{"id":56157,"date":"2016-12-17T06:30:45","date_gmt":"2016-12-16T22:30:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=56157"},"modified":"2017-02-06T12:35:58","modified_gmt":"2017-02-06T04:35:58","slug":"%e5%ad%a6%e6%9c%af%e5%b9%b2%e8%b4%a7%e4%b8%a8%e7%94%b1%e6%b5%85%e5%85%a5%e6%b7%b1-%e8%a7%a3%e6%9e%90%e9%94%82%e7%94%b5%e6%b1%a0%e7%94%b5%e5%8c%96%e5%ad%a6%e6%b5%8b%e9%87%8f%e6%96%b9","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=56157","title":{"rendered":"\u5b66\u672f\u5e72\u8d27\u4e28\u7531\u6d45\u5165\u6df1\u2014\u2014\u89e3\u6790\u9502\u7535\u6c60\u7535\u5316\u5b66\u6d4b\u91cf\u65b9\u6cd5"},"content":{"rendered":"

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\u5728\u4e0d\u5177\u6709\u6d41\u52a8\u76f8\u7684\u7535\u6c60\u4e2d\uff0c\u5b58\u5728\u77403\u79cd\u7c7b\u578b\u7684\u6781\u5316\uff1a<\/p>\n

1\u3001\u5316\u5b66\u6781\u5316\u2014\u2014 \u4e0e\u7535\u8377\u8f6c\u79fb\u8fc7\u7a0b\u6709\u5173\u7684\u6781\u5316\uff0c\u6781\u5316\u7684\u9a71\u52a8\u529b\u662f\u7535\u573a\u68af\u5ea6\u3002\u7535\u5316\u5b66\u6781\u5316\u7684\u5927\u5c0f\u662f\u7531\u7535\u5316\u5b66\u53cd\u5e94\u901f\u7387\u51b3\u5b9a\u7684\uff0c\u7535\u5316\u5b66\u6781\u5316\u7535\u963b(Rct<\/sub>)\u7684\u5927\u5c0f\u4e0e\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u76f4\u63a5\u76f8\u5173\u3002<\/p>\n

2\u3001\u6d53\u5dee\u6781\u5316\u2014\u2014\u4e0e\u53c2\u4e0e\u7535\u5316\u5b66\u53cd\u5e94\u7684\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u7684\u6269\u6563\u8fc7\u7a0b\u6709\u5173\u7684\u6781\u5316\uff0c\u6781\u5316\u7684\u9a71\u52a8\u529b\u4e3a\u6d53\u5ea6\u68af\u5ea6\u3002\u6d53\u5dee\u6781\u5316\u4e0e\u4f20\u8d28\u7c92\u5b50\u7684\u6269\u6563\u7cfb\u6570\u6709\u5173\u3002<\/p>\n

3\u3001\u6b27\u59c6\u6781\u5316\u2014\u2014\u4e0e\u8f7d\u6d41\u5b50\u5728\u7535\u6c60\u4e2d\u5404\u76f8\u8f93\u8fd0\u6709\u5173\u7684\u6781\u5316\uff0c\u9a71\u52a8\u529b\u662f\u7535\u573a\u68af\u5ea6\u3002\u6b27\u59c6\u6781\u5316\u7684\u5927\u5c0f\u662f\u7531\u7535\u6c60\u5185\u90e8\u6d89\u53ca\u5230\u7535\u8fc1 \u79fb\u7684\u5404\u7c7b\u7535\u963b\u4e4b\u548c\uff0c\u5373\u6b27\u59c6\u7535\u963b\u51b3\u5b9a\u7684\u3002<\/p>\n

\u82e5\u8fd8\u5b58\u5728\u5176\u5b83\u57fa\u672c\u7535\u6781\u8fc7\u7a0b\uff0c\u5982\u5300\u76f8\u6216\u591a\u76f8\u5316 \u5b66\u53cd\u5e94\u8fc7\u7a0b\uff0c\u5219\u53ef\u80fd\u5b58\u5728\u5316\u5b66\u53cd\u5e94\u6781\u5316\u3002<\/p>\n

\u7535\u5316\u5b66\u6d4b\u91cf\u65b9\u6cd5\u5728\u9502\u7535\u6c60\u4e2d\u7684\u7ecf\u5178\u5e94\u7528<\/strong><\/span><\/p>\n

