{"id":50549,"date":"2016-11-09T06:30:07","date_gmt":"2016-11-08T22:30:07","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=50549"},"modified":"2016-11-09T12:07:16","modified_gmt":"2016-11-09T04:07:16","slug":"%e5%a4%8d%e6%97%a6angew-chem-int-edit-%ef%bc%9a%e5%8c%96%e5%ad%a6%e4%b8%8d%e5%af%b9%e7%a7%b0%e7%9a%84sio2%e7%ba%b3%e7%b1%b3%e7%93%b6%e7%9a%84%e5%88%b6%e5%a4%87%e5%8f%8a%e5%9c%a8%e8%bf%90%e8%be%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=50549","title":{"rendered":"\u590d\u65e6Angew. Chem. Int. Edit.\uff1a\u5316\u5b66\u4e0d\u5bf9\u79f0\u7684SiO2\u7eb3\u7c73\u74f6\u7684\u5236\u5907\u53ca\u5728\u8fd0\u8f93\u8f7d\u4f53\/\u7eb3\u7c73\u53cd\u5e94\u5668\/\u7eb3\u7c73\u9a6c\u8fbe\u4e0a\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8bed\u3011<\/strong><\/p>\n

2016\u5e7410\u670820\u65e5\uff0cAngew. Chem. Int. Edit.\u7f51\u7ad9\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201cSynthesis of Chemically Asymmetric Silica Nanobottles and Their Application for Cargo Loading and as Nanoreactors and Nanomotors\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u590d\u65e6\u5927\u5b66\u7684Deliang Yi\uff0c\u901a\u8baf\u4f5c\u8005\u4e3a\u590d\u65e6\u5927\u5b66\u7684\u738b\u4e9a\u519b\u6559\u6388\u3002<\/strong>\u5728\u8fd9\u7bc7\u5feb\u8baf\uff08communication\uff09\u6587\u7ae0\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86\u4e00\u79cd\u5236\u5907\u5177\u6709\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027\u7684SiO2<\/sub>\u7eb3\u7c73\u74f6\uff08NBs\uff09\u7684\u65b9\u6cd5\uff0c\u8fd9\u79cd\u7eb3\u7c73\u74f6\u7ed3\u6784\u5177\u6709\u758f\u6c34\u7684\u5916\u8868\u9762\u548c\u4eb2\u6c34\u7684\u5185\u8868\u9762\uff0c\u662f\u4e00\u79cd\u5177\u6709\u7a7a\u95f4\u9009\u62e9\u6027\u7684\u8fd0\u8f93\u8f7d\u4f53\uff0c\u5e76\u80fd\u5e94\u7528\u5728\u7eb3\u7c73\u53cd\u5e94\u5668\u548c\u7eb3\u7c73\u9a6c\u8fbe\u7b49\u65b9\u9762\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u81ea\u4ece1992\u5e74de Gennes\u9996\u5148\u62a5\u9053\u4e86\u4e24\u6027\u7c92\u5b50\uff0c\u8fd9\u4e9b\u7c92\u5b50\u7531\u4e8e\u5177\u6709\u4e0d\u540c\u7684\u5f62\u8c8c\u548c\u8868\u9762\u6027\u8d28\u5df2\u7ecf\u5f97\u5230\u4e86\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u7531\u4e8e\u5176\u5316\u5b66\u4e0d\u5bf9\u79f0\uff0c\u4e24\u6027\u7c92\u5b50\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u4e00\u7cfb\u5217\u9886\u57df\uff0c\u5982\u8d85\u7ed3\u6784\u7ec4\u88c5\u3001\u56fa\u4f53\u8868\u9762\u6d3b\u6027\u5242\u3001\u81ea\u63a8\u52a8\u7eb3\u7c73\u9a6c\u8fbe\u3001\u836f\u7269\u4f20\u9012\u4e0e\u4e34\u5e8a\u8bca\u65ad\u3002\u5176\u4e2d\uff0c\u81ea\u63a8\u52a8\u7eb3\u7c73\u9a6c\u662f\u4e00\u79cd\u5c0f\u578b\u7684\u72ec\u7acb\u88c5\u7f6e\uff0c\u5b83\u80fd\u591f\u6267\u884c\u6d41\u4f53\u4e2d\u590d\u6742\u7684\u4efb\u52a1\u3002\u8fd9\u4e9b\u72ec\u7acb\u88c5\u7f6e\u5728\u8fd0\u8f93\u8f7d\u4f53\u3001\u751f\u7269\u4f20\u611f\u6280\u672f\u3001\u73af\u5883\u79d1\u5b66\u548c\u663e\u5fae\u5916\u79d1\u624b\u672f\u6cbb\u7597\u4e2d\u8d77\u5230\u5173\u952e\u4f5c\u7528\uff0c\u5e76\u5177\u6709\u76f8\u5f53\u5927\u7684\u6f5c\u529b\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u5236\u9020\u5404\u79cd\u4e0d\u540c\u7ed3\u6784\u7684\u7eb3\u7c73\u53d1\u52a8\u673a\u7684\u76f8\u5173\u5de5\u827a\u5df2\u88ab\u591a\u6b21\u62a5\u9053\uff0c\u5982\u5229\u7528\u7535\u5316\u5b66\u6c89\u79ef\u5236\u5907\u53cc\u5c42\u91d1\u5c5e\u7eb3\u7c73\u9a6c\u8fbe\uff0c\u5229\u7528\u6a21\u677f\u6cd5\u6765\u5236\u5907\u9525\u5f62\u7ba1\u72b6\u5fae\u7c73\u9a6c\u8fbe\uff0c\u5229\u7528\u673a\u68b0\u7ffb\u5377\u65e0\u673a\u7eb3\u7c73\u8584\u819c\u5236\u5907\u7ba1\u72b6\u7eb3\u7c73\u9a6c\u8fbe\uff0c\u548c\u5229\u7528\u52a8\u6001\u9634\u5f71\u751f\u957f\u5de5\u827a\u5236\u5907\u81ea\u52a8\u578b\u7684\u5f02\u8d28\u7ed3\u6784\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u5de5\u827a\u9700\u8981\u7279\u6b8a\u7684\u8bbe\u5907\u6216\u662f\u590d\u6742\u7684\u5b9e\u9a8c\u6d41\u7a0b\u3002<\/p>\n

