{"id":43114,"date":"2016-10-01T06:30:18","date_gmt":"2016-09-30T22:30:18","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=43114"},"modified":"2016-09-30T20:57:05","modified_gmt":"2016-09-30T12:57:05","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-eesjacsangew%e7%ad%89%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6mof%e6%9d%90%e6%96%99%e6%9c%80%e6%96%b0%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=43114","title":{"rendered":"\u9876\u520a\u52a8\u6001 | EES\/JACS\/Angew\u7b49\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u6750\u6599\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u7cbe\u9009\u3010\u7b2c9\u671f\u3011"},"content":{"rendered":"

1\u3001Energ. Environ. Sci. \u7531\u53cc-MOF\u884d\u751f\u7684\u7535\u50ac\u5316\u5242\u7528\u4e8e\u6c27\u8fd8\u539f<\/strong><\/p>\n

\u5305\u62ec\u71c3\u6599\u7535\u6c60\u548c\u91d1\u5c5e\u6c14\u8d28\u7535\u6c60\u7684\u7535\u5316\u5b66\u80fd\u6e90\u50a8\u5b58\u548c\u8f6c\u5316\u6280\u672f\u4e2d\u7528\u4e8e\u6c27\u8fd8\u539f\u7684\uff08ORR\uff09\u7684\u9ad8\u6548\u50ac\u5316\u5242\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002\u9ad8\u6027\u80fd\u548c\u4ef7\u683c\u4f4e\u5ec9\u7684ORR\u7535\u50ac\u5316\u5242\u76f8\u5bf9\u4e8e\u8d35\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb\u66f4\u6709\u5229\u4e8e\u5927\u8303\u56f4\u7684\u5de5\u4e1a\u5e94\u7528\u3002\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u7814\u7a76\u7ec4\u901a\u8fc7\u70ed\u89e3\u6cd5\u5728\u5728\u57fa\u8d28\u4e0a\u88c5\u914d\u7531\u78b3\u5316\u94c1\u7eb3\u7c73\u9897\u7c92\u5d4c\u5165N-\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u7ba1\u7528\u4e8eORR\u7684\u7535\u50ac\u5316\u5242\uff0c\u5373\u5c06\u57fa\u4e8eFe\u7684MIL-88B\u5f15\u5165\u57fa\u4e8eZn\u7684ZIF-8\u4f5c\u4e3a\u9650\u5236\u6027\u70ed\u89e3\u7684\u5171\u524d\u4f53\u3002\u7531\u4e8e\u5c0f\u5c3a\u5bf8\u7684Fe3C\u7eb3\u7c73\u6676\u548c\u591a\u5b54\u7684\u6c2e\u63ba\u6742\u78b3\u57fa\u8d28\u5f62\u6210\u7684Fe3C@\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u68d2\u5728ORR\u8fdb\u7a0b\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u7684\u7535\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u79cd\u7b56\u7565\u53ef\u7528\u4e8e\u5176\u5b83\u590d\u5408\u529f\u80fd\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\uff0c\u5e76\u4e3aMOF\u884d\u751f\u7684\u9ad8\u6d3b\u6027\u7535\u50ac\u5316\u5242\u7684\u5f00\u53d1\u63d0\u4f9b\u65b0\u65b9\u6cd5\u3002<\/p>\n

\"\u56fe\u72471\"<\/p>\n

\u00a0\u56fe1<\/strong> Fe3C\u5d4c\u5165\u6c2e\u63ba\u6742\u7684\u78b3\u7eb3\u7c73\u68d2(Fe3C@N-CNT)\u7684\u5408\u6210\u793a\u610f\u56fe<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aA dual-metal\u2013organic-framework derived electrocatalyst for oxygen reduction<\/a>\u00a0(Energ. Environ. Sci., 2016, \u00a0DOI: 10.1039\/c6ee02171a)<\/p>\n

2\u3001J. Am. Chem. Soc. \u5229\u7528\u6a21\u677f\u6548\u5e94\u53ef\u91cd\u590d\u5408\u6210\u9ad8\u5b54\u7387\u7684\u53cc\u516b\u73af\u578bmer-Zn(Im)2 (ZIF-10)<\/strong><\/p>\n