\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u5728\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4e00\u822c\u7ecf\u5386\u4ee5\u4e0b\u51e0\u4e2a\u6b65\u9aa4\uff1a<\/p>\n

1\u3001\u5242\u5316\u7684\u9502\u79bb\u5b50\u4ece\u7535\u89e3\u6db2\u5185 \u8fc1\u79fb\u5230\u7535\u89e3\u6db2\/\u56fa\u4f53\u7535\u6781\u7684\u4e24\u76f8\u754c\u9762\uff1b<\/p>\n

2\u3001\u6eb6\u5242\u5316\u7684\u9502 \u79bb\u5b50\u5438\u9644\u5728\u7535\u89e3\u6db2\/\u56fa\u4f53\u7535\u6781\u7684\u4e24\u76f8\u754c\u9762\uff1b<\/p>\n

3\u3001\u53bb\u6eb6\u5242\u5316\uff1b<\/p>\n

4\u3001\u7535\u8377\u8f6c\u79fb\uff0c\u7535\u5b50\u6ce8\u5165\u7535\u6781\u6750\u6599\u7684\u5bfc\u5e26\uff0c\u5438\u9644\u6001\u7684\u9502\u79bb\u5b50\u4ece\u7535\u89e3\u6db2\u76f8\u8fc1\u79fb\u81f3\u6d3b\u6027\u6750\u6599\u8868\u9762\u6676\u683c\uff1b<\/p>\n

5\u3001\u9502\u79bb\u5b50\u4ece\u6d3b\u6027\u6750\u6599\u8868\u9762\u6676\u683c\u5411\u5185\u90e8\u6269\u6563\u6216\u8fc1\u79fb\uff1b<\/p>\n

6\u3001\u7535\u5b50\u4ece\u96c6\u6d41\u4f53\u5411\u6d3b\u6027\u6750\u6599\u7684\u8fc1\u79fb\u3002<\/p>\n

\u5faa\u73af\u4f0f\u5b89\u6cd5<\/strong><\/span><\/p>\n

\u5e38\u7528\u4e8e\u7535\u6781 \u53cd\u5e94\u7684\u53ef\u9006\u6027\u3001\u7535\u6781\u53cd\u5e94\u673a\u7406(\u5982\u4e2d\u95f4\u4f53\u3001\u76f8\u754c\u5438 \/\u8131\u9644\u3001\u65b0\u76f8\u751f\u6210\u3001\u5076\u8054\u5316\u5b66\u53cd\u5e94\u7684\u6027\u8d28\u7b49)\u53ca\u7535\u6781\u53cd\u5e94\u52a8\u529b\u5b66\u53c2\u6570(\u5982\u6269\u6563\u7cfb\u6570\u3001\u7535\u6781\u53cd\u5e94\u901f\u7387\u5e38\u6570\u7b49)\u7684\u63a2\u7a76\u3002<\/p>\n

\u7535\u52bf\u5411\u9634\u6781\u65b9\u5411\u626b\u63cf\u65f6\uff0c\u7535\u6d3b\u6027\u7269\u8d28\u5728\u7535\u6781\u4e0a\u8fd8\u539f\uff0c\u4ea7\u751f\u8fd8\u539f\u5cf0\uff1b\u5411\u9633\u6781\u65b9\u5411\u626b\u63cf\uff0c\u8fd8\u539f\u4ea7\u7269\u91cd\u65b0\u5728\u7535\u6781\u4e0a\u6c27\u5316\uff0c\u4ea7\u751f\u6c27\u5316\u5cf0\u3002\u56e0\u800c\u4e00\u6b21\u626b\u63cf\uff0c\u5b8c\u6210\u4e00\u4e2a\u8fd8\u539f\u548c\u6c27\u5316\u8fc7\u7a0b\u7684\u5faa\u73af\uff0c\u5176\u7535\u6d41\u4e00\u7535\u538b\u66f2\u7ebf\u79f0\u4e3a\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002<\/p>\n