\u738b\u4e9a\u519b\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86\u4e00\u6b65\u6cd5\u5236\u5907\u5177\u6709\u957f\u9888\u74f6\u5f62\u72b6\u7684SiO2<\/sub>\u7a7a\u5fc3\u7c92\u5b50\uff08\u7528SiO2<\/sub>\u7eb3\u7c73\u74f6\u6765\u8868\u793a\uff0cNBs\uff09\uff0c\u5b83\u5177\u6709\u758f\u6c34\u6027\u7684\u5916\u8868\u9762\u548c\u4eb2\u6c34\u6027\u7684\u5185\u8868\u9762\u3002\u7814\u7a76\u4eba\u5458\u8fd8\u5c55\u793a\u4e86\u4e00\u79cd\u5236\u5907\u7eb3\u7c73\u53d1\u52a8\u673a\u7684\u7b80\u5355\u9ad8\u6548\u7684\u7684\u65b9\u6cd5\uff0c\u5373\u5728\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027\u7684SiO2<\/sub>\u7eb3\u7c73\u74f6\u7684\u5185\u90e8\u88c5\u8f7dPt\u7eb3\u7c73\u7c92\u5b50\uff08NPs\uff09\u3002SiO2<\/sub>\u7eb3\u7c73\u74f6\u5177\u6709\u72ec\u7279\u7684\u7ed3\u6784\uff0c\u5305\u62ec\u4e00\u4e2a\u5927\u7684\u7a7a\u8154\u548c\u4e00\u4e2a\u8fde\u63a5\u7a7a\u8154\u4e0e\u5916\u90e8\u73af\u5883\u7684\u72ed\u7a84\u5f00\u53e3\u3002\u5229\u7528\u5c1a\u672a\u6210\u5f62\u7684\u5927\u7a7a\u6d1e\u751f\u6210\u7a7a\u5fc3\u9897\u7c92\uff0c\u5982\u74f6\u72b6\u3001\u53e3\u5f62\u7ea2\u7ec6\u80de\u72b6\u548c\u7897\u72b6\u7ed3\u6784\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u6709\u6548\u6269\u6563\u80fd\u529b\u548c\u76f8\u5bf9\u4e8e\u8f83\u5927\u7684\u5ba2\u4f53\u5206\u5b50\u548c\u7eb3\u7c73\u7c92\u5b50\u7684\u9ad8\u5438\u6536\u80fd\u529b\uff0c\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u5174\u8da3\u3002\u7531\u4e8e\u5176\u72ec\u7279\u7684\u8868\u9762\u5316\u5b66\u6027\u8d28\uff0c\u5728\u672c\u6587\u4e2d\u62a5\u9053\u7684\u5177\u6709\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027\u7684SiO2<\/sub>\u7eb3\u7c73\u74f6\u57fa\u4e8e\u201c\u8d27\u7269\u201d\u548c\u5176\u5185\u8868\u9762\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u53ef\u9009\u62e9\u6027\u5730\u5c06\u201c\u8d27\u7269\u201d\u8fd0\u8f93\u5230\u4ed6\u4eec\u7684\u7a7a\u8154\u5185\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027<\/strong>SiO2<\/sub><\/strong>\u7eb3\u7c73\u74f6\u7684\u5f62\u6210\u793a\u610f\u56fe<\/strong><\/p>\n