\u534e\u76db\u987f\u4e54\u6cbb\u6566\u5927\u5b66K. Travis Holman\u7814\u7a76\u7ec4\u5229\u7528\u5927\u73af\u6eb6\u5242-MeMeCH2-\u4f5c\u4e3a\u52a8\u6001\u6a21\u677f\u5b9e\u73b0\u4e86\u950c\u76d0\/\u54aa\u5511\u8102\u6750\u6599\uff08mer-Zn(Im)2 \u6216ZIF-10\uff09\u7684\u9ea6\u94be\u6cb8\u77f3\u578b\u62d3\u6251\u7ed3\u6784\u7684\u91cd\u590d\u5408\u6210\u3002\u76f8\u5bf9\u5e94\u7684\u591a\u5b54\u6027\u7eaf\u76f8\u6750\u6599 mer-MeMeCH2@Zn16(Im)32\u6bd4\u8868\u9762\u79ef\u5b9e\u9a8c\u503c\u4e3a1893 m2\/g\uff0c\u6bd4\u5df2\u62a5\u9053\u7684\u4efb\u4f55ZIF\u7cfb\u5217\u6bd4\u8868\u9762\u79ef\u90fd\u9ad8\u3002mer-MeMeCH2@Zn16(Im)32\u00b7xsolvent\u7684\u5355\u6676\u7ed3\u6784\u5c55\u73b0\u51fa\u7ecf\u6a21\u677f\u5316\u540e\u5f97\u5230\u7684\u5355\u4f4d\u6846\u67b6\u4e2d\u53cc\u516b\u73af(d8r)\u4e2d\u7684\u6c22\u952e\u53d7\u4f53\u4e2a\u6570\u662f\u672a\u6a21\u677f\u5316\u76848\u500d\u3002<\/p>\n

\"\u56fe\u72472\"<\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u56fe2<\/strong> \u5229\u7528MeMeCH2\u6a21\u677f\u5f97\u5230\u53cc\u516b\u73af\u578bmer-MeMeCH2@Zn16(Im)32\u00b7xsolvent<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aReproducible Synthesis and High Porosity of mer-Zn(Im)2 (ZIF-10):Exploitation of an Apparent Double-Eight Ring Template<\/a>\u00a0(J. Am. Chem.Soc., 2016, DOI:10.1021 \/ jacs.6b06375)<\/p>\n

3\u3001J. Am. Chem. Soc. CO2\u5728\u5927\u5c3a\u5bf8Cu-BTC\u5355\u6676\u4e2d\u7684\u6269\u6563<\/strong><\/p>\n

MOF\u5438\u9644CO2\u7528\u4e8e\u78b3\u6355\u83b7\u548c\u9694\u79bb\u5df2\u5f97\u5230\u5e7f\u6cdb\u7814\u7a76\u3002\u800c\u5bf9\u6269\u6563\u901f\u7387\u7684\u6d4b\u91cf\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u88ab\u5ffd\u7565\u3002\u8303\u5fb7\u5821\u5927\u5b66M. Douglas LeVan\u3001\u5317\u5361\u7f57\u83b1\u7eb3\u5dde\u7acb\u5927\u5b66Gregory N. Parsons\u7b49\u4eba\u901a\u8fc7\u96c6\u4e2d\u53cd\u5e94\u7269\u548c\u4e59\u9178\u8c03\u63a7\u5f97\u5230\u6beb\u7c73\u7ea7Cu-BTC\u5355\u6676\u3002\u663e\u5fae\u955c\u3001XRD\u7c89\u672b\u3001BET\u6bd4\u8868\u9762\u79ef\u3001TGA\u7b49\u8868\u5f81\u624b\u6bb5\u8bc1\u660e\u4e86Cu-BTC\u5355\u6676\u7684\u7eaf\u5ea6\u3002\u8fd9\u79cd\u5927\u5c3a\u5bf8\u5355\u6676\u6709\u5229\u4e8e\u6d4b\u91cf\u5fae\u5b54\u6269\u6563\u7cfb\u6570\u3002\u5728\u4e0d\u540c\u6c14\u76f8\u6d53\u5ea6\u4e0b\u5f97\u5230\u7684\u6269\u6563\u7cfb\u6570\u8868\u660e\u8d1f\u8f7d\u538b\u4e3a0.1bar\u5bf9\u6269\u6563\u7cfb\u6570\u7684\u5f71\u54cd\u4e0d\u5927\u3002\u6240\u6d4b\u5f97CO2\u5728Cu-BTC\u7684\u5fae\u5b54\u6269\u6563\u7cfb\u6570\u4e3a1.7 x 10-9 m2\/s.<\/p>\n

