3aNi3<\/sub>Fe\u7eb3\u7c73\u9897\u7c92\u5d4c\u5165\u5230\u4e862D\u7f51\u72b6\u77f3\u58a8\u78b3\u4e2d\uff0c\u6240\u4ee5\u5faa\u73af\u7a33\u5b9a\u6027\u975e\u5e38\u597d\u3002\u88c5\u914d\u5728\u950c\u7a7a\u6c14\u7535\u6c60\u7684\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u8fd9\u79cd\u65b0\u578b\u7ed3\u6784\u7684\u5faa\u73af\u5bff\u547d\u8fdc\u9ad8\u4e8e\u5148\u524d\u6d41\u884c\u7684Pt\/C + IrO2 \u00a0<\/sub>\u7ec4\u6210\u7684\u9634\u6781\u50ac\u5316\u5242\u3002<\/p>\n

\u56fe1.\u00a0Ni3<\/sub>Fe\/N-C \u50ac\u5316\u5242\u5c42\u5408\u6210\u6b65\u9aa4\u53ca\u8868\u5f81<\/strong><\/p>\n

\"1\"<\/p>\n

a) .Ni3<\/sub>Fe\/N-C \u50ac\u5316\u5242\u5c42\u7684\u5408\u6210\u6b65\u9aa4\u56fe<\/p>\n

b).XRD\u884d\u5c04\u56fe<\/p>\n

c).\u70ed\u91cd\u91cf\u5206\u6790(TGA)\u66f2\u7ebf<\/p>\n

\u56fe2.\u00a0 Ni3<\/sub>Fe\/N-C \u5c42\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"2\"<\/p>\n

a,b).\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c(SEM)\u7167\u7247\uff1a\u767d\u8272\u7bad\u5934\u8868\u793a\u5747\u4e00\u5206\u5e03\u7684Ni3<\/sub>Fe\u9897\u7c92\uff0c\u7ea2\u8272\u7bad\u5934\u8868\u793a\u88c5\u914d\u9897\u7c92\u540e\u5f62\u6210\u7684\u7eb3\u7c73\u5b54<\/p>\n

c).\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(TEM)\u7167\u7247<\/p>\n

d).\u56fe(c)\u4e2d\u7ea2\u8272\u65b9\u6846\u5185\u7684\u9ad8\u5206\u8fa8\u653e\u5927\u56fe\u50cf<\/p>\n

\u56fe3. <\/strong> Ni3<\/sub>Fe\/N-C \u5c42\u4e2d\u63ba\u6742\u76f8\u5206\u5e03\u60c5\u51b5\u53ca\u80fd\u8c31\u5206\u6790<\/p>\n

\"3\"<\/p>\n

a).Ni3<\/sub>Fe\/N-C\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(STEM)\u7167\u7247\u548cNi\u3001Fe\u3001C\u3001N\u7684X\u5c04\u7ebf\u80fd\u8c31\u56fe<\/p>\n

b).EDX\u56fe\u8c31\u5bf9Ni3<\/sub>Fe\/N-C\u7684\u5206\u6790<\/p>\n

c).X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u4eea\u5bf9Ni3<\/sub>Fe\/N-C\u7684\u5206\u6790<\/p>\n

\u56fe4. \u00a0Ni3<\/sub>Fe\/N-C sheets, Ni3<\/sub>Fe\/C sheets, \u5206\u6563\u7684 Ni3<\/sub>Fe\/C, \u548c IrO2<\/sub>\u5728OER\u8fc7\u7a0b\u4e2d\u5206\u522b\u7684\u6027\u80fd\u6d4b\u8bd5<\/strong>\uff1a<\/p>\n

\"4\"<\/p>\n

a).O2 <\/sub>\u9971\u548c\u76841 m KOH\u6807\u51c6\u6db2\u4e2dOER\u8fc7\u7a0b\u7684\u6781\u5316\u504f\u632f\u66f2\u7ebf\uff08\u81ea\u4f20\u901f\u7387\uff1a1600rmp;\u626b\u63cf\u9891\u7387\uff1a5mV s-1 <\/sup>\uff09,\u63d2\u56fe\u6240\u793a\u7535\u6d41\u5bc6\u5ea6\u4e3a1.60 V<\/p>\n

b).\u7535\u6d41\u5bc6\u5ea6\u4e3a10mA cm -1 <\/sup>\u6761\u4ef6\u4e0b\u7684\u8fc7\u7535\u538b\u6d4b\u8bd5\u56fe<\/p>\n

c).\u56fe(a)\u7684\u5854\u83f2\u5c14\u66f2\u7ebf<\/p>\n

d).\u56db\u79cd\u6837\u54c1\u572860 V \u65f6 \uff0c\u5728O2<\/sub>\u6e17\u900f\u76840.1 m KOH \u6761\u4ef6\u4e2d\u50ac\u5316\u6548\u679c\u8ba1\u65f6\u56fe<\/p>\n

