{"id":50719,"date":"2016-11-11T06:30:30","date_gmt":"2016-11-10T22:30:30","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=50719"},"modified":"2016-11-10T10:35:08","modified_gmt":"2016-11-10T02:35:08","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%ef%bd%9c%e8%81%9a%e7%83%af%e7%83%83shish-kebab%e7%bb%93%e6%9e%84%e7%9a%84%e5%bd%a2%e6%88%90%e6%9c%ba%e7%90%86%e5%8f%8a%e7%a0%94%e7%a9%b6%e7%83%ad%e7%82%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=50719","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\uff5c\u805a\u70ef\u70c3\u4e32\u6676\u7ed3\u6784\u7684\u5f62\u6210\u673a\u7406\u53ca\u7814\u7a76\u70ed\u70b9"},"content":{"rendered":"<p>\u4f17\u591a\u7684\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\uff0c\u534a\u7ed3\u6676\u805a\u5408\u7269\u5927\u7ea6\u5360\u4e09\u5206\u4e4b\u4e8c\uff0c\u5c24\u5176\u662f\u805a\u70ef\u70c3\u4ef7\u5ec9\u6613\u5f97\uff0c\u54c1\u79cd\u591a\u6837\u4e14\u90fd\u6709\u7740\u4f18\u826f\u7684\u5316\u5b66\u7269\u7406\u6027\u80fd\uff0c\u5728\u73b0\u4ee3\u793e\u4f1a\u7684\u8863\u98df\u4f4f\u884c\u56fd\u9632\u7b49\u8bf8\u591a\u9886\u57df\u5e7f\u6cdb\u5e94\u7528\u3002\u4f46\u662f\u9ad8\u5206\u5b50\u6750\u6599\u7ed3\u6676\u7684\u7a0b\u5ea6\u4ee5\u53ca\u5f62\u6001\u5bf9\u5176\u6027\u80fd\u90fd\u6709\u7740\u5f88\u5927\u5f71\u54cd\u3002\u5728\u805a\u5408\u7269\u52a0\u5de5\u8fc7\u7a0b\uff08\u6324\u51fa\uff0c\u6ce8\u5851\uff0c\u5439\u819c\u548c\u7eba\u4e1d\u7b49\uff09\u4e2d\uff0c\u4e0d\u53ef\u907f\u514d\u5730\u5b58\u5728\u7740\u590d\u6742\u6d41\u52a8\u573a\uff08\u526a\u5207\u6216\u62c9\u4f38\uff09\uff0c\u56e0\u6b64\u6d41\u52a8\u8bf1\u5bfc\u7ed3\u6676\uff08flow-induced crystallization , FIC\uff09\u4e0d\u4ec5\u5bf9\u9ad8\u5206\u5b50\u7269\u7406\u7684\u7406\u8bba\u7814\u7a76\uff0c\u800c\u4e14\u5bf9\u5b9e\u9645\u9ad8\u5206\u5b50\u52a0\u5de5\u7684\u6307\u5bfc\uff0c\u90fd\u5177\u6709\u91cd\u5927\u610f\u4e49\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50720\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe1.png\" alt=\"%e5%9b%be1\" width=\"500\" height=\"368\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe1.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe1-300x221.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe1<\/strong> \u805a\u5408\u7269\u5728\u4e0d\u540c\u6d41\u52a8\u573a\u4e0b\u7684\u5f62\u6001\uff08\u4ece\u5de6\u5230\u53f3\u4f9d\u6b21\u662f\u9759\u6001\uff0c\u5f31\u573a\uff0c\u5f3a\u573a\uff09<\/p>\n<p>\u534a\u7ed3\u6676\u805a\u5408\u7269\u5728\u9759\u6001\u7ed3\u6676\u751f\u6210\u7403\u6676\uff0c\u5728\u8f83\u5f31\u7684\u6d41\u52a8\u573a\u4e0b\u751f\u6210\u53d6\u5411\u7ed3\u6784\uff0c\u800c\u5728\u5f3a\u70c8\u7684\u526a\u5207\u6216