\"\u56fe\u72473\"
\n\u56fe3<\/strong> \u5927\u5c3a\u5bf8Cu-BTC\u5355\u6676\u53caCO2\u5728\u5176\u4e2d\u7684\u6269\u6563<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDiffusion of CO2 in large crystals of Cu-BTC MOF<\/a>\u00a0(J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b05930)<\/p>\n

4\u3001J. Am. Chem. Soc. \u7531MOF\u884d\u751f\u51fa\u7684\u591a\u5b54\u78b3\u80f6\u56ca\u8d1f\u8f7d\u50ac\u5316\u6d3b\u6027\u7684\u53cc\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92<\/strong><\/p>\n

\u6885\u897f\u5927\u5b66\u7684Shane G. Telfer\u548cHui Yang\u53ca\u5965\u514b\u5170\u5927\u5b66\u7684Paul E. Kruger\u7b49\u4eba\u62a5\u9053\u4e86\u5728\u4e2d\u7a7a\u63ba\u6c2e\u7684\u78b3\u80f6\u56ca\u4e2d\u5236\u5907\u5355\u91d1\u5c5e\u6216\u53cc\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u65b0\u65b9\u6cd5\u8bba\u3002\u7531MOF\u5355\u6676\u884d\u751f\u7684\u80f6\u56ca\u5916\u8868\u6d82\u8986\u91d1\u5c5e-\u5355\u5b81\u9178\u914d\u4f4d\u805a\u5408\u7269\u6216\u95f4\u82ef\u4e8c\u915a-\u7532\u919b\u805a\u5408\u7269\uff0cPt\u7eb3\u7c73\u7c92\u5b50\u5939\u4e8eMOF\u6838\u58f3\u4e4b\u95f4\u3002MOF-\u58f3\u590d\u5408\u6750\u6599\u70ed\u89e3\u5f97\u5230\u7684\u4e2d\u7a7a\u7684\u542b\u5355\u91d1\u5c5e\uff08Pt\uff0cCo\u548cNi\uff09\u6216\u53cc\u91d1\u5c5e\uff08PtCo\u548cPtNi\uff09\u591a\u5b54\u63ba\u6c2e\u78b3\u7eb3\u7c73\u6750\u6599\u3002\u4e2d\u7a7a\u80f6\u56ca\u9632\u6b62\u4e86\u7eb3\u7c73\u9897\u7c92\u7684\u70e7\u7ed3\u548c\u5206\u88c2\u4e14\u591a\u5b54\u5916\u58f3\u5141\u8bb8\u8d28\u91cf\u4f20\u9012\u3002\u5728\u4e2d\u7a7a\u80f6\u56ca\u5916\u58f3\u5750\u843d\u7740\u5df2\u7194\u5408\u7684PtCo\u7eb3\u7c73\u9897\u7c92\uff0c\u53ef\u4ee5\u4f5c\u4e3a\u82b3\u785d\u57fa\u5316\u5408\u7269\u5230\u82ef\u80fa\u7c7b\u7684\u52a0\u6c22\u53cd\u5e94\u7684\u9ad8\u6d3b\u6027\u3001\u9009\u62e9\u6027\u3001\u53ef\u56de\u6536\u7684\u50ac\u5316\u5242\u3002<\/p>\n

\"\u56fe\u72474\"<\/p>\n

\u56fe4<\/strong> \u7531MOF\u884d\u751f\u51fa\u7684\u591a\u5b54\u78b3\u80f6\u56ca\u8d1f\u8f7d\u53cc\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCatalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal\u2212Organic Framework Composites<\/a>\u00a0(J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b06736, IF=13.038)<\/p>\n

5\u3001J. Am. Chem. Soc. \u5728Zr8(\u03bc2-O)8(\u03bc2-OH)4 MOF\u8282\u70b9\u4e0a\u7684\u5355\u4f4d\u70b9\u94b4\u50ac\u5316\u5242\u7528\u4e8e\u70ef\u70c3\u3001\u4e9a\u80fa\u3001\u91d1\u5c5e\u7fb0\u57fa\u5316\u5408\u7269\u6742\u73af\u5316\u5408\u7269\u7684\u6c22\u5316\u53cd\u5e94<\/strong><\/p>\n