\u56fe5. Ni3<\/sub>Fe\/N-C sheets, Ni3<\/sub>Fe\/C sheets, \u5206\u6563\u7684 Ni3<\/sub>Fe\/C, \u548c Pt\/C \u5206\u522b\u5728ORR\u8fc7\u7a0b\u4e2d\u5206\u522b\u7684\u6027\u80fd\u6d4b\u8bd5<\/strong>\uff1a<\/p>\n

\"5\"<\/p>\n

a).O2 <\/sub>\u9971\u548c\u76841 m KOH\u6807\u51c6\u6db2\u4e2dORR\u8fc7\u7a0b\u7684\u6781\u5316\u504f\u632f\u66f2\u7ebf\uff08\u81ea\u4f20\u901f\u7387\uff1a1600rmp;\u626b\u63cf\u9891\u7387\uff1a5mV s-1 <\/sup>\uff09,\u63d2\u56fe\u6240\u793a\u7535\u6d41\u5bc6\u5ea6\u4e3a1.60 V<\/p>\n

b).\u56db\u79cd\u6837\u54c1\u5728\u4e0d\u540c\u767e\u5206\u542b\u91cf\u7684\u8fc7\u6c27\u5316\u6c22\u4e2d\u50ac\u5316\u53ca\u5176\u5728\u8be5\u7535\u4f4d\u4e0b\u7535\u5b50\u8f6c\u79fb\u91cf<\/p>\n

c).\u56db\u79cd\u6837\u54c1\u57287 V \u65f6\uff0c O2<\/sub>\u6e17\u900f\u7684 0.1 m KOH \u6761\u4ef6\u4e2d\u50ac\u5316\u6548\u679c\u8ba1\u65f6\u56fe<\/p>\n

d).ORR\u548cOER\u7535\u5316\u5b66\u7a97\u53e3\u5185\u56db\u79cd\u6837\u54c1\u7684\u6781\u5316\u504f\u632f\u66f2\u7ebf\uff0c\u63d2\u56fe\u662f\u56db\u79cd\u50ac\u5316\u5242\u5171\u540c\u7684\u6709\u6548\u50ac\u5316\u5e73\u53f0<\/p>\n

\u56fe6.\u00a0\u950c\u7a7a\u6c14\u7535\u6c60\u7684\u5145\u653e\u7535\u6d4b\u8bd5\u56fe\uff08\u7535\u6d41\u5bc6\u5ea6\uff1a10mV cm-1<\/sup> \uff0c\u5ba4\u6e29\uff09<\/strong><\/p>\n

\"6\"<\/p>\n

a,b). Ni3<\/sub>Fe\/N-C\u5c42\u50ac\u5316\u5242\u7535\u6c60<\/p>\n

c,d).\u4f20\u7edf\u7684Pt\/C+IrO2 <\/sub>\u6df7\u5408\u578b\u50ac\u5316\u5242<\/p>\n

\u5c55\u671b\uff1a<\/strong><\/p>\n

\u63d0\u5230\u9ad8\u6548\u50ac\u5316\u5242\u9996\u5148\u60f3\u5230\u7684\u662fPt\u3001Rh\u548cPd\u7b49\u8d35\u91d1\u5c5e,\u7531\u4e8e\u9ad8\u6602\u7684\u9020\u4ef7\u5236\u7ea6\u4e86\u5546\u4e1a\u5316\u7684\u5e94\u7528\uff0c\u6765\u81ea\u7f8e\u56fd\u5fb7\u5dde\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u7684\u9502\u7535\u5927\u5e08John B. Goodenough\u548c\u4ed6\u7684\u56e2\u961f\u6210\u5458\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u53cc\u5b98\u80fd\u56e2\u50ac\u5316\u5242\uff0c\u5c06\u50ac\u5316ORR\u53cd\u5e94\u7684\u50ac\u5316\u7ec4\u5206\u5d4c\u5165\u52302D\u591a\u5b54\u77f3\u58a8\u78b3\u7684\u7f51\u683c\u4e2d\uff0c\u50ac\u5316OER\u53cd\u5e94\u7684\u50ac\u5316\u7ec4\u5206\u63ba\u6742\u5230\u77f3\u58a8\u78b3\u6846\u67b6\u4e0a\uff0c\u65b0\u5408\u6210\u7684\u50ac\u5316\u5242\u5e94\u7528\u5728\u950c\u7a7a\u6c14\u7535\u6c60\u7684\u9634\u6781\uff0c\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u52a0\u901f\u6c27\u6c14\u7684\u751f\u6210\u548c\u6d88\u8017\u3002\u7531\u4e8e\u77f3\u58a8\u78b3\u6574\u4f53\u6846\u67b6\u7684\u9650\u5236\uff0c\u4f7f\u5176\u7ed3\u6784\u53d8\u5f97\u7a33\u5b9a\uff0c\u5faa\u73af\u5bff\u547d\u76f8\u5e94\u589e\u9ad8\uff0c\u76f8\u5bf9\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6210\u672c\u5927\u5927\u964d\u4f4e\uff0c\u5e94\u7528\u524d\u666f\u5e7f\u9614\u3002<\/p>\n