\u901a\u8fc7\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u7684\u6c27\u5316\u5cf0\u548c\u8fd8\u539f\u5cf0\u7684\u5cf0\u9ad8\u3001\u5bf9\u79f0\u6027\u3001\u6c27\u5316\u5cf0\u4e0e\u8fd8\u539f\u5cf0\u7684\u8ddd\u79bb\uff0c\u4e2d\u70b9\u4f4d\u7f6e\uff0c\u53ef\u5224\u65ad\u7535\u6d3b\u6027\u7269\u8d28\u5728\u7535\u6781\u8868\u9762\u53cd\u5e94\u7684\u53ef\u9006\u7a0b\u5ea6\u548c\u6781\u5316\u7a0b\u5ea6\u3002\u5982\u679c\u6c27\u5316\u4e0e\u8fd8\u539f\u53cd\u5e94\u7684\u8fc7\u7535\u4f4d \u5dee\u522b\u4e0d\u5927\u7684\u5316\uff0c\u8fd8\u53ef\u4ee5\u628a\u4e00\u5bf9\u6c27\u5316\u5cf0\u4e0e\u8fd8\u539f\u5cf0\u4e4b\u95f4\u7684\u4e2d\u70b9\u503c\u8fd1\u4f3c\u4f5c\u4e3a\u8be5\u53cd\u5e94\u7684\u70ed\u529b\u5b66\u5e73\u8861\u7535\u4f4d\u503c\u3002<\/p>\n

\u53e6\u5916\u6052\u7535\u6d41\u5145\u653e\u7535\u7684\u7535\u538b\u5bb9\u91cf\u66f2\u7ebf\u5fae\u5206\u540e\u4ee5dQ\uff0fdV \u4f5c\u4e3a\u7eb5\u8f74\uff0c\u6a2a\u8f74\u4e3a\u7535\u538b\uff0c\u53ef\u4ee5\u83b7\u5f97\u4e0eCV\u66f2\u7ebf\u5341\u5206\u76f8\u4f3c\u7684\u7ed3\u679c\uff0c\u5176\u5b9e\u672c\u8d28\u5e76\u6ca1\u533a\u522b\u3002<\/p>\n

\u5faa\u73af\u4f0f\u5b89\u6cd5\u8ba1\u7b97\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570<\/span><\/p>\n

\u6ce8\u610f\uff1a\u4ec5\u9002\u7528\u4e8e\u6269\u6563\u8fc7\u7a0b\u4e3a\u63a7\u5236\u6b65\u9aa4\u4e14\u7535\u6781\u4e3a\u53ef\u9006\u4f53\u7cfb\uff0c\u6b64\u65f6\u6709\u516c\u5f0f<\/p>\n

\"1\"<\/a><\/p>\n

\u5e38\u6e29\u65f6\uff0c<\/p>\n

\"2\"<\/a><\/p>\n

\u5f0f\u4e2d\uff0cI<\/em>p<\/sub>\u4e3a\u5cf0\u7535\u6d41\u7684\u5927\u5c0f\uff0cn\u4e3a\u53c2\u4e0e\u53cd\u5e94\u7684\u7535\u5b50\u6570\uff0cA\u4e3a\u6d78\u5165\u6eb6\u6db2\u4e2d\u7684\u7535\u6781\u9762\u79ef\uff0cF\u4e3a\u6cd5\u62c9\u7b2c\u5e38\u6570\uff0cD<\/em>Li<\/sub>\u4e3aLi\u5728\u7535\u6781\u4e2d\u7684\u6269\u6563\u7cfb\u6570\uff0cv\u4e3a\u626b\u63cf\u901f\u7387\uff0c\u25b3C0<\/sub>\u4e3a\u53cd\u5e94\u524d\u540e\u5f85\u6d4b\u6d53\u5ea6\u7684\u53d8\u5316\u3002<\/p>\n

\u53ef\u4ee5\u6309\u5982\u4e0b\u6b65\u9aa4\u6765\u8ba1\u7b97\uff1a<\/p>\n

1\u3001\u6d4b\u91cf\u7535\u6781\u6750\u6599\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff1b<\/p>\n

2\u3001\u5c06\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684\u5cf0\u503c\u7535\u6d41\u5bf9\u626b\u63cf\u901f\u7387\u7684\u5e73\u65b9\u6839\u4f5c\u56fe\uff1b<\/p>\n