\u6797\u6587\u658c\u7814\u7a76\u7ec4\u5408\u6210\u57fa\u4e8eZr-\u548cHf-\u7684\u6df7\u5408\u8282\u70b9\u7684MOF\uff0c\u5177\u6709\u4ece\u672a\u62a5\u9053\u8fc7M8(\u03bc2-O)8(\u03bc2-OH)4\u7684\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u3002\u7531\u4e8e\u91d1\u5c5e\u8282\u70b9\u652f\u6491\u7684\u542b\u94b4\u6c22\u5316\u7269\u5177\u6709\u5f00\u653e\u7684\u73af\u5883\u548c\u9694\u79bb\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u7531\u94b4\u529f\u80fd\u5316\u7684Zr-MTBC-CoH\u5728\u4e00\u7cfb\u5217\u5e95\u7269\u7684\u6c22\u5316\u53cd\u5e94\u4e2d\u5177\u6709\u5f88\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u5305\u62ec\u4f4d\u963b\u5927\u3001 \u4f4e\u6d3b\u6027\u7684\u70ef\u70c3\u3001\u4e9a\u80fa\u3001\u91d1\u5c5e\u7fb0\u57fa\u5316\u5408\u7269\u3001\u6742\u73af\u5316\u5408\u7269\u3002\u8fd9\u79cd\u9ad8\u7a33\u5b9a\u3001\u4f4e\u6210\u672c\u7684\u5177\u6709\u5f02\u5e38\u6d3b\u6027\u7684\u91d1\u5c5e\u6027\u8282\u70b9\u652f\u6491\u7684\u7684MOF\u50ac\u5316\u5242\u6709\u671b\u5e94\u7528\u4e8e\u5316\u5b66\u5236\u54c1\u3001\u836f\u7269\u3001\u519c\u7528\u5316\u5b66\u54c1\u7b49\u5de5\u4e1a\u5408\u6210\u3002<\/p>\n

\"\u56fe\u72475\"<\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u56fe5<\/strong> Zr-MTBC-CoH\u7684\u5355\u6676\u7ed3\u6784\u53ca\u5bf9\u4e00\u7cfb\u5217\u5e95\u7269\u7684\u6c22\u5316\u53cd\u5e94\u7684\u50ac\u5316<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aSingle-Site Cobalt Catalysts at New Zr8(\u03bc2-O)8(\u03bc2-OH)4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines,Carbonyl and Heterocycles<\/a>\u00a0(J. Am. Chem. Soc., 2016, DOI:10.1021\/jacs. 6b06759)
\n<\/strong><\/p>\n

6\u3001J. Am. Chem. Soc. \u5728MOF\u4e2d\u8fd0\u7528\u5c40\u90e8\u914d\u4f53\u4ea4\u6362\u5efa\u7acb\u5b54\u9699\u5ea6\u5927\u5c0f\u68af\u5ea6<\/strong><\/p>\n

\u7531\u4e8e\u542b\u6709\u4e0d\u540c\u7a7a\u9699\u548c\u529f\u80fd\u7684\u76f8\u4e92\u8fde\u63a5\u7684\u7ed3\u6784\u57df\uff0c3-D\u5355\u6676\u6750\u6599\u80fd\u591f\u5728\u4e09\u7ef4\u7a7a\u95f4\u5185\u7684\u7279\u5b9a\u4f4d\u7f6e\u7ec4\u7ec7\u548c\u68ad\u52a8\u5206\u5b50\u548c\u7eb3\u7c73\u7ea7\u7269\u8d28\u3002\u7f8e\u56fd\u5339\u5179\u5821\u5927\u5b66Nathaniel L. Rosi\u7814\u7a76\u7ec4\u63d0\u51fa\u7684\u521b\u5efa\u539f\u578bMOF\u6750\u6599\u7684\u65b9\u6cd5\u4fbf\u6709\u8fd9\u6837\u7684\u7279\u70b9\u3002\u7279\u522b\u662f\u5728\u4e09\u7ef4\u7f51\u72b6\u4ecb\u5b54MOF\u6750\u6599bMOF-100\u7684\u57fa\u7840\u4e0a\u901a\u8fc7\u914d\u4f53\u4ea4\u6362\u6269\u5f20\u5b54\u7a74\u7684\u8fc7\u7a0b\u3002\u7814\u7a76\u53d1\u73b0\u5b54\u7a74\u7684\u6269\u5f20\u5728\u5355\u4e2a\u6676\u4f53\u4e2d\u7531\u201c\u5916\u201d\u5230\u201c\u5185\u201d\u7684\u6a21\u5f0f\u7f13\u6162\u9012\u589e\u3002\u5728\u5b8c\u5168\u7ed3\u6676\u524d\u901a\u8fc7\u914d\u4f53\u4ea4\u6362\u53ef\u5f97\u5230\u4e2d\u95f4\u4f53MOFs(\u547d\u540d\u4e3abMOF-100\/102\u548cbMOF-102\/106)\u4ece\u5355\u6676\u5916\u56f4\u5230\u5185\u6838\u7ecf\u5386\u4e86\u5b54\u7a74\u7684\u68af\u5ea6\u964d\u4f4e\u3002\u57fa\u4e8e\u6982\u5ff5\u7684\u9a8c\u8bc1\uff0c\u5bf9\u4e8e\u5c3a\u5bf8\u654f\u611f\u6027\u7684\u91d1\u7eb3\u7c73\u9897\u7c92\uff0cAu133(SR) 52\u9009\u62e9\u6027\u4ea4\u6362\u5230bMOF-102\/106\u5355\u6676\u7684\u5916\u56f4\u533a\u3002\u8fd9\u79cd\u65b0\u65b9\u6cd5\u5c55\u73b0\u4e86\u5728\u591a\u5b54MOF\u6750\u6599\u5185\u63a7\u5236\u5206\u5b50\u7ec4\u7ec7\u548c\u4f20\u8f93\u7684\u53ef\u80fd\u6027\u3002<\/p>\n

