{"id":45849,"date":"2016-10-14T14:00:56","date_gmt":"2016-10-14T06:00:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=45849"},"modified":"2017-08-20T15:20:37","modified_gmt":"2017-08-20T07:20:37","slug":"jacs%ef%bc%9a%e5%88%a9%e7%94%a8%e7%a6%bb%e5%ad%90%e9%85%8d%e5%af%b9%e6%96%b9%e6%b3%95%e7%9a%84%e6%89%8b%e6%80%a7%e5%8f%8c%e9%87%91%e5%b1%9eag28cu12sr244-%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=45849","title":{"rendered":"\u90d1\u5357\u5cf0JACS\uff1a\u5229\u7528\u79bb\u5b50\u914d\u5bf9\u65b9\u6cd5\u7684\u624b\u6027\u53cc\u91d1\u5c5e[Ag28Cu12(SR)24]4-\u7eb3\u7c73\u56e2\u7c07\u975e\u5bf9\u79f0\u5408\u6210"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

2016\u5e749\u670814\u65e5\uff0cJACS\u7f51\u7ad9\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201cAsymmetric Synthesis of Chiral Bimetallic [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup> Nanoclusters via Ion Pairing<\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u53a6\u95e8\u5927\u5b66\u7684\u90d1\u5357\u5cf0\u6559\u6388\u548cBoon K. Teo\u6559\u6388\u4e3a\u672c\u6587\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>\u3002\u8fd9\u7bc7\u6587\u7ae0\u5229\u7528\u624b\u6027\u94f5\u6839\u79bb\u5b50\u548c\u6e29\u548c\u79bb\u5b50\u914d\u5bf9\u7684\u65b9\u6cd5\u975e\u5bf9\u79f0\u5408\u6210\u4e86\u5e26\u8d1f\u7535\u8377\u7684\u5149\u6d3b\u6027\u624b\u6027\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4e0d\u8bba\u5728\u5fae\u89c2\u8fd8\u662f\u5b8f\u89c2\u4e16\u754c\uff0c\u624b\u6027\u90fd\u662f\u662f\u7269\u8d28\u6700\u57fa\u672c\u7684\u5c5e\u6027\u3002\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u5f00\u53d1\u51fa\u591a\u79cd\u624b\u6027\u5206\u5b50\u7684\u5bf9\u6620\u4f53\u9009\u62e9\u6027\u5408\u6210\u65b9\u6cd5\u3002\u4f46\u662f\uff0c\u4e0d\u50cf\u624b\u6027\u5206\u5b50\u7684\u5408\u6210\u6216\u8005\u89c4\u6a21\u624b\u6027\u7ed3\u6784\u7684\u7ec4\u88c5\uff0c\u76ee\u524d\u5173\u4e8e\u624b\u6027\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u7684\u5408\u6210\u6216\u5206\u79bb\u65b9\u6cd5\u5374\u662f\u9c9c\u6709\u62a5\u9053\u3002<\/p>\n

\u53a6\u95e8\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u8fd9\u4e00\u65b0\u578b\u624b\u6027\u786b\u9187\u5316\u53cc\u91d1\u5c5e\u56e2\u7c07\u7684\u5408\u6210\u3002\u8fd9\u79cd\u56e2\u7c07\u4e2d\u768428\u4e2aAg\u539f\u5b50\u6392\u5217\u6210\u53d8\u5f62\u7684\u9762\u5fc3\u7acb\u65b9\u6a21\u5f0f\uff0c\u800cAg\/ Cu\u754c\u9762\u5219\u662f\u626d\u66f2\u7684\u516d\u65b9\u5bc6\u5806\u79ef\u3002\u800c\u8fd9\u79cd\u53d8\u5f62\u4f1a\u964d\u4f4eAg28<\/sub>Cu12<\/sub>\u6846\u67b6\u70b9\u7fa4\u7684\u5bf9\u79f0\u6027\uff0c\u4ece\u800c\u5411\u624b\u6027\u56e2\u7c07\u8f6c\u53d8\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5f15\u5165Bu4<\/sub>N+<\/sup>\u8fd9\u4e00\u56e2\u7c07\u53cd\u79bb\u5b50\uff0c[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u91d1\u5c5e\u56e2\u7c07\u4e2d\u7684\u5916\u6d88\u65cb\u4f53\uff08racemate\uff09\u80fd\u591f\u88ab\u6210\u529f\u5730\u5bf9\u6620\u5206\u79bb\uff08enantioseparation\uff09\u51fa\u6765\u3002\u7531\u6b64\uff0c\u5149\u5b66\u6027\u5730\u7eaf\u5316\u5206\u79bb\u5bf9\u6620\u5f02\u6784\u4f53\u5f97\u4ee5\u5b9e\u73b0\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a\u5355\u6676<\/strong>X<\/strong>\u5c04\u7ebf\u7ed3\u6784\u6d4b\u91cf<\/strong><\/p>\n

\"121<\/a>
\n<\/a>(a) [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u91d1\u5c5e\u56e2\u7c07\u7684\u5168\u5c40\u7ed3\u6784\uff1b<\/p>\n

(b) \u70f7\u57fa\u7701\u7565\u7684[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u91d1\u5c5e\u56e2\u7c07\u7ed3\u6784\uff1b<\/p>\n

(c) T\u5bf9\u79f0[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u6846\u67b6\u4e2d\u7684Ag28<\/sub>Cu12<\/sub>\u7684\u5f02\u6784\u4f53\uff08\u5de6\u65cb\uff09\uff1b<\/p>\n

(d) \u975e\u624b\u6027Ag28<\/sub>Cu12<\/sub>\u91d1\u5c5e\u6846\u67b6\u7684\u7406\u60f3\u5316\u9762\u5fc3\u7acb\u65b9\u5bc6\u5806\uff1b<\/p>\n