3\u3001\u5bf9\u5cf0\u503c\u7535\u6d41\u8fdb\u884c\u79ef\u5206\uff0c\u6d4b\u91cf\u6837\u54c1\u4e2d\u9502\u7684\u6d53\u5ea6\u53d8\u5316\uff1b<\/p>\n

4\u3001\u5c06\u76f8\u5173\u53c2\u6570\u5e26\u5165\u5f0f(2)\uff0c\u5373\u53ef\u6c42\u5f97\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\u9700\u8981\u6ce8\u610f\u7684\u662f\uff0c\u7531\u4e8e\u4ee5\u4e0b\u51e0\u4e2a\u539f\u56e0\uff0c\u5176\u6d4b\u5f97\u7684\u7edd\u5bf9\u503c\u5728\u4e0d\u540c\u6587\u732e\u4e2d\u4e0d\u5c3d\u76f8\u540c<\/p>\n

\u9700\u8981\u8be5\u53cd\u5e94\u6536\u6269\u6563\u63a7\u5236\uff0c\u800c\u4e14\u5faa\u73af\u4f0f\u5b89\u6d4b\u5230\u7684\u5316\u5b66\u6269\u6563\u7cfb\u6570\u5e76\u975e\u7535\u6781\u6750\u6599\u5185\u90e8\u672c\u5f81\u7684\u79bb\u5b50\u6269\u6563\u7cfb\u6570\uff08\u8be6\u7ec6\u5185\u5bb9\u8bf7\u89c1\u6269\u5c55\u9605\u8bfb\uff09\u3002\u8fd8\u6709\u5c31\u662f\uff0c\u5982\u679c\u662f\u591a\u5b54\u7c89\u672b\u7535\u6781\uff0c\u5176\u771f\u5b9e\u53cd\u5e94\u9762\u79ef\u8fdc\u5927\u4e8e\u7535\u6781\u51e0\u4f55\u9762\u79ef\uff0c\u4e14\u96be\u4ee5\u7cbe\u786e\u6d4b\u91cf\uff0c\u7ed9\u7ed3\u679c\u5e26\u6765\u5f88\u5927\u7684\u4e0d\u786e\u5b9a\u6027\u3002<\/p>\n

\u5f53\u7136\uff0c\u5173\u4e8e\u5faa\u73af\u4f0f\u5b89\u6cd5\u539f\u7406\u4f7f\u7528\u7b49\uff0c\u6211\u4eec\u4f1a\u53e6\u5916\u8be6\u7ec6\u4ecb\u7ecd\u3002<\/p>\n

\u4ea4\u6d41\u963b\u6297\u8c31<\/strong><\/span><\/p>\n

\u6211\u4eec\u5c06\u4ea4\u6d41\u963b\u6297\u8c31\u5355\u72ec\u8fdb\u884c\u4ecb\u7ecd\uff0c\u8be6\u60c5\u89c1\u6b64\u6587\uff1a\u5b66\u672f\u5e72\u8d27\u4e28\u5c11\u4e9b\u516c\u5f0f\u591a\u70b9\u5e94\u7528\u2014\u2014\u4ea4\u6d41\u963b\u6297\u8c31\u7684\u5feb\u6377\u6253\u5f00\u65b9\u5f0f<\/a><\/p>\n

\u6052\u7535\u6d41\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f<\/strong><\/span><\/p>\n

\u6052\u7535\u6d41\u95ee\u6b47\u6ef4\u5b9a\u6280\u672f(galvanostatic intermittent titration technique)\u7531\u5fb7\u56fd\u79d1\u5b66\u5bb6W\uff0eWeppner\u63d0\u51fa\uff0c \u57fa\u672c\u539f\u7406\u662f\u5728\u67d0\u4e00\u7279\u5b9a\u73af\u5883\u4e0b\u5bf9\u6d4b\u91cf\u4f53\u7cfb\u65bd\u52a0\u4e00\u6052 \u5b9a\u7535\u6d41\u5e76\u6301\u7eed\u4e00\u6bb5\u65f6\u95ee\u540e\u5207\u65ad\u8be5\u7535\u6d41\uff0c\u89c2\u5bdf\u65bd\u52a0\u7535\u6d41\u6bb5\u4f53\u7cfb\u7535\u4f4d\u968f\u65f6\u95f4\u7684\u53d8\u5316\u4ee5\u53ca\u5f1b\u8c6b\u540e\u8fbe\u5230\u5e73\u8861\u7684\u7535\u538b\uff0c\u901a\u8fc7\u5206\u6790\u7535\u4f4d\u968f\u65f6\u95fe\u7684\u53d8\u5316\u53ef\u4ee5\u5f97\u51fa\u7535\u6781\u8fc7 \u7a0b\u8fc7\u7535\u4f4d\u7684\u5f1b\u8c6b\u4fe1\u606f\uff0c\u8fdb\u800c\u63a8\u6d4b\u548c\u8ba1\u7b97\u53cd\u5e94\u52a8\u529b\u5b66\u4fe1\u606f\u3002<\/p>\n