\"1\"<\/a><\/p>\n

(a) \u6c34\u89e3\u7684CPTMS\u5728\u6c34-\u6cb9\u754c\u9762\u5904\u6392\u5217\uff0c\u800c\u6c34\u89e3\u7684TBOS\u5728\u6c34\u4fa7\u754c\u9762\u5904\u7f29\u5408\uff1b<\/p>\n

(b) CPTMS\u548cTBOS\u5171\u7f29\u805a\u5f62\u6210\u6df7\u5408\u4e8c\u6c27\u5316\u7845\u58f3\u7ed3\u6784\u7684\u8fc7\u7a0b\uff1bTBOS\u8fde\u7eed\u6c89\u79ef\u5c06\u6c34\u4ece\u58f3\u4e2d\u6324\u538b\u51fa\u6765\uff0c\u5f62\u6210\u4e00\u4e2a\u65b0\u7684\u6cb9-\u6c34\u754c\u9762\uff1b<\/p>\n

(c) CPTMS\u548cTBOS\u5728\u65b0\u5f62\u6210\u7684\u6c34\u6cb9\u754c\u9762\u5904\u5171\u7f29\u5408\u9020\u6210\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027\u7684NBs\u5f62\u6210\u3002<\/p>\n

(d-g) SiO2 <\/sub>NBs\u7684SEM\u56fe\u50cf\u548cTEM\u56fe\u50cf\uff1b<\/p>\n

(h) \u6709\u673a\u6b8b\u7559\u7269\u53bb\u9664\u524d(\u7ea2\u7ebf)\u540e(\u9ed1\u7ebf) NBs\u7684\u7ea2\u5916\u5149\u8c31\u56fe\uff1b<\/p>\n

(i) \u5236\u5907\u597d\u7684NBs (\u9ed1\u7ebf)\u548c\u9664\u53bb\u758f\u6c34\u6709\u673a\u57fa\u56e2\u5c01\u76d6\u540e\u7684NBs (\u7ea2\u7ebf)\u7684\u7c92\u5ea6\u5206\u5e03\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a\u4eb2\u6c34\u7eb3\u7c73\u9897\u7c92\u5728\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027<\/strong>SiO2<\/sub><\/strong>\u7eb3\u7c73\u74f6\u5185\u8868\u9762\u4e0a\u548c\u758f\u6c34\u7eb3\u7c73\u9897\u7c92\u5728\u5916\u8868\u9762\u4e0a\u7684\u9009\u62e9\u6027\u8fd0\u8f93<\/strong><\/p>\n