John B. Goodenough\u6559\u6388\u7b80\u4ecb\uff08\u9aa8\u7070\u7ea7\u9502\u7535\u5927\u725b\uff09<\/strong><\/p>\n

John B. Goodenough\uff08\u7ea6\u7ff0\u00b7\u73ed\u5b81\u65af\u7279\u00b7\u53e4\u8fea\u7eb3\u592b\uff09\u76ee\u524d\u4e3a\u7f8e\u56fd\u5fb7\u5dde\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\uff0c\u673a\u68b0\u5de5\u7a0b\u7cfb\u6559\u6388\uff0c\u8457\u540d\u56fa\u4f53\u7269\u7406\u5b66\u5bb6\uff0c\u662f\u94b4\u9178\u9502\u3001\u9530\u9178\u9502\u548c\u78f7\u9178\u94c1\u9502\u6b63\u6781\u6750\u6599\u7684\u53d1\u660e\u4eba\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5960\u57fa\u4eba\u4e4b\u4e00\uff0c\u88ab\u4e1a\u754c\u79f0\u4e3a\u201c\u9502\u7535\u4e4b\u7236\u201d\u3002\u4ed6\u5bf9\u6750\u6599\u79d1\u5b66\u4e0e\u6280\u672f\uff0c\u7279\u522b\u662f\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u505a\u51fa\u4e86\u91cd\u8981\u8d21\u732e\u3002\u901a\u8fc7\u7814\u7a76\u5316\u5b66\u3001\u7ed3\u6784\u4ee5\u53ca\u56fa\u4f53\u7535\u5b50\/\u79bb\u5b50\u6027\u8d28\u4e4b\u95f4\u7684\u5173\u7cfb\u6765\u8bbe\u8ba1\u65b0\u6750\u6599\u89e3\u51b3\u6750\u6599\u79d1\u5b66\u95ee\u9898\u3002
\n1952-1976\u5e74\uff0c\u9996\u6b21\u53d1\u73b0\u4e86\u94c1\u6c27\u4f53\u78c1\u82af\u7684\u7535\u6d41\u91cd\u5408\u8bb0\u5fc6\u529f\u80fd\uff0c\u88ab\u79f0\u4e3aGoodenough-Kanamori\u89c4\u5f8b\uff0c\u8fd9\u4e00\u53d1\u73b0\u5bf9\u7535\u5b50\u8ba1\u7b97\u673a\u7684\u53d1\u5c55\u6781\u4e3a\u5173\u952e\u3002
\n1976\u5e74\uff0c\u5f00\u59cb\u56fa\u4f53\u5316\u5b66\u7814\u7a76\uff0c\u4e3b\u8981\u7814\u7a76\u53ef\u7528\u4e8e\u80fd\u91cf\u8f6c\u6362\u7684\u65b0\u6750\u6599\uff0c\u63d0\u51fa\u4e86\u78b1\u91d1\u5c5e\u79bb\u5b50\u56fa\u6001\u7535\u89e3\u8d28\u7684\u6784\u67b6\u7ed3\u6784\u6982\u5ff5\u5e76\u4e14\u83b7\u5f97\u4e86\u4ee5\u5c16\u6676\u77f3\u5c42\u72b6\u7ed3\u6784\u6c27\u5316\u7269\u4f5c\u4e3a\u9634\u6781\u7684\u9502\u79bb\u5b50\u4e8c\u6b21\u7535\u6c60\u7684\u57fa\u672c\u4e13\u5229\u3002
\n1980\u5e74\u548cSONY\u516c\u53f8\u5408\u4f5c\u5f00\u53d1\u51fa\u4e86\u57fa\u4e8e\u78b3\u6750\u6599\u8d1f\u6781\u548c\u9502\u94b4\u6c27LiCoO2\u6750\u6599\u6b63\u6781\u7684\u53ef\u5145\u7535\u79bb\u5b50\u7535\u6c60\uff0c\u4e5f\u5c31\u662f\u76ee\u524d\u5e7f\u6cdb\u91c7\u7528\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6280\u672f\uff0c\u4f46\u662fLiCoO2\u53d7\u9650\u4e8e\u6709\u6bd2\u3001\u94b4\u8d44\u6e90\u7a00\u7f3a\u7b49\u56e0\u7d20\uff0c\u6025\u9700\u66ff\u4ee3\u6750\u6599\u3002
\n1982\u5e74\u4f0a\u5229\u8bfa\u4f0a\u7406\u5de5\u5927\u5b66R.R.Agarwal\u548cJ.R.Selman\u53d1\u73b0\u9502\u79bb\u5b50\u5177\u6709\u5d4c\u5165\u77f3\u58a8\u7684\u7279\u6027\uff0c\u9996\u4e2a\u53ef\u7528\u7684\u9502\u79bb\u5b50\u77f3\u58a8\u7535\u6781\u7531\u8d1d\u5c14\u5b9e\u9a8c\u5ba4\u8bd5\u5236\u6210\u529f\u3002
\n1983\u5e74M.Thackeray\u548cGoodenough\u7b49\u4eba\u53d1\u73b0\u9530\u5c16\u6676\u77f3\u662f\u4f18\u826f\u7684\u6b63\u6781\u6750\u6599\uff0c\u5177\u6709\u4f4e\u4ef7\u3001\u7a33\u5b9a\u548c\u4f18\u826f\u7684\u5bfc\u7535\u3001\u5bfc\u9502\u6027\u80fd\u3002\u5176\u5206\u89e3\u6e29\u5ea6\u9ad8\uff0c\u4e14\u6c27\u5316\u6027\u8fdc\u4f4e\u4e8e\u94b4\u9178\u9502\uff0c\u5373\u4f7f\u51fa\u73b0\u77ed\u8def\u3001\u8fc7\u5145\u7535\uff0c\u4e5f\u80fd\u591f\u907f\u514d\u4e86\u71c3\u70e7\u3001\u7206\u70b8\u7684\u5371\u9669\uff0c\u5927\u5927\u63d0\u9ad8\u5b89\u5168\u6027\u3002
\n1997\u5e74\u5f00\u53d1\u4e86\u4f4e\u6210\u672c\u7684\u78f7\u9178\u94c1\u9502LiXFePO4\u6b63\u6781\u6750\u6599\uff0c\u52a0\u5feb\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u5546\u4e1a\u5316\u3002\u5176\u5e7f\u6cdb\u5e94\u7528\u4e8e\u624b\u673a\u7b49\u65e0\u7ebf\u4fbf\u643a\u8bbe\u5907\u3001\u7535\u52a8\u5de5\u5177\u3001\u6df7\u5408\u52a8\u529b\u6c7d\u8f66\u3001\u5c0f\u578b\u7535\u52a8\u8f66\u4ee5\u53ca\u65b0\u80fd\u6e90\u7cfb\u7edf\u50a8\u80fd\uff0c\u5df2\u6210\u4e3a\u5f53\u524d\u4e3b\u6d41\u7684\u6b63\u6781\u6750\u6599\uff0c\u5b83\u5bf9\u5168\u7403\u7ecf\u6d4e\u4ea7\u751f\u4e86\u91cd\u8981\u5f71\u54cd\uff0c\u5e76\u51cf\u5c11\u4e86\u6e29\u5ba4\u6c14\u4f53\u7684\u6392\u653e\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5<\/strong>\uff1aNi3Fe-N Doped Carbon Sheets as a Bifunctional Electrocatalyst for Air Cathodes<\/a>\u00a0 \uff08Adv.\u00a0Energy\u00a0Mater. \uff0c2016\uff0cDOI:<\/span>10.1002\/aenm.201601172<\/span>\uff09<\/p>\n