\u5f53\u4f53\u7cfb\u6ee1\u8db3\u5982\u4e0b\u6761\u4ef6\u65f6\uff0c\u53ef\u4ee5\u8ba1\u7b97\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570<\/p>\n

1\u3001\u7535\u6781\u4f53\u7cfb\u4e3a\u7b49\u6e29\u7edd\u70ed\u4f53\u7cfb\uff1b<\/p>\n

2\u3001\u7535\u6781\u4f53\u7cfb\u5728\u65bd\u52a0\u7535\u6d41\u65f6\u65e0\u4f53\u79ef\u53d8\u5316\u4e0e\u76f8\u53d8\uff1b<\/p>\n

3\u3001\u7535\u6781\u54cd\u5e94\u5b8c\u5168\u7531\u79bb\u5b50\u5728\u7535\u6781\u5185\u90e8\u7684\u6269\u6563\u63a7\u5236\uff1b<\/p>\n

4\u3001\u03c4\u2264L2<\/sup>\/D\uff0cL\u4e3a\u79bb\u5b50\u6269\u6563\u957f\u5ea6\uff1b<\/p>\n

5\u3001\u7535\u6781\u6750\u6599\u7684\u7535\u5b50 \u7535\u5bfc\u8fdc\u5927\u4e8e\u79bb\u5b50\u7535\u5bfc\u7b49\u6761\u4ef6<\/p>\n

\u8ba1\u7b97\u516c\u5f0f\u5982\u4e0b\uff1a<\/p>\n

\"5\"<\/a><\/p>\n

\u5f0f\u4e2d\uff0cD<\/em>Li<\/sub>\u4e3a\u201c\u5728\u7535\u6781\u4e2d\u7684\u5316\u5b66\u6269\u6563\u7cfb\u6570\uff0cV<\/em>m<\/sub>\u4e3a\u6d3b\u6027\u7269\u8d28\u7684\u4f53\u79ef\uff0cA<\/em>\u4e3a\u6d78\u5165\u6eb6\u6db2\u4e2d\u7684\u771f\u5b9e\u7535\u6781\u9762\u79ef\uff0cF\u4e3a\u6cd5\u62c9\u7b2c\u5e38\u6570\uff0cn\u4e3a\u53c2\u4e0e\u53cd\u5e94\u7684\u7535\u5b50\u6570\u76ee\uff0cI<\/em>0<\/sub>\u4e3a\u6ef4\u5b9a\u7535\u6d41\u503c\uff0cdE<\/em>\/dx<\/em>\u4e3a\u5f00\u8def\u7535\u4f4d\u5bf9\u7535\u6781\u4e2dLi\u6d53\u5ea6\u66f2\u7ebf\u4e0a\u67d0\u6d53\u5ea6\u5904\u7684\u659c\u7387(\u5373\u5e93\u4ed1\u6ef4\u5b9a\u66f2\u7ebf)\uff0cdE<\/em>\/dt<\/em>1\/2<\/sup>\u4e3a\u6781\u5316\u7535\u538b\u5bf9\u65f6\u95f4\u5e73\u65b9\u6839\u66f2\u7ebf\u7684\u659c\u7387\u3002<\/p>\n