\"2\"<\/p>\n

(a, b) \u4eb2\u6c34\u7eb3\u7c73\u9897\u7c92\u5728\u5185\u8868\u9762\u4e0a\u548c\u758f\u6c34\u7eb3\u7c73\u9897\u7c92\u5728\u5916\u8868\u9762\u4e0a\u7684\u9009\u62e9\u6027\u8fd0\u8f93\u793a\u610f\u56fe\uff1b<\/p>\n

(c) \u4eb2\u6c34Pt\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u5728SiO2 <\/sub>NBs\u8154\u5185\u7684TEM\u56fe\uff1b<\/p>\n

(d) Pt\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u5728NBs\u5185(1)\u548c\u5438\u9644\u5728NBs\u5916\u8868\u9762\u7684\u9ad8\u5206\u8fa8\u7387TEM\u56fe\uff1b<\/p>\n

(e-h) c\u56fe\u4e2dPt\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7dNBs\u7684\u5143\u7d20\u5206\u5e03\u914d\u7f6e\u56fe\uff1b<\/p>\n

(i) \u758f\u6c34Fe3<\/sub>O4<\/sub>\u7eb3\u7c73\u9897\u7c92\u5438\u9644\u5728NBs\u758f\u6c34\u8868\u9762\u7684TEM\u56fe\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a<\/strong>Pt NPs@NBs<\/strong>\u7684\u81ea\u63a8\u52a8\u6027<\/strong><\/p>\n

\"3\"<\/p>\n

(a) Pt NPs@NBs\u7684\u81ea\u63a8\u52a8\u793a\u610f\u56fe\uff1b<\/p>\n

(b-d) \u57283 wt% H2<\/sub>O2<\/sub>\u4e2d\u7684\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027SiO2<\/sub>\u7eb3\u7c73\u9a6c\u8fbe\u7684\u5149\u5b66\u5f55\u50cf\u4e2d\u63d0\u53d6\u7684\u5feb\u7167\uff08\u56fe\u4e2d\u7684\u7ea2\u8272\u7bad\u5934\u8868\u793a\u7eb3\u7c73\u9a6c\u8fbe\u7684\u8fd0\u52a8\u65b9\u5411\uff09\uff1b<\/p>\n

(e) \u5728\u4e0d\u540c\u6d53\u5ea6H2<\/sub>O2<\/sub>\u5b58\u5728\u4e0b\u7eb3\u7c73\u9a6c\u8fbe\u8fd0\u52a8\u7684\u603b\u8ddd\u79bb\uff1b<\/p>\n

(f) \u7eb3\u7c73\u9a6c\u8fbe\u5728\u5916\u8868\u9762\u5b58\u5728\uff08\u9ed1\uff09\u6216\u4e0d\u5b58\u5728\uff08\u7ea2\uff09\u758f\u6c34\u6027\u6709\u673a\u57fa\u56e2\u5728\u60c5\u51b5\u4e0b\u7684\u8868\u89c2\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\u00a0<\/strong>\u56fe<\/strong>4<\/strong>\uff1a\u4f5c\u4e3a\u7eb3\u7c73\u53cd\u5e94\u5668\u7684\u5316\u5b66\u4e0d\u5bf9\u79f0\u6027<\/strong>SiO2 <\/sub>NBs<\/strong><\/p>\n

\"4\"<\/p>\n

(a-c) \u5728\u5316\u5b66\u4e0d\u5bf9\u79f0SiO2<\/sub>\u4e2d\u539f\u4f4d\u5236\u5907Au\u7eb3\u7c73\u7c92\u5b50\u7684\u793a\u610f\u56fe\uff0c\u9996\u5148\u5728\u542b\u6709HAuCl4<\/sub>\u548c\u67e0\u6aac\u9178\u94a0\u6eb6\u6db2\u4e2d\u5206\u6563\u4e8c\u6c27\u5316\u7845NBs\uff1b\u518d\u7528\u5fae\u5b54\u79bb\u5fc3\u7ba1\u79bb\u5fc3\u53bb\u9664\u591a\u4f59\u7684\u6eb6\u6db2\uff1b\u6700\u540e\u8fd8\u539fHAuCl4<\/sub> 24 h\uff0c\u5f62\u6210\u91d1\u7eb3\u7c73\u7c92\u5b50\uff1b<\/p>\n