\u62c9\u4f38\u573a\u4e2d\u5f80\u5f80\u5f62\u6210shish-kebab\uff08\u4e32\u6676\uff09\u7ed3\u6784\uff0c\u7531\u5404\u5411\u540c\u6027\u7684\u7403\u6676\u53d8\u4e3a\u9ad8\u5ea6\u53d6\u5411\u7684shish-kebab\u7ed3\u6676\uff0c\u53ef\u4ee5\u5927\u5e45\u5ea6\u63d0\u9ad8\u805a\u5408\u7269\u7684\u5f3a\u5ea6\u548c\u521a\u5ea6\uff0c\u51cf\u5c0f\u6e17\u900f\u6027\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u30101. shish-kebab\u7684\u7ed3\u6784\u3011<\/strong><\/span><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50726\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe2.png\" alt=\"%e5%9b%be2\" width=\"500\" height=\"345\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe2.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe2-300x207.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe2<\/strong> Pennings\u57281964\u5e74\u53d1\u73b0\u901a\u8fc7\u6405\u62ccPE\u6eb6\u6db2\u53ef\u4ee5\u751f\u6210shish-kebab\u7ed3\u6784<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50727\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe3.png\" alt=\"%e5%9b%be3\" width=\"470\" height=\"325\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe3.png 470w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe3-300x207.png 300w\" sizes=\"(max-width: 470px) 100vw, 470px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe3<\/strong> \u805a\u4e59\u70efshish-kebab\u5fae\u7ed3\u6784\u6a21\u578b<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50731\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe4.png\" alt=\"%e5%9b%be4\" width=\"383\" height=\"625\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe4.png 383w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe4-184x300.png 184w\" sizes=\"(max-width: 383px) 100vw, 383px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4<\/strong> \u5305\u542b3\u4e2ashish\uff08\u4f38\u76f4\u94fe\u6676\u4f53\uff09\u7684\u5728\u5fae\u7c73\u7ea7\u522b\u7684\u6392\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50729\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe5-1.png\" alt=\"%e5%9b%be5\" width=\"500\" height=\"190\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe5-1.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe5-1-300x114.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5<\/strong>\u00a0 \u6742\u5316\u805a\u4e59\u70ef\/\u5355\u58c1\u78b3\u7eb3\u7c73\u7ba1shish\u548c\u805a\u4e59\u70efkebab\u6676\u4f53<\/p>\n<p>1965\u5e74\uff0cPennings\u5229\u7528\u7535\u5b50\u663e\u5fae\u955c\u89c2\u5bdf\u5230\u6405\u62cc\u4e0b\u7684\u805a\u4e59\u7a00\u6eb6\u6db2\u4e2d\u4e00\u79cd\u7ea4\u7ef4\u72b6\u7684\u6676\u4f53\u7ed3\u6784\uff0c\u4ece\u800c\u5728\u5b9e\u7a7a\u95f4\u91cc\u9762\u7ed9\u51fa\u4e86\u6d41\u52a8\u8bf1\u5bfc\u805a\u4e59\u70efshish-kebab\u7684\u6676\u4f53\u7ed3\u6784\u3002\u8fd9\u4e00\u65b0\u7684\u6676\u4f53\u7c7b\u578b\u7531\u4e2d\u5fc3\u7684\u7ea4\u7ef4\u6676\u4f53\u548c\u6cbf\u7740\u4e2d\u5fc3\u9aa8\u5e72\u6210\u4e32\u751f\u957f\u7684\u7247\u6676\u4e24\u90e8\u5206\u7ec4\u6210\uff0c\u56e0\u6b64\u5f62\u8c61\u5730\u5c06\u8be5\u6676\u4f53\u5f62\u6001\u79f0\u4e3a\u4e32\u6676\uff08shish-kebab\uff09\u3002\u5b9e\u9a8c\u8fd8\u53d1\u73b0shish\u5177\u6709\u6bd4\u7403\u6676\u66f4\u9ad8\u7684\u7194\u70b9\uff0c\u63a8\u65adshish\u662f\u7531\u4f38\u76f4\u94fe\u6676\u4f53\u7ec4\u6210\uff0c\u800ckebab\u7531\u6298\u53e0\u94fe\u6676\u4f53\u7ec4\u6210\u3002<\/p>\n<p>\u4eac\u90fd\u5927\u5b66\u7684Kanaya\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528SAXS\u548c\u5bbdQ\u503c\u8303\u56f4\u5185\u7684SANS\u6280\u672f\uff0c\u63ed\u793a\u4e86shish-kebab\u5177\u6709\u5206\u5c42\u7ed3\u6784\uff0c\u5982\u56fe3\uff0c\u957f12 \u03bcm\u76f4\u5f842 \u03bcm\u7684\u957f\u53d6\u5411\u7ed3\u6784(shish)\u91cc\u9762\u5305\u542b\u4e09\u4e2a\u534a\u5f84\u7ea6\u4e3a45 \u00c5\u7684\u4f38\u76f4\u94fe\u6676\u4f53,\u8868\u660e\u4e86micro-shish-kebab\u548cmacro-shish-kebab\u7684\u5b58\u5728\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u30102. \u4e32\u6676\u7684\u5f62\u6210\u673a\u7406\u3011<\/strong><\/span><\/p>\n<p>\u867d\u7136shish-kebab\u6676\u4f53\u7ed3\u6784\u53d1\u73b0\u8ddd\u4eca\u5df2\u7ecf\u670950\u591a\u5e74\uff0c\u8bb8\u591a\u9ad8\u5206\u5b50\u7269\u7406\u5b66\u5bb6\u8fdb\u884c\u4e86\u5927\u91cf\u7684\u7814\u7a76\uff0c\u4f46\u662f\u5176\u5f62\u6210\u673a\u7406\u5c1a\u6ca1\u6709\u5b9a\u8bba\uff0c\u7279\u522b\u662f\u5728shish-kebab\u5f62\u6210\u521d\u671f\u7684shish\u7684\u7ec4\u6210\u53ca\u5f62\u6210\u673a\u7406\u3002\u4e0b\u9762\u4e3b\u8981\u4ecb\u7ecd\u88ab\u5927\u5bb6\u6240\u63a5\u53d7\u7684\u4e24\u79cd\u4e3b\u8981\u7406\u8bba\u3002<\/p>\n<p><strong>(a) \u8737\u66f2-\u4f38\u76f4\u8f6c\u53d8\uff08Coil-Stretch Transition\uff0cCST\uff09<\/strong><\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50730\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe6.png\" alt=\"%e5%9b%be6\" width=\"500\" height=\"174\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe6.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe6-300x104.