{"id":52186,"date":"2016-11-17T14:00:46","date_gmt":"2016-11-17T06:00:46","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=52186"},"modified":"2016-11-17T10:37:30","modified_gmt":"2016-11-17T02:37:30","slug":"nano-letters-%e7%ad%89%e7%a6%bb%e5%ad%90%e4%bd%93%e8%be%85%e5%8a%a9%e5%90%88%e6%88%90nicop%e7%94%a8%e4%ba%8e%e9%ab%98%e6%95%88%e7%9a%84%e5%85%a8%e8%a7%a3%e6%b0%b4","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=52186","title":{"rendered":"Nano Letters \u7b49\u79bb\u5b50\u4f53\u8f85\u52a9\u5408\u6210NiCoP\u7528\u4e8e\u9ad8\u6548\u7684\u5168\u89e3\u6c34"},"content":{"rendered":"

\u5f15\u8a00<\/strong><\/span><\/p>\n

\u4e3a\u5e94\u5bf9\u65e5\u76ca\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\uff0c\u6c22\u80fd\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u6e05\u6d01\u53ef\u518d\u751f\u80fd\u6e90\u3002\u7535\u89e3\u6c34\u662f\u6700\u6709\u53ef\u80fd\u7528\u4e8e\u4ea7\u751f\u6c22\u6c14\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u9ad8\u6548\u7684\u6c34\u7684\u7535\u89e3\u9700\u8981\u9ad8\u6d3b\u6027\uff0c\u5730\u7403\u5b58\u91cf\u4e30\u5bcc\uff0c\u9ad8\u7a33\u5b9a\u6027\u7684\u50ac\u5316\u5242\u3002\u5355\u91d1\u5c5e\u78f7\u5316\u7269\u5bf9\u4e8e\u6c34\u7684\u5206\u89e3\u5177\u6709\u660e\u663e\u7684\u50ac\u5316\u4f5c\u7528\uff0c\u6bd4\u5982\u78f7\u5316\u954d\u3002\u7406\u8bba\u5206\u6790\u8868\u660e\u6df7\u5408\u91d1\u5c5e\u78f7\u5316\u7269\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u4ed6\u4eec\u7684\u50ac\u5316\u6027\u80fd\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/strong><\/span><\/p>\n

\u8fd1\u671f\uff0c\u963f\u535c\u675c\u62c9\u56fd\u738b\u79d1\u6280\u5927\u5b66\uff08\u6c99\u7279\u963f\u62c9\u4f2f\uff09Husam N. Alshareef \u56e2\u961f\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528PH3<\/sub>\u7b49\u79bb\u5b50\u4f53\u8f85\u52a9\u5408\u6210NiCoP\u7684\u65b9\u6cd5\u3002\u4ed6\u4eec\u5229\u7528PH3<\/sub>\u7b49\u79bb\u5b50\u4f53\u5b9e\u73b0\u4e86NiCo-OH\u5411NiCoP\u7684\u8f6c\u53d8\uff0c NiCoP\u751f\u957f\u5728\u6ce1\u6cab\u954d\u57fa\u5e95\u4e0a\uff0c\u5bf9\u4e8e\u7535\u5316\u5b66\u6790\u6c22\uff08HER\uff09\u548c\u7535\u5316\u5b66\u6790\u6c27\uff08OER\uff09\u90fd\u6709\u5f88\u5f3a\u7684\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u5408\u6210\u591a\u91d1\u5c5e\u78f7\u5316\u7269\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u56fe\u6587\u5bfc\u8bfb<\/strong><\/span><\/p>\n

\u56fe1 \u6676\u4f53\u7ed3\u6784\u548c\u7406\u8bba\u9884\u6d4b<\/p>\n

\u00a0\"figure1\"<\/a><\/strong><\/p>\n

\uff08a,b\uff09Ni2<\/sub>P\u548cNiCoP\u7684\u6676\u4f53\u7ed3\u6784\uff1b\uff08c,d\uff09Ni2<\/sub>P\u548cNiCoP\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\uff1b<\/p>\n

\uff08e\uff09Ni2<\/sub>P\uff0cNiCoP\uff080001\uff09\u6676\u9762\uff0cPt\uff08111\uff09\u6676\u9762\u5bf9\u4e8e\u6c22\u539f\u5b50\u5438\u9644\u7684\u81ea\u7531\u80fd\u56fe\uff1b\uff08f\uff09\u6c34\u7684\u5438\u9644\u80fd\u3002<\/p>\n

\u56fe2 NiCoP\u7684\u5408\u6210\u65b9\u6cd5\u548c\u7ed3\u6784\u8868\u5f81<\/p>\n

\"figure2\"<\/a><\/p>\n

\uff08a\uff09\u901a\u8fc7\u6c34\u70ed\u6cd5\u5728\u6ce1\u6cab\u954d\u8868\u9762\u751f\u957fNiCo-OH\u7684\u7eb3\u7c73\u7247\uff0c\u7136\u540e\u5229\u7528PH3<\/sub>\u7b49\u79bb\u5b50\u4f53\u5c06NiCo-OH\u8f6c\u5316\u4e3aNiCoP\uff1b<\/p>\n