\u5229\u7528GITT\u65b9\u6cd5\u6d4b\u91cf\u7535\u6781\u6750\u6599\u4e2d\u7684\u9502\u5316\u5b66\u6269\u6563\u7cfb\u6570\u57fa\u672c\u8fc7\u7a0b\u5982\u4e0b\uff1a\u5728\u7535\u6c60\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684\u67d0\u4e00 \u65f6\u523b\uff0c\u65bd\u52a0\u5fae\u5c0f\u7535\u6d41\u5e76\u6052\u5b9a\u4e00\u6bb5\u65f6\u95f4\u540e\u5207\u65ad\uff1b\u8bb0\u5f55\u7535\u6d41\u5207\u65ad\u540e\u7684\u7535\u6781\u7535\u4f4d\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff1b\u505a\u51fa\u6781\u5316\u7535\u538b\u5bf9\u65f6\u95f4\u5e73\u65b9\u6839\u66f2\u7ebf\uff0c\u5373dE<\/em>\/dt<\/em>1\/2<\/sup>\u66f2\u7ebf\uff1b\u6d4b\u91cf\u5e93\u4ed1\u6ef4\u5b9a\u66f2\u7ebf\uff0c\u5373dE<\/em>\/dx<\/em>\u66f2\u7ebf\uff1b\u4ee3\u5165\u76f8\u5173\u53c2\u6570\uff0c\u5229\u7528\u516c\u5f0f\u6c42\u89e3\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\u6052\u7535\u52bf\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f<\/strong><\/span><\/p>\n

\u6052\u7535\u4f4d\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f(potentiostatic intermittent titration technique)\u662f\u901a\u8fc7\u77ac\u65f6\u6539\u53d8\u7535\u6781\u7535\u4f4d\u5e76\u6052\u5b9a \u8be5\u7535\u4f4d\u503c\uff0c\u540c\u65f6\u8bb0\u5f55\u7535\u6d41\u968f\u65f6\u95f4\u53d8\u5316\u7684\u6d4b\u91cf\u65b9\u6cd5\u3002 \u901a\u8fc7\u5206\u6790\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\u53ef\u4ee5\u5f97\u51fa\u7535\u6781\u8fc7\u7a0b\u7535\u4f4d\u5f1b\u8c6b\u4fe1\u606f\u4ee5\u53ca\u5176\u5b83\u52a8\u529b\u5b66\u4fe1\u606f\uff0c \u7c7b\u4f3c\u4e8e\u6052\u7535\u4f4d\u9636 \u8dc3\uff0c\u53ea\u662fPITT\u662f\u591a\u7535\u4f4d\u70b9\u6d4b\u91cf\u3002<\/p>\n

\u4f7f\u7528\u6052\u7535\u4f4d\u95f4\u6b47\u6ef4\u5b9a\u6280\u672f\u6d4b\u91cf\u9502\u79bb\u5b50\u5316\u5b66\u6269\u6563\u7cfb\u6570\u516c\u5f0f\u5982\u4e0b\uff1a<\/p>\n

\"3\"<\/a><\/p>\n

\u5f0f\u4e2d\uff0ci\u4e3a\u7535\u6d41\u503c\uff0ct\u4e3a\u65f6\u95f4\uff0c\u25b3Q\u4e3a\u5d4c\u5165\u7535\u6781\u7684\u7535\u91cf\uff0cD<\/em>Li<\/sub>\u4e3aLi\u5728\u7535\u6781\u4e2d\u7684\u6269\u6563\u7cfb\u6570\uff0cd\u4e3a\u6d3b\u6027\u7269\u8d28\u7684\u539a\u5ea6\u3002<\/p>\n

\u57fa\u672c\u64cd\u4f5c\u5982\u4e0b\uff1a\u4ee5\u6052\u5b9a\u7535\u4f4d\u6b65\u957f\u77ac\u95f4\u6539\u53d8\u7535 \u6781\u7535\u4f4d\uff0c\u8bb0\u5f55\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff1b\u5229\u7528\u65b9\u7a0b(8)\u505a \u51faln(i)\u4e00t\u66f2\u7ebf\uff1b\u622a\u53d6ln(i)\u4e00t\u66f2\u7ebf\u7ebf\u6027\u90e8\u5206\u7684\u6570\u636e\uff0c\u6c42\u659c\u7387\u5373\u53ef\u6c42\u51fa\u9502\u79bb\u5b50\u5316\u5b66\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\u7535\u4f4d\u5f1b\u8c6b\u6280\u672f<\/strong><\/span><\/p>\n