(e) T\u5bf9\u79f0[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u6846\u67b6\u4e2d\u7684Ag28<\/sub>Cu12<\/sub>\u7684\u5f02\u6784\u4f53\uff08\u53f3\u65cb\uff09\uff1b<\/p>\n

(f) Ag\u539f\u5b50\u548cCu\u539f\u5b50\u7684ACBAB\u5806\u53e0\u65b9\u5f0f\u3002<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a\u7d2b\u5916<\/strong>–<\/strong>\u53ef\u89c1\u5149\u5149\u8c31\u4ee5\u53ca<\/strong>ESI-MS<\/strong>\u56fe\u8c31<\/strong><\/p>\n

\"121<\/p>\n

(a) (n<\/sup>Bu4<\/sub>N)4<\/sub>[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]\u5355\u6676\u53ca\u5176\u7eb3\u7c73\u9897\u7c92\u7684\u5149\u8c31\u6bd4\u8f83\uff1b<\/p>\n

(b) (n<\/sup>Bu4<\/sub>N)4<\/sub>[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]\u5355\u6676\u7684ESI-MS\uff1b<\/p>\n

(c) [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u7684\u5b9e\u9a8c\uff08\u9ed1\uff09\u548c\u6a21\u62df\uff08\u7ea2\uff09MS\u56fe\uff1b<\/p>\n

(d) [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>(n<\/sup>Bu4<\/sub>N)]3-<\/sup>\u7684\u5b9e\u9a8c\uff08\u9ed1\uff09\u548c\u6a21\u62df\uff08\u7ea2\uff09MS\u56fe\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a<\/strong>CD<\/strong>\u5149\u8c31\u5206\u6790<\/strong><\/p>\n

\"121<\/p>\n

(a) 0 \u00b0C\u65f6\u624b\u6027\u5206\u79bb\u7684\u65f6\u95f4\u8ffd\u8e2aCD\u5149\u8c31\uff1b<\/p>\n

(b) 0 \u00b0C\u65f6\u624b\u6027\u5206\u79bb\u7684\u65f6\u95f4\u8ffd\u8e2a\u7d2b\u5916-\u53ef\u89c1\u5149\u5149\u8c31\uff1b<\/p>\n

(c) [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u7684\u8ba1\u7b97CD\u56fe\u8c31\uff08\u7ea2\u8272\u66f2\u7ebf\uff09\u4ee5\u53caAg28<\/sub>\u5185\u6838\u7684\u8ba1\u7b97CD\u56fe\u8c31\uff08\u9ed1\u8272\u66f2\u7ebf\uff09\uff1b<\/p>\n

(d) \u4ece\u56fe3c\u5206\u6790\u7684[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u4f18\u9009\u7684L-\u5bf9\u6620\u5f02\u6784\u4f53\u3002<\/p>\n

\u56fe<\/strong>4<\/strong>\uff1a\u5176\u4ed6\u79cd\u7c7b\u624b\u6027\u5b63\u94f5\u76d0\u7528\u4e8e\u975e\u5bf9\u79f0\u5408\u6210<\/strong><\/p>\n

\"121<\/p>\n

(a) \u5bf9\u6620\u4f53\u5bf9(AgCu)40<\/sub>BCDC\u4ee5\u53ca(AgCu)40<\/sub>\u2022BCNC\u7684CD\u56fe\u8c31\uff08[Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4-<\/sup>\u7b80\u5199\u4e3a(AgCu)40<\/sub>\uff09\uff1b<\/p>\n

(b) (AgCu)40<\/sub>BCNC\u4ea7\u7269\u7684ESI-MS\u56fe\u8c31\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u624b\u6027\u53cd\u79bb\u5b50\u7684\u79bb\u5b50\u914d\u5bf9\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5229\u7528\u5bf9\u6620\u5206\u79bb\u548c\u975e\u5bf9\u79f0\u5408\u6210\u6280\u672f\u5149\u5b66\u7eaf\u5316\u624b\u6027\u91d1\u5c5e\u56e2\u7c07\u3002\u7814\u7a76\u4eba\u5458\u5e0c\u671b\u8fd9\u4e9b\u7b80\u5355\u6709\u6548\u7684\u6280\u672f\u65b9\u6cd5\u80fd\u591f\u540c\u6837\u5e94\u7528\u5230\u5176\u4ed6\u79cd\u7c7b\u7684\u624b\u6027\u91d1\u5c5e\u56e2\u7c07\uff0c\u5e76\u63a8\u52a8\u8fd9\u4e9b\u91d1\u5c5e\u56e2\u7c07\u5728\u50ac\u5316\u548c\u836f\u7269\u5de5\u7a0b\u7b49\u9886\u57df\u7684\u53d1\u5c55\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Asymmetric Synthesis of Chiral Bimetallic [Ag28<\/sub>Cu12<\/sub>(SR)24<\/sub>]4\u2013<\/sup> Nanoclusters via Ion Pairing<\/a>\uff08JACS, 2016, DOI: 10.1021\/jacs.6b08100\uff09<\/p>\n

\u8be5\u6587\u732e\u6c47\u603b\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4John-chern\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 2016\u5e749\u670814\u65e5\uff0cJACS\u7f51\u7ad9\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201cAsymmetric Synthesis of Chiral Bimetallic [Ag28Cu1…<\/p>\n","protected":false},"author":82,"featured_media":45854,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[33,2179],"class_list":["post-45849","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nano","tag-zhengnanfeng"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45849"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/82"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=45849"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45849\/revisions"}],"predecessor-version":[{"id":46623,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/45849\/revisions\/46623"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/45854"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=45849"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=45849"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=45849"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}