\uff08b\uff09NiCo-OH\uff0cNiCoP\u7684XRD\u56fe\uff1b\uff08c,d\uff09NiCoP\u7684SEM\u56fe\uff1b\uff08e\uff09NiCoP\u7684mapping\u56fe\uff1b<\/p>\n

\uff08f,g\uff09NiCoP\u7684\u4f4e\u500d\u548c\u653e\u5927TEM\u56fe\uff1b\uff08h\uff09NiCoP\u7684\u9009\u533a\u884d\u5c04\u56fe\uff1b\uff08i\uff09NiCoP\u7684HRTEM\u56fe\uff08\u63d2\u56fe\uff1aEDX\u56fe\uff09\u3002<\/p>\n

\u56fe3 NiCoP\u7684\u5149\u7535\u5b50\u80fd\u8c31\u56fe<\/p>\n

\"figure3\"<\/a><\/p>\n

\uff08a\uff09Ni 2p3\/2\u7684\u80fd\u8c31\u56fe\uff1b\uff08b\uff09Co 2p3\/2\u7684\u80fd\u8c31\u56fe\uff1b\uff08c\uff09P 2p\u7684\u80fd\u8c31\u56fe\uff1b<\/p>\n

\u56fe4 HER\u50ac\u5316\u6d3b\u6027<\/p>\n

\"figure4\"<\/a><\/p>\n

\uff08a\uff09HER\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf\uff1b\uff08b\uff09HER\u5bf9\u5e94\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b\uff08c\uff09\u7535\u6d41\u5bc6\u5ea6-10 mA cm-2<\/sup>\u65f6\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u5bf9\u53cc\u7535\u5c42\u7684\u5f71\u54cd\uff1b\uff08e\uff09\u6781\u5316\u66f2\u7ebf\uff1b\uff08f\uff09H2<\/sub>\u7684TOFs\u3002<\/p>\n

\u56fe5 OER\u50ac\u5316\u6d3b\u6027<\/p>\n

\"figure5\"<\/a><\/p>\n

\uff08a\uff09OER\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u66f2\u7ebf\uff1b\uff08b\uff09OER\u5bf9\u5e94\u7684\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b\uff08c\uff09\u7535\u6d41\u5bc6\u5ea6-10 mA cm-2<\/sup>\u65f6\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

\uff08d\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u5bf9\u53cc\u7535\u5c42\u7684\u5f71\u54cd\uff1b\uff08e\uff09\u6781\u5316\u66f2\u7ebf;\uff08f\uff09O2<\/sub>\u7684TOFs\u3002<\/p>\n

\u56fe6 \u7535\u50ac\u5316\u5168\u89e3\u6c34<\/p>\n

\"figure6\"<\/a><\/p>\n

\uff08a\uff09NiCoP\u4f5c\u4e3a\u9634\u6781\u548c\u9633\u6781\u5168\u89e3\u6c34\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff090.5 mV s-1<\/sup>\u626b\u901f\u65f6\u7684\u6781\u5316\u66f2\u7ebf\uff08\u63d2\u56fe\uff1a\u5168\u89e3\u6c34\u7684\u5149\u5b66\u7167\u7247\uff09<\/p>\n

\uff08c\uff09\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u3002<\/p>\n

\u5c55\u671b<\/strong><\/p>\n

\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u7684\u4f4e\u6e29\u5408\u6210NiCoP\u7684\u65b9\u6cd5\uff0c\u5408\u6210NiCoP\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5bf9\u7535\u5316\u5b66\u6790\u6c22\uff08HER\uff09\u548c\u7535\u5316\u5b66\u6790\u6c27\uff08OER\uff09\u90fd\u5177\u6709\u5f88\u597d\u7684\u50ac\u5316\u6027\u80fd\u3002\u8fd9\u79cd\u65b9\u6cd5\u4e3a\u5408\u6210\u5176\u4ed6\u53cc\u91d1\u5c5e\u78f7\u5316\u7269\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff0c\u4e3a\u63d0\u9ad8\u5176\u7535\u5316\u5b66\u50ac\u5316\u6027\u80fd\u53ca\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPlasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting<\/a>. (Nano Lett, 2016, DOI:10.1021\/acs.nanolett.6b03803<\/em>)<\/span><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 \u4e3a\u5e94\u5bf9\u65e5\u76ca\u589e\u957f\u7684\u80fd\u6e90\u9700\u6c42\uff0c\u6c22\u80fd\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6f5c\u5728\u7684\u6e05\u6d01\u53ef\u518d\u751f\u80fd\u6e90\u3002\u7535\u89e3\u6c34\u662f\u6700\u6709\u53ef\u80fd\u7528\u4e8e\u4ea7\u751f\u6c22\u6c14\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u9ad8\u6548\u7684\u6c34\u7684\u7535\u89e3\u9700\u8981\u9ad8\u6d3b\u6027\uff0c\u5730\u7403\u5b58\u91cf\u4e30\u5bcc\uff0c\u9ad8\u7a33\u5b9a\u6027\u7684…<\/p>\n","protected":false},"author":51,"featured_media":52194,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-52186","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/52186"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/51"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=52186"}],"version-history":[{"count":1,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/52186\/revisions"}],"predecessor-version":[{"id":52195,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/52186\/revisions\/52195"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/52194"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=52186"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=52186"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=52186"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}