\u7535\u4f4d\u5f1b\u8c6b\u6280\u672f(potential relax technique)\u662f\u5728\u7535\u6c60\u4e0e\u5916\u754c\u65e0\u7269\u8d28\u548c\u80fd\u91cf\u4ea4\u6362\u7684\u6761\u4ef6\u4e0b\u7814\u7a76\u7535\u6781\u7535 \u52bf\u968f\u65f6\u95f4\u7684\u53d8\u5316\u5173\u7cfb\uff0c\u8be5\u65b9\u6cd5\u5c5e\u4e8e\u7535\u6d41\u9636\u8dc3\u6d4b\u91cf\u65b9 \u6cd5\u4e2d\u7684\u65ad\u7535\u6d41\u6cd5\uff0c\u4e0eGITT\u5b9e\u9a8c\u65b9\u6cd5\u4e00\u81f4\uff0c\u4e0d\u540c\u7684\u662f\u5206\u6790\u5f1b\u8c6b\u8fc7\u7a0b\u4e2d\u7684\u7535\u4f4d\u53d8\u5316\u3002\u8be5\u65b9\u6cd5\u6700\u65e9\u7531\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u738b\u5e86\u7b49\u8fd0\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7535\u6781\u6750\u6599\u4e2d\u7684\u79bb\u5b50\u6269\u6563\u52a8\u529b\u5b66\u7814\u7a76\u3002<\/p>\n

\u8ba1\u7b97\u516c\u5f0f\u4e3a\uff1a<\/p>\n

\"4\"<\/a><\/p>\n

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\u5177\u4f53\u6d4b\u91cf\u6b65\u9aa4\u5982\u4e0b\uff1a\u5bf9\u7535\u6c60\u9884\u5145\u653e\u7535\uff0c\u4f7f\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\u964d\u81f397\uff05\u5de6\u53f3\uff1b\u5728\u7535\u6c60\u5145\/\u653e\u7535\u5230\u4e00 \u5b9a\u7a0b\u5ea6\u65f6\uff0c\u5207\u65ad\u7535\u6d41\uff0c\u91c7\u7528CPT(chrono potentiometry technique)\u8bb0\u5f55\u7535\u538b\u968f\u65f6\u95ee\u7684\u53d8\u5316\u66f2\u7ebf\uff1b\u8fd0\u7528\u516c\u5f0f\u5bf9ln[exp(\u03c8m<\/sub>-\u03c8)xF\/RT-1]-t\u4f5c\u56fe\uff0c\u5e76\u5bf9\u540e\u534a\u90e8\u5206\u4f5c\u7ebf\u6027\u62df\u5408\uff1bln[exp(\u03c8m<\/sub>-\u03c8)xF\/RT-1]-t\u66f2\u7ebf\u8fdb\u884c\u62df\u5408\uff0c\u6c42\u89e3\u62df\u5408\u66f2\u7ebf\u659c\u7387\uff0c\u5e26\u516c\u5f0f\u5373\u53ef\u6c42\u5f97\u9502\u7684\u5316\u5b66\u6269\u6563\u7cfb\u6570\u3002<\/p>\n