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6<\/strong> \u00a0\u968f\u526a\u5207\u901f\u7387\u589e\u52a0\uff0c\u7a00\u6eb6\u6db2\u4e2d\u805a\u5408\u7269\u5355\u94fe\u7684Coil-stretch Transition<\/p>\n<p>\u7b2c\u4e00\u4e2a\u5177\u6709\u7a81\u7834\u6027\u7684\u7406\u8bba\u662f\u7531de Gennes\u63d0\u51fa\u7684coil-stretch\u8f6c\u53d8\u7406\u8bba\uff0c\u57fa\u4e8e\u4e0d\u540c\u526a\u5207\u4f5c\u7528\u4e0b\u5355\u6839\u94fe\u5728\u7a00\u6eb6\u6db2\u4e2d\u7684\u52a8\u529b\u5b66\u7814\u7a76\uff0c\u5206\u5b50\u94fe\u5728\u5927\u4e8e\u4e34\u754c\u526a\u5207\u901f\u7387\u4f5c\u7528\u4e0b\uff0c\u4f1a\u76f4\u63a5\u7531\u65e0\u89c4\u7ebf\u56e2\u8f6c\u53d8\u4e3a\u4f38\u76f4\u94fe\u6784\u8c61\uff0c\u4e0d\u7ecf\u5386\u4efb\u4f55\u4e2d\u95f4\u6784\u8c61\uff0c\u4ece\u800c\u5efa\u7acb\u4e86\u4f38\u76f4\u94fe\u751f\u6210shish\uff0c\u800c\u8737\u66f2\u94fe\u751f\u6210kebab\uff0c\u5b8c\u7f8e\u7684\u5bf9\u5e94\u5173\u7cfb\u3002<\/p>\n<p>\u968f\u540eKeller\u7b49\u7ed9\u51fa\u4e86\u7a00\u6eb6\u6db2\u4e2dcoil-stretch\u8f6c\u53d8\u7684\u76f4\u63a5\u5b9e\u9a8c\u8bc1\u636e\uff0c\u5e76\u63d0\u51fa\u4e86\u5728\u4e00\u5b9a\u526a\u5207\u901f\u7387\u4e0b\uff0c\u53ea\u6709\u9ad8\u4e8e\u4e34\u754c\u5206\u5b50\u91cf\u7684\u805a\u5408\u7269\u94fe\u624d\u53ef\u4ee5\u53d1\u751fcoil-stretch\u8f6c\u53d8\u88ab\u62c9\u76f4\uff0c\u5f62\u6210shish\uff1b\u4f4e\u4e8e\u4e34\u754c\u5206\u5b50\u91cf\u7684\u9ad8\u5206\u5b50\u94fe\u7531\u4e8e\u5feb\u901f\u677e\u5f1b\u800c\u96be\u4ee5\u4f38\u76f4\u5f62\u6210\u6298\u53e0\u94fe\u6676\u4f53kebab\u3002<\/p>\n<p>Keller\u8ba4\u4e3acoil-stretch\u8f6c\u53d8\u540c\u6837\u5b58\u5728\u4e8e\u805a\u5408\u7269\u6d53\u6eb6\u6db2\u548c\u7194\u4f53\u4e2d\uff0c\u4e14\u5f88\u591a\u5b66\u8005\u7684\u540e\u7eed\u7814\u7a76\u53d1\u73b0\u7194\u4f53\u4e2dshish-kebab\u5f62\u6210\u786e\u5b9e\u5b58\u5728\u4e34\u754c\u5206\u5b50\u91cf\u3002<\/p>\n<p>\u4f46\u662f\uff0c\u7531\u4e8ecoil-stretch\u7406\u8bba\u662f\u57fa\u4e8e\u7a00\u6eb6\u6db2\u6d41\u4f53\u529b\u5b66\u76f8\u4e92\u4f5c\u7528\uff0c\u56e0\u6b64\u7194\u4f53\u4e2d\u7f3a\u4e4f\u7269\u7406\u57fa\u7840\uff0c\u4ece\u800c\u88ab\u4e00\u4e9b\u5b66\u8005\u6240\u53cd\u5bf9\u3002<\/p>\n<p><strong>(b) \u4f38\u76f4\u7f51\u7edc\u6a21\u578b\uff08Streched Network Model , SNM\uff09<\/strong><\/p>\n<p>\u4e0a\u4e16\u7eaa40\u5e74\u4ee3\uff0cFlory\u901a\u8fc7\u5e94\u7528\u5728\u6a61\u80f6\u5f39\u6027\u7406\u8bba\u4e2d\u4f7f\u7528\u7684\u7c7b\u4f3c\u7684\u7edf\u8ba1\u7406\u8bba\uff0c\u5efa\u7acb\u4e86SNM\u7684\u65e9\u671f\u7406\u8bba\uff0c\u5728CST\u7406\u8bba\u89e3\u91ca\u805a\u5408\u7269\u7194\u4f53\u4e2dshish-kebab\u5f62\u6210\u4e2d\u9047\u5230\u56f0\u96be\u4e4b\u540e\uff0cPennings\u57fa\u4e8eUHMWPE\u51dd\u80f6\u7eba\u4e1d\u63d0\u51fashish-kebab\u7ed3\u6676\u6676\u6838\u662f\u7531\u62c9\u4f38\u7684\u7f20\u7ed3\u7f51\u7edc\u62c9\u4f38\u5f62\u6210\u7684\u3002<\/p>\n<p>\u62c9\u4f38\u7f51\u7edc\u6a21\u578b\uff08SNM\uff09\u4ece\u6210\u6838\u52a8\u529b\u5b66\u8003\u8651\u6d41\u52a8\u573a\u8bf1\u5bfc\u7ed3\u6676\u673a\