{"id":45189,"date":"2016-10-07T10:00:32","date_gmt":"2016-10-07T02:00:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=45189"},"modified":"2016-10-07T09:45:08","modified_gmt":"2016-10-07T01:45:08","slug":"nature%ef%bc%9a%e5%9b%bd%e5%ae%b6%e7%ba%b3%e7%b1%b3%e7%a7%91%e5%ad%a6%e4%b8%ad%e5%bf%83%e5%9c%a8mof%e7%94%a8%e4%ba%8e%e9%80%89%e6%8b%a9%e6%80%a7%e5%8a%a0%e6%b0%a2%e5%8f%8d%e5%ba%94%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=45189","title":{"rendered":"Nature\uff1a\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u5728MOF\u7528\u4e8e\u9ad8\u6548\u9009\u62e9\u6027\u52a0\u6c22\u53cd\u5e94\u7814\u7a76\u4e2d\u83b7\u91cd\u5927\u7a81\u7834"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/b><\/strong><\/p>\n

\u7531\u4e8e\u81ea\u7136\u8d44\u6e90\u7684\u6709\u9650\u5229\u7528\u5ea6\uff0c\u5728\u9999\u6599\u3001\u9999\u6c34\u3001\u5236\u836f\u5de5\u4e1a\u4e2d\u5bf9\u4e0d\u9971\u548c\u9187\u7684\u9700\u6c42\u901a\u5e38\u662f\u901a\u8fc7\u7fb0\u57fa\u7684\u9009\u62e9\u6027\u52a0\u6210\u5f97\u5230\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u9187\u800c\u5b9e\u73b0\u3002\u7136\u800c\u5f00\u53d1\u7528\u4e8e\u8be5\u7c7b\u53cd\u5e94\u7684\u50ac\u5316\u5242\u662f\u4e00\u4e2a\u6311\u6218\uff0c\u56e0\u4e3a\u7fb0\u57fa\u7684\u52a0\u6210\u53cd\u5e94\u53d7\u70ed\u529b\u5b66\u63a7\u5236\uff0c\u800c\u57fa\u4e8e\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u91d1\u5c5e\u578b\u7eb3\u7c73\u9897\u7c92\u50ac\u5316\u5242\u5bf9\u4e8e\u70ed\u529b\u5b66\u7684\u9009\u62e9\u6027\u662f\u4e0d\u8d77\u663e\u8457\u4f5c\u7528\u7684\u3002\u901a\u5e38\u6765\u8bb2\u7eb3\u7c73\u9897\u7c92\u8fb9\u7f18\u76f4\u63a5\u63a5\u89e6\u91d1\u5c5e\u6c27\u5316\u7269\u8f7d\u4f53\u624d\u5177\u6709\u9009\u62e9\u6027\u50ac\u5316\u6027\u8d28\uff0c\u591a\u6570\u88f8\u9732\u7684\u7eb3\u7c73\u9897\u7c92\u8868\u9762\u4e0d\u5b58\u5728\u8fd9\u79cd\u60c5\u51b5\u3002\u800cMOF\u5185\u914d\u4f4d\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u4f4d\u70b9\u53ef\u4ee5\u76f4\u63a5\u8c03\u8282MOF\u4e0e\u53cd\u5e94\u7269\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6d3b\u5316\u76ee\u6807\u5316\u5b66\u952e\uff0c\u964d\u4f4e\u5316\u5b66\u53cd\u5e94\u7684\u80fd\u5792\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u5317\u4eac\u65f6\u95f42016\u5e7410\u67086\u65e5\uff0c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u7684\u5510\u667a\u52c7\u3001\u674e\u56fd\u680b\u548c\u6fb3\u5927\u5229\u4e9a\u683c\u91cc\u83f2\u65af\u5927\u5b66\u7684Huijun Zhao\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u5728Nature\u4e0a\u5728\u7ebf\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u5c06\u94c2\u7eb3\u7c73\u9897\u7c92\u5c01\u88c5\u5230MOF\u5c42\u95f4\u6216\u5b54\u9053\u5185\u6784\u5efa\u5177\u6709\u9ad8\u6548\u9009\u62e9\u6027\u50ac\u5316\u7684\u53cd\u5e94\u5bb9\u5668\u3002<\/strong>\u8be5\u53cd\u5e94\u5668\u7531\u542bFe3<\/sup>+<\/sup>, Cr3<\/sup>+<\/sup>\u6216\u517c\u800c\u6709\u4e4b\uff08\u00a0MIL-101\uff09\u91d1\u5c5e\u8282\u70b9\u7684MOF\u5c06\u94c2\u7eb3\u7c73\u9897\u7c92\u5c01\u88c5\u5176\u4e2d\u5f62\u6210\u7684\u4e09\u660e\u6cbb\u5e73\u53f0\u5bf9\u50ac\u5316\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u919b\u7684\u52a0\u6c22\u53cd\u5e94\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9ad8\u9009\u62e9\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1. <\/b><\/strong>MIL-101@Pt@MIL-101<\/b><\/strong>\u7684\u4e09\u660e\u6cbb\u5f0f\u7eb3\u7c73\u7ed3\u6784<\/b><\/strong>\u00a0<\/b><\/strong><\/p>\n