\"ja-2016-07445b_0001\"
\n\u00a0 \u00a0 \u00a0 \u00a0 \u56fe6<\/strong> \u901a\u8fc7\u914d\u4f53\u4ea4\u6362\u4ece bMOF-100 \u5230bMOF-102\u5230 bMOF-106 \u5230bMOF-107\u7684\u5b54\u7a74\u8fde\u7eed\u6269\u5f20\u793a\u610f\u56fe<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aEstablishing Porosity Gradients within Metal-Organic Frameworks using Partial Postsynthetic Ligand Exchange<\/a> (J. Am. Chem. Soc., 2016, DOI: 10.1021\/jacs.6b07445, IF=13.038)<\/p>\n

7\u3001Angew. Chem. Int. Ed. MOF-5-\u805a\u82ef\u4e59\u70ef\uff1a\u7531\u5355\u4f53\u76f4\u63a5\u5408\u6210\uff0c\u66f4\u4f18\u826f\u7684\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u72ec\u7279\u7684\u5ba2\u4f53\u5438\u9644\u6027<\/strong><\/p>\n

\u7f8e\u56fd\u5bc6\u6b47\u6839\u5927\u5b66Adam J. Matzger\u7814\u7a76\u7ec4\u901a\u8fc7\u7b80\u6613\u65b9\u6cd5\u5408\u6210\u4e86\u65b0\u578b\u7684MOF-5-PS\u590d\u5408\u6750\u6599\u3002\u5728\u76f8\u5bf9\u6e7f\u5ea6\u4e3a53%\u7684\u6761\u4ef6\u4e0b\uff0cMOF-5-PS-24h\u590d\u5408\u7269\uff083\u4e2a\u6708\uff09\u6bd4\u539f\u59cbMOF-5\uff084\u5c0f\u65f6\uff09\u5177\u6709\u8f83\u5f3a\u7684\u6c34\u89e3\u7a33\u5b9a\u6027\u3002MOF-5-PS-24h\u4e0e\u539f\u59cbMOF\u5438\u9644\u7532\u57fa\u7ea2\u548c\u5c3c\u7f57\u7ea2\u67d3\u6599\u7684\u6eb6\u5242\u81f4\u53d8\u8272\u884c\u4e3a\u5bf9\u6bd4\u8bd5\u9a8c\u8868\u660eMOF-5\u5ac1\u63a5\u4e86\u805a\u5408\u7269\u540e\u7684\u5b54\u7a74\u73af\u5883\u53d1\u751f\u4e86\u53d8\u5316\u3002MOF-5-PS\u590d\u5408\u7269\u57281atm\uff0c298K\u548c273K\u65f6\u5bf9CO2\u7684\u5438\u9644\u91cf\u9ad8\u4e8e\u539f\u59cbMOF-5\u4e5f\u8bc1\u660e\u4e86\u4e86\u8fd9\u4e00\u70b9\u3002\u901a\u8fc7\u7b80\u6613\u65b9\u6cd5\u5728MOF\u6846\u67b6\u4e0a\u5ac1\u63a5\u9ad8\u5206\u5b50\u5b9e\u73b0\u6539\u6027\u62d3\u5bbd\u4e86MOF\u6750\u6599\u4e0e\u9ad8\u5206\u5b50\u6750\u6599\u5728\u5438\u9644\u548c\u5206\u79bb\u65b9\u9762\u7684\u5e94\u7528\u6027\u3002<\/p>\n