u5236\uff0c\u5176\u57fa\u672c\u601d\u60f3\u662f\u7531\u4e8e\u6d41\u52a8\u573a\u8bf1\u5bfc\u7684\u53d6\u5411\u6838\u4f38\u5c55\uff0c\u5bfc\u81f4\u7cfb\u7edf\u71b5\u51cf\uff0c\u4ece\u800c\u5f15\u8d77\u6210\u6838\u4f4d\u5792\u7684\u964d\u4f4e\uff0c\u8fdb\u800c\u589e\u52a0\u6210\u6838\u901f\u7387\uff0c\u589e\u52a0\u805a\u5408\u7269\u5728\u6d41\u52a8\u573a\u4e0b\u7684\u7ed3\u6676\u901f\u7387\u3002\u805a\u5408\u7269\u7f20\u7ed3\u7f51\u7edc\u4e2d\uff0cshish\u5f62\u6210\u53ea\u9700\u8981\u7f20\u7ed3\u70b9\u4e4b\u95f4\u7684\u94fe\u6bb5\u88ab\u62c9\u4f38\uff0c\u800c\u4e0d\u662f\u6574\u4e2a\u5206\u5b50\u94fe\u88ab\u62c9\u4f38\u3002<\/p>\n<p>\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u77f3\u6eaa\u5206\u6821Benjamin S. Hsiao\u8bfe\u9898\u7ec4\u53d1\u73b0UHMWPE shish-kebab\u6676\u4f53\u4e2d\u5b58\u5728multi-shish\u7ed3\u6784\uff0c\u8ba4\u4e3a\u662f\u7f20\u7ed3\u7f51\u7edc\u4e2d\u94fe\u6bb5\u88ab\u62c9\u4f38\u7684\u8bc1\u636e\uff0c\u56fd\u5185\u7684\u4e2d\u79d1\u5927\u7684\u674e\u826f\u5f6c\u8bfe\u9898\u7ec4\u548c\u5ddd\u5927\u7684\u674e\u5fe0\u660e\u8bfe\u9898\u7ec4\u90fd\u7528\u8f7b\u5ea6\u4ea4\u8054\u805a\u4e59\u70ef\u505a\u4e86\u76f8\u5173\u7684\u7814\u7a76\uff0c\u90fd\u8bc1\u660e\u4e86\u7a33\u5b9a\u7f20\u7ed3\u7f51\u7edc\u5bf9\u4e8eshish-kebab\u7ed3\u6784\u5f62\u6210\u7684\u4f5c\u7528\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50732\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe7.png\" alt=\"%e5%9b%be7\" width=\"500\" height=\"328\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe7.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe7-300x197.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7<\/strong> \u573a\u53d1\u5c04SEM\u89c2\u5bdf\u5230UHMWPE shish-kebab \u7ed3\u6784\u5177\u6709multi-shish\u7ed3\u6784(Benjamin S. Hsiao\u8bfe\u9898\u7ec4)<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u30103. \u7814\u7a76\u70ed\u70b9\u2014\u2014shish\u7684\u5f62\u6210\u673a\u7406\u3011<\/strong><\/span><\/p>\n<p>\u6d41\u52a8\u8bf1\u5bfcshish-kebab\u7ed3\u6676\u7814\u7a76\u7684\u91cd\u70b9\u662f\u7ed3\u6676\u521d\u671fshish\u7684\u5f62\u6210\u8fc7\u7a0b\uff0c\u800c\u88ab\u5927\u5bb6\u666e\u904d\u63a5\u53d7\u7684\u662fshish\u662f\u6709\u9ad8\u5ea6\u53d6\u5411\u7684\u4f38\u76f4\u94fe\u6676\u4f53\u7ec4\u6210\uff0c\u4f46\u662f\u5176\u5f62\u6210\u8fc7\u7a0b\u4e2d\uff0c\u957f\u77ed\u94fe\u7684\u4f5c\u7528\u4ee5\u53ca\u662f\u5426\u53d1\u751f\u957f\u77ed\u94fe\u5206\u79bb\u90fd\u5b58\u5728\u4e89\u8bae\u3002<\/p>\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-50733\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe8.png\" alt=\"%e5%9b%be8\" width=\"500\" height=\"363\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe8.png 