(d) \u5728\u5316\u5b66\u4e0d\u5bf9\u79f0SiO2<\/sub>\u4e2d\u539f\u4f4d\u5236\u5907Au\u7eb3\u7c73\u7c92\u5b50\u7684TEM\u56fe\uff1b<\/p>\n

(e) \u5229\u7528Au NPs@NBs\u7eb3\u7c73\u53cd\u5e94\u5668\u50ac\u5316\u8fd8\u539f\u5bf9\u785d\u57fa\u82ef\u915a\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u5229\u7528\u4e00\u6b65\u51dd\u80f6\u6eb6\u80f6\u751f\u957f\u5de5\u827a\u5408\u6210\u4e86\u5177\u6709\u758f\u6c34\u5916\u8868\u9762\u548c\u4eb2\u6c34\u5185\u8868\u9762\u7684SiO2<\/sub> NBs\u3002CPTMS\u5728\u63a7\u5236NB\u5f62\u72b6\u4e2d\u548c\u8d4b\u4e88NB\u9002\u5ea6\u7684\u8868\u9762\u758f\u6c34\u6027\u65b9\u9762\u8d77\u7740\u5173\u952e\u7684\u4f5c\u7528\u3002\u67e0\u6aac\u9178\u76d0\u4fee\u9970\u7684Pt NPs\u53ef\u4ee5\u5229\u7528\u94c2\u7eb3\u7c73\u7c92\u5b50\u548cNBs\u5185\u8868\u9762\u4e4b\u95f4\u6c22\u952e\u9009\u62e9\u6027\u5730\u8d1f\u8f7d\u5230NBs\u7684\u7a7a\u8154\u5185\u7684\u7c98\u7ed3\u3002Pt NPs@NB\u7eb3\u7c73\u53d1\u52a8\u673a\u53ef\u4ee5\u81ea\u884c\u50ac\u5316\u5206\u89e3H2<\/sub>O2<\/sub>\uff0c\u5e76\u4e14\u76f8\u5bf9\u4e8e\u5916\u8868\u9762\u6ca1\u67093-\u6c2f\u4e19\u70f7\u57fa\u56e2\u4fee\u9970\u7684\u7eb3\u7c73\u9a6c\u8fbe\uff0c\u5b83\u8868\u73b0\u51fa\u53cc\u91cd\u9ad8\u7684\u6269\u6563\u7cfb\u6570\u3002\u8bd5\u9a8c\u7814\u7a76\u8868\u660e\uff0cNBs\u53ef\u4ee5\u4f5c\u4e3a\u7eb3\u7c73\u5bb9\u5668\u6709\u6548\u5730\u7528\u4e8e\u5404\u79cd\u4e0d\u540c\u7684\u53cd\u5e94\uff0c\u6bd4\u5982\u539f\u4f4d\u751f\u957fAu NPs\u548c\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Synthesis of Chemically Asymmetric Silica Nanobottles and Their Application for Cargo Loading and as Nanoreactors and Nanomotors<\/a> (Angew. Chem. Int. Edit., 2016, DOI: 10.1002\/anie.201607330)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u7ec4Junhan Kong\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8bed\u3011 2016\u5e7410\u670820\u65e5\uff0cAngew. Chem. Int. Edit.\u7f51\u7ad9\u5728\u7ebf\u53d1\u8868\u4e86\u9898\u4e3a\u201cSynthesis of Chemically Asymme…<\/p>\n","protected":false},"author":82,"featured_media":50551,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[33],"class_list":["post-50549","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-nano"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50549"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/82"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=50549"}],"version-history":[{"count":8,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50549\/revisions"}],"predecessor-version":[{"id":50861,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50549\/revisions\/50861"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/50551"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=50549"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=50549"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=50549"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}