\u8fd0\u7528\u7535\u4f4d\u5f1b\u8c6b\u6280\u672f\u6d4b\u91cf\u7535\u6781\u8fc7\u7a0b\u52a8\u529b\u5b66\u4fe1\u606f \u9700\u8981\u6ee1\u8db3\u4e00\u5b9a\u7684\u524d\u63d0\u6761\u4ef6\u3002\u901a\u5e38\uff0c\u9502\u79bb\u5b50\u7535\u6c60\u5728\u9996 \u5468\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f34\u968f\u7740\u4e00\u4e9b\u526f\u53cd\u5e94\uff0c\u5178\u578b\u7684\u526f\u53cd\u5e94 \u4e3aSEI\u819c\u7684\u5f62\u6210\uff0c\u4e3a\u907f\u514d\u526f\u53cd\u5e94\u7684\u53d1\u751f\u5bf9\u9502\u79bb\u5b50\u5316 \u5b66\u6269\u6563\u7cfb\u6570\u6d4b\u91cf\u6240\u5e26\u6765\u7684\u5e72\u6270\uff0c\u901a\u5e38\u7535\u6c60\u9700\u8981\u8fdb\u884c \u51e0\u4e2a\u5145\u653e\u7535\u5faa\u73af\u4e4b\u540e\u5f00\u59cb\u6d4b\u91cf\u5176\u5316\u5b66\u6269\u6563\u7cfb\u6570\u3002\u6b64 \u5916\uff0c\u7531\u4e8e\u7535\u4f4d\u5f1b\u8c6b\u662f\u4e00\u4e2a\u975e\u5e38\u7f13\u6162\u7684\u8fc7\u7a0b\uff0c\u4e00\u822c\u5728 8 h\u5de6\u53f3\uff0c\u5728\u7ecf\u8fc7\u957f\u65f6\u95f4\u7684\u5f1b\u8c6b\u540e\uff0c\u7535\u4f4d\u4ecd\u4e0d\u80fd\u8fbe\u5230\u5e73\u8861\u72b6\u6001\uff0c\u5219\u6709\u53ef\u80fd\u662f\u4eea\u5668\u6f0f\u7535\u6240\u9020\u6210\uff0c\u9700\u8981\u7279\u522b\u6ce8\u610f\u3002<\/p>\n

\u5173\u4e8e\u51e0\u79cd\u65b9\u6cd5\u7684\u5e94\u7528\u548c\u5bf9\u6bd4\uff0c\u6709\u4e00\u7bc7\u5f88\u597d\u7684\u6587\u732e\u63a8\u8350\uff1aKinetic analysis on LiFeP04<\/sub> thin films by CV\uff0cGITT\uff0cand EIS\uff0eElectrochimica Acta\uff0c 201l\uff0c56(13)\uff1a4869\u20144875<\/span><\/p>\n

\u5f3a\u70c8\u63a8\u8350\uff0c\u6269\u5c55\u9605\u8bfb\uff1a\u9502\u79bb\u5b50\u7535\u6c60\u57fa\u7840\u79d1\u5b66\u95ee\u9898\u2014\u2014\u7535\u5316\u5b66\u6d4b\u91cf\u65b9\u6cd5<\/a><\/p>\n

\u672c\u6587\u7d20\u6750\u6765\u81ea\u7f51\u7edc\uff0c\u6750\u6599\u4eba\u7f51\u7f16\u8f91\u6574\u7406\uff0c\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u5411\u5404\u5927\u56e2\u961f\u8bda\u5fc3\u7ea6\u7a3f\uff0c\u8bfe\u9898\u7ec4\u6700\u65b0\u6210\u679c\u3001\u65b9\u5411\u603b\u7ed3\u3001\u56e2\u961f\u8bbf\u8c08\u3001\u5b9e\u9a8c\u6280\u80fd\u7b49\u7686\u53ef\u6295\u7a3f\uff0c\u8bf7\u8054\u7cfb\uff1a\u90ae\u7bb1tougao@cailiaoren.com \u6216 QQ\uff1a97482208\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5728\u524d\u4e24\u671f\u4e2d\u6211\u4eec\u9646\u7eed\u4ecb\u7ecd\u4e86\u9502\u7535\u6750\u6599\u7684\u5e38\u7528\u8868\u5f81\u65b9\u5f0f\u4ee5\u53ca\u4ea4\u6d41\u963b\u6297\u8c31\u5728\u9502\u7535\u6c60\u4e2d\u7684\u5e94\u7528\uff0c\u4eca\u5929\u6211\u4eec\u4ece\u9502\u7535\u6c60\u7535\u6781\u53cd\u5e94\u51fa\u53d1\uff0c\u7531\u6d45\u5165\u6df1\u7684\u4ecb\u7ecd\u9502\u7535\u6c60\u7684\u7535\u5316\u5b66\u6d4b\u91cf\u65b9\u6cd5\u3002 \u9502\u79bb\u5b50\u7535\u6c60\u7535…<\/p>\n","protected":false},"author":51,"featured_media":56178,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-56157","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56157"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/51"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=56157"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56157\/revisions"}],"predecessor-version":[{"id":56185,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/56157\/revisions\/56185"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/56178"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=56157"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=56157"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=56157"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}