500w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2016\/11\/\u56fe8-300x218.png 300w\" sizes=\"(max-width: 500px) 100vw, 500px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe8<\/strong> \u957f\u77ed\u94fe\u6c18\u4ee3\u6837\u54c1\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0bSANS\u56fe\u6848\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027\uff08S,M,L\u5206\u522b\u4ee3\u8868\u77ed\uff0c\u4e2d\uff0c\u957f\u94fe\u88ab\u6c18\u4ee3\u7684\u805a\u4e19\u70ef\u5171\u6df7\u7269\u6837\u54c1\uff09<\/p>\n<p>\u7531\u4e8e\u957f\u94fe\u5206\u5b50\u7684\u677e\u5f1b\u65f6\u95f4\u5f88\u957f\uff0c\u5728\u5916\u573a\u4f5c\u7528\u4e0b\u5bb9\u6613\u4fdd\u6301\u53d6\u5411\uff0c\u800c\u77ed\u94fe\u5f88\u5bb9\u6613\u677e\u9a70\uff0c\u56e0\u6b64\u65e9\u671f\u5f88\u591a\u7814\u7a76\u8005\u57fa\u4e8ecoil-stretch\u8f6c\u53d8\u7406\u8bba\uff0c\u5c06\u957f\u77ed\u94fe\u5206\u522b\u4e0eshish\u548ckebab\u8054\u7cfb\u5230\u4e00\u8d77\uff0c\u6307\u51fashish\u4e3b\u8981\u7531\u957f\u94fe\u7ec4\u6210\u7684\u89c2\u70b9\u3002\u4f46\u662f\u52a0\u5dde\u7406\u5de5\u5927\u5b66\u7684Kornfield\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u5c0f\u89d2\u4e2d\u5b50\u6563\u5c04\uff08SANS\uff09\u5bf9\u4e0d\u540c\u5206\u5b50\u94fe\u7684\u6c18\u4ee3\u805a\u4e19\u70ef\u5171\u6df7\u6837\u54c1\u8fdb\u884c\u526a\u5207\uff0c\u7ed3\u679c\u53d1\u73b0shish\u4e2d\u957f\u77ed\u94fe\u542b\u91cf\u4e0e\u672c\u4f53\u4e2d\u5e76\u65e0\u5dee\u522b\uff0c\u5426\u5b9a\u4e86shish\u4e3b\u8981\u7531\u957f\u94fe\u7ec4\u6210\u7684\u89c2\u70b9\u3002\u4f46\u662f\u5f88\u591a\u7814\u7a76\u8005\u5bf9\u6dfb\u52a0\u4e0d\u540c\u542b\u91cf\u957f\u94fe\u7684\u9ad8\u5206\u5b50\u8fdb\u884c\u62c9\u4f38\u6216\u526a\u5207\u5b9e\u9a8c\u53d1\u73b0\uff0c\u957f\u94fe\u7ec4\u5206\u5bf9shish\u7684\u5f62\u6210\u6709\u5f88\u5927\u7684\u4fc3\u8fdb\u4f5c\u7528\u3002<\/p>\n<p>Shish\u5f62\u6210\u4e4b\u524d\u662f\u5426\u5b58\u5728\u9884\u6709\u5e8f\u6216\u8005\u9884\u53d6\u5411\u7684\u8fc7\u7a0b\u4e5f\u662f\u8fd1\u4e9b\u5e74\u6765\u7684\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\u3002\u65e5\u672c\u4eac\u90fd\u5927\u5b66\u7684Kanaya\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u540c\u6b65\u8f90\u5c04\u5c0f\u89d2X\u5c04\u7ebf\u6563\u5c04\u548c\u5e7f\u89d2X\u5c04\u7ebf\u884d\u5c04\uff08SAXS\/WAXD\uff09\u548c\u9ad8\u5206\u8fa8\u7387\u5149\u5b66\u663e\u5fae\u955c\uff0c\u53d1\u73b0\u805a\u4e19\u70ef\u4f53\u7cfb\u5728\u526a\u5207\u8fc7\u7a0b\u4e2d\u5df2\u6709\u7ed3\u6784\u53d8\u5316\uff0cWAXD\u672a\u68c0\u6d4b\u5230\u4efb\u4f55\u6676\u4f53\u4ea7\u751f\uff0c\u4f46\u662fSAXS\u7ed9\u51fa\u4e86\u660e\u663e\u7684\u53d6\u5411