\u8be5\u6587\u732e\u5bfc\u8bfb\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u5c0f\u7ec4 yuezhou \u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\"2016-08-\u65b0\u80fd\u6e90\u524d\u7ebf-2\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u950c-\u7a7a\u6c14\u7535\u6c60\u662f\u4ee5\u7a7a\u6c14\u4e2d\u7684\u6c27\u4e3a\u6b63\u6781\uff0c\u950c\u4e3a\u8d1f\u6781\u7684\u4e00\u79cd\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\uff0c\u7531\u4e8e\u91d1\u5c5e\u950c\u50a8\u91cf\u4e30\u5bcc\u5e76\u4e14\u53ef\u4ee5\u7535\u89e3\u56de\u6536\uff0c\u6b63\u6781\u4f7f\u7528\u6c27\u6c14\u6210\u672c\u57fa\u672c\u53ef\u4ee5\u5ffd\u7565\uff0c\u6240\u4ee5\u7535\u6c60\u9020\u4ef7\u8f83\u4f4e\u3002\u9664…<\/p>\n","protected":false},"author":1203,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1393,129],"class_list":["post-41171","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-john-b-goodenough","tag-battery"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/41171"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1203"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=41171"}],"version-history":[{"count":9,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/41171\/revisions"}],"predecessor-version":[{"id":42352,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/41171\/revisions\/42352"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=41171"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=41171"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=41171"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}