\"nature19763-f1\"<\/b><\/strong><\/p>\n

a, \u4e09\u660e\u6cbb\u5f0f\u00a0MIL-101@Pt@MIL-101\u7684\u5408\u6210\u8def\u7ebf<\/p>\n

b-e, MIL-101(Fe)@Pt@MIL-101(Fe)\u7684\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

f-g,\u00a0MIL-101(Cr)@Pt@MIL-101(Cr)\u7684\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

h-k,\u00a0MIL-101(Cr)@Pt@MIL-101(Fe)\u7684\u900f\u5c04\u7535\u955c\u56fe<\/p>\n

l, MIL-101(Cr)@Pt@MIL-101(Fe)\u9ad8\u89d2\u5ea6\u73af\u5f62\u6697\u573a-\u626b\u63cf\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u56fe\u50cf\u548c\u76f8\u5e94\u6a2a\u622a\u9762\u80fd\u91cf\u8272\u6563x\u5c04\u7ebf\u80fd\u8c31(EDS)\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/p>\n

\u56fe<\/b><\/strong>2<\/b><\/strong>\u00a0<\/b><\/strong>. <\/b><\/strong>MIL-101@Pt<\/b><\/strong>\u7684\u53cd\u5e94\u673a\u5236\u7814\u7a76<\/b><\/strong><\/p>\n

\"nature19763-f2\"<\/p>\n

a<\/b><\/strong>, MIL-101(Fe)@Pt\u50ac\u5316\u8089\u6842\u919b\u7684\u53cd\u5e94\u7406\u8bba\u8ba1\u7b97<\/p>\n

b<\/b><\/strong>,\u00a0MIL-101(Cr)@Pt\u50ac\u5316\u8089\u6842\u919b\u7684\u53cd\u5e94\u7406\u8bba\u8ba1\u7b97<\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>\u00a0<\/b><\/strong>. <\/b><\/strong>\u4e0d\u540c\u50ac\u5316\u5242\u4e2d<\/b><\/strong>Pt, Fe, Cr <\/b><\/strong>\u548c<\/b><\/strong>O<\/b><\/strong>\u7684<\/b><\/strong>XPS<\/b><\/strong>\u56fe<\/b><\/strong><\/p>\n

\"nature19763-f3\"<\/p>\n

a, Pt 4f<\/i><\/em>\u00a0<\/i><\/em>. b, Fe 2p <\/i><\/em>. c, Cr 2p <\/i><\/em>. d, O 1s<\/i><\/em>.<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Metal\u2013organic frameworks as selectivity regulators\u00a0for hydrogenation reactions<\/a>\u00a0(Nature, 2016, DOI: 10.1038\/nature19763)\uff08\u6587\u732e\u5168\u6587PDF\u5df2\u4e0a\u4f20\u81f3\u6750\u6599\u4eba\u8d44\u6e90\u5171\u4eab\u4ea4\u6d41\u7fa4 425218085\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8MOF\u7ec4\u7f51\u8001\u742a\u742a<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u53c2\u4e0eMOF\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3MOF\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4ebaMOF\u5b66\u672f\u4ea4\u6d41\u7fa4\uff08120199039\uff09\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 \u7531\u4e8e\u81ea\u7136\u8d44\u6e90\u7684\u6709\u9650\u5229\u7528\u5ea6\uff0c\u5728\u9999\u6599\u3001\u9999\u6c34\u3001\u5236\u836f\u5de5\u4e1a\u4e2d\u5bf9\u4e0d\u9971\u548c\u9187\u7684\u9700\u6c42\u901a\u5e38\u662f\u901a\u8fc7\u7fb0\u57fa\u7684\u9009\u62e9\u6027\u52a0\u6210\u5f97\u5230\u03b1\uff0c\u03b2-\u4e0d\u9971\u548c\u9187\u800c\u5b9e\u73b0\u3002\u7136\u800c\u5f00\u53d1\u7528\u4e8e\u8be5\u7c7b\u53cd\u5e94\u7684\u50ac\u5316\u5242\u662f…<\/p>\n","protected":false},"author":1123,"featured_media":45208,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[293,245],"class_list":["post-45189","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nature","tag-mof"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45189"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1123"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=45189"}],"version-history":[{"count":14,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45189\/revisions"}],"predecessor-version":[{"id":45253,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45189\/revisions\/45253"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/45208"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=45189"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=45189"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=45189"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}