\u4fe1\u53f7\u3002\u526a\u5207\u505c\u6b62\u540e\uff0cSAXS\u548cWAXD\u4fe1\u53f7\u90fd\u6709\u660e\u663e\u7684\u51cf\u5f31\uff0c\u8868\u660e\u5b58\u5728\u7a33\u5b9a\u6027\u8f83\u4f4e\u7684\u9884\u6709\u5e8f\u7ed3\u6784\u7684\u677e\u5f1b\u8fc7\u7a0b\u3002<\/p>\n<p>\u867d\u7136\u8fd1\u51e0\u5341\u5e74\u5bf9\u6d41\u52a8\u8bf1\u5bfc\u7ed3\u6676\u521d\u671f\u6210\u6838\u7406\u8bba\u8fdb\u884c\u4e86\u5927\u91cf\u7814\u7a76\uff0c\u4f46\u662f\u8981\u5f7b\u5e95\u63ed\u793ashish\u7684\u5f62\u6210\u673a\u5236\u4ee5\u53ca\u5176\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u8fd8\u9700\u8981\u5728\u5b9e\u9a8c\u4ee5\u53ca\u7406\u8bba\u4e0a\u505a\u51fa\u66f4\u5927\u52aa\u529b\u3002<\/p>\n<p><span style=\"color: #0000ff;\"><strong>\u30104. \u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n<p>\u6d41\u52a8\u573a\u8bf1\u5bfc\u9ad8\u5206\u5b50\u7ed3\u6676\u662f\u4e00\u4e2a\u5178\u578b\u7684\u5916\u573a\u9a71\u52a8\u548c\u52a8\u529b\u5b66\u63a7\u5236\u7684\u975e\u5e73\u8861\u76f8\u53d8\u8fc7\u7a0b\uff0c\u5bf9\u5176\u6df1\u5165\u7814\u7a76\u5bf9\u9ad8\u5206\u5b50\u7269\u7406\u7406\u8bba\u53d1\u5c55\u53ca\u5b9e\u9645\u52a0\u5de5\u90fd\u6709\u7740\u91cd\u8981\u610f\u4e49\u3002<\/p>\n<p>\u4f46\u662f\uff0cshish\u7684\u5f62\u6210\u673a\u7406\u81f3\u4eca\u5c1a\u65e0\u5b9a\u8bba\uff0c\u9ad8\u5206\u5b50\u7194\u4f53\u5728\u5916\u573a\u4f5c\u7528\u4e0b\u5b58\u5728\u7684\u9884\u6709\u5e8f\u8fc7\u7a0b\u662f\u5982\u4f55\u53d1\u751f\u7684\uff0c\u5916\u573a\u662f\u5982\u4f55\u5f71\u54cd\u5176\u5f62\u6210\u7684\uff0cPE\u6216PP\u4f53\u7cfb\u5728\u5f3a\u6d41\u52a8\u573a\u4e0b\u5f88\u5bb9\u6613\u89c2\u5bdf\u5230shish\uff0c\u4f46\u662f\u6709\u4e9b\u4f53\u7cfb\u5982\u805a\u6c27\u5316\u4e59\u70ef\uff08PEO\uff09\u6216\u8005\u805a\u4e01\u70ef\u4ee5\u53ca\u805a\u4e73\u9178\uff08PLA\uff09\u5374\u5f88\u96be\u7b49\u7b49\u95ee\u9898\u90fd\u6709\u5f85\u7814\u7a76\u8005\u8fdb\u4e00\u6b65\u6df1\u5165\u7814\u7a76\u3002<\/p>\n<p><strong>\u53c2\u8003\u6587\u732e<\/strong><\/p>\n<p>1. Wang, Z.; Ma, Z.; Li, L., Flow-Induced Crystallization of Polymers: Molecular and Thermodynamic Considerations. Macromolecules 2016, 49 (5), 1505-1517.<\/p>\n<p>2. Pennings, A. J.; Kiel, A. M., FRACTIONATION OF POLYMERS BY CRYSTALLIZATION FROM SOLUTION .3. ON MORPHOLOGY OF FIBRILLAR POLYETHYLENE CRYSTALS GROWN IN SOLUTION. Kolloid-Zeitschrift and Zeitschrift Fur Polymere 1965, 205 (2), 160-&amp;.<\/p>\n<p>3. Somani, R. H.; Yang, L.; Zhu, L.; Hsiao, B. S., Flow-induced shish-kebab precursor structures in entangled polymer melts. Polymer 2005, 46 (20), 8587-8623.<\/p>\n<p>4. Kanaya, T.; Matsuba, G.; Ogino, Y.; Nishida, K., Hierarchic structure of shish-kebab by neutron scattering in a wide Q range. Abstracts of Papers of the American Chemical Society 2007, 234.