\"\u56fe\u72477\"
\n \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u56fe7 \u7531\u5355\u4f53\u76f4\u63a5\u5408\u6210MOF-5-PS-4\u201324h\u590d\u5408\u7269\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aMOF-5-Polystyrene: Direct Production from Monomer, Improved Hydrolytic Stability, and Unique Guest Adsorption<\/a>(Angew. Chem. Int. Ed., 2016, DOI: 10.1002\/ange.201606185)<\/p>\n

8\u3001Nat. Commun. \u4f4d\u4e8eMOF\u8282\u70b9\u4e0a\u5177\u6709\u5316\u5b66\u9009\u62e9\u6027\u4e14\u5730\u7403\u4e0a\u5145\u8db3\u7684\u5355\u4e2d\u5fc3\u91d1\u5c5e\u50ac\u5316\u5242<\/strong><\/p>\n

\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u5728MOF\u8282\u70b9\u4e0a\u5236\u5907\u65b0\u5947\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7b56\u7565\u5e76\u5e94\u7528\u4e8e\u5927\u8303\u56f4\u7684\u6709\u673a\u53cd\u5e94\u3002\u8fd9\u79cd\u901a\u8fc7Co\u76d0\u6216Fe\u76d0\u4e0e\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u95f4\u7684\u7b80\u5355\u91d1\u5c5e\u5316\u4f5c\u7528\u5f97\u5230\u7684\u56fa\u76f8\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u5177\u6709\u9ad8\u6d3b\u6027\u70b9\u548c\u53ef\u91cd\u590d\u4f7f\u7528\u7684\u5355\u4e2d\u5fc3\u56e0\u6b64\u53ef\u50ac\u5316\u5927\u91cf\u6709\u673a\u53cd\u5e94\uff0c\u5305\u62ec\u5316\u5b66\u9009\u62e9\u6027\u787c\u5316\u53cd\u5e94\u3001\u7532\u7845\u70f7\u5316\u3001\u82c4\u57faC-H\u952e\u7684\u80fa\u5316\u3001\u70ef\u5c5e\u70c3\u548c\u916e\u7c7b\u6c22\u5316\u548c\u787c\u6c22\u5316\u53cd\u5e94\u3002\u8be5\u8bfe\u9898\u7ec4\u8fdb\u884c\u7684\u7ed3\u6784\u5b66\u3001\u5149\u8c31\u5b66\u3001\u52a8\u529b\u5b66\u7814\u7a76\u8868\u660e\u5177\u6709\u9009\u62e9\u6027\u7684\u5316\u5b66\u53cd\u5e94\u53d1\u751f\u5728\u5b64\u4f4d\u70b9\u3001\u7f3a\u7535\u5b50\u3001\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u4e2d\u5fc3\u3002\u800c\u4f4d\u4e8e\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u7684\u91d1\u5c5e\u4e2d\u5fc3\u7684\u8fd9\u4e9b\u7279\u70b9\u662f\u901a\u8fc7\u03c3\u952e\u7f6e\u6362\uff0c\u7531\u50ac\u5316\u4f4d\u70b9\u5468\u56f4\u7684\u7acb\u4f53\u73af\u5883\u6240\u81f4\u3002 \u5728\u7cbe\u7ec6\u5316\u5b66\u54c1\u7684\u6301\u7eed\u5408\u6210\u4e2d\uff0cMOFs\u4e3a\u9ad8\u6d3b\u6027\u548c\u8010\u78b1\u6027\u50ac\u5316\u5242\u63d0\u4f9b\u5e73\u53f0\u3002<\/p>\n

\"\u56fe\u72478\"
\n\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u56fe8<\/strong> UiO-68\u7684\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u4e0eCoCl2\u7684\u91d1\u5c5e\u5316\u4f5c\u7528<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aChemoselective single-site Earth-abundant metal catalysts at metal\u2013organic framework nodes<\/a> (Nat. Commun., 2016, DOI:10.1038\/ ncomms12610)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4\u7f51\u8001\u742a\u742a<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0eMOF\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3MOF\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09<\/strong>\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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