<\/p>\n<p>5. Minus, M. L.; Chae, H. G.; Kumar, S., Polyethylene crystallization nucleated by carbon nanotubes under shear. ACS Appl Mater Interfaces 2012, 4 (1), 326-30.<\/p>\n<p>6. Kimata, S.; Sakurai, T.; Nozue, Y.; Kasahara, T.; Yamaguchi, N.; Karino, T.; Shibayama, M.; Kornfield, J. A., Molecular basis of the shish-kebab morphology in polymer crystallization. Science 2007, 316 (5827), 1014-1017.<\/p>\n<p>&nbsp;<\/p>\n<p>\u611f\u8c22\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u9ad8\u5206\u5b50\u7ec4Fang_WenX\u63d0\u4f9b\u7d20\u6750\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u53c2\u4e0e\u9ad8\u5206\u5b50\u8bdd\u9898\u8ba8\u8bba\u6216\u4e86\u89e3\u9ad8\u5206\u5b50\u7ec4\u62db\u52df\u8be6\u60c5\uff0c\u8bf7\u52a0\u5165\u9ad8\u5206\u5b50\u4ea4\u6d41\u7fa4\uff08298064863\uff09<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n<p>\u6750\u6599\u4eba\u7f51\u5c0a\u91cd\u6240\u6709\u8fdb\u884c\u77e5\u8bc6\u4f20\u64ad\u7684\u5a92\u4f53\uff0c\u8f6c\u8f7d\u8bf7\u8054\u7cfbtougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u786c\u5e7f\u65f6\u95f4\uff1a<\/strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4f17\u591a\u7684\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\uff0c\u534a\u7ed3\u6676\u805a\u5408\u7269\u5927\u7ea6\u5360\u4e09\u5206\u4e4b\u4e8c\uff0c\u5c24\u5176\u662f\u805a\u70ef\u70c3\u4ef7\u5ec9\u6613\u5f97\uff0c\u54c1\u79cd\u591a\u6837\u4e14\u90fd\u6709\u7740\u4f18\u826f\u7684\u5316\u5b66\u7269\u7406\u6027\u80fd\uff0c\u5728\u73b0\u4ee3\u793e\u4f1a\u7684\u8863\u98df\u4f4f\u884c\u56fd\u9632\u7b49\u8bf8\u591a\u9886\u57df\u5e7f\u6cdb\u5e94\u7528\u3002\u4f46\u662f\u9ad8\u5206\u5b50&#8230;<\/p>\n","protected":false},"author":393,"featured_media":50724,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[42],"class_list":["post-50719","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo","tag-gaofenzi"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50719"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/393"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=50719"}],"version-history":[{"count":11,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50719\/revisions"}],"predecessor-version":[{"id":51098,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/50719\/revisions\/51098"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/50724"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=50719"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=50719"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=50719"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}